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Photochemical Reactions Research Articles

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15030 Articles

Published in last 50 years

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  • Photoinduced Reactions
  • Photoinduced Reactions
  • Photochemical Transformations
  • Photochemical Transformations

Articles published on Photochemical Reactions

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Microenvironments as an Explanation for the Mismatch between Photochemical Absorptivity and Reactivity.

Photochemistry is at the forefront of many modern technologies, from additive manufacturing to phototherapeutics to sun protection and organic synthesis. It is commonly believed that an absorbance spectrum, showing the likelihood of a photon to be absorbed by a chromophore at a given wavelength, is an accurate predictor of how well a photochemical process will proceed when irradiated with different colors of light. Over the past decade this paradigm has been repeatedly challenged for many photochemical systems, as a distinct mismatch between the absorption spectrum and the wavelength-resolved photochemical reactivity has been observed. Herein, we unravel the underlying mechanisms behind the mismatched reactivity and absorbance in photocycloadditions. Initially, we probe the impact that an equilibrium established between reversible photochemical processes has on the mismatch for a pyrene-chalcone molecule. Subsequently, we establish a critical link between photophysics and photochemistry with a theory based on the selective excitation of specific microenvironments, leading to molecular transitions that allow for favorable wavelength-dependent reactivity. Time-resolved and steady-state fluorescence spectroscopy measurements confirm the presence of this selectivity, with both displaying significant red-edge effects that are observed in the fluorescence spectroscopy literature, further supporting our theory. By synthetically tethering chromophores together, we evidence the importance of microenvironments and their wavelength-dependent excited-state lifetimes, presenting the missing link that explains the mismatch in many photochemical systems. The implications of the theory presented herein stretch from additive manufacturing to photodynamic therapy and beyond, meaning that researchers can leverage mismatched photochemical reactivity by simply changing the properties of the environment surrounding the chromophore.

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  • Journal IconJournal of the American Chemical Society
  • Publication Date IconJul 16, 2025
  • Author Icon Joshua A Carroll + 7
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Singlet Oxygen in Food: A Review on Its Formation, Oxidative Damages, Quenchers, and Applications in Preservation

Singlet oxygen (1O2) has been proven to simultaneously cause oxidative damage to food and the death of microorganisms. In order to enhance the utilization of 1O2 in food systems, this review presents an overview of recent studies on the formation mechanisms of 1O2, the damage mechanisms of 1O2 on food, the self-protective mechanisms in food against 1O2, and the applications of 1O2 in food preservation based on the narrative review guidelines. Studies have shown that in vegetable and meat systems, 1O2 is mainly produced through photochemical reactions. It has been suggested that proteins and lipids are the main target compounds for oxygen in food. Natural antioxidants in food (such as vitamin E and carotenoids) can remove 1O2 through physical or chemical quenching mechanisms. Novel preservation techniques featuring a thin film technology coupled with photosensitizers have been employed on the surface of food to prolong the shelf life. However, how to balance the bactericidal effect of 1O2 and its oxidative effects on food still requires further research. It could be feasible that 1O2 will play an increasingly important role in the future food industry on the premise of strengthening supervision over food safety risks induced by 1O2.

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  • Journal IconAntioxidants
  • Publication Date IconJul 15, 2025
  • Author Icon Limei Xiao + 6
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Observing the Diurnal Variations of Ozone‐NOx‐VOC Chemistry Over the U.S. From the Geostationary TEMPO Instrument

Abstract Ground‐level ozone (O3) is an air pollutant formed by the photochemical reactions between oxides of nitrogen (NOx) and volatile organic compounds (VOCs). A key challenge in mitigating O3 pollution is to determine whether the O3 production is NOx‐limited or NOx‐saturated. Using the hourly observations of O3 precursors, formaldehyde (HCHO) and NO2, from the newly launched geostationary Tropospheric Emissions: Monitoring of Pollution (TEMPO), we present the first space‐based observations of diurnal variations of O3‐NOx‐VOC chemistry over the CONUS during 2024 warm season. We integrate a steady‐state model with global simulations to derive the regime thresholds of the HCHO to NO2 ratio (HCHO/NO2), and identify the O3 production regimes using the provisional TEMPO products, which have been validated with limited measurements. We find that O3 production is dominated by NOx‐saturated regime in the morning but NOx‐limited regime in the afternoon over major U.S. O3 nonattainment metropolitan areas.

