Pollutant Emission Characteristics Research Articles

Characteristics of Fuel-Borne Nitrogen Pollutants in Hydrogen-Ammonia Mixtures Using Argon-Oxygen Atmosphere Under Engine Conditions

Abstract Amid climate change, reducing reliance on fossil fuels and transitioning to renewable energy sources is crucial. Ammonia, a carbon-free and renewable fuel, shows significant potential as an alternative energy source. By incorporating hydrogen as an additive, its flammability can be enhanced to suit existing spark ignition engines. However, understanding the characteristics of nitrogen pollutant emissions (i.e., NOx, which includes NO and NO2, and N2O) from ammonia-hydrogen combustion is challenging due to contributions from both fuel-borne and air-borne nitrogen. However, understanding the characteristics of nitrogen pollutant emissions from ammonia-hydrogen combustion is challenging due to contributions from both fuel-borne and air-borne nitrogen. Therefore, a comprehensive understanding of fuel-borne nitrogen pollutants during ammonia-hydrogen combustion is essential. This study focuses on investigating fuel-borne nitrogen pollutants in an argon-oxygen atmosphere, thereby eliminating nitrogen from the oxidizer and its role in thermal NOx formation. The research examines the formation and evolution of fuel-borne nitrogen pollutants during ammonia-hydrogen combustion under engine-like conditions. Results indicate that fuel-borne nitrogen pollutants act as intermediates, potentially originating from chemical equilibrium. While fuel NO predominantly forms in the burning zone, it undergoes reduction in the burned zone. N2O, absent in thermal NOx mechanisms, shows significant concentrations in the burning zone and is mostly converted to N2, leading to limited N2O in the final fuel-borne nitrogen pollutant concentration. Lean burn conditions, hydrogen addition, and oxyfuel combustion promote fuel NOx formation. Additionally, the equivalence ratio affects the ammonia-hydrogen premixed flame structure due to the de-NOx effect of ammonia. Overall, these findings highlight that fuel-borne nitrogen pollutant mechanisms differ from thermal NOx mechanisms, necessitating specially designed reduction technologies for clean spark ignition engines.

Flame propagation, explosion hazard, and pollutant emission characterization of typical clean fuels leaks in plateau low-pressure region

To accelerate energy transformation and sustainable development, various countries are rushing to lay hydrogen doped natural gas pipelines. However, the installation of pipelines will pass through plateau low-pressure region, and the impact of low-pressure environments on the flame propagation, explosion hazards, and pollutant emission characteristics of hydrogen doped natural gas is not yet clear. To solve this problem, a combination of constant volume combustion experiment and numerical simulations is used. The characterization parameters of flame, explosion and pollutant concentration of natural gas/H2/air under low-pressure environment are obtained, and their chemical reaction kinetics are analyzed. When the pressure drops, the laminar burning velocity (LBV) of them increases, and the Lewis number (Le) gradually increases by more than 1. Thermal diffusion is stronger than mass diffusion, and the growth rate of flame thickness exceeds 26 %. The effect of hydrodynamic instability enhances, causing an increment in the average size of flame cells, the critical instability radius, and the Markstein length (Lu). At the equivalent ratio (φ) of 1, there is a change from negative to positive in the Lu, and flame stability continuously strengthens. The explosion overpressure is reduced by 78 % to 90 %, the explosion temperature by 16 % to 20 %. As the φ increases, the LBV exhibits an inverted U-shaped relationship, reaching its maximum value near “φ = 1″. The flame stability first weakens and then strengthens. The explosion hazard is strongest in the range of ”φ = 1–1.2″. With a decrease in pressure, the total reaction rate of fuel consumption is reduced by more than 50 %. The continuous reaction distance is extended by 12 %. Changes in pressure have a relatively weak impact on the content of CO and CO2. The increase in the φ results in an increase in CO content of over 7 %. The content of CO2 reaches its maximum value around “φ = 1″. It is an essential reference for the safe delivery of hydrogen energy and the reduction of environmental pollution.

