Orion Bar Research Articles

The ALMA view of UV-irradiated cloud edges: unexpected structures and processes

AbstractFar-UV photons (FUV, E < 13.6 eV) from hot massive stars regulate, or at least influence, the heating, ionization, and chemistry of most of the neutral interstellar medium (H i and H2 clouds). Investigating the interaction between FUV radiation and interstellar matter (molecules, atoms and grains) thus plays an important role in astrochemistry.The Orion Bar, an interface region between the Orion A molecular cloud and the H ii region around the Trapezium cluster, is a textbook example of a strongly illuminated dense PDR (photodissociation region). The Bar is illuminated by a FUV field of a few 104 times the mean interstellar radiation field. Because of its proximity and nearly edge-on orientation, it provides a very good template to investigate the chemical content, structure, and dynamics of a strongly irradiated molecular cloud edge. We have used ALMA to mosaic a small field of the Bar where the critical transition from atomic to molecular gas takes place. These observations provide an unprecedented sharp view of this transition layer (≲ 1″ resolution or ≲ 414 AU). The resulting images (so far in the rotational emission of CO, HCO+, H13CO+, SO+, SO, and reactive ions SH+ and HOC+) show the small-scale structure in gas density and temperature, and the steep abundance gradients. The images reveal a pattern of high-density substructures, photo-ablative gas flows and instabilities at the edge of the molecular cloud. These first ALMA images thus show a more complex morphology than the classical clump/interclump static model of a PDR.In order to quantify the chemical content in strongly FUV-irradiated gas, we have also used the IRAM-30 m telescope to carry out a complete line-survey of the illuminated edge of the Bar in the millimeter domain. Our observations reveal the presence of complex organic molecules (and precursors) that were not expected in such a harsh environment. In particular, we have reported the first detection of the unstable cis conformer of formic acid (HCOOH) in the ISM. The energy barrier to internal rotation (the conversion from trans to cis) is approximately 4827 cm−1 (≈7000 K). Hence, this detection is surprising. The low inferred trans-to-cis abundance ratio of 2.8±1.0 supports a photoswitching mechanism: a given conformer absorbs a FUV stellar photon that radiatively excites the molecule to electronic states above the interconversion barrier. Subsequent fluorescent decay leaves the molecule in a different conformer form. This mechanism, which we have specifically studied with ab initio quantum calculations, was not considered so far in astrochemistry although it can affect the structure of a variety of molecules in PDRs.

Herschel/HIFI spectral line survey of the Orion Bar

Photon Dominated Regions (PDRs) are interfaces between the mainly ionized and mainly molecular material around young massive stars. Analysis of the physical and chemical structure of such regions traces the impact of far-ultraviolet radiation of young massive stars on their environment. We present results on the physical and chemical structure of the prototypical high UV-illumination edge-on Orion Bar PDR from an unbiased spectral line survey with a wide spectral coverage. A spectral scan from 480-1250 GHz and 1410-1910 GHz at 1.1 MHz resolution was obtained by the HIFI instrument onboard the Herschel Space Observatory. For molecules with multiple transitions we used rotational diagrams to obtain excitation temperatures and column densities. For species with a single detected transition we used an optically thin LTE approximation. In case of species with available collisional rates, we also performed a non-LTE analysis to obtain kinetic temperatures, H2 volume densities, and column densities. About 120 lines corresponding to 29 molecules (including isotopologues) have been detected in the Herschel/HIFI line survey, including 11 transitions of CO, 7 transitions of 13CO, 6 transitions of C18O, 10 transitions of H2CO, and 6 transitions of H2O. Most species trace kinetic temperatures in the range between 100 and 150 K and H2 volume densities in the range between 10^5 and 10^6 cm^-3. The species with temperatures and / or densities outside of this range include the H2CO transitions tracing a very high temperature (315 K) and density (1.4x10^6 cm^-3) component and SO corresponding to the lowest temperature (56 K) measured as a part of this line survey. The observed lines/species reveal a range of physical conditions (gas density /temperature) involving structures at high density / high pressure, obsoleting the traditional 'clump / interclump' picture of the Orion Bar.

Spatial distribution of FIR rotationally excited CH+ and OH emission lines in the Orion Bar PDR.

