Partial Orientation Research Articles

Electrolyte jet tomography: Three-dimensional microstructure mapping with an electrochemical machine tool and an optical microscope

There is a general separation between the manufacturing processes that add value to materials on the factory floor and the techniques engineers use in the laboratory to evaluate the microstructures and the surface integrity that results. These techniques are often destructive or require a vacuum and are incompatible with production lines. However, this information has intrinsic value and could be exploited to inform production decisions during manufacture. In this study, a novel approach to acquire this information is presented that is underpinned by electrolyte jet machine tool coupled with optical microscopy, which can allow the extraction of both grain-wise partial orientation and morphological information, and crystallographic macro textures in three dimensions. Here, iterative sections are precisely machined into the near surface of a commercially pure titanium alloy using an electrochemical jet and subsequently imaged, allowing the reconstruction of high-fidelity microstructure models rapidly and under ambient conditions. In doing so, new insights into the specific orientation-dependent dissolution mechanisms are offered, and the acquisition of appropriate conditions that result in nanoscale roughness surfaces (avoiding the dominance of pitting and preferential grain removal) is firstly explored. Building on prior work, a piecewise approach is presented to analyse the acquired image stacks to map partial crystal orientations, while different approaches are proposed to account for jet-specific surface artefacts and waviness. This is repeated over 20 layers in an individual specimen and layer-wise orientation maps are used to construct volumetric models of the specimen. These data sets are then explored from the perspective of materials/manufacturing engineers, who may use to this information to effect advancements to materials processing technologies.

Simplified channel model for indoor VLC systems.

The channel model of indoor visible light communication (VLC) is primarily influenced by the receiver's position and orientation. In this study, we decouple the effects of receiver position and orientation, treating them as independent random variables. This decoupling enables a clearer understanding of how each factor independently influences the channel model. Specifically, we focus on the impact of the azimuth angle, a critical component of orientation, on the VLC channel. We present a simplified channel model for indoor VLC systems based on partial orientation information. Theoretical analysis and simulation results collectively indicate that the accuracy of the simplified channel model is influenced by the field-of-view (FOV), with higher accuracy achieved at narrower FOVs. To evaluate practical performance, we compare our simplified model with the existing complete channel model in a two-user precoding system. Results show that our proposed simplified channel model maintains value, particularly in narrow-FOV scenarios. The research findings indicate that this simplified model is suitable for applications with high demands for channel accuracy in narrow-FOV indoor VLC systems, and can be extended to applications in wide-FOV systems where perfect channel information is not required.

Surface crack effect on frequency and vibration mode switching of solar-powered aerospace structures

In the engineering design of modern wing panels and their optimal control system, the first step is to find and predict their dynamic characteristics. These characteristics are dependent on material properties, panel geometry, and boundary conditions. In addition, possible fracture existence, imperfections and environmental conditions may unpredictably change the frequency and modes shape of the panel and then the parameters of a control system. In the present paper, the effect of surface fracture depth and orientation on frequency and vibration mode switching of perovskite solar cells-based aircraft wing panels is investigated for the first time. The PSC (perovskite solar cell) panel is made of a polymer substrate reinforced with even-distributed graphene platelets (GPLs) and thin solar layers to enhance the overall electromechanical performance of the whole structure. Equations of motion of the panel are obtained by the Hamilton approach based on the properties of Reddy's third-order shear deformation theory and linear components of the Green-Lagrange strain tensor. The novel aspect is a line-spring model of surface crack by Cartmell et al. adapted to the model of the PSC panel under consideration. The discretization of the established equations of motion for the cracked panel is carried out by the element-free IMLS-Ritz method with mesh-free features. Validation of the obtained solutions is carried out by comparisons with results from previous studies for cracked laminated plates.First, material and geometric properties effect on vibration characteristics of the PSC structure was investigated. Next, partial surface crack depth and orientation angle are examined to show changes in frequency and vibration modes shape of the panel. It is shown, that there is a mode swapping between the second and third modes when transitioning from an intact panel to a cracked one. As the crack length increases, higher-order mode variations become more noticeable, potentially leading to their swapping or the excitation of new ones. Additionally, the findings demonstrate that the surface crack orientation angle significantly impacts the higher-order modes of the panel. When the orientation angle is 90°, the first six modes align with those of the intact plate. Mode shapes and frequency shifts are significant for crack orientation angles between 0° and 90°.

