Organic Matter Enrichment Mechanism Research Articles

Palaeoenvironment evolution and organic matter enrichment mechanisms of the Wufeng-Longmaxi shales of Yuanán block in western Hubei, middle Yangtze: Implications for shale gas accumulation potential

The deposition of black shale is influenced by several factors, including organic matter input, which is controlled by primary productivity; preservation, which is governed by redox conditions and deposition rates; and dilution, which is controlled by terrigenous input. However, determining the individual contribution of these factors to organic matter enrichment (OME) is complex due to significant variations in palaeodepositional conditions across different regions. In this study, we aimed to investigate the palaeoenvironmental conditions and OME mechanisms in the Wufeng-Longmaxi Formation in western Hubei by integrating data on total organic carbon (TOC) content, mineral compositions, and major and trace elements. We also examined the rapid variations in the palaeoenvironment, which led to the mass extinction in the Late Ordovician. Our findings indicate that dolomite siltstone and silty dolomite are present in the Guanyinqiao Formation (GYQ), which differs from other regions. The silica in the Wufeng-Longmaxi Formation has a mainly nonhydrothermal origin, while the upper Wufeng Formation (WF) has an entirely biogenic source. The organic-rich shales were primarily deposited in a warm and humid climate with low terrigenous input, low salinity, dysoxic conditions, and moderate to high palaeoproductivity due to moderate to strong upwelling. The GYQ serves as a transitional section from the WF to the Longmaxi Formation, which was characterized by a cold climate, oxic conditions, weak upwelling, and deposition in a strongly restricted setting, potentially leading to the mass extinction. Overall, OME was primarily dominated by preservation, with factors that influenced OME changing vertically. Palaeoproductivity, combined palaeoproductivity and palaeoredox conditions, and palaeoredox conditions were the main controlling factors in the WF, the Lower Longmaxi Formation (LLMX), and the Upper Longmaxi Formation (ULMX), respectively. Additionally, the Huangling basement, a submarine high, and the Xuefeng uplift's uplift and compression played important roles in OME. However, shale gas exploration prospects in the study area are limited due to the thinness of the organic-rich shales, oxic to dysoxic conditions, and relatively low palaeoproductivity.

Organic geochemistry and organic matter enrichment mechanisms of the lacustrine source rocks from a small-faulted Basin: A case study of the Bayindulan, A'er and Wuliyasitai sags in the Erlian Basin, Northern China

Lacustrine organic-rich shales in the lower Tengger member (K1bt1) are the most important source rocks in the Erlian Basin. The Erlian Basin contains many sags with independent subsidence-sedimentation histories, structure styles and hydrocarbon exploration potential. A comprehensive study was carried out to investigate the organic geochemical characteristics of the shales from three typical sags (the Bayindulan, A'er and Wuliyasitai sags) in the Erlian Basin to define the differences to their depositional environment, dominant source material, and hydrocarbon generation potential in small-faulted basins. Kerogen types in these shales in the study area can be classified into type Ⅱ1-Ⅰ kerogen in the Bayindulan Sag, type Ⅱ2 to type Ⅱ1 in the A'er Sag and type Ⅱ2 in the Wuli Sag. Biomarker characteristics indicate that the dominant algae-sourcing organic matter (OM) in the shales in the Bayindulan Sag was formed under the salty and reducing conditions. Source rocks from the A'er Sag were formed under the fresh-brackish and weak reducing-weak oxidizing conditions with a mixing input of algae and higher plants. Organic-rich shales from the Wuli Sag were deposited under the fresh water and oxidizing environment with a terrestrially dominated organic matter input. The correlation among parameters including average chain length (ACL) of C25–C33n-alkanes, the aquatic/macrophytes proxy (Paq), TAR, the proportion of saropelinite, the wax indexes, Pr/Ph, and TOC were used to investigate the main controlling factors of the enrichment of the organic matter in these three sags. The organic matter accumulation models on the formation of high-quality shales in the Erlian Basin are anisotropic due to various depositional environments and biological sources of source rocks in different regions. The characteristics of organic matter accumulation in the Erlian Basin can be classified into three patterns. Firstly, the good preservation condition that favored the accumulation of organic matter is the main controlling factor resulting in the organic matter enrichment in the Bayindulan Sag. Secondly, the bloom of algae in nutrient-rich surface water favored the accumulation of OM in the A'er Sag. Finally, large influx of vascular plants in the oxygen-rich condition is the main factor leading to the formation of the high-quality shales in the Wuli Sag. Further, these three organic matter accumulation models could be used for reference in the assessment of the petroleum potential of the faulted basins that are similar with the Erlian Basin.