The methylidyne cation (CH+) and hydroxyl (OH) are key molecules in the warm interstellar chemistry, but their formation and excitation mechanisms are not well understood. Their abundance and excitation are predicted to be enhanced by the presence of vibrationally excited H2 or hot gas (~500-1000 K) in photodissociation regions with high incident FUV radiation field. The excitation may also originate in dense gas (> 105 cm-3) followed by nonreactive collisions with H2, H, and electrons. Previous observations of the Orion Bar suggest that the rotationally excited CH+ and OH correlate with the excited CO, a tracer of dense and warm gas, and formation pumping contributes to CH+ excitation. Our goal is to examine the spatial distribution of the rotationally excited CH+ and OH emission lines in the Orion Bar in order to establish their physical origin and main formation and excitation mechanisms. We present spatially sampled maps of the CH+ J=3-2 transition at 119.8 µm and the OH Λ-doublet at 84 µm in the Orion Bar over an area of 110″×110″ with Herschel (PACS). We compare the spatial distribution of these molecules with those of their chemical precursors, C+, O and H2, and tracers of warm and dense gas (high-J CO). We assess the spatial variation of CH+ J=2-1 velocity-resolved line profile at 1669 GHz with Herschel HIFI spectrometer observations. The OH and especially CH+ lines correlate well with the high-J CO emission and delineate the warm and dense molecular region at the edge of the Bar. While notably similar, the differences in the CH+ and OH morphologies indicate that CH+ formation and excitation are strongly related to the observed vibrationally excited H2. This, together with the observed broad CH+ line widths, indicates that formation pumping contributes to the excitation of this reactive molecular ion. Interestingly, the peak of the rotationally excited OH 84 µm emission coincides with a bright young object, proplyd 244-440, which shows that OH can be an excellent tracer of UV-irradiated dense gas. The spatial distribution of CH+ and OH revealed in our maps is consistent with previous modeling studies. Both formation pumping and nonreactive collisions in a UV-irradiated dense gas are important CH+ J=3-2 excitation processes. The excitation of the OH Λ-doublet at 84 µm is mainly sensitive to the temperature and density.

Modelling clumpy photon-dominated regions in 3D

Context. Models of photon-dominated regions (PDRs) still fail to fully reproduce some of the observed properties. In particular they do not reproduce the combination of the intensities of different PDR cooling lines together with the chemical stratification, as observed for example for the Orion Bar PDR.

Trans-cis molecular photoswitching in interstellar Space.

As many organic molecules, formic acid (HCOOH) has two conformers (trans and cis). The energy barrier to internal conversion from trans to cis is much higher than the thermal energy available in molecular clouds. Thus, only the most stable conformer (trans) is expected to exist in detectable amounts. We report the first interstellar detection of cis-HCOOH. Its presence in ultraviolet (UV) irradiated gas exclusively (the Orion Bar photodissociation region), with a low trans-to-cis abundance ratio of 2.8 ± 1.0, supports a photoswitching mechanism: a given conformer absorbs a stellar photon that radiatively excites the molecule to electronic states above the interconversion barrier. Subsequent fluorescent decay leaves the molecule in a different conformer form. This mechanism, which we specifically study with ab initio quantum calculations, was not considered in Space before but likely induces structural changes of a variety of interstellar molecules submitted to UV radiation.

THE ORION H ii REGION AND THE ORION BAR IN THE MID-INFRARED

ABSTRACT We present mid-infrared photometry of the Orion bar obtained with the Faint Object infraRed Camera for the SOFIA Telescope (FORCAST) on board SOFIA at 6.4, 6.6, 7.7, 19.7, 31.5, and 37.1 μm. By complementing this observation with archival FORCAST and Herschel/PACS images, we are able to construct a complete infrared spectral energy distribution of the Huygens region in the Orion nebula. Comparing the infrared images with gas tracers, we find that PACS maps trace the molecular cloud, while the FORCAST data trace the photodissociation region (PDR) and the H ii region. Analysis of the energetics of the region reveal that the PDR extends for 0.28 pc along the line of sight and that the bar is inclined at an angle of 4°. The infrared and submillimeter images reveal that the Orion bar represents a swept-up shell with a thickness of 0.1 pc. The mass of the shell implies a shock velocity of ≃3 km s−1 and an age of ≃105 years for the H ii region. Our analysis shows that the UV and infrared dust opacities in the H ii region and the PDR are a factor 5 to 10 lower than in the diffuse interstellar medium. In the ionized gas, Lyα photons are a major source of dust heating at distances larger than ≃0.06 pc from θ 1 Ori C. Dust temperatures can be explained if the size of the grains is between 0.1 and 1 μm. We derive the photoelectric heating efficiency of the atomic gas in the Orion bar. The results are in good qualitative agreement with models and the quantitative differences indicate a decreased polycyclic aromatic hydrocarbon abundance in this region.

