Metal Ores Research Articles

Renewable energy and institutional quality effect on carbon dioxide emissions empirical study: a multi-factor analysis

ABSTRACT With the development of society, the development of industry, the demand for fossil fuels and metal ores has also increased, leading to the uncontrolled exploitation of natural resources and their further reduction. Due to the widespread use of fossil fuels, carbon dioxide emissions are increasing every day. This is a common concern of many countries. In countries along the Belt and Road, carbon emissions have increased due to rising incomes, financial growth and urbanization. This paper investigates CO2 emissions in Belt and Road countries, using Stochastic Impacts by Regression on Population, Affluence, and Technology Framework and Driscoll-Kraay regression model were used for multi-factor analysis. Research shows that more renewable energy can help improve the energy system and reduce carbon dioxide emissions. In addition, research shows that the better the quality of the institution, the lower the carbon dioxide emissions. The government should also improve the system to reduce pollution from the second.

Balancing Submarine Landslides and the Marine Economy for Sustainable Development: A Review and Future Prospects

To proactively respond to the national fourteenth Five-Year Plan policy, we will adhere to a comprehensive land and sea planning approach, working together to promote marine ecological protection, optimize geological space, and integrate the marine economy. This paper provides a comprehensive review of the sustainable development of marine geological hazards (MGHs), with a particular focus on submarine landslides, the marine environment, as well as the marine economy. First, the novelty of this study lies in its review and summary of the temporal and spatial distribution, systematic classification, inducible factors, and realistic characteristics of submarine landslides to enrich the theoretical concept. Moreover, the costs, risks, and impacts on the marine environment and economy of submarine engineering activities such as oil and gas fields, as well as metal ores, were systematically discussed. Combined with the current marine policy, an analysis was conducted on the environmental pollution and economic losses caused by submarine landslides. Herein, the key finding is that China and Mexico are viable candidates for the future large-scale offshore exploitation of oil, gas, nickel, cobalt, cuprum, manganese, and other mineral resources. Compared to land-based mining, deep-sea mining offers superior economic and environmental advantages. Finally, it is suggested that physical model tests and numerical simulation techniques are effective means for investigating the triggering mechanism of submarine landslides, their evolutionary movement process, and the impact on the submarine infrastructure. In the future, the establishment of a multi-level and multi-dimensional monitoring chain for submarine landslide disasters, as well as joint risk assessment, prediction, and early warning systems, can effectively mitigate the occurrence of submarine landslide disasters and promote the sustainable development of the marine environment and economy.

Editorial for Special Issue “Rare Metal Ore Formations and Rare Metal Metallogeny”

Rare metals (usually defined as including elements such as Li, Rb, Cs, Be, Sn, Nb, Ta, Zr, Y, U, and rare-earth elements) are included in the list of “critical mineral resources” by major economies around the world [...]

Recycling and Reutilization of Metals Aided by Deep Eutectic Solvents: from NMC Cathodes of Spent Li-ion Batteries to Electrolytes for Supercapacitors.

With the rapidly increasing demand for lithium ion batteries (LIBs), recycling the metals found in spent cathodes is mandatory to both alleviate shortages resulting from the mining of natural metal ores and manage the disposal of spent LIBs. The use of deep eutectic solvents (DESs) for metals recovery from spent cathodes of LIBs (e. g., LCO and NMC types) offers a sustainable yet efficient alternative to conventional hydrometallurgical processes. Nonetheless, g efforts are required to use milder temperatures and higher mass loadings, thus ensuring cost-effectiveness. In this latter regard, addressing the reutilization of DESs in subsequent stages of metal extraction, and streamlining or eliminating the chemical procedures employed for metal separation, is even more crucial to guarantee the economic feasibility of the recycling process. Herein, we have prepared a DES that provides extraction efficiencies of ca. 100 % for every metal of NMC cathodes even at mild experimental conditions (e. g., 60 °C) and for loadings as high as 70 mgNMC/gDES. Moreover, we have pioneered the direct use of leachates containing DESs and metals as electrolytes for supercapacitors. This approach enables the reintroduction of DESs and the recovered metals into the value chain with a minimal economic and environmental impact.

