This paper presents a numerical investigation into the solidification behavior of phase change material (PCM) in duplex and triplex-tube latent heat thermal energy storage (LHTES) systems enhanced with nickel foam and MXene nanoparticles. The study aims to investigate how nickel foam integration enhances heat transfer during PCM solidification, aiming for faster, more uniform solidification, and to analyse energy and exergy efficiency for optimizing thermal energy storage systems. The study also assesses the impact of nickel foam on enhancing PCM thermal conductivity, improving solidification rates, and overall thermal management. Focusing on a nickel foam/PCM/MXene (5 % v/v.) composite, the study explores the effects of solidification characteristics, as well as the Stefan and Fourier numbers, in both duplex tube thermal energy storage (DuT-TES) and triplex tube thermal energy storage (TrT-TES) systems. It provides detailed insights into the thermal performance of these systems by evaluating key factors such as liquid fraction, solidification temperature profiles, exergy destruction, exergetic efficiency, system efficiency, and discharged energy.The findings reveal that systems incorporating nickel foam/PCM-MXene composites significantly outperformed those using nickel foam/PCM and pure PCM alone, achieving notably faster solidification. Specifically, the nickel foam/PCM composite demonstrated higher discharge exergy than pure cetyl alcohol PCM. The TrT-TES system with the nickel foam/PCM composite solidified 48.40% faster than the DuT-TES system. Additionally, the discharge energy of the TrT-TES system with nickel foam/PCM and nickel foam/PCM/MXene composites was 2.26 % and 3.65 % greater, respectively, than that of the DuT-TES system. At 90 s, the DuT-TES with nickel foam/PCM/MXene showed a 2.91 % improvement in system efficiency. Overall, the TrT-TES system using the nickel foam/PCM/MXene composite exhibited a 48.39 % faster solidification rate than the DuT-TES system. Thus, this study highlights the superior potential of the TrT-TES system with nickel foam/PCM/MXene composite for enhancing latent heat thermal energy storage, outperforming the DuT-TES system in terms of solidification speed, discharge energy, and efficiency.
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