Mechanisms for the Accumulation of Organic Matter in Sediments of the Middle Permian around Bogda Mountain, Southern Junggar Basin, NW China

The organic-rich shales and mudstones of the Middle Permian are the most important unconventional petroleum targets in the southern Junggar Basin of northwestern China. Although numerous studies have been vigorously conducted on paleoenvironment reconstructions, the organic matter enrichment mechanism is still controversial due to the utilization of problematic geochemical proxies established in early studies. In this study, major and trace elemental compositions, molecular markers, stable carbon isotopic compositions, and organic petrology were used to study multiple factors affecting the accumulation of organic matter in sediments. According to the results, a relatively hydrostatic, brackish, anoxic environment is proposed in the northern periphery of the Bogda Mountain, where the original structure of organic matter could be preserved with non-correlations between the productivity proxies (P and Ba) and TOC. In the western Bogda area, organic-rich sediments were deposited under suboxic conditions, with frequent fluctuation occurring between the top and bottom water columns. The accumulation of organic matter was the result of productivity blooms and rapid sedimentation. This improved study of the enrichment of organic matter in the Middle Permian around the Bogda Mountain can contribute to improved evaluations of the petroleum potential and distinguishing the characteristics of different organic matter enrichment models.

Geochemical characteristics of shales from the first member of Qingshankou Formation in Gulong Sag, Songliao Basin, China: Implication for mechanism of organic matter enrichment

Commercial oil production from the first member of the Qinshankou Formation in the Songliao Basin, China has proven it can be a promising target for shale oil recovery. However, geochemical characteristics and the mechanism of organic matter (OM) enrichment in this layer remain unknown. Herein, a large number of samples collected from the first member were analyzed through a combination of organic and inorganic geochemical methods. Results show, bedding oil shale and laminated shale are prominent facies in this member. Moreover, this member mainly consists of type-I and –II kerogen at highly thermal mature stage, belonging to good to excellent source rock. Overall, this member has been deposited in the semi-humid to humid and warm paleoclimate, fresh to brackish water mass, and dysoxic to anoxic conditions. This member is enriched in P2O5, indicating the high primary productivity. Moreover, lack of relation between P2O5, with Al2O3 and Fe2O3 concentrations, suggests that the contribution of terrigenous detritus influx and the effect of Fe cycle for P enrichment in sediments can be disregarded. The terrigenous detritus influx, rapid sedimentation rate and marine transgression were found to be detrimental to the OM enrichment. Moreover, more serious oxygen deficiency in water mass along with slightly lower sedimentation rate, made the lower part of this member to yield better preservation conditions and weaker dilution effect, which resulted in the formation of OM with better quality and higher abundance. Collectively preservation conditions were found to be significant for the OM enrichment.

Organic matter enrichment mechanism of Youganwo Formation oil shale in the Maoming Basin

The Youganwo Formation oil shale located in the Maoming Basin represents a large commercially valuable lacustrine oil shale resource and a potential bio-shale gas reservoir in South China. With the aim of deepening the understanding of factors that influence organic matter enrichment, this research conducted a geochemical investigation to reconstruct the depositional paleoenvironment of bioproductivity, preservation and dilution. Youganwo Formation oil shale is mainly deposited in semi-deep to deep-lake environments with relatively warm and humid paleoclimate in the subtropical-temperate zone. The total organic carbon (TOC) content (1.46–11.85%), S2 values (4.79–115.80 mg HC/mg rock) and HI (328–1040 mg HC/mg TOC) indicate that the oil shale has a good oil source rock potential. TOC content, (S1 + S2) values and vitrinite reflectance values show that its marginally mature organic matter (OM) belongs to kerogen type I-III with good oil-generating potential.A 3rd order sequence was identified in the Yougnwo formation. Subsequently, the multiple factors including bioproductivity, preservation and dilution that control the OM enrichment of oil shale within system tracts were discussed. Moderate-quality oil shales (Oy-1) were developed in the transgressive systems tract (TST) in an oxidizing condition with abundant detrital input. High-quality oil shales (Oy-2) were deposited during the high-stand systems tract (HST) with increased accommodation space, improved preservation conditions, warm and humid climate, higher water bioproductivity and minimum detrital matter input. During the regressive systems tract (RST, Oy-3), higher detrital matter input and fresher water led to lower TOC values. Among these multiple factors, dilution condition was the major one that influences OM abundance and variation on the basis of sufficient organic matter input. Thus, OM enrichment models of Oy-1, Oy-2 and Oy-3 sub-members were established. The OM enrichment and quality in oil shale were controlled by the combined effect of bioproductivity, preservation, and dilution.

