Polyester Research Articles

Optimum mechanical properties of repair mortar containing hybrid fibers using the Taguchi method and analysis of variance

In this study, a hybrid fiber containing micro steel fiber (MSF), polyester fiber (PEF) and glass fiber (GF) was employed to improve a hardened properties of repair mortar. The design of experiments for the repair mortar was based on Taguchi method and included hybrid fiber-MSF, PEF and GF- at three levels, along with additional parameters such as the binder-to-sand ratio, silica fume (SF) content, latex content and the water-to-binder ratio at different levels. The compressive strength, flexural strength, and shear bond strength were determined to study the effect of the hybrid fibres on the properties of repair mortar. The results of experimental tests were optimized through the analysis of variance (ANOVA). The findings indicated that hybridization of 1.0%MSF + 0.25%PEF + 0.25%GF as the optimal combination significantly improved the compressive strength and also enhanced the flexural and shear bond strength of the repair mortar.

Synchronously strengthening and plasticizing of unsaturated polyester resin based on styrene-maleic anhydride oligomer

To synchronously strength and plasticize unsaturated polyester resin (UPR), maleic anhydride were directly added in the unsaturated polyester resin solution and form the styrene-maleic anhydride oligomer (SMAO) without initiation. The creating SMAO cross link with UPR by curing reaction, and the prepared UPR resin exhibit higher tensile, elongation, bending strength and higher impact strength simultaneously, 0.45, 0.36, 0.76 and 0.12 times than UPR matrix, SMAO-UPR exhibits obvious plastic fracture characteristics; The DSC result indicates that the curing degree of SMAO-UPR is 96.55% which is 1.45% lower than that of UPR; The TG result indicates that MA and St mainly form an alternating copolymer below 90°C. The SEM and DMA result indicates that SMAO improves the morphology and structure which shows plastic deformation of UPR, and there is a certain interface effect between SMAO and UPR. Compared with the traditional method of large molecular weight SMA modified UPR, this method of reinforcing UPR is better for mechanical property, easy to operate, inexpensive, and highly applicable in industrial production.

Study on the impact of water absorption processes on the application of wood waste in composite material production

The issue of recycling and reusing waste from the wood processing industry has garnered significant attention from researchers, as effective solutions could yield economic benefits while mitigating environmental impacts. This article focuses on the development of artificial wood using unsaturated polyester resin combined with waste materials from carpentry workshops, specifically investigating its water absorption properties. Research findings indicate that the water absorption coefficient of the samples increased with longer immersion times, higher organic filler content, and larger particle diameters. The calculated density reveals a broad spectrum of solid industrial boards that can be produced from these compositions, suggesting that consistent forming conditions enhance economic viability. Notably, optimal results were achieved with samples made from mixed wood powder without prior sorting, which contributes to reduced production costs, aligning with the study's objectives. Furthermore, the investigation highlighted that the water absorption coefficient escalates with increased soaking time, organic filler content, and particle size, indicating that in humid environments, it is advisable to limit both filler content and particle size to maintain performance. Overall, the studies confirm the feasibility of utilizing wood powder as a filler, with varying particle diameters imparting distinct characteristics to the final product. These findings underscore the potential for innovative approaches to wood waste management in the industry.

Micro- and mesoplastic pollution in the surface water and nekton from the Eastern Indian Ocean: Spatiotemporal variation, correlation and risk assessment.