Astrophysics: Violent emissions of newborn stars.

Interactions between young stars and their parent molecular clouds are poorly understood. High-resolution observations of the Orion nebula now reveal these interactions, which have implications for star formation. See Letter p.207 The feature in the Orion nebula known as the Orion Bar provides astronomers with a clear edge-on view of a molecular cloud surface and the associated transition from atomic to molecular gases. One-arcsecond-resolution millimetre-wave images of this region obtained by the ALMA radio telescope reveal a fragmented ridge of high-density substructures, photoablative gas flows and instabilities, which suggest that the cloud edge has been compressed by a high-pressure wave expanding into the molecular cloud, in contrast to predictions from static equilibrium models.

Compression and ablation of the photo-irradiated molecular cloud the Orion Bar.

The Orion Bar is the archetypal edge-on molecular cloud surface illuminated by strong ultraviolet radiation from nearby massive stars. Owing to the close distance to Orion (about 1,350 light-year), the effects of stellar feedback on the parental cloud can be studied in detail. Visible-light observations of the Bar1 show that the transition between the hot ionised gas and the warm neutral atomic gas (the ionisation front) is spatially well separated from the transition from atomic to molecular gas (the dissociation front): about 15 arcseconds or 6,200 astronomical units. (One astronomical unit is the Earth-Sun distance.) Static equilibrium models2,3 used to interpret previous far-infrared and radio observations of the neutral gas in the Bar4,5,6 (typically at 10-20 arcsecond resolution) predict an inhomogeneous cloud structure consisting of dense clumps embedded in a lower density extended gas component. Here we report 1 arcsecond resolution millimetre-wave images that allow us to resolve the molecular cloud surface and constrain the gas density and temperature structures at small spatial scales. In contrast to stationary model predictions7,8,9, there is no appreciable offset between the peak of the H2 vibrational emission (delineating the H/H2 transition) and the edge of the observed CO and HCO+ emission. This implies that the H/H2 and C+/C/CO transition zones are very close. These observations reveal a fragmented ridge of high-density substructures, photo-ablative gas flows and instabilities at the molecular cloud surface. They suggest that the cloud edge has been compressed by a high-pressure wave that currently moves into the molecular cloud. The images demonstrate that dynamical and nonequilibrium effects are important. Thus, they should be included in any realistic description of irradiated interstellar matter.

SUBMILLIMETER/THz ROTATIONAL SPECTROSCOPY OF SH+(${X}^{3}{{\rm{\Sigma }}}^{-}$): THE COMPLETEN= $1\leftarrow 0$ TRANSITION

The N = 1 0 transition of SH ( in its complete fine structure multiplet (J = 0 1, 2 1, and 1 1) has been measured using submillimeter/THz direct absorption spectroscopy in the frequency range near 346–683 GHz. This work is the first direct laboratory measurement of the J = 0 1 and 1 1 spin components. This molecular ion was created in the gas phase from a mixture of H2S and argon in an AC discharge. Hyperfine components, arising from the nuclear spin of H (I = 1/2), were resolved in every fine structure multiplet. The data have been analyzed using a Hund's case Hamiltonian, resulting in further improvement in the accuracy of the rotational, spin–rotation, spin–spin, and magnetic hyperfine constants for SH From these new data, frequency predictions have been made for the N = 2 1 and 3 2 transitions, with an estimated uncertainty of less than 1 MHz. These data also confirm the recent detection of the two hyperfine components of the N = 1 0, J = 0 1 transition of SH in the Orion Bar, as well as the J = 1 1 component of this molecular ion near 683 GHz toward Sgr B2.

Water in the interstellar media of galaxies

AbstractThis paper reviews recent observations of water in Galactic interstellar clouds and nearby galactic nuclei. Two results are highlighted: (1) Multi-line H2O mapping of the Orion Bar shows that the water chemistry in PDRs is driven by photodissociation and -desorption, unlike in star-forming regions. (2) High-resolution spectra of H2O and its ions toward 5 starburst / AGN systems reveal low ionization rates, unlike as found from higher-excitation lines. We conclude that the chemistry of water strongly depends on radiation environment, and that the ionization rates of interstellar clouds decrease by at least 10 between galactic nuclei and disks.