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  • Journal IconGeophysical Research Letters
  • Publication Date IconJul 15, 2025
  • Author Icon Xiaomeng Jin + 4
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The seascape of VOC production and cycling in a tropical coral reef

Volatile organic compounds (VOCs) have been proposed to indicate coral reef health, but little is known about their cycling processes in coral reefs and the roles of reef components. We studied the distribution and cycling of ocean-leaving VOCs (dimethylsulfide (DMS), carbonyl sulfide (COS), CS2, dimethyl disulfide, isoprene, CH3I, CH2ClI, and bromomethanes CH2Br2 and CHBr3) across a coral reef in Mo’orea (French Polynesia) that has a fast and unidirectional water flow. Repeated sampling of transects between the open ocean and the reef outflow channel, across the shelf, the reef crest, and the back-reef lagoon, showed that reef waters were depleted in dissolved organic carbon, chlorophyll, phytoplankton, and bacteria, and enriched in nutrients. All studied VOCs increased in concentration after oceanic waters crossed the reef crest, with bromomethanes showing the largest increase. Incubation experiments of back-reef waters around midday suggested that: (a) photochemical reactions were a major source for COS and major sink for DMS; (b) microbial plankton were the main daytime source for DMS, isoprene, and CH3I, and an important sink for COS; (c) seaweeds were the main source of CH2ClI, CHBr3, and CH2Br2; and (d) carbonate sediments were a major source for CS2 and CH2ClI, an important source for DMS and isoprene, and the main sink for COS. The dominant coral Pocillopora sp. was a source only for DMS and COS. Decomposing seaweed rafts were an important but unquantified source for all VOCs except CH3I. In April 2018, the reef was a net producer of VOCs compared to the ocean, with the anticipation that production would increase if corals were lost and replaced by seaweeds. Using VOCs and other chemical tracers of reef waters, we estimated that one third of the water entering the reef is recirculated water from the same reef, with implications for ecosystem self-recruitment and genetic maintenance.

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  • Journal IconElem Sci Anth
  • Publication Date IconJul 10, 2025
  • Author Icon Marta Masdeu-Navarro + 11
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Adsorption and reaction co-induced bifunctional catalytic removal of NOx and toluene over a reaction site-isolation catalyst.

Adsorption and reaction co-induced bifunctional catalytic removal of NOx and toluene over a reaction site-isolation catalyst.

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  • Journal IconJournal of hazardous materials
  • Publication Date IconJul 8, 2025
  • Author Icon Junjie Jiang + 4
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Advancing Air Quality Management: A Comprehensive Review of UV Technology, Pyrolysis, and Their Integration

Air pollution is a significant global issue, with pollutants like fine particulate matter (PM2.5), volatile organic compounds (VOCs), nitrogen oxides (NOx), and sulfur oxides (SOx) posing severe health risks. Combining ultraviolet (UV) technologies with pyrolysis has emerged as a promising control strategy, based on a literature review of peer-reviewed journals, industrial documents, and scholarly papers. UV-based technologies like photocatalytic oxidation (PCO), vacuum ultraviolet (VUV), and deep-ultraviolet (deep-UV) use reactive oxygen species (ROS) to break down pollutants. Pyrolysis transforms waste such as plastics, biomass, and medical waste into synthesis gas (syngas) and biochar with less toxic emissions. Integrating UV radiation with pyrolysis forms a hybrid system where photochemical reactions lower activation energies, increase pollutant degradation efficiency, and enable lower-temperature operation. This paper analyzes mechanisms, reactor configurations, and kinetic improvements, along with challenges like residual ozone generation (secondary pollutant), catalytic deactivation, and high energy consumption. Solutions include advanced reactor designs, cost-efficient UV sources, and hybrid catalytic materials. UV-enhanced pyrolysis is a cost-effective, adaptable method for reducing air pollution. Future research should optimize reaction conditions, develop integrated systems for industrial use, and conduct economic feasibility studies.

