Performance Of Lithium-ion Batteries Research Articles

Investigating the Performance and Safety of Li-Ion Cylindrical Cells Using Acoustic Emission and Machine Learning Analysis

Acoustic emission (AE) is a low-cost, non-invasive, and accessible diagnostic technique that uses a piezoelectric sensor to detect ultrasonic elastic waves generated by the rapid release of energy from a localised source. Despite the ubiquity of the cylindrical cell format, AE techniques applied to this cell type are rare in literature due to the complexity of acoustic wave propagation in cylindrical architectures alongside the challenges associated with sensor coupling. Here, we correlate the electrochemical performance of cells with their AE response, examining the differences during pristine and aged cell cycling. AE data was obtained and used to train various supervised binary classifiers in a supervised setting, differentiating pristine from aged cells. The highest accuracy was achieved by a deep neural network model. Unsupervised machine learning (ML) models, combining dimensionality reduction techniques with clustering, were also developed to group AE signals according to their form. The groups were then related to battery degradation phenomena such as electrode cracking, gas formation, and electrode expansion. There is the potential to integrate this novel ML-driven approach for widespread cylindrical cell testing in both academic and commercial settings to help improve the safety and performance of lithium-ion batteries.

Polymer-based solid/semi-solid electrolytes in lithium ion batteries

Abstract The inception of lithium-ion batteries with liquid electrolytes can be traced back to the early 1980s. Nevertheless, the utilization of liquid electrolytes has many drawbacks, including its susceptibility to combustion, limited energy density, and very brief operational lifespan. Consequently, there is currently a concerted effort to substitute liquid electrolytes with solid compounds. This study investigates the electrochemical and mechanical features of solid/semi-solid electrolytes used in lithium ion batteries (LIBs) as well as their performance relative to conventional liquid electrolytes, with LIBs having unique challenges related to high flammability, electrochemical instability, and low mechanical stability posed by conventional liquid electrolytes versus solid polymer electrolytes (SPEs) which provide greater safety, mechanical stability but lower ionic conductivity than liquid counterparts. SPEs offer better safety but lack sufficient ionic conductivity which limits their potential. In order to overcome these obstacles, the implementation of gel-based and composite solid and semi-solid electrolytes is proposed as a means to improve ionic conductivity, electrochemical stability, and mechanical stability. The study suggests that a focus should be placed on solid composite electrolytes as they possess higher mechanical stability, which contributes to improved safety. Additionally, these electrolytes exhibit enhanced ionic conductivity within the range of 10−4 to 10−2 S/cm, hence enhancing the performance of LIBs.

Thermal management of lithium-ion batteries with direct and counter flow channels: A comparative study of different cooling fluids

The study addresses the crucial issue of thermal management in lithium-ion batteries (LIBs) and the maintenance of safe operational temperatures. It emphasizes the importance of efficient cooling mechanisms in preventing damage. A comparative analysis was conducted to assess the impact of various cooling fluids on the thermal performance of LIBs using direct and counter fluid flow channels. The study involved the use of different cooling fluids including water, water-glycol, Novec7000, mineral oil, and silicon oil. The researchers examined temperature variation, surface Stanton number (SN), surface Nusselt number (Nu), surface heat transfer coefficient (HTC), battery surface temperature, and pressure drop to evaluate the battery cooling process with different cooling configurations. The battery cooling part proved highly effective in managing heat, achieving a significant maximum temperature reduction of 30.70 % and 37.43 % for direct and counter flow channels, respectively. The Nu values of various fluids showed notable differences, with water-glycol showing a 3.76 % increase, Novec 7000 with an 11.39 % increase, mineral oil with a 15.46 % improvement, and silicon oil with a 20.09 % increase. The HTC values in the direct flow channel proved a consistent decrease from 16.09 to 57.73 to 11.07–25.69 W/m2K, respectively. Similarly, the HTC values for the counter flow channel ranged from 15.88 to 55.38 to 11.07–25.69 W/m2K. Additionally, it was seen that silicon oil outperformed other cooling fluids with a 6.0 % improvement in HTC in both direct flow and counter flow channels. The SN showed increases of 17.34 %, 20.11 %, 26.76 %, 29.57 %, and 29.60 %, respectively, at all five liquid flow velocities through the direct channel, and 19.39 %, 22.18 %, 28.34 %, 36.58 %, and 37.64 %, respectively, through the counter flow channel. These findings clearly show the superior heat transfer capabilities of silicon oil compared to other coolants. However, it is important to note that the use of silicon oil also resulted in a lower pressure drop, a critical consideration for ensuring efficient cooling. These findings have significant implications for the advancement of battery thermal management systems for electric vehicles, as designers can optimize the cooling process by considering different cooling configurations to enhance the thermal performance of battery packs while ensuring safe and stable operation.

