The structure of tetrahedrally close-packed phases (known also as Frank-Kasper phases) in superalloys has recently been extensively studied at the atomic level by high-resolution electron microscopy (HREM) in the Laboratory of Atom Image of Solids, Academia Sinica. In addition to a magnitude of domain structures, no less than six new phases have been found. This is a resume of the study. First, a brief description of the crystal structures of these phases is given to illustrate the capability of HREM in revealing the building of complex structures from simple structural units. Secondly, the crystallographic features of the new phases and microdomain structures are discussed. Finally, the principle of juxtaposition of parallel oriented coordination polyhedra in these tetrahedrally close-packed phases is presented and this not only explains the existing structures of such phases but may also be important in the study of the quasi-crystalline state in rapidly quenched amorphous alloys.
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