Obituary: Surendra Abaji Pandhare (1940 – 2023)

Shri Surendra Abaji Pandhare, Retired Director, Geological Survey of India (GSI), did his schooling from Chandrapur. He completed his post graduation in Applied Geology from the University Department of Geology, Nagpur University, in 1965, topping the merit list. He worked with the Directorate of Geology and Mining (DGM), Maharashtra, for two years thereafter, and joined GSI as Assistant Geologist in February 1968. Shri Pandhare was promoted as Geologist in 1972 and as Senior Geologist in 1981. Posted at Raipur and Bhopal, he was engaged in systematic mapping. Thereafter, he was engaged in magnesite exploration in Bastar dist, bauxite in Amarkantak and East Coast, base metals in Sidhi district and iron ore in Raoghat area, all in the then undivided M.P. state. During 1968, he compiled technical information on the till then, all the GSI Engineering Geology projects in Central India and prepared a reference map. Shri Pandhare was transferred to the then Planning and Coordination Division (now Policy Support System Division), Central Region, GSI, Nagpur, in 1982, where he continued to be posted till 1998. Here, he handled matters related to technical coordination of field items in the Central Region, material management (stores) and was also inquiry officer for many vigilance cases . He was elected as President of the GSI Scientific Officers Association (GSISOA) for the 1993- 95 term. His keen administrative acumen helped him navigate through as a popular leader, during the turbulent years of career progression of GSI geoscientists. He was liked by a vast majority in the geoscientific fraternity of the GSI.

Tin-polymetallic mineralization and granitic rocks in the Nanling daping mining area: Geochemical and geochronological constraints

The Daping polymetallic deposit in the Nanling is a recently discovered deposit with significant potential in the Dayishan area. High-precision geochronological studies indicate that the emplacement ages of two fine-grained porphyritic (containing tourmaline) biotite granite units are 153.2 ± 0.9 Ma and 152.3 ± 1.0 Ma, representing products of the fifth magmatic activity in the Dayishan intrusion. The cassiterite U-Pb ages from the residual skarn type and greisen-type tin ores are 153.4 ± 3.6 Ma and 150.22 ± 0.37 Ma, respectively, and they are consistent within the error range, both belonging to the Yanshanian Early period. Petrogeochemical analyses of the granite reveal characteristics of high silica content (73.56 ∼ 75.91 %), alkali (K2O = 4.04 ∼ 5.58 %, Na2O = 2.22 ∼ 3.67 %), low calcium (0.42 ∼ 0.80 %), low magnesium (0.075 ∼ 0.29 %), and peraluminous nature (A/CNK = 1.26 ∼ 1.35). The rare earth element (REE) contents range from 35.78 × 10-6 to 111.57 × 10-6, with δEu values between 0.006 and 0.026, LREE/HREE ratios of 2.23 ∼ 3.41, and (La/Yb)N values of 1.20 ∼ 2.42. The granite is enriched in elements such as Rb, K, Th, U, Nd, Hf, and depleted in Ba, Sr, P, Nb, Ti, indicating strong crystal differentiation in the area. Sr, Nd, and Hf isotope studies show that the granite samples have ISr values of 0.67612–0.70040, εNd(t) values of −5.83 ∼ -8.23, εHf(t) values of −6.1 ∼ -1.9, (Nd)TDM2 values ranging from 1361 to 1573 Ma, and (Hf)TDM2 values ranging from 1147 to 1408 Ma. It is proposed that the Dayishan intrusion originated from the mixing of a mid-Paleoproterozoic mafic rock and a metamorphic sedimentary source region, with the latter being predominant. The detachment of source rocks from the mantle reservoir occurred in the mid-Paleoproterozoic. Combining lithological, petrogeochemical, and comparative analyses, it is classified as a highly fractionated A-type granite formed in a local extensional setting related to the subduction of the Pacific Plate. Additionally, this paper constructs a ore-forming model for the Daping tin deposit, aiming to provide reference for regional rare metal ore exploration.