A Review of Design Strategies in SiO/C Composite Anodes for Rechargeable Lithium-Ion Batteries.

Lithium-ion batteries (LIBs) are widely used in electric vehicles, portable electronic devices, clean energy storage, and other fields due to their long service life, high energy density, and low self-discharge rate, which also puts forward higher requirements for the performance of lithium-ion batteries. As an anode for lithium-ion batteries, SiO materials have garnered significant attention from researchers due to its high specific capacity (2400 mAh g-1), abundance of raw materials, and simple preparation. However, its large volume change (~200 %) and poor electrical conductivity hinder its large-scale commercial application. Researchers employ various methods to reduce the volume change of SiO during lithium intercalation and improve its structural stability during cycling. This work mainly reviews the chemical structure and lithium storage mechanism of SiO, as well as the latest research progress on the preparation methods of SiO/C anode materials, focusing on summarizing the following preparation strategies: chemical vapor deposition, mechanical ball milling, spray drying, and in-situ reduction/oxidation methods. The obtained SiO-based anode materials' structural characteristics and electrochemical properties are compared and summarized. Finally, this review discusses the advantages and disadvantages of the current preparation methods, the future research directions, and the development prospects of SiO-based anode materials.

Fabrication electro-spun Poly(vinyl alcohol)-Melamine nonwoven membrane composite separator for high-power lithium-ion batteries

Current commercial separators used in lithium-ion batteries have inherent flaws, especially poor thermal stability, which pose substantial safety risks. This study introduces a high-safety composite membrane made from electrospun poly(vinyl alcohol)-melamine (PVAM) and polyvinylidene fluoride (PVDF) polymer solutions via a dip coating method, designed for high-voltage battery systems. The poly(vinyl alcohol) and melamine components enhance battery safety, while the PVDF coating improves lithium-ion conductivity. The dip-coated PVDF/Esp-PVAM composite separators were evaluated for electrolyte uptake, contact angle, thermal stability, porosity, electrochemical stability and ionic conductivity. Notably, our Dip 1 % PVDF@Esp-PVAM composite separator exhibited excellent wettability and a lithium-ion conductivity of approximately 7.75 × 10⁻⁴ S cm⁻1 at room temperature. These separators outperformed conventional PE separators in half-cells with Ni-rich NCM811 cathodes, showing exceptional cycling stability with 93.4 % capacity retention after 100 cycles at 1C/1C, as compared to 84.8 % for PE separators. Our Dip 1 % PVDF@Esp-PVAM composite separator demonstrates significant potential for enhancing the long-term durability and high-rate performance of lithium-ion batteries, making it a promising option for long-term energy storage applications.

Optimizing porous medium electrode suspension drying: A numerical simulation

The drying process of porous medium electrodes is crucial for optimizing the performance of lithium-ion batteries. Among various drying methods, convection drying has been proven to be an effective double-sided and contactless technique for these electrodes, enhancing manufacturing quality and efficiency. This study investigates the impact of different drying parameters on the drying process of porous medium electrodes by establishing a coupling model for convective drying. The particle swarm algorithm optimized the drying parameters to minimizing drying time and energy consumption. As a result of this optimization, the optimal drying temperature and Reynolds number were found to be 104.77 °C and 3082.55, respectively. Furthermore, implementing a multi-stage drying process effectively prevents internal binder migration within the porous medium and ensures even distribution of components, thereby enhancing electrode performance. This study examines the effects of different multi-stage drying schemes on the drying time and energy consumption of porous medium electrodes based on the optimal drying parameters. The optimal multi-stage drying scheme, characterized by temperature profiles of 104.77 (0–15 s) − 90 (15–44 s) − 104.77 (>44 s) °C, was proposed to achieve both reduced drying time and low energy consumption. With this scheme, the drying process of porous medium electrodes achieved a suitable drying time of 137.50 s and a low energy consumption of 285 110.09 kJ/m3. The proposed model explores the drying process and provides valuable theoretical guidance for establishing appropriate drying parameters in the actual production of lithium-ion battery electrodes.