Trends in Emissions from Road Traffic in Rapidly Urbanizing Areas

The process of urbanization has facilitated the exponential growth in demand for road traffic, consequently leading to substantial emissions of CO2 and pollutants. However, with the development of urbanization and the expansion of the road network, the distribution and emission characteristics of CO2 and pollutant emissions are still unclear. In this study, a bottom-up approach was initially employed to develop high-resolution emission inventories for CO2 and pollutant emissions (NOx, CO, and HC) from primary, secondary, trunk, and tertiary roads in rapidly urbanizing regions of China based on localized emission factor data. Subsequently, the standard road length method was utilized to analyze the spatiotemporal distribution of CO2 emissions and pollutant emissions across different road networks while exploring their spatiotemporal heterogeneity. Finally, the influence of elevation and surface vegetation cover on traffic-related CO2 and pollutant emissions was taken into consideration. The results indicated that CO2, CO, HC, and NOx emissions increased significantly in 2020 compared to those in 2017 on trunk roads, and the distribution of CO2 and pollutant emissions in Fuzhou was uneven; in 2017, areas of high emissions were predominantly concentrated in the central regions with low vegetation coverage levels and low topography but expanded significantly in 2020. This study enhances our comprehension of the spatiotemporal variations in carbon and pollutant emissions resulting from regional road network expansion, offering valuable insights and case studies for regions worldwide undergoing similar infrastructure development.

Emission Rate Estimation of Industrial Air Pollutant Emissions Based on Mobile Observation

Mobile observation has been widely used in the monitoring of air pollution. However, studies on pollution sources and emission characteristics based on mobile navigational observation are rarely reported in the literature. A method for quantitative source analysis for industrial air pollutant emissions based on mobile observations is introduced in this paper. NOx pollution identified in mobile observations is used as an example of the development of the method. A dispersion modeling scheme that fine-tuned the meteorological parameters according to the actual meteorological conditions was adopted to minimize the impact of uncertainties in meteorological conditions on the accuracy of small-scale dispersion modeling. The matching degree between simulated and observed concentrations was effectively improved through this optimization search. In response to the efficiency requirements of source resolution for multiple sources, a random search algorithm was first used to generate candidate solution samples, and then the solution samples were evaluated and optimized. Meanwhile, the new index Smatch was established to evaluate the quality of candidate samples, considering both numerical error and spatial distribution error of concentration, in order to address the non-uniqueness of the solution in the multi-source problem. Then, the necessity of considering the spatial distribution error of concentration is analyzed with the case study. The average values of NOx emission rates for the two study cases were calculated as 69.8 g/s and 70.8 g/s. The Smatch scores were 0.92–0.97 and 0.92–0.99. The results were close to the online monitoring data, and this kind of pollutant emission monitoring based on the mobile observation experiment was initially considered feasible. Additional analysis and clarifications were provided in the discussion section on the impact of uncertainties in meteorological conditions, the establishment of a priori emission inventories, and the interpretation of inverse calculation results.

Prediction of pollutant emission characteristics in ISO50001 energy management in the Americas: Uni and multivariate machine learning approach

The American continent is experiencing significant economic and industrial development driven by sustainability principles. In this context, discussions on improving energy consumption have become increasingly frequent and dynamic across various sectors of civil society, including the implementation of energy efficiency measures as advocated by the ISO50001 energy management standard. However, there is a pressing need to investigate which socioeconomic aspects are responsible for the issuance of this certification in the Americas and how these factors relate to characteristic industrial emissions, especially particulate matter. This study aims to evaluate the socioeconomic factors influencing ISO50001 standard issuance and how these adjusted factors correlate with particulate matter of 2.5 μm and 10 μm dimensions. To achieve this, machine learning techniques were employed, considering the complex nature and risk of data overfitting. Model fitting was performed through multiple lasso regression, and the relationship between the adjusted factors was examined through cross-correlation analysis. The analyses indicate a strong correlation of adjusted macroeconomic indicators, especially with PM2.5, suggesting an association with cardiorespiratory problems and methane-related origins. This work is of great relevance to academia as it proposes new concepts regarding the interaction between energy efficiency standards and particulate matter. For the industrial sector, the adjusted factors provide guidance for standard implementation while also helping to mitigate health issues. Additionally, for the government, these results can assist in formulating policies to address specific health problems related to this area.