What Extra Information Can Be Provided by Multi-Component Seismic Data: A Case Study of 2D3C Prospecting of a Copper–Molybdenum Mine in Inner Mongolia, China

With the decrease in shallow mineral reserves, deep mineral resources have become the focus of exploration. Seismic exploration, renowned for its deep penetration and high spatial resolution and precision, stands as a primary technique in geophysical exploration. In comparison to traditional P-wave seismic exploration, multi-component seismic techniques offer the advantage of simultaneously acquiring P-wave and S-wave data, overcoming the limitations of single P-wave impedance in predicting lithology and enabling high-precision imaging of subsurface structures. Constrained by field survey costs, the reflection seismic illumination is lower and results in a poor signal-to-noise ratio of multi-component seismic data in metallic ore exploration, which poses great challenges in imaging converted S-waves. Based on the seismic and geological characteristics of metallic ores, this study conducts imaging research on metallic ore models through synthetic data and field multi-component seismic data from a copper–molybdenum mine in Inner Mongolia, China. The emphasis is given to PS-wave pre-stack time migration based on precisely sorting the commonly converted point so as to explore the feasibility and technical advantages of multi-component seismic exploration in metal mines. Synthetic data and field data testing demonstrate that PS-wave imaging contains more abundant structural and lithological information compared to PP-waves, indicating promising prospects for the application of multi-component seismic data in metallic ore exploration.

Full-Waveform Modeling of Complex Media Seismic Waves for Irregular Topography and Its Application in Metal Ore Exploration

Full-Waveform Modeling of Complex Media Seismic Waves for Irregular Topography and Its Application in Metal Ore Exploration

Microbial Sulfur and Arsenic Oxidation Facilitate the Establishment of Biocrusts during Reclamation of Degraded Mine Tailings.

Degraded tailings generated by the mining of metal ores are major environmental threats to the surrounding ecosystems. Tailing reclamation, however, is often impeded due to adverse environmental conditions, with depleted key nutrients (i.e., nitrogen (N) and phosphorus (P)) and elevated sulfur and metal(loid) concentrations. Formation of biocrusts may significantly accelerate nutrient accumulation and is therefore an essential stage for tailing reclamation. Although suggested to play an important role, the microbial community composition and key metabolisms in biocrusts remain largely unknown and are therefore investigated in the current study. The results suggested that sulfur and arsenic oxidation are potential energy sources utilized by members of predominant biocrust bacterial families, including Beijerinckiaceae, Burkholderiaceae, Hyphomicrobiaceae, and Rhizobiaceae. Accordingly, the S and As oxidation potentials are elevated in biocrusts compared to those in their adjacent tailings. Biocrust growth, as proxied by chlorophyll concentrations, is enhanced in treatments supplemented with S and As. The elevated biocrust growth might benefit from nutrient acquisition services (i.e., nitrogen fixation and phosphorus solubilization) fueled by microbial sulfur and arsenic oxidation. The current study suggests that sulfur- and arsenic-oxidizing microorganisms may play important ecological roles in promoting biocrust formation and facilitating tailing reclamation.

Geophysical Assessment of Structurally Controlled Mineral Resources at Wadi El-Nakheel, Eastern Desert, Egypt

It is of great importance to evaluate simple methods to identify mineral occurrence for the future development of society. Applying a reconnaissance magnetic data analysis can help detect the main structural trends mounted to the occurrence of minerals. In this study, geological and geophysical data were analyzed to evaluate the main structural trends affecting mineralization in the area of Wadi El-Nakheel. Geomagnetic data were processed to remove the earth’s magnetic field and reduce the magnetic pole. Some mathematical filters related to detecting and enhancing boundaries between rock units, depending on their magnetization affinity, were applied, including the first vertical derivative, the analytic signal, and 3D Euler deconvolution. After structural analysis of these data, we reached the following findings: The main structural trends from the surface and subsurface estimations were the northwest–southeast trend and the northeast–southwest trend. The orientation and origin of Wadi El-Nakheel are aligned with the main structural trend affecting the area that formed during the Red Sea Rift movement and the Pan-African orogeny. The depth of the deep-seated structure controlling the valley is 1500 m and all mineral occurrence is mainly structurally controlled in the studied area; phosphate ore outcrops are usually aligned with the northwest–southeast geological trend, and metallic ores are related to basement rock succession and the main dominant geological structures in the studied area. Finally, the magnetic method was demonstrated to be a reliable tool for detecting the subsurface boundary between geologic units.