The chemistry and spatial distribution of small hydrocarbons in UV-irradiated molecular clouds: the Orion Bar PDR(Corrigendum)

The chemistry and spatial distribution of small hydrocarbons in UV-irradiated molecular clouds: the Orion Bar PDR<i>(Corrigendum)</i>

Widespread galactic CF+absorption: detection toward W49 with the Plateau de Bure Interferometer

To study the usefulness of \CFP\ as a tracer of the regions where C\p\ and \HH\ coexist in the interstellar medium. We used the Plateau de Bure Interferometer to synthesize \CFP\ J=1-0 absorption at 102.6 GHz toward the core of the distant HII region W49N at l = 43.2\degr, b=0.0\degr, and we modeled the fluorine chemistry in diffuse/translucent molecular gas. We detected \CFP\ absorption over a broad range of velocity showing that \CFP\ is widespread in the \HH-bearing Galactic disk gas. Originally detected in dense gas in the Orion Bar and Horsehead PDR, \CFP\ was subsequently detected in absorption from diffuse and translucent clouds seen toward \bll\ and 3C111. Here we showed that \CFP\ is distributed throughout the diffuse and translucent molecular disk gas with N(\CFP)/N(\HH) $= 1.5-2.0\times10^{-10}$, increasing to N(\CFP)/N(\HH) $= 3.5\times10^{-10}$ in one cloud at 39 \kms\ having higher N(\HH) $\approx 3\times10^{21}\pcc$. Models of the fluorine chemistry reproduce the observed column densities and relative abundance of HF, from which \CFP\ forms, but generally overpredict the the column density of \CFP\ by factors of 1.4-4. We show that a free space photodissociation rate $\Gamma \ga 10^{-9}\ps$, comparable to that of CH, might account for much of the discrepancy but a recent calculation finds a value about ten times smaller. In the heavily blended and kinematically complex spectra seen toward W49, \CFP\ absorption primarily traces the peaks of the \HH\ distribution.

C2H observations toward the Orion Bar

C$_2$H is one of the first radicals to be detected in the interstellar medium. Its higher rotational transitions have recently become available with the Herschel Space Observatory. We aim to constrain the physical parameters of the C$_2$H emitting gas toward the Orion Bar. We analyse the C$_2$H line intensities measured toward the Orion Bar CO$^+$ Peak and Herschel/HIFI maps of C$_2$H, CH, and HCO$^+$, and a NANTEN map of [CI]. We interpret the observed C$_2$H emission using radiative transfer and PDR models. Five rotational transitions of C$_2$H have been detected in the HIFI frequency range toward the CO$^+$ peak. A single component rotational diagram gives a rotation temperature of ~64 K and a beam-averaged C$_2$H column density of 4$\times$10$^{13}$ cm$^{-2}$. The measured transitions cannot be explained by any single parameter model. According to a non-LTE model, most of the C$_2$H column density produces the lower-$N$ C$_2$H transitions and traces a warm ($T_{\rm{kin}}$ ~ 100-150 K) and dense ($n$(H$_2$)~10$^5$-10$^6$ cm$^{-3}$) gas. A small fraction of the C$_2$H column density is required to reproduce the intensity of the highest-$N$ transitions ($N$=9-8 and N=10-9) originating from a high density ($n$(H$_2$)~5$\times$10$^6$ cm$^{-3}$) hot ($T_{\rm{kin}}$ ~ 400 K) gas. The total beam-averaged C$_2$H column density in the model is 10$^{14}$ cm$^{-2}$. Both the non-LTE radiative transfer model and a simple PDR model representing the Orion Bar with a plane-parallel slab of gas and dust suggest, that C$_2$H cannot be described by a single pressure component, unlike the reactive ion CH$^+$, which was previously analysed toward the Orion Bar CO$^+$ peak. The physical parameters traced by the higher rotational transitions ($N$=6-5,...,10-9) of C$_2$H may be consistent with the edges of dense clumps exposed to UV radiation near the ionization front of the Orion Bar.

