Organic Chain Research Articles

Unlocking the drivers behind logistics service providers' participation in Morocco's logistics clusters

PurposeIn recent years, the concept of logistics clusters has attracted the attention of several researchers and practitioners. It is an agglomeration of different types of companies and operations, notably those providing logistics services, such as supply chain organization, storage and distribution. The paper focuses on this concept by examining the factors influencing LSPs to enter the logistics clusters.Design/methodology/approachAn exploratory qualitative study based on semi-structured interviews was conducted. Regarding the sample size, the author interviewed 31 professionals belonging to logistics clusters located in the Moroccan economic metropolis of Casablanca.FindingsThe results show that the cost reduction, the reputation of the cluster, the learning from other LSPs, the communal services, the geographical proximity and the role of public authorities are the main factors impacting the entry of logistics service providers into these clusters.Originality/valueThis theme has never been investigated. Therefore, this research expands the literature review and tries to examine this gap of literature by studying the factors that can affect the adhesion of logistics service providers to these clusters.

Twenty Years of Socio-Economic Research on Organic Agriculture Across the World: Looking at the Past to Be Ready for the Future

The world organic sector has evolved in a rapid way over the last few decades, driven by consumer interest, producer and retailer strategies, as well as by the evolving normative context. This growth has stimulated an increase in academic research, particularly in socio-economic research. The present work aims to understand the evolution of organic socio-economic research in terms of the research themes covered within this field, their relative importance, and how this importance has changed over time. The implementation of a structural topic model on scientific abstracts from the last 20 years allowed us to identify three broad areas of interest for organic socio-economic researchers: consumers, production, and society. The relevance of these strands varies in different areas of the world, mostly aligning with the prominent aspects of local organic sectors. This signals a good integration of organic socio-economic research within local contexts, with the possible development of place-based skills to be exploited within the global debate on organic agriculture. Overall, a reasonably strong imbalance emerges, with consumer-focused studies being more prominent than production-focused ones, especially those investigating producers’ economic results. The latter seems to call for renewed attention on and analysis of the organic sector, assisted by robust evidence on both ends of the organic supply chain.

Polyfluorene-based conjugated nanocomposites with in-situ gold nanoparticles: Synthesis via rational chemical passivation and characterization of supramolecular fibrillar structures

We present a rational and innovative chemical approach for synthesizing and characterizing conjugated polymer nanocomposites as direct passivation of gold nanoparticles (AuNPs), highlighting intrinsic morphologies and distinct photophysical properties in the solid state. The pioneering synthesis of polyfluorene with thiol, LaPPS79.10, revolutionized its application as a direct passivator of AuNPs, resulting in stable nanocomposites with the capacity for storage in the dry state and subsequent redispersion in organic solvent. The presence of AuNPs with average diameters of 3.5 ± 1.3 nm induced the formation of an interconnected fibrillar supramolecular network (ribbon-like) and several microdomains in the nanocomposite (LaPPS79.10+AuNPs), correlated by XRD, TEM and SEM measurements. Characterization of the polyfluorene precursor derivative, LaPPS10, revealed bundle-like morphologies with aggregation-induced emission (AIE). Introducing thiol groups into the intermediate structure induced polymer chain organization (LaPPS79.10), leading to unique straw-like and lenticular bundle morphologies, disrupting the non-planar π-π packing and quenching the emission, a case of aggregation-caused quenching (ACQ). In LaPPS79.10+AuNPs, the proximity of the π system to the Au localized surface plasmon resonance (LSPR) resulted in high absorption, negligible self-absorption, and efficient emission quenching, as well as improved thermal resistance compared to the original polymer. The unprecedented discovery of the properties resulting from the electronic interaction between the π system of the AuNPs passivating polymer and the effects of plasmonic resonance represents a significant advance in nanoscience, opening new perspectives for exciting applications in organic photovoltaic devices and metamaterials.

Nanoengineering Spikey Surfaces: Investigation of Reversible Organizational Control of Surface-Tethered Polypeptide Brushes.