The pollution of micro- and mesoplastic (MMP) in the Eastern Indian Ocean (EIO) remains poorly understood. The present study revealed that MMP abundance in nekton from EIO in 2022 (mean: 2.30 ± 0.39 items individual-1 and 1.81 ± 0.54 items g-1) was significantly higher than that in 2021 (mean: 1.60 ± 0.22 items individual-1 and 0.80 ± 0.13 items g-1). In contrast, MMP abundance in surface water varied insignificantly between 2021 (mean: 0.04 ± 0.01 items m-3) and 2022 (mean: 0.05 ± 0.02 items m-3). The rise in predominant polymers-polypropylene (PP), rayon (RA), and polyester (PES)-in nekton from 2021 to 2022 may suggest increased pollution from face masks and home textiles along coastal regions. Notable spatial variation in PP and RA between the northeastern and southeastern regions was observed only in nekton, suggesting they are better indicators of MMP spatiotemporal variation than surface water. Shadow driftfish ingested more MMPs than purpleback flying squid and mackerel scad, likely due to its deeper habitat. By simultaneously considering color, composition, and shape, integrated MMP analysis showed insignificant correlation between MMP pollution in surface water and nekton, suggesting that nekton may ingest MMPs through multiple pathways beyond surface water. Risk indices for surface water and nekton reached moderate to upper levels globally, emphasizing the need for continued monitoring in the EIO. Epoxy resin, rubber, and PP + acrylic were identified as the most hazardous polymers, providing a valuable basis for developing effective strategies to mitigate plastic pollution.

The effect of single walled carbon nanotubes on conductivity and thermal properties of glass fiber reinforced composites

Abstract This paper reports on a comprehensive study of the effect of single-walled carbon nanotube (SWCNT) on the alternating current (AC) conductivity, thermal and morphological properties of the unsaturated polyester based glass fiber reinforced polymer composite (GFRPC). AC conductivity measurements were carried out using the impedance spectrum and thermal measurements were carried out using differential scanning calorimetry (DSC) at a temperature range of 24-900 °C and heating rates of 20 °C/min. Impedance results showed that the conductivity behavior in the nanotube-loaded composite laminate obeys a Jonscher-type mechanism. At low frequencies, the conductivity value remains almost constant for the doped material and takes the value of 10-5 S/cm. It is observed that the AC conductivity starts to increase after the critical frequency value of approximately 103 Hz and increases up to 10-2 S/cm due to hopping and tunneling mechanisms caused by space charge polarization accumulated in the local regions at high frequencies. The pure material with an insulating nature also exhibited a typical insulating behavior. Thermal testing showed that nanotube reinforcement increases thermal conductivity in three different directions. DSC thermocurves analysis also revealed that the addition of carbon nanotubes increased the glass transition temperature of the material from 180°C to 190°C. The scaling and fractal analysis methods were also applied to obtain hetero morphological structure of materials. The fractal analysis results indicated that carbon nanotube doping to the standard sample increases the coating rates, scalability and heterogeneity of the solid phase surface of the sample. The coating rates of composite surfaces were calculated as 45% and 36%, respectively. Morphology analysis revealed that the probability of finding surface particles for the nanotube-doped sample decreased compared to the undoped sample, but the fractal dimension value increased. While this value was 1.83 in the pure sample, it increased to 1.92 in the nanotube material.

Comprehensive Approach to Evaluating the Macro- and Micropore Structures of Textile Materials

Introduction. The assessment of the macro- and microporous structure of textile fabrics is increasingly relevant for predicting their permeability, dyeability, and decorative potential. This evaluation plays a crucial role in determining the hygienic properties of clothing materials, optimizing dyeing and finishing processes, and assessing the filtration capabilities of technical fabrics in various dispersed media.Problem Statement. Challenges persist in accurately predicting the permeability of textile fabrics, as well as in determining the optimal parameters for dyeing and finishing processes.Purpose. The purpose of this research is developing a rapid, cost-effective, and accurate method to evaluate the macro- and microporous structure of textile materials is essential for assessing their permeability and suitability for dyeing and fi nishing processes.Materials and Methods. To study the porous structure of textile fabrics, we select the fabrics that varied in the thread structure — yarn produced by traditional and shortened methods — and in the fibrous composition. The first fabric is made from complex polyamide threads in a plain weave, the second from twill-woven polyester fiber yarn, and the third differs from the second in the structure of the weft thread. The macro- and microporous structures of these textile fabrics have been assessed by means of drying methods and sorption thermograms.Results. The micro- and macroporous structures of textile fabrics made from polyamide threads and polyester fibers have been compared. It has been found that the fabric made from polyamide threads exhibits a significantly higher sorption capacity than the fabric made from polyester fibers. This finding suggests that the fabrics made from polyamide threads possess a more developed microporous structure. This fact enhances their dyeing and decorating capabilities as compared with the fabrics made from polyester fibers. A comprehensive approach, utilizing both drying methods and sorption thermograms, has been employed to evaluate the macro- and microporous structures of the textile fabrics. Conclusions. The proposed comprehensive approach enables comparative studies of various textile materials, allowing for the refinement of technological processes for dyeing and decorating, as well as the identification of potential applications for these materials.