Climate fluctuations during the Ordovician-Silurian transition period in South China: Implications for paleoenvironmental evolution and organic matter enrichment

The Ordovician-Silurian (OS) transition witnessed dramatic tectonic, climatic, marine, and biological coevolution, during which organic-rich black shale was widely deposited and is considered an important source rock. However, the potential links between the differential enrichment pattern of organic matter and climate fluctuations and paleoenvironmental evolution during this period are still unclear. In this paper, the Late Ordovician-early Silurian black shale in a JieLong (JL) section in South China was identified by graptolitic fossils, total organic carbon (TOC) content, X-ray diffraction (XRD), scanning electron microscopy (SEM) and geochemical analysis. The results show that the provenances of sedimentary rocks are all granodiorite-like. According to the variations in the TOC content and geochemical indicators, four layers are delineated. Under warm and humid climatic conditions, sea level rise and unstable seasonal upwelling led to Unit 1 organic matter enrichment controlled by high primary productivity, anoxic conditions and effective smectite production. Unit 2 organic matter burial was controlled by cold, arid and oxic environmental conditions, but primary productivity was still relatively high. After the end of the glacial period, warm and humid climatic conditions and rapid transgression were the main factors affecting the burial of organic matter in Unit 3. Under hot and humid climate conditions, higher terrigenous detrital inputs and unfavourable preservation environments, the dilution of organic matter in Unit 4 was accelerated. The corrected chemical index of alteration (CIAcorr) values show that the study area experienced a climate change of alternating cold and warm conditions in response to the climate fluctuation during the glacial-interglacial period. The CIAcorr value is negatively correlated with the TOC content, while the generation of available clay minerals (smectite) in warm and humid climates is usually consistent with the enhanced burial flux of organic matter, supporting the important role of climate fluctuations in the accumulation of organic matter. Finally, a comparison of the data from the present study with geochemical data from different profiles in South China reveals the role of climatic fluctuations during the OS transition in controlling paleoenvironmental evolution and organic matter enrichment, while such a heterogeneous factor is usually associated with global or regional geological events. Our study highlights this differential enrichment mechanism as a combined response of multiple factors and provides important implications for glacial-interglacial organic matter enrichment mechanisms.

Extremely High Primary Productivity and Organic Matter Enrichment in Lacustrine Sediments: Late Triassic Chang 73 Sub-Member, Western Ordos Basin

The 7th member of the Late Triassic Yanchang Formation is the most important Mesozoic source rocks and shale oil reservoir in the Ordos Basin. The hydrocarbon potential and organic matter enrichment mechanism of this organic-rich member are questioned because of the high heterogeneity of continental sediments. In particular, the lack of drilling in the Chang 73 sub-member of the western Ordos Basin (central Tianhuan Depression) hinders this understanding and the progress of shale oil exploration in this region. In this study, 87 samples were collected from the well DP1 in the Tianhuan Depression, western Ordos Basin, and analyzed for sedimentology and geochemistry to unravel the paleoenvironment, paleo-productivity, and hydrocarbon potential of the Chang 73 sub-member. The results show that the Chang 73 shale is characterized by ultra-high organic matter abundance (up to 10.60%), type II kerogen, and good hydrocarbon generation potential. An intermediate chemical weathering intensity suggests that this set of organic-rich shale was deposited in a warm and humid paleoclimate setting. Extreme organic matter enrichment in study area may be attributed to ultra-high productivity (hypereutrophic lake), superimposed terrigenous organic matter input, and transgression, rather than volcanism and anoxic bottom water. This model is different from those of Chang 73 interval with higher organic matter content in the central and southern parts of the Ordos Basin. Therefore, this study proposes that the Chang 73 shale in the central Tianhuan Depression is not a good target layer for shale oil exploration and that the favorable area may be located in an undisturbed deep lake with higher organic matter abundance (e.g., southwestern Ordos Basin).