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  • Journal IconOODBODHAN
  • Publication Date IconJul 8, 2025
  • Author Icon Tulsi Mandal Dhanuk + 3
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Impact of the East Asian Stratospheric Intrusion on Lower Tropospheric Ozone in the Yangtze River Delta

Abstract Tropospheric ozone (O3) pollution has aroused increasing attention in past decades, especially in China, with escalating near‐surface O3 levels. Apart from photochemical reactions, stratospheric intrusion (SI) also contributes to tropospheric O3 pollution. In this study, a strong SI event that greatly influenced the near‐surface O3 pollution was identified in May 2023. To quantitatively analyze the contribution to surface O3 over the Yangtze River Delta (YRD), meteorological reanalysis data, in situ observations, and a regional meteorology‐chemistry coupled model were integrated. Our findings reveal that the severe O3 pollution observed over the YRD region cannot be solely attributed to photochemical processes. Noteworthily, a distinct signal of stratospheric air masses injecting into the troposphere was observed, indicating a more complex interplay between atmospheric chemical and physical processes. The clustering analysis of the backward trajectories shows that the O3‐rich air masses injected into the lower troposphere are primarily driven by westerly jets and downwelling behind the troughs accompanying the low‐pressure weather system at 46°N–60°N. The stratospheric O3‐rich air masses can be transported to the YRD region driven by the strong downwelling occurring with a high‐altitude wind field toward the south. Using the regional meteorology‐chemistry model Weather Research and Forecasting model coupled with Chemistry (WRF‐Chem) with real‐time input of the upper chemical boundary conditions, it is estimated that such regionally transported SI O3 contributed more than 12 ppb to surface O3 pollution over the YRD region.

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  • Journal IconJournal of Geophysical Research: Atmospheres
  • Publication Date IconJul 1, 2025
  • Author Icon Jinpeng Lu + 7
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Soil and litter emission sources as important contributors to ozone production from volatile organic compounds in island tropical forests.

Soil and litter emission sources as important contributors to ozone production from volatile organic compounds in island tropical forests.

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  • Journal IconEnvironmental research
  • Publication Date IconJul 1, 2025
  • Author Icon Huayuan Zhou + 9
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Thermal hydrolysis-induced molecular transformations in sludge: Implications for photochemical reactivity and dissolved antibiotics photodissipation.

Thermal hydrolysis-induced molecular transformations in sludge: Implications for photochemical reactivity and dissolved antibiotics photodissipation.

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  • Journal IconJournal of hazardous materials
  • Publication Date IconJul 1, 2025
  • Author Icon Haifeng Wen + 6
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Molecular modeling of methylene blue photosensitizer and its in vivo evaluation against canine fibrosarcoma under light irradiation

Abstract Methylene blue is a widely used photosensitizer in biophotonics, particularly in photodynamic therapy (PDT). In this work, we conducted a comprehensive theoretical investigation of its molecular and electronic properties including frontier molecular orbital energies, electron spin density, theoretical electronic transitions, and reactivity indices to better understand its biomedical potential. These theoretical insights were closely integrated with experimental analyses, including UV–Vis spectral measurements and a preliminary PDT application. Theoretical calculations revealed distinct redox characteristics: the cationic form ([MB]+) exhibited high electron affinity and pronounced electrophilicity, while the neutral form (MB) showed low polarizability and minimal electrophilicity. These electronic features provide a mechanistic basis for methylene blue’s photochemical reactivity and its interaction profile in biological systems. Experimental UV–Vis spectra corroborated the absorption bands predicted by the theoretical models, demonstrating strong agreement between computational and experimental data. Furthermore, after 90 d of PDT treatment, significant clinical improvements were observed in the treated canine subjects, including enhanced wound healing, increased mobility, and improved sociability. The convergence of theoretical and experimental findings reinforces methylene blue’s role as an effective photosensitizer, supporting its potential for safe and impactful therapeutic applications.