Simulation Studies of Pollutant Emission from Passenger Cars

<div>The article presents the results of simulation studies of pollutant emissions from passenger cars. The characteristics of emissions were determined using the vehicle driving test procedures, in consideration of differentiated average velocities as well as model traffic conditions: urban traffic jam, urban traffic with no congestion, rural, motorways, and highways. This article also presented the possibility of determining the characteristics of pollutant emission based on a singular realization of the vehicle velocities processes, as well as the intensity of pollutant emission, with the use of the Monte Carlo method. The pollutant emission characteristics enable specification of pollutant emission intensity, which can be used for the inventory of pollutant emissions from road transport (COPERT software applied as standard) and can be useful in the assessment of a degree of environmental hazard by modeling pollutant dispersion. In this article, the results related to pollutant emission characteristics were obtained with the use of the software HBEFA INFRAS AG for the cumulative category of passenger cars, in terms of their representative structure in Europe in 2020. The simulation driving tests were carried out separately for cars with spark ignition engines and for those with compression ignition engines. It was concluded that using specialized software to simulate emissions from road vehicles is an effective way to determine the characteristics of emissions from road transport.</div>

Co-combustion of municipal sewage sludge and food wastes-derived anerobic digestates: Combustion characteristics, HCl/NO/SO2 emission and ash behaviors

Co-combustion of sewage sludge (SS) and food wastes-derived anerobic digestate (AD) is a promising way of waste-to-energy. Therefore, it is crucial to examine their combustion performance, ash behaviors, and gaseous pollutants emissions during the combustion of AD-SS blends using a thermogravimetric analyzer and a tube furnace combustion system. Results show that obvious interactions between AD and SS are observed in their co-combustion process. In terms of comprehensive combustion index, co-combustion can improve their combustion performance with the decrement of burnout temperature and enhanced combustion reactivity. Higher blending ratio of AD favors the increment of their ash fusion temperature, i.e., from 1109 to 1403 °C for deformation temperature due to the formation of high melting point minerals (i.e., Ca9Fe(PO4)7, 2CaO·Al2O3·SiO2). Significant in-situ reduction of NO and HCl as well as self-desulfurization is observed during the combustion of AD-SS blends. Compared to the theoretical values, the emission amount of HCl, NO, and SO2 is reduced by 0.13, 1.39, and 0.35 mg·g−1, respectively at 850 °C and blending ratio of AD to SS = 0.75:0.25. These phenomena are associated with the reducing environment and reducing substances by their high volatiles as well as the abundant minerals such as CaCO3 and Fe2O3 in AD and SS. However, high combustion temperature is unfavorable for chlorine fixation. This work provides a better understanding of their thermal behaviors, ash characteristics, and gaseous pollutants emission characteristics to realize their stable and clean incineration.

Interaction mechanism and pollutant emission characteristics of sewage sludge and corncob co-combustion

The co-combustion of sewage sludge and biomass has demonstrated significant potential for reducing carbon emissions and realizing the resource utilization of solid waste. In this study, the co-combustion behavior and pollutant emissions of sewage sludge and corncob were systematically investigated using thermogravimetric-Fourier transform infrared spectroscopy-mass spectrometry (TG-FTIR-MS) and a fixed-bed reactor. When the corncob blending ratio reached 30 %, the ignition temperature was 179.01 °C lower than that of sewage sludge, and the comprehensive combustion index increased by 13.92 times. The corncob in the mixed fuel dominated the volatiles' release and combustion process. The interaction strength increased as the corncob blending ratio increased. When the corncob blending ratio reached 70 %, it promoted the thermal weight loss process of sewage sludge. The release rate of CO2 increased as the biomass ratio increased, and a 30 % corncob content could inhibit CO2 emissions. Simultaneously, the interaction between sewage sludge and corncob inhibited the emissions of CO and NO during the co-combustion process, improving the combustion efficiency. This study provides theoretical support for developing the fuel value of sewage sludge, improving the amount of solid waste collaborative disposal, and realizing the leading carbon peak in thermal power industry.