Climate change controls on extreme organic matter enrichment in Late Permian marine–terrestrial transitional shales in Guizhou, south China

Black organic-rich shale is an important target for unconventional natural gas exploration. However, compared with marine shale, the mechanism of organic matter enrichment in shale deposited in the marine–continental transitional environment is controversial because of the strong heterogeneity. In this study, an integrated sedimentological and elemental geochemical investigation was conducted for the dark shales in the Lopingian coal-bearing strata of western Guizhou, South China. This study aims to clarify the detailed control mechanism of major geological events on the organic matter accumulation in the transitional facies. Sedimentological observations show that the Lopingian in the Liupanshui area is mainly composed of coal, tight sandstones, and dark mudstones, which were deposited in the tidal flat-lagoon and fluvial delta. Petrological and geochemical evidence suggests the provenance was mainly resulted from the Emeishan basalt weathering in the west of the study area. In addition, the geochemical proxies indicate that the Longtan shales are characterized by low primary productivity, oxic–suboxic bottom water, and a relatively low depositional rate. The paleoclimate index indicates that the climate was predominantly warm and humid with intense chemical weathering during the Lopingian period, and changed to an extremely hot climate in the Early Triassic. Combined with the previous research, this study proposes that the Large Igneous Province (LIP) played a critical role on the organic matter enrichment of the Lopingian across the western Yangtze Block. Firstly, the onset of Emeishan LIP created an essential tectonic background and paleogeographic pattern for massive terrigenous debris to gather here from the west. Secondly, the climate was significantly affected due to the continuous weathering of the Emeishan basalt plateau and the greenhouse gases emission from the Siberian LIP. During the Lopingian, the plants flourished under the tropical rainforest climate and supplied the terrigenous organic matter. Accompanying chemical weathering increased, massive reworked coal fragments were brought into the brackish tidal flat-lagoon environment. Particularly, global warming related to the Siberian LIP and regional transgression occurred in the late Lopingian, forming the black shales with the highest organic matter content (up to 26.39%) of member Ш of the Longtan Formation. However, both the production and supplementation of organic matter significantly decreased because of the end-Permian mass extinction, thus stopped the organic matter enrichment in the Early Triassic Feixianguan Formation.

Organic matter enrichment of the Late Triassic Bagong Formation (Qiangtang Basin, Tibet) driven by paleoenvironment: Insights from elemental geochemistry and mineralogy

The Upper Triassic dark mudstones in the Qiangtang Basin are key source rocks for petroleum exploration. However, the factors controlling organic matter enrichment in these dark mudstones remain unclear, especially for pro-deltaic core mudstones, which inhibit source rock distribution predictions. Well QZ-7 contains several Upper Triassic dark mudstone intervals (marked by A to G) with total organic carbon (TOC) contents of 0.57–2.73% (avg. of 1.13%). The TOC contents in intervals A, C, E, and G are generally higher than those in intervals B, D, and F. Here, detailed mineralogical and geochemical analyses of these dark mudstones are analyzed to address the organic matter enrichment mechanism. Paleosalinity, redox, detrital influx, sedimentation rate, and productivity proxies suggest that these dark mudstones were deposited in a brackish-salt and anoxic-dysoxic water environment with low detrital influx, sedimentation rate, and primary productivity. Organic-rich intervals of A, C, E, and G generally show higher salinity, lower oxygen levels, detrital influx, and sedimentation rates than the organic-poor intervals of B, D, and F. The significant positive correlations of TOC with paleosalinity proxies and redox indices indicate that anoxic and stratified high-salinity water columns primarily controlled organic matter preservation. The significant negative correlations between TOC and detrital influx proxies and moderate negative correlation between TOC and (La/Yb)N suggest that increasing detrital influxes diluted organic matter, while a low sedimentation rate promoted organic matter preservation. The effect of primary productivity on organic matter enrichment was limited, as evidenced by the weak correlation between TOC and P/Ti.