Nature serves as an important source of inspiration for the innovation and development of micro- and nanostructures for advanced functional surfaces and substrates. One example used in nature is a spikey surface ranging from micrometer-sized spikes on pollen grains down to the nanometer-scale protein spikes found on viruses. This study explored the realization of such highly textured surfaces via the nanoengineering of self-assembled poly(γ-benzyl-l-glutamate) "nanospikes", exploiting solvent-induced chain organization, controlled surface chemical functionality, and enhanced stability in the form of polymer brushes. The reversible solvent-responsive behavior of these polymer chains and the aggregation behavior of the chain-ends were investigated via fluorescence characterization and studied through molecular simulations. Vapor-based solvent treatments were developed for orientation control with in situ analysis to understand film response and brush organizational behavior under different selected conditions. The effect of sub-100 nm nanopatterning on surface morphology and chain organization was examined via an integrated approach of experimental and computational studies. The methodologies established in this study present opportunities for engineering sophisticated nanoscale spikey surfaces with high customizability by means of nanolithography combined with solvent-assisted treatments.

Recent Advances of Organic-Inorganic Hybrid Fluorescent Hyperbranched Polymer: Synthesis, Performance Regulation Strategies and Applications.

The organic-inorganic hybrid fluorescent hyperbranched polymer, including hyperbranched polysiloxane and hyperbranched polyborate, have attracted much attention due to their excellent optical properties and wide range of applications. Hyperbranched polysiloxane and polyborates, prepared by introducing Si or B elements into organic polymer chains at the molecular level through rational molecular design and novel synthesis methods, exhibit outstanding photophysical properties as an indispensable branch of organic-inorganic hybrid fluorescent materials. Herein, this review highlights the recent research progress on hyperbranched polysiloxanes and hyperbranched polyborates, including strategies for regulating their emission wavelengths, quantum yields, and fluorescence lifetimes, potential emission mechanisms, and various applications. Finally, some challenges and promising future directions in the field of organic-inorganic hybrid fluorescent polymers are summarized.

A methodology to map chains of general practices in the Netherlands

Abstract Background Commercial entities are increasingly interested in acquiring Dutch general practices (GPs). They see profitable opportunities in upscaling by forming chains. Chain organizations integrate business processes of GPs within one organizational unit. The governance structure of these chains can be complex, leading to opacity and difficulties to see conflicts of interest and market power. To investigate how this development may have an impact on quality and accessibility of care, it is first needed to establish the ways in which these chains are formed. By mapping the chain structure in a data-driven way, impact monitoring becomes possible. For the Netherlands we investigated how chain structures of GPs can be empirically identified. Methods Background data of approximately 4,800 Dutch GPs from the Nivel Healthcare Professional Registries was linked with data from the Chamber of Commerce’s Trade Register. This enabled the determination of the legal form, business location, ownership, and director identification for all GPs. By this data-driven manner, the variation in organizational structures of all Dutch GPs was mapped and analyzed. Results Four different chain variants of Dutch GP chains were identified based on three types of relations between the chain organization and their GPs: ownership, location and the composition of the board of directors. Based on ownership, two ‘top-down’ chain variants were identified. Two ‘bottom-up’ chain variants were found based on location and board composition: (1) a chain organization acquires a seat on the board of the GP, and (2) the GP and the chain organization share the same business address. Combining these variants provides a new typology of GP chains in the Netherlands. Conclusions Our methodology enables to empirically map chain formation in primary care. By developing a new typology in a systematic way, a foundation is created to monitor organizational developments and their impact on quality and accessibility of care. Key messages • A typology of Dutch GP chains was developed based on three relations: the ownership, composition of the board and the establishment location of the chain organization and its practices. • Our methodology was put into practice to map different chain structures of GPs in the Netherlands, but it is not limited to primary care and can also be applied in other sectors and countries.