The Chain of Processes Forming Porphyry Copper Deposits—An Invited Paper

Abstract Porphyry-related mineral deposits are giant geochemical anomalies in the Earth’s crust with orders-of-magnitude differences in the content and proportion of the three main ore metals Cu, Au, and Mo. Deposit formation a few kilometers below surface is the product of a chain of geologic processes operating at different scales in space and time. This paper explores each process in this chain with regard to optimizing the chances of forming these rare anomalies. On the lithosphere scale, deposits with distinct metal ratios occur in provinces that formed during brief times of change in plate motions. Similar metal ratios of several deposits in such provinces compared with global rock reservoirs suggest preceding enrichment of Au or Mo in lithospheric regions giving rise to distinct ore provinces. The largest Cu-dominated deposits and provinces are traditionally explained by selective removal of Au during generation or subsequent evolution of mantle magmas, but the possibility of selective Cu pre-enrichment of lithosphere regions by long-term subduction cannot be dismissed, even though its mechanism remains speculative. Evolution of hydrous basaltic melts to fertile magmas forming porphyry Cu deposits requires fractionation toward more H2O-rich magmas in the lower crust, as shown by their adakite-like trace element composition. The prevailing interpretation that this fractionation leads to significant loss of chalcophile ore metals by saturation and removal of magmatic sulfide might be inverted to a metal enrichment step, if the saturating sulfides are physically entrained with the melt fraction of rapidly ascending magmas. Ascent of fertile magma delivers a large mass of H2O-rich ore fluid to the upper crust, along points of weakness in an overall compressive stress regime, within a limited duration as required by mass and heat balance constraints. Two mechanisms of rapid magma ascent are in debate: (1) wholesale emplacement of highly fractionated and volatile-rich granitic melt into a massive transcrustal channelway, from which fluids are exsolved by decompression starting in the lower crust, or (2) partly fractionated magmas filling a large upper crustal magma chamber, from which fluids are expelled by cooling and crystallization. Transfer of ore-forming components to a hydrothermal ore fluid is optimized if the first saturating fluid is dense and Cl rich. This can be achieved by fluid saturation at high pressure, or after a moderately H2O rich intermediate-composition melt further crystallizes in an upper crustal reservoir before reaching fluid saturation. In either case, metals and S (needed for later hydrothermal sulfide precipitation) are transferred to the fluid together, no matter whether ore components are extracted from the silicate melt or liberated to the ore fluid by decomposition of magmatic sulfides. Production and physical focusing of fluids in a crystallizing upper crustal magma chamber are controlled by the rate of heat loss to surrounding rocks. Fluid focusing, requiring large-scale lateral flow, spontaneously occurs in mushy magma because high water content and intermediate melt/crystal ratio support a network of interconnected tubes at the scale of mineral grains. Calculated cooling times of such fluid-producing magma reservoirs agree with the duration of hydrothermal ore formation measured by high-precision zircon geochronology, and both relate to the size of ore deposits. Ore mineral precipitation requires controlled flow of S- and metal-rich fluids through a vein network, as shown by fluid inclusion studies. The degree of hydrothermal metal enrichment is optimized by the balance between fluid advection and the efficiency of cooling of the magmatic fluid plume by heat loss to convecting meteoric water. The depth of fluid production below surface controls the pressure-temperature (P-T) evolution along the upflow path of magmatic fluids. Different evolution paths controlling density, salinity, and phase state of fluids contribute to selective metal precipitation: porphyry Au deposits can form at shallow subvolcanic levels from extremely saline brine or salt melt; high-grade Au-Cu coprecipitation from coexisting and possibly rehomogenizing brine and vapor is most efficient at a depth of a few kilometers; whereas fluids cooling at greater depth tend to precipitate Cu ± Mo but transport Au selectively to shallower epithermal levels. Exhumation and secondary oxidation and enrichment by groundwater finally determine the economics of a deposit, as well as the global potential of undiscovered metal resources available for future mining.