Application of porous carbon nanoelectrode materials for lithium-ion batteries

Abstract In order to achieve carbon neutrality and gradually improve the current global warming environmental situation, the world’s major research teams are committed to developing lithium-ion batteries with better performance, trying to use in various new energy facilities, such as electric vehicles, which can effectively reduce polluting gas emissions. Nowadays, many electrode materials that can improve the performance of lithium-ion batteries have been continuously emerging, such as carbon nanotubes and silicon-based nanomaterials. However, carbon nanotube electrode materials have the disadvantages of high irreversible capacity, voltage lag and high manufacturing cost, while silicon-based nanomaterials also have the drawbacks of volume expansion and poor electrical conductivity. Based on the mature research of carbon materials, extensive raw material sources and large reserves, completely non-toxic and low comprehensive cost, this research analyzes three new porous carbon nanoelectrode materials with high development potential, and shows their electrochemical performance advantages, such as high charge-discharge specific capacity, excellent rate performance, and low charge transfer impedance.

Robust silicon/carbon composite anode materials with high tap density and excellent cycling performance for lithium-ion batteries

Achieving high density while ensuring structural stability and low volume expansion during cycling remains challenging for Si-based anode materials in lithium-ion batteries (LIBs). Herein, we introduce a novel approach to address this issue by developing high tap-density carbon-coated sub-nano-Si-embedded activated carbon (ACSC) anode materials. The resulting ACSC exhibits an ultra-high true density exceeding 0.99 g cm−3 and a Si content of 48 % (abbreviated as ACS0.48C), leading to an impressive volumetric capacity of 2182 mA h cm−3. Despite the high tap density and Si content of ACS0.48C, the ACS0.48C/artificial graphite (ACS0.48C/AG) mixture demonstrates a remarkable capacity retention rate of 97.9 % after 200 cycles at 0.5 C, with a modest volume expansion rate of 7.3 % after 50 cycles. The outstanding electrochemical performance can be attributed to the structural stability of ACS0.48C throughout cycling. The AC scaffold provides a robust mechanical framework to prevent volume expansion and agglomeration of sub-nano-sized Si particles. Furthermore, the homogeneous mixing of amorphous Si and carbon at the atomic level ensures isotropic expansion, thereby enhancing structural stability. The unique structure of ACS0.48C, combining high tap density and superior cycling performance, offers a solution to the low tap density issue in nanostructures and introduces innovative concepts for the morphology and structural design of Si/C secondary particles.

How new nanomaterials can improve the performance of lithium batteries

Abstract In recent years, lithium batteries have become energy storage methods in many fields for their advantages of high energy density, and many fields such as civil electric vehicles, electronic products, and aerospace rely on lithium batteries. At present, the performance demand for lithium batteries in electric vehicles is increasing, and finding ways to improve the performance of lithium batteries has become a top priority. Since silicon has the highest theoretical specific capacity, carbon nanotube technology is relatively mature, and the research and development prospects of new negative electrode materials for nano-batteries are broad. This paper analyzes the different influences of nano-silicon-based materials, carbon nanotubes modified by new materials and new negative nano-lithium materials on lithium batteries from nanomaterials. And summarize their respective roles to help readers further understand the application of nanomaterials in lithium batteries. It is designed to help readers further understand the application of nanomaterials in lithium batteries.

Electrode design to improve the performance of batteries

Abstract The development of electric energy effectively improved the lack of energy and the environment damage causing by fossil fuel abuse. Batteries, as a common electric power source, can be able to provide no carbon emission or polluted air compared to internal combustion engine and is now replacing them in increasing number of fields. Among them, lithium-ion batteries (LIBs) hold the highest energy density and capacity, and own the most widely usage. However, their properties are still limited and confine the LIBs being used in more extremely condition. To solve the problems, scientists are now researching on every part of the LIBs, trying to create innovation and improve the LIBs performance. This summarize focuses on electrode design, summing up 4 types of electrode material choices researched by different groups and 10 manufacturing processes. Through them, the research will conclude the method of LIBs improvement and give direction for the further research.