The chemistry and spatial distribution of small hydrocarbons in UV-irradiated molecular clouds: the Orion Bar PDR

We study the spatial distribution and chemistry of small hydrocarbons in the Orion Bar PDR. We used the IRAM-30m telescope to carry out a millimetre line survey towards the Orion Bar edge, complemented with ~2'x2' maps of the C2H and c-C3H2 emission. We analyse the excitation of the detected hydrocarbons and constrain the physical conditions of the emitting regions with non-LTE radiative transfer models. We compare the inferred column densities with updated gas-phase photochemical models including 13CCH and C13CH isotopomer fractionation. ~40% of the lines in the survey arise from hydrocarbons (C2H, C4H, c-C3H2, c-C3H, C13CH, 13CCH, l-C3H and l-H2C3). We detect new lines from l-C3H+ and improve its rotational spectroscopic constants. Anions or deuterated hydrocarbons are not detected: [C2D]/[C2H]<0.2%, [C2H-]/[C2H]<0.007% and [C4H-]/[C4H]<0.05%. Our gas-phase models can reasonably match the observed column densities of most hydrocarbons (within factors <3). Since the observed spatial distribution of the C2H and c-C3H2 emission is similar but does not follow the PAH emission, we conclude that, in high UV-flux PDRs, photodestruction of PAHs is not a necessary requirement to explain the observed abundances of the smallest hydrocarbons. Instead, gas-phase endothermic reactions (or with barriers) between C+, radicals and H2 enhance the formation of simple hydrocarbons. Observations and models suggest that the [C2H]/[c-C3H2] ratio (~32 at the PDR edge) decreases with the UV field attenuation. The observed low cyclic-to-linear C3H column density ratio (<3) is consistent with a high electron abundance (Xe) PDR environment. In fact, the poorly constrained Xe gradient influences much of the hydrocarbon chemistry in the more UV-shielded gas. We propose that reactions of C2H isotopologues with 13C+ and H atoms can explain the observed [C13CH]/[13CCH]=1.4(0.1) fractionation level.

Submillimeter Polarimetry with PolKa, a Reflection-Type Modulator for the APEX Telescope

Imaging polarimetry is an important tool for the study of cosmic magnetic fields. In our Galaxy, polarization levels of a few up to ∼10% are measured in the submillimeter dust emission from molecular clouds and in the synchrotron emission from supernova remnants. Only few techniques exist to image the distribution of polarization angles as a means of tracing the plane-of-sky projection of the magnetic field orientation. At submillimeter wavelengths, polarization is either measured as the differential total power of polarization-sensitive bolometer elements, or by modulating the polarization of the signal. Bolometer arrays such as LABOCA at the APEX telescope are used to observe the continuum emission from fields as large as in diameter. Here we present PolKa, a polarimeter for LABOCA with a reflection-type waveplate of at least 90% efficiency. The modulation efficiency depends mainly on the sampling and on the angular velocity of the waveplate. For the data analysis, the concept of generalized synchronous demodulation is introduced. The instrumental polarization toward a point source is at the level of ∼0.1%, increasing to a few percent at the -10 db contour of the main beam. A method to correct for its effect in observations of extended sources is presented. Our map of the polarized synchrotron emission from the Crab nebula is in agreement with structures observed at radio and optical wavelengths. The linear polarization measured in OMC1 agrees with results from previous studies, while the high sensitivity of LABOCA enables us to also map the polarized emission of the Orion Bar, a prototypical photon-dominated region.

Physical parameters of the Orion Bar photodissociation region from radio recombination line observations at 8 mm

Observations of carbon (C), hydrogen and helium (H, He) radio recombination lines (RRLs) at four positions in the Orion Bar photodissociation region (PDR) and toward the center of Orion A have been performed with the RT-22 radio telescope (Pushchino) at 8 mm. The physical parameters of the PDR at these points have been estimated by comparing the carbon RRLs and infrared CII and OI lines. A hydrogen number density in the range 1.2–3.1 × 105 cm−3 and a mean size of the region along the line of sight (L) in the range 0.006–0.04 pc have been derived. The PDR temperature decreases with increasing distance from the exciting star (θ 1 C Ori) from 210–230 to 140–150 K (a distance of ≈5′). The data obtained confirm the increase in the PDR size along the line of sight toward the Orion Bar, where, however, L has turned out to be less than the available values in the literature, which can be explained by the presence of clumps in the PDR. A density jump is evident in the Orion Bar region. The PDR zone encompasses the core of the HII region by a thin layer and extends farther, delineating the boundary and the ionization front of the core of the HII region in the Orion Bar and further out the boundary between the halo of the HII region and the molecular cloud. The derived emission measure (EM) toward the Orion Bar has been compared with other C RRL observations. The EM measured from carbon RRLs is EM ≈ 100(±50%) pc cm−6, imposing constraints on the possible two-component PDR structure. Estimates show that the star θ 1 C Ori is quite sufficient as a carbon ionization source in the Orion Bar PDR. Some of the data on the ionized hot gas (HII) in this direction have been obtained from H and He RRLs. In particular, the radial velocities (V lsr) of the HII region are blueshifted with respect to V lsr of the PDR by 10–17 km s−1, while the relative ionized helium abundance decreases with increasing distance from the star, indicating that the helium ionization zone is smaller than the ionized hydrogen one.