PVDF/PI/BT nanocomposites with excellent charge/discharge efficiency obtained by inserting linear polymer to adjust the ferroelectricity

The problem of low charge/discharge efficiency of ceramic/polymer composites is still one of the hot topics in current research on dielectric materials. Here, we demonstrate that the ferroelectric property of ceramic/PVDF-based composites can be modulated by the introduction of linear polymer PI and the use of a spin-coating process. PI inhibits some polarization and partial dipole orientation by interacting with the molecular chains of the amorphous phase of PVDF and BT nanoparticles. As a result, the decrease in crystallinity and loss led to improved dielectric properties and charge/discharge efficiency. The findings demonstrate that the microstructure of PVDF-PI/BT nanocomposite is uniform and dense, with outstanding dielectric characteristics and high charge/discharge efficiency. The permittivities were stabilized in the range of 12.87–17.86 at 100 Hz, and the dielectric losses were all less than 0.27. Compared with the previously reported binary ceramic/polymer composites, the PVDF-PI/BT nanocomposites possessed a high charge/discharge efficiency with a small variation (63%-84%). This work offers an easy and efficient scheme to obtain nanocomposites with outstanding dielectric characteristics and charge/discharge efficiency. It may be a potential candidate for flexible dielectric substrates for advanced flexible capacitive energy storage devices.

Pragmatic Implications of Contextual Constraints and Delivery Styles in Selected Academic Sermons

Academic sermons (preaching tests) which depend largely on pragmatic choices, are used to determine the preachers’ quality and qualification for theological certification. Previous studies on religious discourse have not recognised the influence of delivery constraints on the overall output of academic sermons. This study, therefore, examined the pragmatic implications of the preachers’ choices. The study adopted aspects of pragmatic act theory. Stratification and purposive sampling methods were used to select three seminaries from which data were gathered. The penultimate year student-pastors were purposively selected for data collection and data were subjected to pragmatic analysis. Four performance contexts and six delivery styles with eight strategies demonstrated training-induced delivery constraints, which conditioned preachers’ pragmatic designs and determined their level of compliance to training in the Nigerian Baptist Theological Seminaries. The perfect orientation to narrative and prescriptive styles suggested compliance to training, but the partial orientation and complete disorientation to analytical, invocational, affiliative and professing styles implied pragmatic misadjustment and professional deficiencies with implications for pastoral competence.

Decompositions of the λ-Fold Complete Mixed Graph into Mixed 6-Stars

Graph and digraph decompositions are a fundamental part of design theory. Probably the best known decompositions are related to decomposing the complete graph into 3-cycles (which correspond to Steiner triple systems), and decomposing the complete digraph into orientations of a 3-cycle (the two possible orientations of a 3-cycle correspond to directed triple systems and Mendelsohn triple systems). Decompositions of the λ-fold complete graph and the λ-fold complete digraph have been explored, giving generalizations of decompositions of complete simple graphs and digraphs. Decompositions of the complete mixed graph (which contains an edge and two distinct arcs between every two vertices) have also been explored in recent years. Since the complete mixed graph has twice as many arcs as edges, an isomorphic decomposition of a complete mixed graph into copies of a sub-mixed graph must involve a sub-mixed graph with twice as many arcs as edges. A partial orientation of a 6-star with two edges and four arcs is an example of such a mixed graph; there are five such mixed stars. In this paper, we give necessary and sufficient conditions for a decomposition of the λ-fold complete mixed graph into each of these five mixed stars for all λ>1.

Manipulating Vertical Phase Separation Enables Pseudoplanar Heterojunction Organic Solar Cells Over 19% Efficiency via Ternary Polymerization.

Controlling vertical phase separation of the active layer to enable efficient exciton dissociation and charge carrier transport is crucial to boost power conversion efficiencies (PCEs) of pseudoplanar heterojunction (PPHJ) organic solar cells (OSCs). However, how to optimize the vertical phase separation of PPHJ OSCs via molecule design is rarely reported yet. Herein, ternary polymerization strategy is employed to develop a series of polymer donors, DL1-DL4, and regulate their solubility, molecular aggregation, molecular orientation, and miscibility, thus efficiently manipulating vertical phase separation in PPHJ OSCs. Among them, DL1 not only has enhanced solubility, inhibited molecular aggregation and partial edge-on orientation to facilitate acceptor molecules, Y6, to permeate into polymer layer and increase donor/acceptor interfaces, but also sustains high crystallinity and appropriate miscibility with Y6 to acquire ordered molecular packing, thus achieving optimized vertical phase separation to well juggle exciton dissociation and charge transport in PPHJ devices. Therefore, DL1/Y6 based PPHJ OSCs gain the best exciton dissociation probability, highest charge carrier mobilities and weakest charge recombination, and thus afford an impressive PCE of 19.10%, which is the record value for terpolymer donors. It demonstrates that ternary polymerization is an efficient method to optimize vertical phase separation in PPHJ OSCs for high PCEs.