Blockchain technology and consumers’ organic food consumption: a moderated mediation model of blockchain-based trust and perceived blockchain-related information transparency

Purpose While the application of blockchain technology in the organic food supply chain has been increasingly recognized, the extant knowledge of how blockchain-driven traceability influences consumer perceptions and purchase intentions remains underexplored. Grounded in the stimulus-organism-response theory, this study aims to construct a moderated mediation model to examine blockchain-enabled traceability’s direct and indirect impacts on organic food purchase intention through perceived blockchain-related information transparency, considering the moderating role of blockchain-based trust. Design/methodology/approach A purposive sample of 5,326 Vietnamese consumers was surveyed using the PROCESS macro to test the proposed hypotheses. Findings The findings indicate that blockchain-enabled traceability significantly enhances perceived blockchain-related information transparency, which positively influences organic food purchase intention. Furthermore, blockchain-based trust was found to positively moderate both the direct effect of transparency on purchase intention and the indirect impact of traceability on purchase intention through transparency. Practical implications Practical and managerial insights for stakeholders in the organic food sector are also discussed. Originality/value These results contribute to the literature by extending the stimulus-organism-response model to the context of blockchain technology in supply chains and highlighting the critical role of trust in moderating the effectiveness of technological innovations.

How does blockchain-based food traceability system drive consumers’ repurchase and word-of-mouth intentions toward organic food: a curvilinear role of producer-retailer (in)congruence

PurposeThis research applies the stimulus-organism-behavior-consequence framework to explore how blockchain-enabled traceability influences trust in organic food producers and retailers, which impacts consumers’ purchase behaviors and subsequent outcomes.Design/methodology/approachUsing a purposive sample of 5,326 Vietnamese consumers, multiple linear and polynomial regression with response surface analysis were employed to examine the hypotheses.FindingsBlockchain-enabled traceability significantly enhances trust in both producers and retailers, which congruently and incongruently influences organic food purchase behaviors. This behavior also drives consumers’ word-of-mouth and repurchase intentions. Serial mediation analysis confirms blockchain’s impact through trust and purchase behaviors.Research limitations/implicationsStakeholders should adopt blockchain to boost transparency and trust, which increases consumer engagement. Policymakers can support this transition through regulations and incentives to enhance food security and sustainability.Originality/valueThis study expands on blockchain research by applying the stimulus-organism-behavior-consequence framework in the organic food supply chain, showing how blockchain-enhanced trust synergistically affects consumers’ purchase behaviors, word-of-mouth and repurchase intentions.

Adaptive Strategies and Sustainable Innovations of Chinese Contractors in the Belt and Road Initiative: A Social Network and Supply Chain Integration Perspective

As global economic integration and rapid technological advancements transform international business, international engineering contracting has become essential for achieving sustainable development goals (SDGs). This paper investigates the significant impact of China’s strategic initiatives, notably the “Going Global” strategy and the Belt and Road Initiative (BRI), on the operational practices of Chinese enterprises involved in overseas investments. Central to this transformation is the Engineering, Procurement, and Construction (EPC) model, which emphasizes the integration of supply chain management and stakeholder collaboration to enhance performance in international EPC projects and underscores the crucial role of these elements in promoting sustainability. Incorporating insights from social network data analysis, this study reveals that contractors collaborating with various stakeholders—such as owners/consulting engineers, domestic and foreign customs departments, and group headquarters/design parties—exhibit a high degree of similarity in personnel profiles. This suggests that the internal organizational structure and personnel allocation of contractors could be optimized to enhance operational efficiency, aligning with the collaborative patterns identified. This study addresses a critical research gap by exploring how effective supply chain management and collaborative stakeholder engagement within multinational EPC projects contribute to sustainable outcomes. Employing advanced social network analysis software, the research examines the complex interactions among stakeholders and their influence on procurement dynamics. Findings indicate that strong relational networks and strategic collaborations significantly enhance procurement efficiency and project success, underscoring the importance of supply chain integration. Ultimately, integrating supply chain management principles into the EPC model not only offers innovative perspectives for advancing sustainability in international projects but also provides actionable insights for improving project outcomes within the BRI framework. This research underscores the pivotal role of supply chain organization and stakeholder cooperation in achieving sustainability objectives, thereby enriching the discourse on sustainable enterprise operation and supply chain management in the context of global initiatives.