Revised spectroscopic parameters of SH(+) from ALMA and IRAM 30m observations.

Hydrides represent the first steps of interstellar chemistry. Sulfanylium (SH(+)), in particular, is a key tracer of energetic processes. We used ALMA and the IRAM 30 m telescope to search for the lowest frequency rotational lines of SH(+) toward the Orion Bar, the prototypical photo-dissociation region illuminated by a strong UV radiation field. On the basis of previous Herschel/HIFI observations of SH(+), we expected to detect emission of the two SH(+) hyperfine structure (HFS) components of the NJ = 10-01 fine structure (FS) component near 346 GHz. While we did not observe any lines at the frequencies predicted from laboratory data, we detected two emission lines, each ~15 MHz above the SH(+) predictions and with relative intensities and HFS splitting expected for SH(+). The rest frequencies of the two newly detected lines are more compatible with the remainder of the SH(+) laboratory data than the single line measured in the laboratory near 346 GHz and previously attributed to SH(+). Therefore, we assign these new features to the two SH(+) HFS components of the NJ = 10-01 FS component and re-determine its spectroscopic parameters, which will be useful for future observations of SH(+), in particular if its lowest frequency FS components are studied. Our observations demonstrate the suitability of these lines for SH(+) searches at frequencies easily accessible from the ground.

A CSO search for l-C3H+: detection in the Orion Bar PDR

The results of a Caltech Submillimeter Observatory (CSO) search for $l$-C$_3$H$^+$, first detected by Pety et al. (2012) in observations toward the Horsehead photodissociation region (PDR), are presented. A total of 39 sources were observed in the 1 mm window. Evidence of emission from $l$-C$_3$H$^+$ is found in only a single source - the Orion Bar PDR region, which shows a rotational temperature of 178(13) K and a column density of 7(2) x $10^{11}$ cm$^{-2}$. In the remaining sources, upper limits of ~10$^{11} - 10^{13}$ cm$^{-2}$ are found. These results are discussed in the context of guiding future observational searches for this species.

Herschel SPIRE FTS spectral mapping calibration

The Herschel SPIRE Fourier transform spectrometer (FTS) performs spectral imaging in the 447-1546 GHz band. It can observe in three spatial sampling modes: sparse mode, with a single pointing on sky, or intermediate or full modes with 1 and 1/2 beam spacing, respectively. In this paper, we investigate the uncertainty and repeatability for fully sampled FTS mapping observations. The repeatability is characterised using nine observations of the Orion Bar. Metrics are derived based on the ratio of the measured intensity in each observation compared to that in the combined spectral cube from all observations. The mean relative deviation is determined to be within 2%, and the pixel-by-pixel scatter is ~7%. The scatter increases towards the edges of the maps. The uncertainty in the frequency scale is also studied, and the spread in the line centre velocity across the maps is found to be ~15 km/s. Other causes of uncertainty are also discussed including the effect of pointing and the additive uncertainty in the continuum.

SEARCH FOR THE INFRARED EMISSION FEATURES FROM DEUTERATED INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS

We report the results of a search for emission features from interstellar deuterated polycyclic aromatic hydrocarbons (PAHs) in the 4um region with the Infrared Camera (IRC) onboard AKARI. No significant excess emission is seen in 4.3-4.7um in the spectra toward the Orion Bar and M17 after the subtraction of line emission from the ionized gas. A small excess of emission remains at around 4.4 and 4.65um, but the ratio of their intensity to that of the band emission from PAHs at 3.3-3.5um is estimated as 2-3%. This is an order of magnitude smaller than the values previously reported and also those predicted by the model of deuterium depletion onto PAHs. Since the subtraction of the ionized gas emission introduces an uncertainty, the deuterated PAH features are also searched for in the reflection nebula GN 18.14.0, which does not show emission lines from ionized gas. We obtain a similar result that excess emission in the 4um region, if present, is about 2% of the PAH band emission in the 3um region. The present study does not find evidence for the presence of the large amount of deuterated PAHs that the depletion model predicts. The results are discussed in the context of deuterium depletion in the interstellar medium.