Matching combination of amorphous ionic hydrogel with elastic fabric enables integrated properties for wearable sensing

The combination of hydrogels and fabrics opens up significant opportunities for flexible materials, particularly in biomedicine and wearable technology. However, the weak interface caused by insufficient interactions between the different phases and the substantial modulus mismatch limit their broader application. In this research, flexible and amorphous polyvinyl alcohol (PVA) hydrogels were integrated with polar and elastic fabrics to create multifunctional composites via in-situ freeze-thawing technology. First, by incorporating antifreeze inorganic salts into the precursor solution, we effectively suppressed ice crystal growth during the cooling process, promoting a uniform and loosely aligned PVA chain structure. This led to the formation of an amorphous crosslinked network while simultaneously releasing free hydroxyl groups. These hydroxyl groups facilitate the formation of robust interfaces within the composite. In addition, an elastic fabric composed of a polyester-polyurethane fiber blend was selected. The polyester fibers, rich in carbonyl groups along their polymer chains, form strong hydrogen bonds with the free hydroxyl groups from the PVA hydrogel, creating a highly resilient interface. The polyurethane fibers contribute to a lower Young's modulus, as well as excellent elasticity and ductility, reducing the fabric's inherent stiffness and mitigating fiber pull-out failure. Further, the incorporation of CaCl2 not only created an environment rich in free ions, but also provided the amorphous structure with increasing spacing between adjacent polymer chains, facilitating the transportation of ions. Therefore, the composite exhibits adept sensing capabilities for intricate human body movements, fostering auspicious prospects in smart sensor applications.

Non-standard adhesives for wood-based composites: powder adhesives and bicomponent fibers

Powder adhesives and bicomponent fibres are widely used for composite manufacturing; mainly, they are used for glueing fibres during non-woven production. However, in the woodworking industry, they are rarely used. This study aims to investigate the possibility of powder adhesive and bicomponent fibres utilisation for gluing wood. For this purpose, epoxy-polyester powder adhesive and polyester (PES) bicomponent fibres were selected, and one-component moisture-curing polyurethane adhesive was used as a reference. The selected wood species were spruce, beech, oak and wenge. The differences between powder adhesive- and bicomponent fibre-glued wood joints were observed using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDX). Mechanical properties of glued wood joints were characterised by tensile shear strength and modelled using finite element modelling (FEM). The adhesives were further characterised using Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The wood joints produced by all combinations of selected wood species and adhesives were comprehensively characterised. The highest values of tensile shear strength were reached by powder epoxy-polyester adhesive (14.85 MPa), whereas joints bonded by bicomponent fibres (5.19 MPa) reached lower values than reference samples.

Magnetic Effects in Textile Fibers Filled with Nanoconstituents Based on Iron Oxides

ABSTRACT The paper proves the possibility of providing magnetic properties in the process of saturation of textile fibers with a nanomixture of divalent and trivalent iron oxides. The mechanisms of interaction of nanostructures with natural and synthetic fibers are analyzed. The peculiarities of the introduction of magnetic components into flax, cotton, polyamide, and polyester fibers are determined. The relative number of particles with nanoscale in the total was statistically proved. To evaluate the macro effects of saturation, the relative amount of the accumulated mixture of divalent and trivalent iron oxides was determined, taking into account the previous fiber weight. Two basic constants characterizing the properties of textile fibers to magnetic interaction are proposed. It is proved that flax fibers exhibit the highest magnetic efficiency. The average size of iron oxide nanoparticles is 80–90 nanometers, which is confirmed by studies using electron microscopy. The final magnetization of the obtained textile materials provides an attractive magnetization of 20–30 mPascal. The magnetic field of magnetic textile fibers acts at a height of up to 6–7 mm. The directions of the use of fibers with magnetic properties are shown as a prospect for the development of textile smart products.

