Women’s participation in political processes is important to address gender inequality and strengthen democracy. In Indian context, to empower women and enable political participation, 73rd Constitutional Amendment Act (1992) was introduced. Subsequently, many women entered politics. Though widespread proxy is reported, still a small proportion engages effectively in governmental participation (Hust, 2002; Mathew, 2003; Palanithurai, 2001). Studies also find female Dalit-headed panchayats are more active (Jayshree, 2010; Kalaiselvi, 2012). As the cultural norms, traditions and patriarchy are rigid, the paper attempts to examine what helps the women to be functional? Does social networks differ? Is there a link between social capital, by way of associationalism, and capacity for self governance as suggested by Putnam (1993) in the Indian context? Social capital is understood through social networks and membership in associations. Thirty-eight elected representatives of Panchayati Raj Institutions of southern Tamil Nadu, south India was interviewed in depth. Active members prominently belong to Dalit community and the social network of the elected active members is larger in size, heterogeneous in terms of age, gender and caste composition, and they are anchors themselves. They are primarily embedded in a web of political, caste and self-help group associations and have access to all women police stations, cooperative societies and political parties through family ties. The elected representative’s mandatory membership in district Dalit federations provides safety-net in dealing with discrimination and atrocities while also intervening at the village-level panchayat. Dalit women who have the capacity to mobilize social capital emerge efficient in local self governance.