Emission Characteristics of Greenhouse Gases and Air Pollutants in Northern Hemisphere Cities: Comprehensive Assessment Using Ground‐Based Fourier Transform Spectrometers

AbstractDespite the importance of understanding the urban emission characteristics of greenhouse gases (GHGs) and air pollutants, few studies have conducted integrated assessments across diverse urban environments. Herein, we conducted a comprehensive evaluation of the emission characteristics of GHGs and air pollutants in seven cities in the Northern Hemisphere using ground‐based Fourier transform spectrometers. Our analysis primarily focused on emission ratios of excess column‐averaged dry‐air mole fractions of carbon monoxide (CO) to carbon dioxide (CO2) (∆XCO:∆XCO2) and those of methane (CH4) to CO2 (∆XCH4:∆XCO2). We found that the emission ratios varied significantly across cities. Xianghe (China) and Pasadena (USA), known for severe air pollution, showed the highest emission ratios. Notably, Seoul (South Korea) showed lower ∆XCO:∆XCO2 (3.32 ± 0.10 ppb/ppm) but relatively higher ∆XCH4:∆XCO2 (4.85 ± 0.04 ppb/ppm), which was comparable to the ∆XCH4:∆XCO2 value of Xianghe (5.15 ± 0.10 ppb/ppm), suggesting that targeted CH4 reduction strategies may be required for climate change mitigation in Seoul.

Emission characteristics and health effects of PM2.5 from vehicles in typical areas.

Vehicle emissions have become an important source of urban air pollution, and the assessment of air pollution emission characteristics and health effects caused by specific pollution sources can provide scientific basis for air quality management. In this paper, vehicle PM2.5 pollution in typical urban agglomerations of China (the Beijing-Tianjin-Hebei urban agglomeration (BTHUA), the triangle of the Central China urban agglomeration (TCCUA) and the Chengdu-Chongqing urban agglomeration (CCUA)) were used as research samples to evaluate the emission characteristics, health effects and economic losses of vehicle PM2.5 pollution based on the emission inventory, air quality model and exposure-response function from 2010 to 2020. The results indicated that PM2.5 emissions from vehicles in the three urban agglomerations during 2010-2020 first showed an upward yearly trend and then showed a slow decrease in recent years. Heavy-duty trucks and buses are the main contribution vehicles of PM2.5, and the contribution rates of light-duty vehicles to PM2.5 is increasing year by year. The contribution rate of PM2.5 in Beijing decreased significantly. In addition to capital cities and municipalities directly under the central Government, the emission of pollutants in other cities cannot be ignored. The evaluation results of the impact of PM2.5 pollution from vehicles on population health show that: the number of each health endpoint caused by PM2.5 pollution from vehicles in the BTHUA and CCUA showed an overall upward trend, while the TCCUA showed a downward trend in recent years. Among them, PM2.5 pollution from vehicles in the three major urban agglomerations cause about 78,200 (95% CI: 20,500-138,800) premature deaths, 122,800 (95% CI: 25,600-220,500) inpatients, and 628,400 (95% CI: 307,400-930,400) outpatients and 1,332,400 (95% CI: 482,700-2,075,600) illness in 2020. The total health economic losses caused by PM2.5 pollution from vehicles in the three major urban agglomerations in 2010, 2015 and 2020 were 68.25 billion yuan (95% CI: 21.65-109.16), 206.33 billion yuan (95% CI: 66.20-326.20) and 300.73 billion yuan (95% CI: 96.79-473.16), accounting for 0.67% (95% CI: 0.21-1.07%), 1.19% (95% CI: 0.38%-1.88%) and 1.21% (95% CI: 0.39%-1.90%) of the total GDP of these cities. Due to the differences in vehicle population, PM2.5 concentration, population number and economic value of health terminal units, there are differences in health effects and economic losses among different cities in different regions. Among them, the problems of health risks and economic losses were relatively prominent in Beijing, Chengdu, Chongqing, Tianjin and Wuhan.

Simulation studies of pollutant emissions from road vehicles using models for inventories of pollutant emissions

Countries are obliged by international regulations to conduct annual pollutant emissions inventories. Road transport is one of the sectors for which an inventory of pollutant emissions is carried out. Determining pollutant emissions from road transport is possible only by modeling these emissions – that is why unified emission models are used. In this work, the COPERT and HBEFA INFRAS software are used to determine pollutant emissions characteristics for various vehicle traffic models. The article presents the principles of modeling pollutant emissions from road vehicles. The rules for qualifying road vehicles into elementary and cumulative categories have been systematized. Models of road vehicle traffic and ways of taking them into account in modeling pollutant emissions are presented. The following emissions of pollutants harmful to the health and life of living organisms are considered: carbon monoxide, non-methane volatile organic compounds, nitrogen oxides and total suspended particles. The trends of the national annual emissions of the tested pollutants in the years 2000 – 2020 and the results of simulation tests of pollutant emissions models are presented.