The ecological and sanitary-hygienic assessment of the river systems located in the technogenic polluted zone of the Caucasus

The Caucasus is characterized by the large and at the same time increasing load from exploited metal and non-metallic mines. The sanitary-hygienic and toxic danger to people and the environment is quite high. There are 44 metal ores in the Syunik Region, and more than 90 non-metal deposits. In 2018, 12 metal and 29 non-metallic deposits were granted with the use rights for the purpose of mineral extraction. Also, geological survey permission was granted for 12 metal deposits. Currently, there are 12 operating and conserved tailings filled with about 400 million m3 of tailings, which are equipped with many heavy metals and other dangerous substances, as the result of the exploitation of the metal mines in Syunik. The present study focuses on the ecological assessment of the waters of the Voghji and the Khalaj Rivers that are located in the technogenic polluted zone of the Caucasus. The research revealed that along with the increase of the volumes of the Kapan-Qajaran copper-molybdenum mines, as well as the increase of the rock dumps and tailings, the organoleptic-chemical indicators of the waters of the Voghji and the Khalaj Rivers had increased. The quantity of the suspended particles and the heavy metals in the waters of these rivers had increased 1.5 and 2.0 times or by 58–100 % and 19.5 − 29.8 %, respectively, in the last 10 years. The trends are also observed in the values of the sulfates, the total dissolved salts, and the electrical conductivity, which are due to the chemical composition of the ores and the improper management of the acid drainage. The content of the heavy metals in the waters of the mentioned rivers is 9 − 20 times higher than the permissible limit density, and the degree of the mineralization is above the permissible limit. Thus, the waters of these rivers, after mixing with the effluent from the mining industry, are not guaranteed to be used for irrigation. Considering that the mobility of the heavy metals decreases several times in the alkaline environment (pH 8.5 − 9.0), it is recommended that the mining industry constantly adds lime (CaO) to the acid drainage of the mines so that the pH of the water become lower: from acid to alkaline (pH 8.5 − 9.0) and only after that, the water could be used for irrigation of the agricultural crops. This is possible for many types of heavy metals, including when using other wastewater treatment measures: engineering, physicochemical and biological.

Formation of the giant Maoping Mississippi Valley-type Pb–Zn (Ge) deposit via fluid mixing: Evidence from trace element and sulfur isotope geochemistry of pyrite

The SYG (Sichuan–Yunnan–Guizhou) area is one of the most economically significant Mississippi Valley Type (MVT) ore provinces, providing approximately 27 % of the Pb–Zn resources in China. The Pb-Zn deposits in this region are renowned for their high grade, and the Maoping deposit with 20.3 % Pb-Zn grade is one prime example. However, the mechanism of such high-grade mineralization remains unclear, and pyrite may record valuable ore-forming information before and during Pb-Zn mineralization. Based on field geology and petrography, three hydrothermal stages were identified in the Maoping deposit: dolomite–pyrite vein (stage I), dolomite–sphalerite–galena vein (stage II), and calcite vein (stage III). Three types of pyrite are recognized: Py1 and Py2 occur in stage I, and Py3 is closely associated with sphalerite and galena in stage II. Py1 exhibits the highest concentrations of S, Pb, Sb, Cu, Co, Ni, V, Ag, Mn, Se, and Mo, and Py3 shows the highest Fe and As contents but the lowest levels of S, Pb, Sb, Cr, Ti, Co, Ni, Mn, and Mo. The element composition of Py2 shows transitional characteristics between those of Py1 and Py3. The Co and Ni contents gradually decrease from Py1 through Py2 to Py3, while their ratios remain within the range of 0.1–1.0. Compared with Py1 and Py2, Py3 exhibits suddenly elevated As levels and apparent acicular structures, indicating that a rapidly precipitating environment was likely triggered by an abrupt temperature decrease. Py1 exhibits δ34S values of 19.7–21.5 ‰, followed by Py2 between 18.6 and 21.1 ‰; both indicate that the sulfur was sourced from sulfates by thermochemical sulfate reduction (TSR). In contrast, Py3 exhibits lower δ34S values ranging from 7.5 to 11.0 ‰, potentially attributed to bacterial sulfate reduction (BSR). The differences in mineral structure, element composition, and sulfur isotopes among the three pyrite types indicate the involvement of two distinct fluids: metal-bearing basin brine and fluid containing reduced sulfur. The former was derived from basin brine that extracted ore metals (Pb2+ and Zn2+) from host sedimentary piles. The latter originated from carbonate strata in the Maoping area containing reduced sulfur formed by BSR. We propose that the ore-bearing basin brine reacted with organic matter in the wallrock through TSR to generate Py1 and Py2 in stage I and then mixed with the positioned fluid containing reduced sulfur via BSR to precipitate Py3, sphalerite, and galena in stage II. Hence, fluid mixing is the primary ore-forming mechanism and effectively accounts for the high-grade Pb–Zn ores in the Maoping deposit.

