Water-soluble ions are an important component of atmospheric particles. However, there has been limited research on water-soluble inorganic ions in atmospheric particulates in agricultural areas until now. In this study, the characteristics of eight water-soluble inorganic ions (Na+, NH4+, K+, Mg2+, Ca2+, NO3-, SO42-, and Cl-) in different sizes of atmospheric particulates (>9.0, 5.8-9.0, 4.7-5.8, 3.3-4.7, 2.1-3.3, 1.1-2.1, 0.65-1.1, 0.43-0.65, and <0.43 μm) were analyzed by sampling farmland in the suburb of Nanjing from December 2020 to November 2021. The results showed that the annual mass concentrations of total suspended particulate matter (TSP), < 9.0 μm and < 2.1 μm particulates were 54.73, 49.04, and 27.35 μg·m-3, respectively, all of which reached the national secondary standards. The mass concentration of < 2.1 μm particulates accounted for 50.0% of TSP, indicating that fine particles were the main components of atmospheric particulates in this area. The concentration of water-soluble inorganic ions in different sizes of particulates was highest in autumn, followed by those in spring/summer and winter. SO42- was the primary contributor among all seasons and particle sizes, accounting for 30.6%-66.5%. The ratio of SO42-/NO3- was much higher than 1, indicating that the contribution of fixed-source pollution played a dominant role in the study area. Moreover, SOR (SO2 gas-particle conversion rate) in different particle sizes was less than 0.1 only at individual times in winter, indicating that SO42- was mainly derived from the secondary oxidation of SO2 in the study area. Significant positive correlations (P < 0.05) between SOR and temperature were observed except for 4.7-5.8 μm particulates, indicating that the increase in temperature significantly promoted the photochemical formation process of SO42- in particles with different sizes. However, the relationship between SOR and relative humidity was significant only in fine particulates smaller than 2.1 μm (P < 0.05), indicating that the liquid phase reaction was an important pathway for the formation of SO42- in fine particles. Principal component analysis was used to analyze the sources of water-soluble inorganic ions in particulates. Moreover, it showed that water-soluble inorganic ions in fine particulates mainly came from the secondary transformation of SO2, while those in the coarse particles mainly came from the soil dust during farmland tillage. The results of this study are of great significance for understanding the characteristics of water-soluble inorganic ion pollution in atmospheric particulate matter in agricultural areas. They provide a reference for understanding the source and formation mechanisms of atmospheric particulate matter pollution in agricultural areas near Nanjing.
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