Are Biobased Microfibers Less Harmful than Conventional Plastic Microfibers: Evidence from Earthworms.

Biobased plastics are sometimes promoted as "environmentally friendly" compared to their conventional petrochemical-based counterparts, but their ecotoxicity is only partially understood. Biobased fibers are widely used in clothing and wet wipes and can accumulate in soils through the application of biosolid fertilizers. This study examined the lethal thresholds and sublethal toxicity of chemically characterized, additive-free, biobased (viscose and lyocell) compared to petrochemical-based (polyester) fibers on the key ecosystem engineer, Esenia fetida. Viscose and lyocell had LC20 values of 14.00 and 22.66 mg·L-1, respectively, and no observed effect concentrations (NOEC) of 0-2.8 mg·L-1 (72 h, OECD TG207 filter paper method), while for polyester these were LC20 15.6-31.3 mg·L-1 and NOEC 0-15.6 mg·L-1. Following 28 days of exposure to soils (OECD TG222) contaminated with environmentally relevant concentrations (100 mg kg-1), viscose significantly reduced the mass of progeny compared to polyester. Earthworms exposed to lyocell had a marginal growth reduction (-18%; compared to -11% to -13% in other treatments) linked to increased bioturbation activity. The biobased fibers examined here have greater acute toxicity at high concentrations and broadly similar sublethal effects on E. fetida compared to polyester. Our study highlights the importance of detailed testing before advocating specific materials as plastic alternatives/substitutes to conventional plastics.

Enhanced steam-sanitizer strategies for eliminating Listeria biofilms on food-contact surfaces

Food processing equipment contaminated with Listeria monocytogenes is a major cause of listeriosis outbreaks implicated in various fresh produce, highlighting the need for effective surface sanitization strategies to eliminate this pathogen from food-contact surfaces. This study evaluated the effectiveness of steam treatments at temperatures ranging from 100 - 142 °C, with or without chemical sanitizers, against L. innocua (a surrogate for L. monocytogenes) biofilms on stainless steel (SS), polyester (PET), and rubber surfaces. Seven-day-old L. innocua biofilms on these surfaces were subjected to short-time steam treatments at 100, 125, and 142 °C, either alone or in combination with 10 ppm peroxyacetic acid (PAA) or quaternary ammonium compound (QAC). Culturable L. innocua cells were then detached and enumerated. Results showed that steam treatments exhibited quick killing efficacy during the come-up time (CUT, 8-12 s), regardless of steam temperatures or surface materials. For example, steam CUT at 100 - 142 °C led to reductions of culturable L. innocua of 3.0 - 4.2 log10 CFU/coupon on SS, 2.5 - 2.9 log10 CFU/coupon on PET, and 2.4 - 2.8 log10 CFU/coupon on rubber, respectively. However, killing rates decreased beyond CUT and at extended steam exposure, with more pronounced survival tails on PET and rubber compared to SS. To enhance the eradication of L. innocua biofilms, PAA or QAC at 10 ppm was applied for 1 min, followed by a short (CUT + 6 s) steam treatment at 125 °C, which resulted in ≥ 4.9 log10 CFU/coupon reductions of culturable L. innocua on all surfaces. Rubber surfaces showed the greatest resistance to these hurdle treatments compared to SS and PET. The findings from this study provide effective surface sanitization strategies for the food industry to control L. monocytogenes in processing facilities.