Non-uniform orientation of H2 molecules in a magnetic field as a critical condition for the appearance of partially negative NMR lines of o-H2 in hyperpolarization experiments using p-H2.

In hyperpolarization experiments using parahydrogen, a partially negative line (PNL) of o-H2 is occasionally spotted in the nuclear magnetic resonance (NMR) spectra. This is a manifestation of the two-spin order (TSO) of the proton spins, appearing transiently in o-H2 molecules freshly derived from p-H2. For the TSO to be observable, the o-H2 NMR signal must be split into a doublet. In the literature, the splitting is believed to originate from a slow exchange of the dissolved dihydrogen with the dihydride moiety bound to a catalyst present in the reaction mixture. Because this hypothesis may be debatable, in this work a different splitting mechanism is proposed. It employs a residual dipolar coupling (RDC) between the hydrogen protons, originating from a partial orientation of the H2 molecules by the external magnetic field. The orientation effect is due to the anisotropic magnetic polarizability of H2. In a magnetic field of 11.74T at room temperature, the currently predicted value of the RDC is -0.0024Hz. Even such small RDC values are sufficient for the PNL effect to be clearly visible in NMR spectra for physically reasonable levels of the TSO in the o-H2 molecules. For RDC values much smaller than the natural linewidth of o-H2, the theoretical frequency distance between the minimum and maximum of PNL proves to be practically independent of the RDC and is of the order of the linewidth. The calculated amplitudes of the PNLs are proportional to the RDC values used in the calculations.

Structure and Properties of Thin Magnetron Films of Cadmium Arsenide on Various Substrates

Purpose of the study. Synthesis of cadmium arsenide magnetron films on various substrates and study of their structure, composition, optical and electrical properties.Methods. The deposition of thin films of cadmium arsenide was carried out by the method of non-reactive highfrequency magnetron sputtering in an argon atmosphere. The structure and composition of the films were studied using X-ray phase analysis, scanning electron microscopy, energy dispersive analysis, and small-angle X-ray diffractometry. Optical studies were performed using Raman spectroscopy. The results of a study of the electrical properties of thin films of cadmium arsenide are presented.Results. On silicon, sapphire, and strontium titanate substrates, thin films of the Dirac semimetal, cadmium arsenide, were obtained with a thickness of about 40 nm. A study of their structure and composition showed a significant effect of annealing in an argon atmosphere following deposition on the crystallinity of the film. After annealing, regardless of the crystal structure of the substrate, partial orientation of the film with the (112) texture axis. The films closest to the stoichiometric composition were obtained by deposition followed by annealing onto an oriented strontium titanate substrate, and to the crystal structure of cadmium arsenide single crystals of a film on a sapphire substrate. Annealing also leads to a smoothing of the film surface, a decrease in structural defects, and the transition of the fractal dimension of its topology to two-dimensional from close to three-dimensional immediately after deposition. The optical properties after annealing also change, which indicates their transition from a polycrystalline (amorphous) state to a single-crystal (textured).Conclusion. Experimental studies of the structure and properties performed by various methods made it possible to establish that single-crystal or textured cadmium arsenide films suitable for studying the manifestation of topological properties can be obtained by controlled annealing.

Closing live video streams: A sequential analysis

Research has argued that “ordinary conversation” and its organization are foundational to “institutional” talk (Drew & Heritage, 1992), and that institutional forms can be characterized as constraints on such a sequential organization. Such an argument can be extended to technology-mediated interaction, in which participants may orient jointly to “standard” conversational sequences and the technology’s interactional “affordances” to achieve interactional ends. We discuss here how such an interactional goal (closing a technology-mediated encounter) may be achieved in live video streaming. We argue that while participants can be seen to do that in a way that orients to the organization of closings in ordinary conversation, they do so in a way that is sensitive to the affordances of live video streams. We find that: a) Most of the streams involve closing sequences, thus framing the live stream as a social encounter for which closing is relevant; b) A partial and relaxed orientation to talking heads configuration in live stream closings; c) A four-part closing sequence; d) Two different topic development in closing the live streams—a topic message comes from the audience and some “mentionable noticeables” initiated by the streamer.