Investigation of the Combustion Properties of Ethylene in Porous Materials Using Numerical Simulations

As industrial modernization advances rapidly, the need for energy becomes increasingly urgent. This paper aims to enhance the current burner design by optimizing the combustion calorific value, minimizing pollutant emissions, and validating the accuracy of the burner model using experimental data from previous studies. The enhanced porous medium burner model is used to investigate the burner’s combustion and pollutant emission characteristics at various flow rates, equivalence ratios, combustion orifice sizes, and porosity of porous media. In comparison with the previous model, the combustion traits during ethylene combustion and the emission properties of pollutants under various operational circumstances have been enhanced with the enhanced porous medium burner model. The maximum temperature of ethylene combustion in the enhanced model is 174 k higher than that before the improvement, and the CO emissions are reduced by 31.9%. It is believed that the findings will serve as a guide for the practical implementation of porous media combustion devices.

Numerical analysis of the landing and take-off cycle standard for supersonic engines based on pollutant emission characteristics

To meet the requirements of the update for the supersonic landing and take-off (LTO) cycle standard, a methodology for studying the LTO supersonic standard based on pollutant emission characteristics is proposed in this paper to analyze the thrust and time of the LTO. In this study, three distinct supersonic engine models were developed based on subsonic engine cores. Subsequently, the pollutant emission calculation models were developed to calculate the pollutant emission index (Ie) of supersonic engines and analyze the pollutant emission characteristics. Findings confirmed the presence of a correlation between standard formulations and pollutant emissions. Finally, considering that the current LTO standard leads to excessive noise during the climb phase and inefficient combustion during the taxi/ground idle phase, the LTO supersonic standard was analyzed for the trade-off, which resulted in the more applicable and fairer standard being formulated. The results indicate that the LTO supersonic standard formulated in this paper proves to be more reasonable than the current LTO standard and accurately represents the pollutant emission characteristics of distinct supersonic engines during both the climb and taxi/ground idle phases. Consequently, this study's results have guiding significance for formulating the future LTO supersonic standard and predicting pollutant emissions from supersonic engines.

Pilot-tests of the coal-fired power plant indirect coupling with multi-source organic solid waste incineration technology

The production of organic solid waste is increasing as the development of society. However, the investment of waste incineration power plant is very high and the thermal efficiency is very low. At the same time, the load of coal-fired power plant is suppressed due to the carbon neutralization policy. Therefore, using the existed coal-fired power plant to co-process the organic solid waste is a feasible method. In this paper, a coal-fired power plant indirect coupling with waste incineration technology based on flue gas circulation was proposed and studied on a 100 kW pilot-test bench. In this technology, the polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) was reduced by a three stages controlling method, which adopts the blending of multi-source organic wastes, high-temperature decomposition and selective catalytic reduction (SCR) catalyst decomposition, simultaneously. The effects of waste incineration coupling, replacement ratio of coal, and flue gas circulation on the combustion and pollutant emission characteristics of the system were studied. The experimental results indicate that the waste incineration coupling has minor influence on the temperature distribution and the toxicity of fly ash of the coal-fired furnace. The NO, HCl, and PCDD/Fs concentrations of flue gas of coal-fired furnace generally decrease as the replacement ratio of coal increases, while the SO2 concentration increases. With the help of three stages controlling method or the flue gas circulation, the PCDDFs concentration of the flue gas of coal-fired furnace can be much lower than 0.1 TEQ ng/Nm3.

