The August 2014 issue of Physics Today contains a letter (page 8) in which M. Y. Amusia comments on the article “Bohr’s molecular model, a century later” by Anatoly Svidzinsky, Marlan Scully, and Dudley Herschbach (Physics Today, January 2014, page 33). Amusia points out that the radial part of the article’s D-dimensional Schrödinger equation in Hartree units isand he criticizes the implication that the Coulomb potential does not depend on D, which it surely does. Half a century ago, following up on the work of Paul Ehrenfest,11. P. Ehrenfest, Proc. Amsterdam Acad. 20, 200 (1917); Ann. Phys. Leipzig 61, 440 (1920). who had studied the hydrogen atom in n spatial dimensions using Bohr orbit theory, I reformulated the problem22. F. R. Tangherlini, Nuovo Cimento 27, 636 (1963). https://doi.org/10.1007/BF02784569 using Schrödinger’s equation extended to n dimensions, in which I had the Coulomb potential for n ≥ 3. I did not include the Coulomb potential for n = 1,2, as discussed by Amusia, as I was only interested in the stability of the higher-dimensional atom for n > 3. (For the dimensionality of space I used “n” rather than “D.”) In that work I gave the radial equation equivalent to the one above: I wrote, “If we now transform to n-dimensional polar coordinates, introduce n-dimensional spherical harmonics, and factor out the angular dependence,33. See, for example, A. Sommerfeld, Partial Differential Equations in Physics, E. G. Straus, trans., Academic Press (1949), app. 4. the resulting radial equation takes the formIn my paper, I did not eliminate the dR/dr term to arrive at a form equivalent to the first equation. However, that is readily done by setting R = r−(n − 1)/2ϕ and generalizing to nuclear charge Z, and setting n → D. The reason I have the D-dependent Coulomb potential for D > 3 and the article authors do not is that they have a different goal—to gain new insight into the real, atomic-molecular 3D world using the limiting behavior of the D-dimensional kinetic energy. In contrast, as indicated above, I was only interested in whether the D-dimensional Schrödinger “hydrogen atom” would have stable bound states for D > 3.REFERENCESSection:ChooseTop of pageREFERENCES <<CITING ARTICLES1. P. Ehrenfest, Proc. Amsterdam Acad. 20, 200 (1917); Google ScholarAnn. Phys. Leipzig 61, 440 (1920). Google Scholar2. F. R. Tangherlini, Nuovo Cimento 27, 636 (1963). https://doi.org/10.1007/BF02784569, Google ScholarCrossref3. See, for example, A. Sommerfeld, Partial Differential Equations in Physics, E. G. Straus, trans., Academic Press (1949), app. 4. Google Scholar© 2015 American Institute of Physics.
Read full abstract