A Haptic Shared Autonomy With Partial Orientation Regulation for DoF Deficiency in Remote Side.

Orientation regulation permits an autonomous controller to regulate the operators' orientation commands automatically. Although kinds of orientation regulation strategies have been proposed for various purposes, few works have focused on the partial orientation regulation (POR), which requires an autonomous controller to prevent the unreachable rotational motion for safety, while preserving the remaining motions for intuitiveness. However, the POR is deeply demanded for systems with Degree-of-Freedom (DoF) deficiency in remote side. The POR is a more challenging task owing to: First, it is difficult to decompose an orientation into reachable and unreachable components due to the non-linear structure of the rotation group SO(3). Second, it is non-trivial to design a haptic rendering algorithm which can indicate the missing DoF information to human operators. To address the rotational DoF deficiency, we propose a haptic shared autonomy with POR ability, based on the perpendicular curve theory in SO(3). The proposed method can partially regulate the operator's orientation command to discard the unreachable motions and preserve the remaining motions for follower robots. Here the conventional "master" and "slave" are all replaced by "leader" and "follower" to avoid the concern of association to racism and human subjugation. In addition, a haptic rendering algorithm is designed to display correct haptic cues about the missing DoF to operators. The simulation and experimental results validate the effectiveness of the proposed method.

Structure of Filter Cakes during the Electroassisted Filtration of Microfibrillated Cellulose

Microfibrillated cellulose (MFC) is a biobased material with unique properties that can be used in a multitude of applications. Water removal from the dilute product streams is, however, challenging and hinders its commercial attractiveness. One possible method of improving dewatering is the use of electroassisted filtration, in which an electric field is applied across part of the filter chamber. In this work, a bench-scale dead-end filter press, modified to allow for electroassisted filtration, was used to dewater a suspension of MFC produced via 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO)-mediated oxidation. A filter cake was produced with a channeled structure related to the design of the anode mesh, indicating that the cellulose microfibrils were aligned in the direction of the electric field. This was investigated, qualitatively and quantitively, using scanning electron microscopy and wide-angle X-ray scattering, which showed a preferred orientation on a microscopic level but only a partial orientation on a molecular level (fc between 0.49 and 0.57). The influence of the density of the anode mesh, in terms of the structure/permeability of the filter cake and dewatering rate, was also evaluated using two different anode mesh densities (5 × 5 and 10 × 10 mm). It was not, however, found to have any major impact on the dewatering rate.

Factors Associated with Disclosure of Sexual Orientation Among Black Sexual Minority Men.

Purpose: This study evaluated the characteristics associated with sexual orientation disclosure among HIV-negative Black sexual minority men (BSMM) in the greater Atlanta, Georgia area. Survey data were collected from 475 HIV-negative BSMM from 2017 to 2019 as part of a larger behavioral intervention study focused on stigma, prejudice, and HIV-testing uptake. Methods: Participants reported their levels of sexual orientation disclosure globally, to their community, and to their family. Data were analyzed using one-way analysis of variance and multinomial logistic regression to determine whether demographic, minority stress, substance use, and mental health were associated with sexual orientation disclosure globally, to community members, and to family members. Results: Findings revealed that participants with older age, bisexual identity, and higher levels of internalized homophobia had higher odds of global, community, and family sexual orientation nondisclosure. Furthermore, participants with higher levels of resilience had lower odds of partial sexual orientation disclosure compared with their fully disclosed counterparts. Conclusions: These findings reveal variations associated with sexual orientation disclosure across varying contexts among HIV-negative BSMM, particularly among family member disclosure.