Formaldehyde: An Essential Intermediate for C1 Metabolism and Bioconversion.

Formaldehyde is an intermediate metabolite of methylotrophic microorganisms that can be obtained from formate and methanol through oxidation-reduction reactions. Formaldehyde is also a one-carbon (C1) compound with high uniquely reactive activity and versatility, which is more amenable to further biocatalysis. Biosynthesis of high-value-added chemicals using formaldehyde as an intermediate is theoretically feasible and promising. This review focuses on the design of the biosynthesis of high-value-added chemicals using formaldehyde as an essential intermediate. The upstream biosynthesis and downstream bioconversion pathways of formaldehyde as an intermediate metabolite are described in detail, aiming to highlight the important role of formaldehyde in the transition from inorganic to organic carbon and carbon chain elongation. In addition, challenges and future directions of formaldehyde as an intermediate for the chemicals are discussed, with the expectation of providing ideas for the utilization of C1.

Evolutionary game theoretical approach for reducing carbon emissions in a complex supply chain organization

PurposeOur research explores the intricate behavior of low-carbon supply chain organizations in an ever-evolving landscape, emphasizing the profound implications of government-mandated low-carbon policies and the growing low-carbon market. Central to our exploration is applying a combined game theory model, merging Evolutionary Game Theory (EGT) with the Shapley Value Cooperative Game Theory Approach (SVCGTA).Design/methodology/approachWe establish a two-tier supply chain featuring retailers and manufacturers within this novel framework. We leverage an integrated approach, combining strategic Evolutionary Game Theory and Cooperative Game Theory, to conduct an in-depth analysis of four distinct low-carbon strategy combinations for retailers and manufacturers.FindingsThe implications of our findings transcend theoretical boundaries and resonate with a trinity of economic, environmental and societal interests. Our research goes beyond theoretical constructs to consider real-world impacts, including the influence of changes in government low-carbon policies, the dynamics of consumer sensitivities and the strategic calibration of retailer carbon financing incentives and subsidies on the identified ESS. Notably, our work highlights that governments can effectively incentivize organizations to reduce carbon emissions by adopting a more flexible approach, such as regulating carbon prices, rather than imposing rigid carbon caps.Originality/valueOur comprehensive analysis reveals the emergence of an Evolutionary Stability Strategy (ESS) that evolves in sync with the phases of low-carbon technology development. During the initial stages, our research suggests that manufacturers or retailers adopt low-carbon behavior as the optimal approach.

A structural, magnetic and colloidal stability study of uncoated and silica coated iron oxide samples prepared in two different surfactants

The discovery of new magnetic materials of interest in the biomedicine field is a relevant topic in current research. For years, our research group has been investigating the obtaining and study of nanostructured magnetic samples that behave superparamagnetically to enable their transport in living organisms. We present here a study that summarizes the structural characteristics, magnetic behavior and stability of two Fe3O4 samples synthesized by coprecipitation that were dispersed using two different surfactants (oleylamine, OL, and oleic acid, OA), and two others prepared from the previous ones by reaction with tetraethyl orthosilicate (TEOS). The relationships between the surfactant used in the synthesis, the presence of a certain maghemite (γ-Fe2O3) content, the influence of silica shell thickness and magnetic behaviour of all samples were systematically studied by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), Mössbauer spectroscopy and H vs. M loops. Rietveld refinements of the XRD profiles confirmed a partial oxidation of the non-silica-coated samples and FTIR spectra of the uncoated samples showed a very strong broad metal-oxygen band and additional sets of bands from the different organic chains of the two surfactants. Individual particles with a mean diameter of 7 and 9 nm were distinguished in TEM images of uncoated magnetic samples. Mössbauer data indicated the presence of non-stoichiometric magnetite in all samples, in agreement with XRD refinements. Magnetic measurements confirmed the superparamagnetic behavior of all the samples. Highest negative zeta potential values are found for the silica covered samples in both acidic and basic medium, being Fe3O4-AO@SiO2 the best suited for the purposes of its dispersibility in future applications. Low polydispersity index (PDI) values confirmed the best stability and dispersibility of all samples investigated in tetrahydrofuran (THF).