Depositional Environment Variation and Organic Matter Accumulation Mechanism of Marine–Continental Transitional Shale in the Upper Permian Longtan Formation, Sichuan Basin, SW China

Marine–continental transitional shale gas exploration is one of the hottest topics in the academic and industrial community. Frequent sedimentary environment changes lead to substantial heterogeneity and complex organic matter enrichment mechanisms, and it is of great practical significance to clarify the paleoenvironment of marine–continental transitional shale and reveal the enrichment mechanism of organic matter for subsequent shale gas exploration. However, strong heterogeneity creates divergence for our understanding of organic matter enrichment mechanisms and resource potential. This paper selected the marine–continental transitional shale of the Permian Longtan Formation in the southeastern Sichuan Basin as an example. Through TOC analysis, XRD measurements, and major and trace element analyses, we identify the depositional cycle and lithofacies, characterize the paleosedimentary environments of different lithofacies, establish depositional models, and clarify the organic matter enrichment mechanism. Four lithofacies can be identified in the Longtan Formation in the study area: organic–lean carbonate shale (LC), organic–lean mixed shale (LM), organic–lean argillaceous shale (LCM), and organic–rich argillaceous shale (RCM). The terrestrial detrital influx of the LCM and RCM shales is obviously strong, while the RCM shale was deposited in a relatively dysoxic and humid environment. For the Longtan shale, the terrestrial detrital influx and redox environment determine the enrichment of organic matter. In the lagoon sediment system, due to the high terrestrial detrital influx, the argillaceous shale in the transitional shale gas system should be given more attention in future exploration. For different kinds of shale gas systems (marine, marine–continental transitional, and lacustrine), the effect of the terrestrial detrital influx is the main difference. In marine–continental and lacustrine shale gas systems, shales with high TOC values can still exist in the context of oxic sedimentary environments. The research results of this paper can provide a theoretical basis for future marine–continental transitional shale gas sweet spot prediction and exploration from geochemical perspectives.

Paleo-Environment Reconstruction of the Middle Permian Lucaogou Formation, Southeastern Junggar Basin, NW China: Implications for the Mechanism of Organic Matter Enrichment in Ancient Lake

Paleo-Environment Reconstruction of the Middle Permian Lucaogou Formation, Southeastern Junggar Basin, NW China: Implications for the Mechanism of Organic Matter Enrichment in Ancient Lake

Geochemistry of Middle Permian lacustrine shales in the Jimusar Sag, Junggar Basin, NW China: Implications for hydrothermal activity and organic matter enrichment

Organic matter enrichment in black shales has frequently been linked with hydrothermal activity. However, it is poorly understood how hydrothermal activity affected paleo-environments and the enrichment of organic matter in ancient lacustrine sediments. The hydrothermal activity recorded in the Middle Permian Lucaogou Formation (LCGF) in the Jimusar Sag, Junggar Basin, Northwest China, provides an ideal sedimentary archive to explore this issue. The mineralogical composition, major and trace element, total organic carbon, and sulfur content of forty-three shale samples of the LCGF were investigated to better understand how hydrothermal activity influences organic matter enrichment in lacustrine shales. The terrigenous influx, redox conditions, paleoproductivity, hydrothermal effects, and organic matter enrichment mechanisms are discussed. The results show that the terrigenous influx is insufficient overall, and the lower section of the LCGF has less detrital materials than the upper section. The redox conditions of the bottom water of the lake in the Jimusar Sag during deposition of the LCGF were suboxic to anoxic, which, combined with relatively high paleoproductivity, is favorable for organic matter enrichment. Hydrothermal activity occurred more frequently during deposition of the lower section compared with the upper section of LCGF. Hydrothermal fluids provided sufficient nutrients to enhance organic matter production during deposition of the LCGF and resulted in organic matter enrichment.

Geochemical characteristics of organic-rich intervals within the Cryogenian non-glacial Datangpo Formation in southeastern Yangtze Block-implications for paleoenvironment and its control on organic matter accumulation

To understand the mechanism of organic matter enrichment in the organic-rich intervals of the Cryogenian non-glacial strata, we report high-resolution geochemical data of the well-developed non-glacial Datangpo Formation at a section in the southeastern margin of the Yangtze Block, including iron (Fe) speciation, sulfur and organic carbon isotopic compositions and elemental contents. The organic-rich intervals are mainly distributed in the basal manganese (Mn) carbonate and Mn-bearing shales (intervalⅠ), and overlying black shales (intervalⅡ). The paleo-redox reconstruction shows a transition from ferruginous-dominated watermass during deposition of the IntervalⅠto euxinic-dominated watermass during deposition of the IntervalⅡ, which provides good conditions for the preservation of organic matter. A variety of geochemical indicators demonstrate that during deposition of the IntervalⅠ, elevated primary productivity in the surface water driven by hydrothermal activities and improved post-glacial basinal watermass exchange, coupled with some organic carbon influx from the dissolved organic carbon reservoir, collectively promoted the enrichment of organic matter. For the interval Ⅱ, enhanced chemical weathering accompanied by persistently warm climatic conditions exerted a major control on the organic matter enrichment by importing abundant nutrients, resulting in enhanced surface-water primary productivity. In addition, favorable sedimentation rates also made positive contributions to the organic-rich black shales in the intervalⅡ. Based on a combined analysis of paleoclimates, hydrological conditions and hydrothermal activities, this study puts forward organic matter enrichment models for the organic-rich intervals deposited during the Cryogenian non-glacial period.