Tomsquarryite, NaMgAl3(PO4)2(OH)6 ● 8H2O, a new crandallite-derivative mineral from Tom's phosphate quarry, Kapunda, South Australia

Abstract. Tomsquarryite, NaMgAl3(PO4)2(OH)6 ⚫ 8H2O, is a new secondary phosphate mineral from Tom's phosphate quarry, Kapunda, South Australia. It occurs as colourless, talc-like hexagonal platelets, with diameters of a few tens of micrometres when formed from the decomposition of minyulite and as thicker (∼ 10 µm) hexagonal crystals when formed from alteration of gordonite. Associated minerals are penriceite, elliottite, minyulite, angastonite and wavellite. The calculated density is 2.22 g cm−3. Tomsquarryite crystals are uniaxial (+) with ω=1.490(3), ε=1.497(3) (white light). Dispersion was not observed. The partial orientation is Z≈c. Electron microprobe analyses of the holotype specimen give the empirical formula Na1.02K0.02Ca0.08Mg1.26Al2.86(PO4)2.00(OH)3.82F2.48 ⚫ 7.70H2O, based on 22 anions. Tomsquarryite belongs to the trigonal crystal system, space group R–3m, with hexagonal unit-cell parameters a=6.9865(5) Å, c=30.634(3) Å and V=1294.9(4) Å3 and with Z=3. The crystal structure was refined using single-crystal diffraction data; R1=0.069 for 303 reflections with I>2σ(I) to a resolution of 0.80 Å. The crystal structure is a derivative of the crandallite structure, with Ca2+ cations replaced by hydrated magnesium ions, [Mg(H2O)6]2+, resulting in an expansion of the interlayer separation from 5.4 Å in crandallite to 10.2 Å in tomsquarryite. The results for tomsquarryite are compared with those for the chemically and structurally related minerals penriceite and elliottite.

Additive Manufacturing

Abstract: Additive manufacturing is a recent trend in manufacturing processes due to its many advantages. It can be defined as the process of manufacturing parts by depositing materials layer by layer. It has been a subject of intense study and examination by many scholars. The development of additive manufacturing as a leading technology and its different stages will be discussed. The importance of partial orientation, construction time estimates and cost calculations were also discussed. A notable aspect of this work was the identification of problems associated with different additive manufacturing methods. Due to the imperfections of additive manufacturing, its hybridization with other methods, such as subtraction manufacturing, has been highlighted.

Enhancement of the creation yield of NV ensembles in a chemically vapour deposited diamond

In this work we investigate the properties of negatively charged nitrogen-vacancy (NV−) centres created during single crystal diamond growth by chemical vapour deposition (CVD) on [113]-oriented substrates and with N2O as a dopant gas. The use of spin echo and double electron-electron resonance (DEER) allows us to assess NV− ratio with respect to substitutional nitrogen impurities (Ns0) incorporated during growth, a critical figure of merit for quantum technologies. We demonstrate that, at moderate growth temperatures (800 °C), dense NV− ensembles of several hundreds of ppb (800 ppb for 50 ppm of added N2O) and with exceptionally high NV−/ Ns0 ratios of up to 25% can be achieved. This NV− creation yield is higher by at least an order of magnitude to that typically obtained on standard [100]-grown diamonds and comparable to the best values reported for electron-irradiated diamonds. The material obtained here thus advantageously combines a high NV− density, high creation yield, long coherence times of several tens of μs together with a partial preferential orientation. These are highly desirable requirements for diamond-based quantum sensors that may spur new developments with this crystalline orientation leading to improved performance and sensitivity.

Elastocaloric and Magnetocaloric Effects Linked to the Martensitic Transformation in Bulk Ni55Fe11Mn7Ga27 Alloys Produced by Arc Melting and Spark Plasma Sintering

The investigation of caloric effects linked to first-order structural transitions in Heusler-type alloys has become a subject of considerable current interest due to their potential utilization as refrigerants in solid-state cooling devices. This study is mainly motivated by the possibility of developing refrigeration devices of improved energy efficiency with a reduced environmental impact. We produced partially textured and isotropic bulk samples of the Heusler-type magnetic shape memory alloy Ni55Fe11Mn7Ga27 by arc melting and spark plasma sintering (SPS), respectively. Their structural, microstructural, and phase transition characteristics and magnetocaloric and elastocaloric effects, associated with first-order martensitic transformation (MT), were studied. The elemental chemical compositions of both samples were close to nominal, and a martensitic-like structural transformation appeared around room temperature with similar starting and finishing structural transition temperatures. At room temperature, austenite exhibited a highly ordered L21-type crystal structure. The partial grain orientation and isotropic nature of the arc-melted and SPS samples, respectively, were revealed by X-ray diffraction and SEM observations of the microstructure. For the arc-melted sample, austenite grains preferentially grew in the (100) direction parallel to the thermal gradient during solidification. The favorable effect of the texture on the elastocaloric response was demonstrated. Finally, due to its partial grain orientation, the arc-melted bulk sample showed superior values of maximum magnetic entropy change (|ΔSM|max = 18.6 Jkg−1K−1 at 5 T) and elastocaloric adiabatic temperature change (|ΔTadme|max = 2.4 K at 120 MPa) to those measured for the SPS sample (|ΔSM|max = 8.5 Jkg−1K−1 and (|ΔTadme|max = 0.8 K).