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  • Journal IconLaser Physics Letters
  • Publication Date IconJul 1, 2025
  • Author Icon Adriana Passos + 6
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Synthesis of 1,2,4-Triazole substituted Co(II) and Cu(II) phthalocyanine compounds and investigation of their photocatalytic activities in the photochemical degradation reaction of 4-nitrophenol

Synthesis of 1,2,4-Triazole substituted Co(II) and Cu(II) phthalocyanine compounds and investigation of their photocatalytic activities in the photochemical degradation reaction of 4-nitrophenol

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  • Journal IconJournal of Molecular Structure
  • Publication Date IconJul 1, 2025
  • Author Icon Anıl Avlar + 4
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Critical role of vertical exchange in the boundary layer on urban photochemical pollution.

Critical role of vertical exchange in the boundary layer on urban photochemical pollution.

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  • Journal IconThe Science of the total environment
  • Publication Date IconJul 1, 2025
  • Author Icon Ying Shen + 3
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Study of the Photochemical Reactions of Thiomethylpropyl Ketone Using the CIDNP Effect

Study of the Photochemical Reactions of Thiomethylpropyl Ketone Using the CIDNP Effect

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  • Journal IconRussian Journal of Physical Chemistry A
  • Publication Date IconJul 1, 2025
  • Author Icon V I Porkhun + 4
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Spatial correlations between summer ozone heatwave dual events and residents mental health in China

In the context of global warming, the frequency and intensity of extreme heat events have significantly increased. Elevated temperatures accelerate atmospheric photochemical reactions, resulting in higher ambient ozone (O3) levels. This convergence of heatwaves and elevated O2 concentrations presents a dual threat to public health. This study analyzes surface ozone concentrations and heatwave data from the summers of 2013 to 2020 across China, integrating these with mental health data from the Chinese population. Using spatiotemporal analysis and econometric models, we investigate the spatiotemporal dynamics of ozone and heatwaves during Chinese summers and assess population exposure risks. Our findings quantitatively elucidate the correlations between combined ozone-heatwave events and residents’ mental health. By 2020, the number of days with high surface ozone, heatwave days, and heatwave events in China had risen by 16.15%, 26.32%, and 15.67%, respectively, with marked spatial heterogeneity and clustering patterns. Despite a slight decline in 2020, the population exposed to high ozone levels (> 160 μg/m3) and prolonged heatwave conditions (> 20 days) showed an overall upward trend. Furthermore, 57.95% and 20.91% of regions are projected to remain at risk from these combined hazards. As surface ozone and heatwave exposure risks escalate, the mental health burden on residents has intensified, with significant spatial disparities observed.

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  • Journal IconScientific Reports
  • Publication Date IconJul 1, 2025
  • Author Icon Rongjun Zeng + 6
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Unveiling the role of dark states in dynamic control of azopyrrole photoisomerization by light-matter interaction

Strong light-matter interactions demonstrated considerable potential to control photochemical reactions. Here, we coupled a single cavity mode to the electronic S0-S1 transition of azopyrrole E and Z-isomers. This allows us to observe the impact on the photoisomerization process “on-the-go”, i.e., capturing a sharp transition in the kinetics when moving from strong to weak coupling. Pumping either at the upper polaritonic state or the uncoupled population shows an acceleration of the photoisomerization process (strong to weak), whereas the opposite is observed when exciting the lower polaritonic state. Excellent correlation between spectral overlap and rate suggests that changes in photochemistry are mediated by relaxation via the dark state manifold. Remaining in the ultra-strong coupling regime affects the reaction kinetics, but without sharp transitions. Our experimental and theoretical findings underline that dynamic transitions between coupling domains might pave the way to a better understanding of how strong coupling modifies photoisomerization reactions.