Fabrication of PVC-based electromagnetic interference shielding composite film by positively charged SMA enhancing the dispersibility of carbon nanomaterial

To address the weak binding force and poor dispersion stability of carbon (C) nanoparticles in current non-covalent modification methods, we employed organic amine-grafted styrene maleic anhydride copolymers (SMA-N) to modify C nanoparticles (C@SMA-N) through π–π conjugation and positive charge interactions. The obtained C@SMA-N has excellent dispersion in N, N-dimethylacetamide (DMAc), which is attributed to the enhanced steric hindrance and electrostatic repulsion from the grafted organic amine chains. To study the impact of surface modification on the electromagnetic interference shielding effectiveness (EMI SE), C@SMA-N was used as a conductive filler in polyvinyl chloride (PVC) composite films, which exhibits a higher EMI SE performance than pristine C nanoparticles. Particularly, the obtained C@SMA-N using polyether amine (PEA) (C@SMA-PEA) exhibits a better EMI SE performance. By optimizing the SMA-PEA grafting parameters, the PVC/C@SMA-PEA composite films transition from insulators to conductors at a C@SMA-PEA content of 0.3 wt%. To achieve a higher EMI SE performance, the filler content, mixed filler composition, and film thickness were optimized. The results indicate that with a total filler content of 20 wt% and a mixed filler comprising fibrous form carbon nanotubes (CNT) and particles form carbon black (CB) in a 10:1 mass ratio (CB@SMA-PEA to CNT@SMA-PEA), the composite film has a thickness of 0.08 mm and an EMI SE value of 20.2 dB. Increasing the thickness to 0.2 mm enhances the EMI SE value to 31.5 dB. These findings indicate that thinner films have a higher EMI SE performance and promising application prospects in the field of electromagnetic shielding.

Blockchain-based food traceability system and pro-environmental consumption: A moderated mediation model of technology anxiety and trust in organic food product

Blockchain technology is increasingly recognized as a transformative tool for enhancing clarity and responsibility in the organic food supply chain, where concerns about product authenticity and safety are paramount. By offering provable and translucent information about the origination, production processes, and administration of organic items, blockchain helps to reduce information asymmetry and builds consumer trust, which is critical for purchase decisions in the organic food market. Drawing on insights from the trust theory and the stimulus-organism-response framework, this study uses a moderated mediation model to explore how technology anxiety negatively moderates the direct and indirect influences of blockchain-based food traceability systems on trust in organic food products and organic food purchase intention. Using a targeted sample of 5326 consumers in Vietnam, the PROCESS macro approach (models 8 and 4) is utilized to examine the formulated hypotheses. The results demonstrate that blockchain-based food traceability systems notably enhance consumer trust in organic food products and their intention to buy these products. Trust in organic food products serves as a mediator in the connection between blockchain-based traceability and purchase intention, while technology anxiety weakens the positive impacts of blockchain technology on trust and purchase intention when anxiety levels are high. This research makes crucial contributions to the literature by offering a mechanism-based explanation of how blockchain technology enhances consumer trust in organic food products and integrates technological anxiety as a moderator, providing a deeper understanding of how technological innovations shape consumer behavior. In light of the findings, several critical recommendations have been proposed for practitioners and policymakers.

