Gold provenance determination is a key forensic challenge in combating illegal mining and associated crimes. This study aims to assess the traceability of gold extracted from illegal mining activities in Brazil by applying a multi-analytical geochemical approach. We employed X-ray fluorescence (XRF), electron microprobe analysis (EPMA), scanning electron microscopy (SEM), and grain-scale compositional mapping to analyze gold samples sourced from artisanal and small-scale mining within the Yanomami Indigenous Territory. To evaluate the impact of post-extraction processes on geochemical signatures, gold samples underwent partial melting and were subsequently reanalyzed focusing on their potential for traceability. The results obtained from the melted samples were compared with gold sponges and ingots of unknown origin, seized during Brazilian Federal Police operations in airports far from our target area, to determine whether their geochemical fingerprints could be matched to known deposits. The findings indicate that different genetic types of gold can be distinguished based on specific elemental distribution patterns. The geochemical signatures of key minor and trace elements, such as Ag, Hg, Bi, Mo, and Co, remained detectable, allowing for the traceability of samples throughout the production process. Bismuth, in particular, demonstrated mineralogical resilience, maintaining the consistent Au/Bi ratio even after amalgamation and melting, reinforcing its potential as a geochemical marker for provenance determination. Furthermore, we revealed that the gold sponge samples likely originated from the northeastern domain of the Yanomami Territory, with the Mutum deposit being the most probable source. These findings highlight the effectiveness of accessible analytical techniques in establishing the traceability of illegally mined gold, as a tool for strengthening regulatory enforcement in the gold supply chain.
Read full abstract