Earth’s Orbital Control on Organic Matter Enrichment in the Black Shales of the Wufeng–Longmaxi Formation in the Upper Yangtze Region, South China

China’s most successful horizon for shale-gas exploration and development is the Upper Ordovician Wufeng Formation through the Lower Silurian Longmaxi Formation in its Upper Yangtze Region. In this study, the Wufeng–Longmaxi Formation black shales in the Upper Yangtze Region are analysed to determine their microstructural characteristics, total organic carbon (TOC) content, and well log characteristics and to identify information on the parameters of Earth’s orbit from its gamma-ray (GR) data series. Then, paleoenvironmental modes are established over a long time scale. On this basis, the Earth’s orbital control on organic matter enrichment in the black shales is examined. The black shales of the Wufeng Formation and the lower Longmaxi Formation are rich in biogenic siliceous fossils and framboidal pyrite. Their TOC content, GR value, and uranium (U) content increase gradually from the bottom of the Wufeng Formation to the Guanyinqiao Member at its top, peak at the Guanyinqiao Member, and then decrease gradually up to the Longmaxi Formation. Approximately six and seven long eccentricity cycles can be identified from the GR curves of the Wufeng Formation and the lower Longmaxi Formation, respectively. During the long eccentricity minima, corresponding to Earth’s cold period, the black shales have a relatively high level of enrichment of organic matter. This study can provide an important reference for investigating the mechanism by which Earth’s orbits control the climate and sedimentary environment, as well as the mechanism of organic matter enrichment.

Organic Matter Enrichment of Black Shale at the Turn of Ordovician-Silurian in the Paleosedimentary Center in Southern Sichuan Basin, Upper Yangtze Area

Abstract Herein, integrated vertical variation characteristic analysis was conducted by measuring total organic carbon (TOC), major and trace elements in Upper Ordovician-Lower Silurian (Wufeng-Longmaxi formations) black shale in Weiyuan, Luzhou, and Changning areas, southern Sichuan Basin to clarify the control of organic matter (OM) enrichment in different sublayers. According to the cycle boundary, it was divided into member 1 (submember 1 and submember 2) and member 2 from early to late Longmaxi formation, while it was divided into 4 sublayers from early to late during submember 1 depositional period. Under the warm and humid paleoclimate, high paleoproductivity, and gradually oxic paleoredox conditions, the TOC content (0.22-3.27 wt% in Luzhou area) in Wufeng formation increased gradually from early to late under the cocontrolling of tectonic framework and stagnant sea. After the glacial period, the warm and humid climate of Wufeng formation continued in Longmaxi formation, and TOC content reached the highest in sublayer 1 (2.02-4.02 wt%, 4.78 wt%, and 6.45 wt% in Weiyuan, Luzhou, and Changning areas, respectively), due to the high paleoproductivity and high sea level caused by melting glaciers, causing the extremely anoxic environment. The OM was preserved best. It remains higher in sublayer 2 (2.39 wt%, 3.69-4.18 wt%, and 3.5-3.86 wt% in three areas, respectively) because of the anoxic environment caused by deep water and the high paleoproductivity, but the temporary hot and dry environment has a certain negative impact on the OM preservation. Under the stable paleoproductivity, sublayer 3 has a character of water decreasing slowly, and the suboxic environment led to the decrease of TOC content (3.82-5.28 wt% and 3.77-4.13 wt% in Luzhou and Changning areas, respectively). Meanwhile, that in the yuan area became deeper and the TOC content became relatively higher (1.92-3.33 wt%). Under the open environment, sublayer 4 was controlled by lower sea level caused by regression, resulting in lower TOC content (1.31-4.57 wt%, 1.64-3.52 wt%, and 3.88-4.49 wt% in three areas, respectively). However, the global regression of the submember 2 period, high terrigenous debris dilution, and oxic environment lead to the no preservation of OM. Generally speaking, the enrichment of OM is not only affected by the changes of global sea level and paleoproductivity to some extent (Longmaxi shale) but also controlled by the tectonic framework in Sichuan Basin (Wufeng shale). The findings of this study can help for a better understanding of the OM enrichment mechanism and provide a theoretical basis for the evaluation of high-quality source rocks.