SAVREMENI FRANKOFONI PISCI U NASTAVI FRANCUSKOG KAO STRANOG JEZIKA: PERIOD IZMEĐU DVA SVETSKA RATA

The paper examines the problem of representation of contemporary Francophone writers in high school teaching of the French language between the two world wars, which, given the curriculum requirements at the higher cycle of Yugoslav grammar schools and high schools, involved the use of textbooks based on literary texts. Although we find important individu- als from universities, such as Bogdan Popović, among the authors of French textbooks, the texts of Francophone writers were included only in Radoje Knežević’s textbooks. Referring to the results of mostly contemporary literary research and applying the descriptive-analytical method, the issue in the title was studied from the aspect of the importance of writers, the representativeness of selected texts and the degree of their linguistic complexity. Starting from the assumption that Knežević had previously consulted the best known French anthologies, we can state that his selection of Francophone writers truly reflected the reputation they gained in the European literature. Thus, the younger students in the higher cycle were introduced to the creator of comic books, Töpffer, through an excerpt from the story of his uncle, while older students had the opportunity to get acquainted with parts of Amiel’s personal diary, as well as with the poetry of Belgian giants of symbolism Rodenbach, Verhaeren and Maeterlinck. Considering the fact that articles on literary texts in French language teaching were very rarely published during the interwar period, we can only speculate on the approach of teachers in the process of processing. In any case, these were representative texts that were generally not par- ticularly demanding in terms of linguistics, which enabled a quality reception. The representa- tion of the mentioned Francophone writers represented a deviation from the traditional choice of French literary classics and a partial orientation towards contemporary literature written in French, which is a significant didactic and pedagogical and literary novelty.

MS-HLMO: Multiscale Histogram of Local Main Orientation for Remote Sensing Image Registration

Multi-source image registration is challenging due to intensity, rotation, and scale differences among the images. Considering the characteristics and differences of multi-source remote sensing images, a feature-based registration algorithm named Multi-scale Histogram of Local Main Orientation (MS-HLMO) is proposed. Harris corner detection is first adopted to generate feature points. The HLMO feature of each Harris feature point is extracted on a Partial Main Orientation Map (PMOM) with a Generalized Gradient Location and Orientation Histogram-like (GGLOH) feature descriptor, which provides high intensity, rotation, and scale invariance. The feature points are matched through a multi-scale matching strategy. Comprehensive experiments on 17 multi-source remote sensing scenes demonstrate that the proposed MS-HLMO and its simplified version MS-HLMO$^+$ outperform other competitive registration algorithms in terms of effectiveness and generalization.

Insights into cation-anion hydrogen bonding in mesogenic ionic liquids: an NMR study.

The hydrogen-bonding interaction is studied in imidazolium-based mesogenic ionic liquids in their isotropic, smectic, and solid phases and in a nanoconfined state by proton solid-state nuclear magnetic resonance (NMR). In the smectic phase, the more basic anions form stronger hydrogen bonds. A small decrease of H-bonding in the mesophase with respect to that in the isotropic phase is associated with the presence of a layered assembly with high orientational order and limited conformational freedom. Hydrogen bond strength is not sensitive to the cation structural modification as long as the aprotic nature of the material is preserved. The strong cation-anion hydrogen bonding observed in the smectic phases provides direct support for the presence of ionic sublayers which form in ionic liquid crystals regardless of the location and alignment of the charged group in the cation, particularly irrespective of whether the charged group occupies a terminal or central position in the cation structure. A comparison of the results obtained in isotropic, liquid-crystalline, and solid states shows that in the bulk materials the dynamic state of ions ranging from high reorientational and translational freedom to partial orientation and positional order to full immobilization, respectively, has no strong impact on the cation-anion hydrogen bond strength. On the other hand, nanoconfinement of ionic liquid crystals led to hydrogen bond disruption due to competing interactions of anions with a solid interface.