A recyclable, toughening, extreme-condition resistant flame retardant for unsaturated polyester: Bridging performance and sustainability

Recycling thermosets presents significant economic benefits and social implications, and to date, a series of controllable recycling strategies have been proposed. However, prior research has primarily focused on neat polymers, neglecting the impact of the recycling process on composites whose additives may lose performance post-recycling. The paradigm shift towards sustainability necessitates the development of additives that not only exhibit high performance but also endure recycling conditions. Herein, taking flame-retardant unsaturated polyester (FRUP) as an example, we designed a new flame retardant (DPPONSi) with multiple flame-retardant elements and a low phosphorous oxidation state. FRUP with 16.7 wt% of DPPONSi achieves a V-0 rating in the UL-94 vertical burning test, and its limiting oxygen index (LOI) reaches 27.1%. Moreover, its peak heat release rate and total heat release are distinctively reduced by 65% and 42%, respectively. The high flame-retardant efficiency structure also protected DPPONSi from by-reactions. Without complex separation processes, FRUP degradation products were integrated with polyvinyl alcohol (PVA) to create flame-retardant aerogels with high flame retardancy. Additionally, we systematically studied the influence of flame retardants with varying oxidation states on FRUP, the corresponding flame-retardant mechanisms, and the degradation process of FRUP. This work realizes the organic combination of strategies to enhance the high efficiency of flame retardants with design methods for flame retardants that are resistant to existing unsaturated polyester degradation systems.

Simple enzymatic depolymerization process based on rapid ball milling pretreatment for high-crystalline polyethylene terephthalate fibers

The high crystallinity (30 %–50 %) of discarded polyester textile waste limits the industrialization of its clean enzymatic depolymerization. In this study, a simple process based on ball milling pretreatment was developed to achieve effective enzymatic hydrolysis of high-crystalline polyester fiber. Ball milling was selected for its short, mild, and chemical-free process, which achieved a remarkable 23.8-fold (60.9 %) increase in terephthalic acid (TPA) yield from waste polyethylene terephthalate (PET) degradation, along with high TPA purity in the released soluble compounds. Just 30 min of ball milling at room temperature induced polyester amorphization, resulting in polyester with 12 % lower crystallinity compared with untreated polyester (51 %), while simultaneously increasing the surface roughness of polyester, thereby enhancing the efficiency of enzymatic hydrolysis. The simple process for effective enzymatic-depolymerization of waste polyester fiber developed in this study has potential industrial applications

Distribution of disperse dyes between supercritical CO2 and polyester fibers: A combined molecular dynamics simulation and experimental study

Distribution of disperse dyes between supercritical CO2 and polyester fibers: A combined molecular dynamics simulation and experimental study

Advanced Machine Learning and Experimental Studies of Polypropylene Based Polyesters Tribological Composite Systems for Sustainable Recycling Automation and Digitalization

Digitalization and automation are emerging solutions to the complex problems of recycling. In this research work, the experimental and Python based Archard deep learning wear rate models are introduced regarding recycling automation and composite tribological systems optimization. The optimum polyester fibers (PESF) of length of 3-3.5 mm were used for fabrication of polypropylene (PP)-PESF composite systems. The deformation, high texture, asperities, and micro-cracks were observed during scanning electron microscope and machine-learning studies. The lowest experimental value of abrasive wear of 3.0 × 10-6 mm3/Nm was observed for PP. Comparatively, higher experimental values of abrasive wear of the PP-PESF composites are found in the range of 4.35 × 10-6 to 4.7 × 10-6 mm3/Nm due to presence micro-defects on the surface of composites. The experimental values of Coefficient of friction (COF) of PP and PP-PESF are found in the range of 0.70 - 0.8 and 1.1 - 1.3, respectively. The experimental values of abrasive wear and COF are found compatible with literature. Similarly, the simulated values of abrasive wear of PP and PP-PESF composites are predicted in the range of 4.8×10-7 to 3.75×10-7 mm3/Nm, respectively. The predicted values of PP and PP-PESF composite show better resistance towards abrasive wear. The proposed experimental and simulated (in terms of Python coding, machine learning, image processing, artificial intelligence, and deep learning studies) research work can be introduced industrially for automation as well as digitalization of grinding of PES waste, processing, tribological testing, and SEM characterization evaluations.