The impact of integrated circuits’ performance in low-temperature environments on charging efficiency of chargers

Abstract This paper explores the current research status of chargers and lithium-ion batteries in low-temperature environments. Based on this, it provides a detailed discussion and analysis of charger charging conditions, lithium-ion battery performance analysis, the correlation between low-temperature environments and charging, and optimization design strategies for charging in low-temperature environments. The study reveals that low-temperature environments distort charger current harmonics, disrupt the power supply capacity of the grid, and reduce fast charging conversion efficiency. The paper elucidates the lithium-ion battery lithiation mechanism, lithiation detection methods, and countermeasures for lithiation issues in low temperatures. Besides highlighting the various adverse effects of lithiation on low-temperature charging, it also points out the shortcomings of detection methods and proposes appropriate strategies to inhibit lithiation. Addressing charging issues in low-temperature environments, the paper introduces charging optimization design strategies involving temperature-modulated current charging and genetic algorithm optimization. This research offers theoretical guidance and technical support for the design and optimization of chargers and lithium-ion batteries in low-temperature environments, further advancing the development and application of low-temperature charging technology.

Bismuth oxychloride nanosheets anchored aramid separator with sponge-like structure for improved lithium-ion battery performance

Functional modification of inorganic particles is an effective approach to tackle the issue of Li+ transport and the lithium dendrites formation in lithium-ion batteries (LIBs). In this study, PMIA/BiOCl composite separators are prepared by nonsolvent induce phase separation (NIPS) method using P-type semiconductor bismuth oxychloride (BiOCl) functionalized poly (m-phenylene isophthalamide) (PMIA) separators. Compared with the polypropylene (PP) separator, PMIA has superior thermal stability and the addition of BiOCl further enhances its flame retardancy. And the prepared PMIA/BiOCl separator presents improved porosity (66.47 %), enhanced electrolyte uptake rate (863 %) and higher ionic conductivity (0.49 mS∙cm−1). Besides, the incorporation of BiOCl can anchor PF6- to the three-dimensional network skeleton of the PMIA/BiOCl separators, enabling the desolvation of Li+ and selectively facilitating Li+ transport (the Li+ transfer number is 0.79). Moreover, the uniform porous structure of the PMIA/BiOCl separators and the efficient transport of Li+ uniformly deposite Li+, and minimize the growth of lithium dendrites. Batteries assembled with PMIA/BiOCl separators have a discharge specific capacity of 124.4 mAh∙g−1 and capacity retention of 96.7 % after 200 cycles at 0.2C. Therefore, this work provides an effective route in the design strategy of separators for LIBs.

Research Trends of Transition Metal Carbonate for Lithium-Ion Batteries

Transition Metal Carbonates (TMCs) have emerged as promising candidates for advancing the performance of lithium-ion batteries (LIBs), driven by the increasing demand for high energy and power density in applications such as electric vehicles. This review paper provides a comprehensive overview of the potential of TMCs as anode materials for LIBs, focusing on their unique electrochemical properties and mechanisms. TMCs offer advantages such as eco-friendliness, low cost, and high capacity compared to traditional graphite anodes. Their electrochemical stability, achieved through redox reactions of transition metals, enables capacities exceeding theoretical limits. However, challenges including volumetric expansion and low electrical conductivity during cycling hinder their rate performance and cycling stability. This paper discusses ongoing research efforts to address these challenges, including strategies to mitigate volumetric expansion and enhance electrical conductivity. Furthermore, the lithiophilic nature of TMCs’ transition metals is explored for its role in stabilizing lithium metal surfaces and interfaces within lithium metal batteries, contributing to improved battery performance and safety. Moreover, integrating carbon capture, utilization, and storage (CCUS) technologies into TMC synthesis offers environmentally friendly synthesis methods, aligning with sustainability goals and reducing the carbon footprint of battery manufacturing processes. Overall, this review highlights the potential of TMCs as anode materials for high-performance LIBs, while also addressing challenges and opportunities for further research and development in this promising field.