Numerical studies of a water-cooled premixed burner for low NOx combustion of natural gas

Natural gas, known for its high combustion efficiency and low CO2 emissions, is experiencing a significant increase in both market share and application range. Despite these advantages, there are also challenges emerged during the combustion process, including occurrence of high flame temperature, difficulty in controlling nitrogen oxide emissions, combustion instability, and a tendency to backfire. To address these issues and achieve clean and stable burning, a novel 14 MW water-cooled pre-mixed burner has been developed. In-depth simulations are conducted to assess the impact of various structural and operating parameters on combustion and pollutant emission characteristics. Results indicate that the combustion temperature follows a “W" shape with height of the low cooling component while its width governs combustion stability. Gas inlet spacing influences the flame center position and anti-backfire performance. The flare angle of gas channels determines the minimum ignition energy of the mixed gas fuel which affects ignition point and flame center position. Although large height of high cooling component contributes to low NOx emissions at the gas outlet, the resultant low temperature is undesirable for combustion stability. Further examinations of operating parameters through simulations reveal that combustion temperature initially decreases and then increases with excess air coefficient, while a significant decrease is noted with lower operating load. The premixed water-cooled technology could achieve low-NOx emissions to 2.89 mg·Nm−3 with the combustion temperature controlled at 1642K. This study provides valuable data for the design of low-NOx gas burners, serving as a reference for achieving clean and stable combustion of gas fuel.

How we deal with transition planning as we approach the e-bus era

With the rapid development of new energy, the widespread adoption of electric buses is significant. This paper delves into the environmental impact, economic implications, and strategic planning solutions associated with the proliferation of electric buses. We initiate this process by using bus data from Qingdao, China. Subsequently, using the fuel life cycle method, we carefully examined CO and the pollutant emission characteristics of Qingdao bus fleet before and after electrification. The research results reveal that CO, nitrogen oxides, and VOC emissions have all increased. An economic analysis of electric vehicle adoption in public transportation was conducted in response to the second question. Considering government subsidies, a cost-saving model for electric vehicles per 100 kilometers was constructed. Furthermore, the study found that as the electrification rate increases, the operating costs of electric buses in Qingdao gradually decrease. We developed a comprehensive linear integer programming model to address the third question. The model, aimed at achieving the lowest comprehensive cost while considering various constraints, was solved through the branch and bound method. We applied this model to analyze the optimal plans for completing the conversion of electric buses in Qingdao, Zhengzhou, and Xi’an within a 10-year timeframe. For the fourth question, we have put forward policy recommendations.

Comprehensive experimental investigations on Co-combustion dynamics and multi-pollutant formation characteristics of coal gangue and biomass in oxy-fuel atmosphere

Based on the co-combustion principle of coal gangue and biomass, the combustion characteristics, kinetic mechanisms, and pollutant emission characteristics of mixed coal gangue and wheat straw in oxy-fuel atmosphere were investigated by conducting experiments with a thermogravimetric analyzer and a tube furnace in this paper. The results indicated that the comprehensive combustion characteristics, reaction rate and burnout rate of the samples can be improved with the increase of O2 concentration in oxy-fuel atmosphere. When O2 concentration is 50 %, the emission peaks of pollutants SO2 and NOx are the highest. The increase of biomass content can accelerate the combustion reaction rate, increase the total weight loss rate, enhance the comprehensive combustion characteristics of the samples significantly, and reduce the release of SO2. A faster heating rate corresponds to higher ignition temperature, burnout temperature, and the maximum weight loss rate temperature, leading to the improvement of comprehensive combustion characteristics and flammability. The combustion temperature has a significant effect on pollutant release, and the release of CO and SO2 is relatively low under the condition of 900∼1000 °C. Therefore, the use of oxy-fuel co-combustion technology holds the potential to significantly improve the combustion performance of coal gangue, reduce pollutant emissions, and provide a theoretical guidance for the resource utilization of coal gangue and biomass.