In-situ generated SiO2 nanoparticles for heat release reduction and smoke suppression in unsaturated polyester composites

In-situ generated SiO2 nanoparticles for heat release reduction and smoke suppression in unsaturated polyester composites

Thermal and mechanical properties of high-performance polyester nanobiocomposites reinforced with pre-treated sunn hemp fiber for automotive applications

The objective of this study is to create high-performance nano biocomposites by utilizing unsaturated polyester resin (PE) reinforced with pre-treated short (2 cm) lengthened sunn hemp (SH) fibers and by incorporating 5 % nanoclay (hydrophilic bentonite) through the compression molding technique. The addition of 5 % nanoclay to the biocomposite significantly increased the flexural strength by approximately 165 % for H2O2-treated SH fiber and 148 % for KMnO4-treated SH fiber, when compared to untreated fibers. This enhancement was achieved through phase separation, intercalation, and exfoliation between the SH fibers, polyester resin (PE), and 5 % nanoclay. In particular, the H2O2-treated SH fiber nanobiocomposite exhibited a 43 % higher flexural strength compared to its corresponding biocomposite. The incorporation of nanoclay significantly decreased the water absorption of the bio-composites from 11.86 % in the untreated samples to a minimum of 2.76 % in the H2O2-treated SH/PE nanobiocomposite. The study suggests that short SH fiber/PE/nanoclay nanobiocomposites could be used as effective alternatives to synthetic composites in various applications, including the aerospace industry, household products, and automotive interior components such as side panels, seat frames, and central consoles. Additionally, they could be utilized in exterior parts like door panels and dashboards.

Insights into the curing and thermal behavior of orthophtalic unsaturated polyester resin with organically modified montmorillonite nanoclay

Insights into the curing and thermal behavior of orthophtalic unsaturated polyester resin with organically modified montmorillonite nanoclay

Autoclaved aerated concrete reinforced by polymeric pins

Autoclaved Aerated Concrete (AAC) is a lightweight and sustainable building material known for its thermal insulation and acoustic properties. However, its relatively low mechanical strength limits its use in load-bearing applications. This paper introduces the concept of incorporating unsaturated polyester resin (UPR) pins into AAC blocks to improve compressive and flexural strength of the material. Pin diameters of 4, 6, 8 and 10 mm were studied, oriented at 90° and 45° in relation to the AAC main plane. The effects of the UPR/AAC interface were analyzed through microscopy. The results point to a substantial increase in mechanical strength of the reinforced AAC, wherein smaller pins with orientation of 45° and 90° presented the best behavior under flexural (up to 298%) and compressive loading (up to 183%), respectively.

Study on Mechanical Properties of Basalt Fiber and its Composite Materials

With the development of civil engineering industry, the use of new composite materials has become an inevitable trend. This paper mainly focuses on the mechanical properties and development status of Basalt Fiber (BF) and its fiber composites which is called Basalt Fiber Reinforced Polymer (BFRP). The raw material of BFRP, the basalt ore and the preparation of blast furnace are discussed. Then, the preparation method of BFRP is introduced. In the process of research, it is found that when the preparation of BFRP is completed, the types of BFRP can be roughly divided into mixed reinforcement type and basic profile type. Subsequently, the factors affecting the mechanical properties of blast furnace are studied, which are mainly divided into interface modification and interface aging. In the aspect of interface modification, four modification methods such as acid-base etching modification, plasma surface treatment, silane coupling agent treatment and nanoparticle modification are introduced in detail. Finally, comparing BF with carbon fiber (CF), polyester fiber (PF) and glass fiber (GF), it is found that BF has better plasticity, toughness, good electrical insulation and low thermal conductivity. However, there are still many difficulties to be solved in the production, preparation, modification and application of BF and BFRP