Living in a post‐industrial landscape: repeated patterns of genetic divergence in brown trout (Salmo trutta L.) across the British Isles

AbstractAimThe British Isles have been worked for millennia to extract metal ores to feed industrial development, leaving a legacy of mine water pollution that continues to impact freshwater communities in many regions. Brown trout (Salmo trutta L.) have long been observed to persist in these metal‐impacted systems as apex predators, with previous studies showing a small number of impacted populations to be highly genetically divergent. We sought to understand the scale of genetic diversity across regions and the repeatability of genetic divergence in trout populations affected by metal pollution.LocationWe examined four mine water‐impacted regions across the British Isles: west Wales, northeast England, southwest England and southeast Ireland.MethodsWe employed a panel of 95 SNP loci to screen 1236 individuals from 71 sites representing paired metal‐impacted and clean sites from across the four regions. From these, we obtained diversity statistics, assessed genetic structuring of populations and modelled historical demographic scenarios to understand which factors most credibly explain genetic variation in divergent populations.ResultsWe evidenced hierarchical population structure in the regions studied, in line with expectations from phylogeographic history. However, in a hierarchical analysis of genetic structuring the first level of differentiation was driven by the divergence of the metal‐impacted trout of Cornwall in southwest England. Within regions we observed reduced genetic diversity and repeated patterns of local genetic sub‐structuring between paired samples from metal‐impacted and relatively clean sites. Demographic history analyses suggested the timing of these splits to be relatively recent and to be associated with periods of peak mining activity.Main conclusionsOur findings demonstrate distinct patterns of genetic isolation and reduced diversity arising from legacy pollution in freshwater ecosystems, with impacts being most apparent where both chemical pollution and physical barriers are present. Management should focus on the amelioration of mine water wash‐out and the removal of barriers to fish movement to safeguard genetic diversity in impacted populations.

NEW TECHNOLOGIES FOR PROCESSING TAILINGS OF A COPPER PROCESSING PLANT FOR THE EXTRACTION OF PLATINOIDS

The most important task of the mining and metallurgical industry in the world is the development of technology for the processing of industrial waste from metallurgical industries. In the world, balance ores of precious metals are practically available. This issue develops the processing of man-made waste, refractory ores, off-balance and low-grade dumps. The article considers studies of the material and rational compositions of the tailings of a copper concentrating plant in the conditions of JSC Almalyk MMC, determines the optimal method for tailings enrichment with an increase in the content of precious metals in the concentrate, and enhances an unconventional new scheme for processing platinum group concentrates with the extraction of platinum, palladium, silver and high recovery gold. Based on the learned subjects and analysis of studies results, the authors concluded that the centrifugal concentration of platinoids from the composition of the tailings was achieved due to accurate determinations of the particle size in the tailings with the selection of intense gravity modes. Combined hydrometallurgical methods for purifying platinoids and gold from impurities using combinations of chemical solvents have been developed. As a result, the developed technologies have achieved the possibility of complex extraction of platinum group metals from the tailings of concentrating plants of copper production with high degrees, through extraction of all precious metals.