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  • Journal IconCommunications Chemistry
  • Publication Date IconJul 1, 2025
  • Author Icon Pallavi Garg + 5
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Mechanistic Investigations of Photocatalytic Systems by Pump‐Pump‐Probe Spectroscopy

Understanding the mechanism through which a photochemical reaction proceeds grants access to thermodynamic and kinetic parameters that allow its optimization for large‐scale applications. In the last few years, photocatalytic systems have been major players in scientific developments on research fields of primary importance, including solar fuel generation in artificial photosynthesis, and the use of excited organic radical ions as photocatalysts in thermodynamically challenging reactions of utmost synthetic relevance. Generally, time‐resolved spectroscopic approaches are the main experimental tools to investigative the dynamics of photoactive systems, with pump‐probe‐based ones being the golden standard in photophysical and photochemical research. However, for photocatalytic systems in which multiple photons are required, which is generally the case for photosynthetic reactions and those promoted by excited organic radical ions, the pump‐probe approach is no longer sufficient since it is based on a single photon‐to‐electron ratio. This is where a second actinic pump excitation comes into play in what is known as pump‐pump‐probe spectroscopy. In this review, we explore how this approach is used to unravel the mechanism of photocatalytic systems triggered by light using different probes of UV–vis absorption and resonance Raman scattering in varying time scales.

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  • Journal IconChemPhotoChem
  • Publication Date IconJun 30, 2025
  • Author Icon Daniel H Cruz Neto + 2
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Polymerization‐Induced Direct Photolithography of Quantum Dots

ABSTRACTThe development of high‐resolution displays has driven the exploration of quantum dot (QD)‐based patterning techniques, ranging from inkjet printing to direct photolithography. Among these methods, direct photolithography stands out as a promising technique for creating high‐resolution QD patterns without the need for a photoresist layer. This approach relies on photochemical reactions that induce solubility changes in target materials when exposed to specific wavelengths of light. While various patterning strategies have been reported, polymerization‐induced network formation offers a straightforward yet effective approach for fabricating QD patterns, simultaneously inheriting the advantageous physical and chemical properties of polymers. This review categorizes and discusses the photochemical reactions that enable polymerization according to their underlying mechanisms. Recent examples utilizing these reactions for direct photolithography of QDs are classified and summarized based on reactive functional groups—alkene, alkane, alkyne, and disulfide—involved in the polymerization process. Finally, we propose future directions for advancing this technology, including improvements in material compatibility, device integration, and the introduction of new functionalities, which could further expand the potential applications of QD‐based optoelectronic devices.

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  • Journal IconMacromolecular Rapid Communications
  • Publication Date IconJun 29, 2025
  • Author Icon Taehyung Kim + 3
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Photoactivated Nano-Compatibilized Two-Phase Polymer Blends: An Approach for Determining Mechanical Behavior.

Light-activated polymers (LAPs) are shape-shifting materials capable of transforming their shapes in response to photoinduced chemical reactions, such as cis-trans isomerization and dimerization. Owing to the underlying photochemical reaction, these materials often exhibit behavior analogous to multicomponent/phase polymer blends. In this work, we present a free-energy-based theoretical framework to predict the mechanical behavior of nanoparticle-compatibilized elastic LAP blends that exhibit phase separation. In particular, we incorporate the impact of domain sizes and interfacial areas and establish a criterion for the materials' susceptibility to mechanical failure under various loading conditions, namely uniaxial and biaxial stretching. Our framework can also be adapted to high-entropy polymers and thermoresponsive or light-activated systems, with potential applications in soft robotics, biomedical devices, micromechanics, 4D printing, and material origami. Additionally, by integrating our model with physics-informed neural networks, we facilitate efficient analysis of complex domain geometries and enable comprehensive parametric studies.