Organic matter enrichment in a terrestrial-marine transitional environment driven by global/regional climate recorded in the Upper Permian succession from the Qiangtang Basin, northern Tibet

Compared to organic matter (OM) accumulation in marine environments, OM enrichment mechanism in terrestrial-marine transitional environments remain unclear. The Late Permian was an important coal-forming period in China. Late Permian coal-bearing mudstones are important petroleum source rocks in the Qiangtang Basin. In this study, the coal-bearing rocks in the Late Permian Nayixiong Formation from the Qiangtang Basin are selected to address OM accumulation process in transitional environments. Our work demonstrates three-stage climatic changes during the deposition of coal-bearing sedimentary rocks: stages I, II and III, corresponding to a semi-warm and semi-humid climate, warm and humid climate, and cold and arid climate, respectively. Based on degree of pyritization (DOP), enrichment factor (EF) of elements, the Late Permian coal-bearing rocks were deposited under oxic-dysoxic environments. Low excessive barium (Baxs) and biogenic silica (Sibio) contents in the coal-bearing rocks indicates a low primary productivity. We suggest that warm and humid conditions, freshwater and terrestrial plants input are the primary factors controlling OM accumulation during the Late Permian coal-bearing deposition. We summarized a global/regional climate-driven model for OM accumulation in transitional environments. The warming climate created a habitable environment for both terrestrial and marine organisms. Subsequent freshwater input brought abundant nutrients and terrestrial OM to the aqueous system to build high OM accumulation.

Sedimentary Environment and Enrichment of Organic Matter During the Deposition of Qiongzhusi Formation in the Upslope Areas—A Case Study of W207 Well in the Weiyuan Area, Sichuan Basin, China

For a more in-depth analysis on the marine chemical condition during the earliest Cambrian, mechanism of organic matter enrichment and exploration potential of shale gas resources, based on the petrology, organic geochemistry, and elemental characteristics of the W207 Well, this study discuss the Early Cambrian paleo-ocean environment and factors controlling of organic matter enrichment during the deposition of black strata Qiongzhusi Formation in the upslope areas, southwestern Sichuan Basin, Yangtze Block, China. The sedimentary cycles show that during the depositon of fine-grained Qiongzhusi Fm, interactive cycles of multiple deep-water and shallow-water shelf developed, and were controlled by the rise and fall in sea level. In particular, the slope turbidite (fan) and gravity flow sediments indicate that the shallow-water shelf facies were dominant in the upslope area (SW Sichuan Basin), where not in deep water for a long time, and the sedimentary thickness of the organic rich black shale was limited. Evidence from organic geochemistry indicates that the organic matter of the Qiongzhusi Fm from the W207 Well was mainly of type I kerogen, with a high degree of thermal evolution, little residual hydrocarbon, and low capacity for hydrocarbon generation. The redox parameters indicate that the marine environment on the upslope was medium restrictive, with some upwelling. The seawater had undergone a transformation according to anoxic–oxidic. Therefore, paleo-ocean productivity in the upslope area was generally low, and exhibited a prominent downward trend from bottom to top. Given its high risk of exploration, the authors suggest that the direction of shale gas resource evaluation should change to the intracratonic sag (downslope) area, which is characterized by deep-water shelf facies.

Influence of Organic Matter on Gas-Bearing Properties and Analysis of Sedimentary Mechanism of Organic Matter Enrichment: A Case Study on the Yangtze Region of Southern China during the Early Cambrian