Numerical Analysis of the Effects of Fuel Injection Duration and Spray Angle on the Combustion Process in a Compression Ignition Engine

The changes in injection strategies for diesel engines have a major impact on the performance and pollutant emission characteristics of diesel engines. If injection strategies like injection duration, injection timing, injection pressure and spray angle are properly adjusted, combustion can be improved. The engine performance will increase and emissions will decrease with the combustion improvement. In this work, the influences of injection duration and spray angle on the combustion characteristics of single cylinder, natural aspirated, electronically controlled injection, compression ignition engine were investigated. In the first stage of the work, experiments were executed on a single cylinder CI engine using a Cussons P8160 DC dynamometer. After the experiments, the piston bowl geometry of the engine was modeled and numerical simulation studies were achieved at 7 different injection durations and 7 different spray angles using Converge CFD software. As a result of this study, it was observed that there is a good match between experimental and simulation data of heat release rate (HRR) and in-cylinder pressure. In-cylinder pressure decreased with longer injection duration. The highest max. in-cylinder pressure was roughly 101.0 bar at 4°CA injection duration and the lowest max. in-cylinder pressure was roughly 82.0 bar at 10°CA injection duration. When the HRR data were analyzed, it was seen that as the injection duration increased, the amount of heat released by combustion decreased. When examining the results of the spray angle analysis, it was concluded that there were not very large differences in-cylinder pressure and HRR data, and there was a difference of 1.4 bar between the highest and lowest max. in-cylinder pressure values. In addition, the highest in-cylinder pressure of approximately 86.7 bar was obtained at a spray angle of 77°. It was observed that the CA50 value was obtained at angles closer to the top dead center by increasing the spray angle and decreasing the injection duration. Moreover, the longest combustion durations were realized at 60° spray angle and 10°CA injection duration.

Feasibility of co-disposal of lignite and eucalyptus wood in coal-fired power plants: thermogravimetric characterization, typical gaseous pollutant emission characteristics, and economic analysis

ABSTRACT Energy issues are becoming increasingly prominent, and biomass blending in coal-fired power plants can improve combustion performance and reduce gaseous pollutant emissions, thereby improving economic efficiency. In this study, a thermogravimetric analyzer, a horizontal tube furnace, and an infrared flue gas analyzer were used to investigate the combustion behavior and gaseous pollutant emissions of the co-combustion of LC and EW. The results show that blending EW into LC cofiring can inhibit the release of volatile matter and promote the decomposition of fixed carbon and lignin simultaneously. The HHV of EW (15.88 MJ/kg) reaches 63.7% of LC’s (24.90 MJ/kg), indicating EW has a high energy utilization value. With increasing combustion temperature, the average value of CR S increased from 47.09% to 59.94%, and the average value of CR Cl increased from 26.15% to 52.15%, leading to a significant increase in SO2 and HCl emissions. The decrease in combustion temperature slightly promoted the release of N (CR N increased from 11.76% to 14.45%). The results of the economic analysis show that the cost of CaO and NH3·H2O used for removing gaseous pollutants decreased the most, and the economic efficiency increased the fastest to 14,000 RMB/day when the EW blending ratio increased from 10% to 20%.

Emission and spatial variation characteristics of odorous pollutants in the aerobic tank of an underground wastewater treatment plant (UWWTP) in southern China

In this study, the spatial concentration of odorous pollutants in the aerobic tank of an underground wastewater treatment plant (UWWTP) in southern China is monitored. The odour activity value, odour contribution rate, and chemical concentration contribution rate are used to evaluate the degree of contribution of odorous substances. Computational fluid dynamics (CFD) simulations of odorous pollutant diffusion are also established. The study shows that the odorous substances detected in the aerobic tank mainly included ammonia (NH3), hydrogen sulfide (H2S), trimethylamine (C3H9N), and methanethiol (CH3SH), and their concentrations are 1.160, 0.778, 0.022, and 0.0006 mg/m3, respectively. The total odour activity value of the aerobic tank is 450.72 (dimensionless), of which the odour activity value of H2S is 432.22, and the contribution rate reaches 95.9%. H2S is the main contributor to odour and a key controlled substance. The air inlets and exhaust outlets in the aerobic tank are cross-arranged at the top of the space, and the CFD model of odorous pollutant diffusion shows that the gas flow organization determines the odorous pollutant diffusion. The spatial distribution of gas flow and odorous substances in the aerobic tank is relatively uniform, and the odour collection efficiency is higher. The production flux and production coefficient of H2S in the aerobic tank are calculated as 25.831 mg/(m2·h) and 14.149 mg/t, respectively. This study determines the reasonable air supply and exhaust design of the aerobic tank, the number of odour pollutants, and the key controlled substances. These findings offer guidance and serve as useful references for the prevention and control of odour pollution in aerobic tanks of the same type of UWWTPs.