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  • Journal IconThe journal of physical chemistry. B
  • Publication Date IconJun 28, 2025
  • Author Icon Surbhi Khewle + 1
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Core-Shell Engineering of One-Dimensional Cadmium Sulfide for Solar Energy Conversion.

Fabricating efficient photocatalysts that can be used in solar-to-fuel conversion and to enhance the photochemical reaction rate is essential to the current energy crisis and climate changes due to the excessive usage of nonrenewable fossil fuels. To attain high photo-to-chemical conversion efficiency, it is important to fabricate cost-effective and durable catalysts with high activity. One-dimensional cadmium sulfides (1D CdS), with higher surface area, charge carrier separation along the linear direction, and visible light harvesting properties, are promising candidates for converting solar energy to H2, reducing CO2 to commodity chemicals, and remediating environmental pollutants. The main disadvantage of CdS is photocorrosion due to the leaching of S2- ions during the photochemical reactions, and further charge recombination rate leads to low quantum efficiency. Therefore, the implementation of core-shell heterostructured morphology, i.e., the growth of the shell on the surface of the 1D CdS, which offers unique features such as protection of CdS from photocorrosion, a tunable interface between the core CdS and shell, and photogenerated charge carrier separation via heterojunctions, provides additional active sites and enhanced visible light harvesting. Therefore, the viability of the core-shell synthesis strategy and synergetic effects offer a new way of designing photocatalysts with enhanced stability and improved charge separation in solar energy conversion systems. This review highlights some critical aspects of synthesizing 1D CdS core-shell heterostructures, underlying reaction mechanisms, and their performance in photoredox reactions. Finally, some challenges and considerations in the fabrication of 1D CdS-based core-shell nanostructures that can overcome the current barriers in industrial applications are discussed.

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  • Journal IconNanomaterials (Basel, Switzerland)
  • Publication Date IconJun 27, 2025
  • Author Icon Rama Krishna Chava + 1
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Coordination Chemistry of Copper and Nickel with Xenon Difluoride and the Hexafluororuthenate(V) Anion: Synthesis and Structural Studies

In the photochemical reactions between MF2 (M = Cu, Ni), Ru, and F2 in anhydrous HF, Cu(RuF6)2 and Ni(RuF6)2 were formed. Only crystals of Cu(RuF6)2 were obtained during crystallization of the powdered products. Cu(RuF6)2 crystallizes in the triclinic space group P . The Cu atoms are coordinated by six F atoms, which are shared with octahedral RuF6 units. Together they form slabs that are interconnected by van der Waals forces. In the reactions between M(RuF6)2 (M = Cu, Ni) and 2XeF2 (1:2 molar ratio), [Cu(XeF2)2](RuF6)2 and [Ni(XeF2)2](RuF6)2 were formed. They both crystallize in the monoclinic space group P21/c. The metal center is coordinated by six F atoms. Two F atoms are provided by two non‐bridging XeF2 molecules, while the remaining four originate from four bridging [RuF6]– anions. In the reactions between M(RuF6)2 (M = Cu, Ni) and an excess of XeF2, [Cu(XeF2)6](RuF6)2 and [Ni(XeF2)6](RuF6)2 were formed. They are not isostructural, as the first crystallizes in the triclinic space group P , while the second crystallizes in the trigonal space group R . In both cases, homoleptic cations [M(XeF2)6]2+ are present, with the metal center coordinated by six non‐bridging XeF2 molecules, while the [RuF6]– anions are discrete.

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  • Journal IconEuropean Journal of Inorganic Chemistry
  • Publication Date IconJun 25, 2025
  • Author Icon Tomaž Mržljak + 3
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