Native organization of alternative NAD(P)H-dehydrogenases NDA and NDB in mitochondria of etiolated pea sprouts

Numerous biochemical and structural studies into the native organization of oxidative phosphorylation in the mitochondria of various eukaryotic organisms have convincingly shown that respiratory complexes can associate with one another to form higher-order structures referred to as supercomplexes. Plant mitochondria are distinguished by a more complicated organization of the respiratory chain due to the presence of a number of alternative oxidoreductases. It is considered that these enzymes do not physically interact with those of the cytochrome pathway. However, the available literature data obtained on yeast mitochondria suggests the possibility of such an association. In this regard, we aimed to study the native organization of alternative NAD(P)H-dehydrogenases NDA and NDB in plant mitochondria. The work was performed on six-day etiolated pea seedlings. The 2D BN/SDS-PAGE in combination with immunochemistry found that, in pea organelles, the main part of the populations of NDA and NDB alternative NAD(P)H dehydrogenases were included in superstructures with masses of 700, 780, and 900 kDa. Additionally, NDA was detected in the region of 1480 and 1600 kDa, and NDB was registered at values of 1330, 340, and 100–120 kDa. An analysis of subunit profiles of the observed associations and a colorimetric detection of ATPase activity in 1D BN-gel suggested that the major part of the NDA and NDB populations identified by the available antibodies was associated with ATP synthase and represented a heterogeneous population of ATP-synthasomes, assumably, with a NDA2/NDB2Va/b1-2 composition. The rest of the enzymes were likely to be part of the NDA2/NDB2III2IV and NDA2IV1Va2 supercomplexes. The physiological significance of the association of alternative NAD(P)H dehydrogenases with ATP synthase requires further study.

Construction of Co(II), Cu(II), and Zn(II) coordination compounds driven by a pyridine-dicarboxylic acid: Hydrothermal assembly, structural and topological versatility, and catalytic properties

A derivative of pyridine-dicarboxylic acid, 5-(3-carboxyphenyl)picolinic acid (H2cpic), was used as a versatile building block to synthesize a series of five novel coordination compounds under hydrothermal conditions and formulated as {[Cu2(μ-cpic)2(phen)]·H2O}n (1), [Co(μ-cpic)(phen)(H2O)]n (2), [Cu2(μ-cpic)2(2,2′-bipy)(H2O)2]·2H2O (3), {[Cu3(μ-cpic)3(μ-4,4′-bipy)1.5(H2O)3]·2H2O}n (4), and {[Zn2(μ-cpic)2(μ-dpe)0.5(H2O)3]·H2O}n (5). The auxiliary ligands used in the synthesis were 1,10-phenanthroline (phen), 2,2′-bipyridine (2,2′-bipy), 4,4′-bipyridine (4,4′-bipy), and 1,2-di(4-pyridyl)ethylene (dpe). The structures of the compounds 1–5 vary significantly, ranging from a 0D tetramer (3) to 1D metal–organic chains (1, 2, 4, and 5). Furthermore, these compounds were evaluated as heterogeneous catalysts for the Henry reaction, achieving high product yields under optimized conditions. We further investigated various reaction parameters, and substrate scope, and assessed the feasibility of catalyst recycling. This thorough investigation highlights the versatility of H2cpic as a dicarboxylate building block in the formation of functional coordination polymers.

Equimolar CO2 adsorption by two Ni-based MOFs and their kinetic and thermodynamic studies

Metal-organic frameworks (MOFs) show great potential in CO2 capture due to their unique structure. This study investigated two Ni-based MOFs, Ni-MOF-74 and IR-MOF-74, with different organic ligand chain lengths. The optimal activation temperatures for each material were determined, resulting in high CO2 adsorption capacities (1.9401 and 1.9475 mmol/g at 30 °C and 0.16 bar, respectively). The adsorption capacities of the two materials were found to reach the equimolar adsorption by the fitting calculation. The adsorption process of Ni-MOF-74 and IR-MOF-74 were found to follow a pseudo-first-order kinetic model. Thermodynamic analysis revealed an entropy-enthalpy complementarity between Ni-MOF-74 and IR-MOF-74 during CO2 capture. Notably, optimal adsorption and desorption temperatures were determined for these materials, a first in the field of porous solid adsorbents. Finally, the materials demonstrated stable adsorption capacity over 10 cycles.

