In addressing challenges in Selective Catalytic Reduction (SCR) systems in vehicles, the development of novel SrCl2 composite materials with high ammonia adsorption and structural stability is crucial. In this context, we employed the porous magnesium oxychloride cement (PMOC) as a carrier material, successfully fabricating a mesoporous PMOC-SrCl2 material via solution impregnation technology. Simultaneously, we employed various characterization techniques such as XRD, full-pore analysis, TG, SEM, TEM, and EDS to examine the material. We conducted static adsorption assessments on numerous candidate materials at 0.1Mpa and 293.15 K. The synthesized C3 series material (Mass ratio of SrCl2 to PMOC = 10:3), solution impregnated for 1 h, exhibited exceptional ammonia adsorption capacity (up to 38.01 mmol·g−1). Through model fitting of experimental data, we discovered that the adsorption process of this material closely aligns with the pseudo-second-order kinetic model and the Langmuir model. Over an adsorption time span of 180 min, the adsorption rate of the composite material increased by 129 % compared to pure SrCl2. In the cycle performance testing phase, we observed that the material exhibited no significant degradation in performance after undergoing 10 cycles of adsorption/desorption. This structurally stable, cost-effective, and readily accessible high-efficiency ammonia adsorption material undoubtedly possesses immense potential to solve the application challenges of ammonia adsorption materials within automotive selective catalytic reduction systems.
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