Experimental study on liquid immersion preheating of lithium-ion batteries under low temperature environment

An experimental platform to examine the effects of single-phase immersion preheating on lithium-ion battery performance at low temperatures was set up in this study. The performance of lithium-ion batteries at low temperatures can be improved through immersion preheating. After preheating from −15 °C to 15 °C, the battery capacity can recover to over 80 % of its rated capacity. The three influencing factors are inlet flow rate, fluid temperature, and cell spacings. The inlet temperature exerts the most influence on the preheating performance. The warming rate can reach 1.63 °C/min at a temperature of 50 °C. While the increase in flow rate has less influence on the heating rate, it has a greater impact on the temperature difference between cells. The maximum temperature difference between cells can still be kept below 4 °C. The impact of spacing on the heating rate and temperature difference is minimal. The temperature difference can be controlled within 6 °C. Finally, it's important to note that immersion preheating consumes significant amount of energy. The energy consumption of preheating at an ambient temperature of −25 °C exceeds 80 % of the rated capacity of the experimental battery pack.

Battery pack passive insulation strategies of electric vehicles under a frigid environment

Further application of electric vehicles (EVs) in frigid regions is hindered by the diminished performance of lithium-ion batteries (LIBs) at sub-zero temperatures. Developing efficient heat preservation strategies has significant implications for the broad application of EVs and LIBs. This study focuses on passive heat preservation strategies (PHPS) for battery packs in frigid environments (−30 °C). A validated 3D battery pack heat preservation model integrated with airflow is constructed in this paper, and the model analysis results indicate that arranging aerogels at the pack level provides superior heat preservation compared to cell and module levels. Additionally, the influence of flow field distribution (FFD) schemes on heat preservation performance is discovered. Both experimental and simulation results confirm that the proposed scheme can optimize the cooling rate to about 2.3 °C/h. Commencing from an initial temperature of 30 °C, extending the battery pack retention time above 0 °C to over 12 h under −30 °C can significantly expand the application of electric vehicles in frigid regions. This paper explores the primary factors affecting the heat dissipation of battery packs in the frigid temperature environment, which have great significance in guiding the heat preservation design of battery systems.

Optimization of Lithium-ion battery thermal performance using dielectric fluid immersion cooling technique

Lithium-ion batteries (LIBs) are crucial for portable electronics, electric vehicles, and renewable energy systems. However, conventional cooling techniques for LIBs struggle to efficiently dissipate heat during rapid charging and discharging, potentially compromising performance and safety. This study explores the immersion cooling technique to optimize the thermal performance of 4S2P LIB module at 3 C discharge rate. The MSMD-NTGK battery model is utilized in numerical simulation to analyze the electrochemical and thermal characteristics of LIBs. Initially, static and forced convection immersion cooling methods are compared using two different cooling media: ester-oil and air. Static convection with ester oil reduces temperature rise by 8.3 % compared to natural air convection, while forced convection with ester oil achieves optimal temperatures (< 5 °C) at a fluid velocity of 0.077 m/s (20 LPM), lower than forced air convection. Furthermore, the study enhances forced convection with ester oil-based immersion cooling for LIB with different inlet and outlet structural designs. Among these, the middle inlet and middle outlet-center (MIMO-C) flow model demonstrates optimal temperature at reduced flow rate of 5 LPM and minimal pressure drop of 230 Pa compared to others. These findings underscore the potential of forced convection-based immersion cooling to improve LIB performance and lifespan.

Deciphering the Lithium-Ion Conduction Mechanism of LiH in Solid-Electrolyte Interphase.

Lithium hydride (LiH) has been widely recognized as the critical component of the solid-electrolyte interphase (SEI) in Li batteries. Although the formation mechanism and structural model of LiH in SEI have been extensively reported, the role in electro-performance of LiH in SEI is stillambiguous and has proven challenging to explored due to the complicated structure SEI and the lack of advanced in situ experimental technology. In this study, the isotopic exchange experiments combined with isotopic tracer experiments is applied to solidly illustrate the superior conductivity and Li+ conduction behavior of the LiH in natural SEI. Importantly, in situ transmission electron microscopy analysis is utilized to visualize the self-electrochemical decomposition of LiH, which is significantly distinctive from LiF and Li2O. The critical experimental evidence discovered by the work demonstrates ion transport behaviors of key components in the SEI, which is imperative for designing novel SEI and augurs a new area in optimizing the performance of lithium batteries.