Shale gas exploration requires studies on the enrichment mechanism of sedimentary organic matter. The Lower Cambrian shale is taken as a study object to analyze the effect of organic matter on gas content using TOC content and porosity analyses, isothermal adsorption experiments, and FIB-HIM scanning electron microscopy observations. Then, we selected typical wells to determine the presence of excessive silica in the siliceous minerals by quantitative calculations. Besides, we analyzed the genesis of excessive siliceous minerals using elements including Al, Fe, and Mn, thus speculating the controlling factors of the redox environment and biological productivity. Results show that total organic carbon content controls the content of free and adsorbed gas, while shale gas mainly exists in organic pores and is developed in large numbers and with high roundness, showing the characteristics of “small pores inside big pores.” In the Lower Yangtze region during the Early Cambrian, the excessive siliceous minerals were of hydrothermal origin, and there were frequent hydrothermal activities due to its closeness to plate boundaries. These activities can intensify the reducibility of the waterbody’s bottom and improve the biological productivity on its surface, resulting in the enrichment of this matter. Most excessive silicon in this region is biogenic, while only a small part is of hydrothermal and biogenic mixed origin. The enclosed waterbody of the Upper Yangtze region was far from plate boundaries and close to the semiclosed “gulf,” resulting in its delamination. The waterbody’s surface was abundant with oxygen, thus increasing the biological productivity, while the high reducibility at the waterbody’s bottom was conducive to preserving sedimentary organic matter.

Depositional Setting and Enrichment Mechanism of Organic Matter of Lower Cretaceous Shale in Ri-Qing-Wei Basin in the Central Sulu Orogenic Belt

A suite of source rock consists of mudstone and shale, with great thickness and continuous deposition was found in the well LK-1 in Lingshan island in Ri-Qing-Wei basin. In order to evaluate the hydrocarbon generation prospects of these source rock and find the mechanism of organic matter enrichment, shale samples were selected from the core for TOC (total organic carbon) and element geochemistry analysis. The results show that organic matter abundance of the source rocks are generally high with average TOC content of 1.26 wt%, suggesting they are good source rocks. The geochemical features show that the sedimentary environment is mostly anoxic brackish water to salt water environment with arid to semiarid climate condition. The enrichment mechanism of organic matter varied with the evolution of the basin, which was divided into three stages according to the sedimentary characteristics. In the initial-middle period of rifting evolution (stage 1 and early stage 2), paleoproductivity is the major factor of OM-enrichment reflecting by high positive correlation between the TOC contents and paleoproductivity proxies. While with the evolution of the rift basin, redox condition and terrigenous clastic input became more and more important until they became the major factor of OM enrichment in the middle stage of rift evolution (stage 2). In the later stage of rift evolution (latest stage 2 and stage 3), besides terrigenous clastic input, the effect of paleoclimate on OM-enrichment increased gradually from a minor factor to a major factor.

Hydrocarbon accumulation characteristics in the inter-salt shale oil reservoir in the Eocene Qianjiang Depression, Hubei Province, China

Research on the migration and accumulation of hydrocarbons in shale oil reservoirs composed solely of organic-rich mudstones has not received adequate attention. The Qianjiang Formation provides an opportunity for research on the hydrocarbon accumulation mechanism due to the presence of hydrocarbon migration characteristics in its inter-salt organic-rich fine-grained rocks. In this study, the inter-salt stratum of the tenth rhythmite can be classified into three sections: lower, middle, and upper. The middle section is mostly composed of laminated marlstones and laminated calcite-bearing argillaceous dolomicrites, whereas, the lower and upper sections mostly contain bedded muddy dolomicrites and glauberite. Geochemical analysis was conducted to study the organic matter enrichment mechanism and shale oil accumulation characteristics. The results indicate that the middle section has the highest organic matter abundance, with poor organic matter abundance displayed by the other sections. The C27/C29 sterane and extended tricyclic terpane ratios suggest that the organic matter types in different sections of the inter-salt stratum differ, and the middle section has more aquatic organic matter than other sections. The sedimentary structures and salinity-related parameters indicate that the middle section was developed in a deep stratified saline lake and that the other sections were formed in a shallow hypersaline lake. This study shows that high biological productivity and stratified lake water facilitated the enrichment of organic matter, resulting in high organic matter content in the middle section. The oil saturation index and hydrocarbon composition suggest that hydrocarbons were differentially accumulated in the inter-salt stratum of the tenth rhythmite. The maturity-related biomarkers further revealed the possible migration paths of hydrocarbons in the inter-salt stratum. Based on the aforementioned analyses, this study established an inter-salt shale oil accumulation model. This study suggests that hydrocarbons were released from the mature source rocks in the deep depression with differential migration laterally and vertically within the inter-salt stratum. The study of the Qianjiang Depression shows that organic-rich fine-grained rocks cannot only form in situ sweet spots but may also possess migrated hydrocarbons inside them, which are characterized by high organic matter abundance and oil saturation. This research provides a new case for further understanding hydrocarbon accumulation inside source rocks.