Charge transfer complex induced confinement effect between organic semiconductor and polymer chains for enhancing high-temperature capacitive energy storage

High-temperature polymer dielectrics, renowned for their ultrahigh power densities, robust voltage endurance, and remarkable reliability, present significant potential in optimizing the functionality of microelectronics and electrical power systems. Herein, to elucidate a notable correlation between the confinement effect induced by charge transfer complexes (CTCs) and the discharged energy density (Ue), a series of PI-based composites were synthesized, integrating organic semiconductors with diverse electron affinities. The density functional theory (DFT) simulations revealed that escaping from the CTCs required higher activation energy, besides, a more pronounced electron localization function was observed in the interfacial region between PI chain and F6TCNNQ in comparison to pristine PI, PI/F2TCNQ, and PI/F4TCNQ. Consequently, the CTCs present in PI/F6TCNNQ exhibit the greatest electron localization, significantly impeding electron transport within the composite. Furthermore, at 200 °C, the Ue for the PI/F6TCNNQ composite remains notably high at 5.06 J cm−3 with an efficiency above 90 %, representing a 2.45-fold increase compared to that of pristine PI (2.03 J cm−3). The findings provide evidence for a positive correlation between the confinement effect induced by CTCs and the discharged energy density (Ue) of the composite materials at elevated temperatures, thus offering valuable insights for future investigations focused on all-organic dielectric composite materials.

Quasi-One-Dimensional Zigzag Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution from Water.

Covalent organic frameworks (COFs) have potential applications in a wide range of fields. However, it remains a critical challenge to constrain their covalent expansions in the one-dimensional (1D) direction. Here, we developed a general approach to fabricate 15 different highly crystalline COFs with zigzag-packed 1D porous organic chains through the condensation of V-shaped ditopic linkers and X-shaped tetratopic knots. Appropriate geometrical combinations of a wide scope of linkers and knots with distinct aromatic cores, linkages, and functionalities offer a series of quasi-1D COFs with dominant pore sizes of 7-13 Å and surface areas of 116-784 m2 g-1. Among them, nitrogen (N)-doped 1D COFs with site-specific doping of heteroatoms favor a tunable control of band structures and conjugations and thus allow a remarkable hydrogen evolution rate up to 80 mmol g-1 h-1 in photocatalytic water splitting. This general strategy toward programming function in porous crystalline materials has the potential to tune the topologically well-defined electronic properties through precisely periodic doping.

An assessment of potential interventions to reduce the totoaba illegal trade market.

The illegal trade in totoaba (Totoaba macdonaldi) is causing adverse social, ecological, and economic impacts. This illegal activity is accelerating the overexploitation of totoaba and pushing the critically endangered vaquita (Phocoena sinus) closer to extinction. Despite extensive efforts to recover vaquita populations, scant attention has been given to the totoaba trade as an independent issue. As a result, data on the totoaba trade are limited, which hampers robust analyses and development of effective interventions to reduce illegal harvesting. We used a previously developed framework specifically designed to examine dynamics of illegal markets and guide measures to mitigate illegal use of totoaba. This framework separates markets into 3 analytical levels: characterization of participating actors (e.g., fishers, intermediaries); examination of how actors interact within the market (e.g., organization of supply chains); and assessment of the overall market dynamics that result from these interactions (e.g., factors determining price and quantity). We reviewed existing literature (108 initial articles) and interviewed key market actors, academics, and nongovernmental organization experts (14) to obtain data for this framework. Our findings offer an overview of the totoaba illegal market operation, highlighting intervention points (e.g., customs agents) and areas where additional information is required to decrease information gaps (e.g., US local market). We describe the structure and complexity of this market, emphasizing the influential role of organized crime in shaping its dynamics (e.g., controlling prices paid to fishers and stockpiling). By providing a systematic and in-depth understanding of the market operation, we aimed to establish a benchmark for effective interventions and future research aimed at reducing uncertainties. Our results provide a crucial step toward addressing this critical issue and can help facilitate development of effective strategies to combat the illegal totoaba trade and promote biodiversity conservation more broadly.