Battery Performance Evaluation through Decision Tree

This study addresses the pervasive concern surrounding battery performance degradation in electronic devices. While some attribute this decline to device aging, a significant portion of the population lacks awareness of the precise factors contributing to diminished battery efficiency. Consequently, the research investigates the factors related to battery performance, aiming to identify the determinants of reduced efficiency. Decision trees are used to meticulously analyze the intricate relationships between variables and discern the factors that respondents perceive as causative of diminished battery performance. This algorithm is chosen since, in predicting high-capacity lithium-ion battery performance, the decision tree outperforms other algorithms in machine learning in accuracy. The study elucidates diverse user preferences, with 55.38% favoring Android and 44.62% expressing a preference for iOS, indicating disparate perceptions of battery health: 61.54% consider their batteries as "Good," while 38.46% acknowledge a decline. The decision tree analysis of 195 participants underscores the pronounced impact of prolonged usage on battery health, revealing that 95% maintain good battery performance. In contrast, 27.69% of Android users face reduced battery performance, emphasizing the need for targeted user education and Android manufacturers to prioritize device longevity. The ultimate objective is to give readers a comprehensive understanding of the dynamics of battery performance in the context of device aging and its contributing factors and give some input to manufacturers and service providers.

The first-principles study of 2D monolayer T-Mo2C as promising anode material for Lithium-ion Batteries

The growing demand for renewable energy technologies emphasizes the necessity for advancements in anode materials to enhance the performance of lithium-ion batteries (LIBs). In this research, we employ first-principles calculations to investigate the properties of a T-Mo2C monolayer proposed as an anode material. Phonon dispersion calculations and ab initio molecular dynamics (AIMD) simulations are conducted to assess the dynamical stability and thermal characteristics of the T-Mo2C monolayer as an anode material. Remarkably low diffusion barriers of 0.029 eV (Li) and 0.01 eV (Na and K) have been identified, facilitating rapid ion mobility. Furthermore, a monolayer of metal ions (M = Li, Na, K) absorbed onto T-Mo2C is explored, revealing a high specific capacity of approximately 1314.37 mAh/g (Li), 262.87 mAh/g (Na), and 32.85 mAh/g (K). The average open circuit voltage is determined to be 0.08 V (Li), 0.68 V (Na), and 2.59 V (K). This research provides a comprehensive overview of T-Mo2C monolayer as a high-capacity anode material, emphasizing its significant contributions to advancing energy storage systems, particularly in the context of LIBs. The findings presented here pave the way for the development of efficient and sustainable energy storage solutions to meet the escalating demands of the renewable energy landscape.

Tailoring amino-functionalized cellulose separators for improved lithium-ion battery performance

This study aims to enhance cellulose separators for energy storage, focusing on achieving high security and superior electrolyte wetting properties. Bacterial cellulose (BC) separators were initially prepared via vacuum filtration. Subsequently, carboxymethyl cellulose (CMC) underwent amino-functionalization by successfully cross-linking polyethyleneimine (PEI) using glutaraldehyde. The amino-functionalized CMC was then composited onto the BC separator. This composite separator demonstrated excellent thermal stability at 200 °C and favorable electrolyte wetting. The amino groups in PEI enhanced Li+ migration by forming hydrogen bonds with PF6− in the electrolyte. Additionally, molecular-level hydrogen bonding between amino groups on PEI and carboxyl/hydroxyl groups in CMC regulated the separator's porosity. The abundant carboxyl groups in CMC facilitated Li+ transfer, notably boosting the lithium-ion battery's electrochemical performance. After 90 charge and discharge cycles, the discharge capacity of the battery assembled with BC/CMC-PEI composite separator is 132.8 mAh/g, which is 25.1 % higher than the 106.1 mAh/g of the battery assembled with traditional PP separator. At a current density of 2C, the minimum discharge capacity of the battery assembled with the composite separator is 71.1 mAh/g, while the minimum discharge capacity of the battery assembled with the PP separator is 53.6 mAh/g. This approach using functional group modification provides a promising approach to improving the performance of lithium-ion batteries.