NEW TECHNOLOGIES FOR PROCESSING TAILINGS OF A COPPER PROCESSING PLANT FOR THE EXTRACTION OF PLATINOIDS

The most important task of the mining and metallurgical industry in the world is the development of technology for the processing of industrial waste from metallurgical industries. In the world, balance ores of precious metals are practically available. This issue develops the processing of man-made waste, refractory ores, off-balance and low-grade dumps. The article considers studies of the material and rational compositions of the tailings of a copper concentrating plant in the conditions of JSC Almalyk MMC, determines the optimal method for tailings enrichment with an increase in the content of precious metals in the concentrate, and enhances an unconventional new scheme for processing platinum group concentrates with the extraction of platinum, palladium, silver and high recovery gold. Based on the learned subjects and analysis of studies results, the authors concluded that the centrifugal concentration of platinoids from the composition of the tailings was achieved due to accurate determinations of the particle size in the tailings with the selection of intense gravity modes. Combined hydrometallurgical methods for purifying platinoids and gold from impurities using combinations of chemical solvents have been developed. As a result, the developed technologies have achieved the possibility of complex extraction of platinum group metals from the tailings of concentrating plants of copper production with high degrees, through extraction of all precious metals.

Utilizing Random Forest algorithm for identifying mafic and ultramafic rocks in the Gameleira Suite, Archean-Paleoproterozoic basement of the Brasília Belt, Brazil

Geological mapping techniques have continuously advanced, particularly with the increasing use of remote data acquisition methods, such as aerogeophysical data analysis and the use of machine learning techniques, both has become essential for mapping and understanding geological environments. Mafic-ultramafic bodies, which may be linked to metallic ore deposits, can be mapped using these innovative techniques. In Brazil, the Tocantins Province is reknown for its primary Cu–Co–Ni–Cr ore deposits, which are found in mafic-ultramafic rocks. The Tocantins Province contains several mafic-ultramafic bodies that have received less attention than the well-known deposits in the Brasília Belt. The Gameleira Suite is a geological unit located in the basement of the North Brasília Belt. Our study aims to use machine learning to identify new potential mafic-ultramafic occurrences in the Gameleira Suite. To achieve this, aerogeophysical surveys data, including magnetometry and radiometry, were used in conjunction with remote sensing. The data collected from aerogeophysics surveys were compiled into a database. The Random Forest algorithm was used to analyze this database, with 1.96% (from a total of 84.535 samples) used for training and generating the predictive map. Three approaches were used to verify and evaluate the data: analyzing magnetic lineaments to assess the influence of structural tectonic factors on body positioning, collecting field samples, and utilizing Magnetic Vector Inversion (MVI) to analyze the magnetic properties of the projected bodies at depth. This was done because the Gameleira Suite bodies display magnetic remanence. Our findings suggest that the utilization of these methods, in conjunction with the verification techniques employed, aids in the mapping and identification of mafic-ultramafic rocks. Machine learning can improve cartography by identifying new occurrences or indicating areas that need more detailed mapping. The use of additional geological knowledge and information not included in the model is crucial because the predictive map does not inherently represent geological truth. It is necessary to interpret the results from a geological perspective.

Trace element (Be, Zn, Ga, Rb, Nb, Cs, Ta, W) partitioning between mica and Li-rich granitic melt: Experimental approach and implications for W mineralization

Mica is the most important carrier of rare alkalis (Li, Rb and Cs) and volatiles, and also a major host of rare metals such as Sn, W, Nb and Ta. Thus, the knowledge of trace element partitioning between mica and silicate melt is crucial to understand enrichment mechanisms of ore metals in evolved silicic systems. However, experimental data are scarce, mainly because the synthesis of large mica grains which can be analyzed with laser ablation techniques is challenging. To address this issue, we conducted two-step experiments, using a high-temperature step at 800 °C, and a low-temperature step at 600 °C with a temperature cycling interval of 30 °C, and variable run durations from 21 to 60 days. The experimental products, at 600 °C, 200 MPa, are mainly composed of mica and alkali feldspars. Ferroholmquistite (Fhlm; a Li-bearing amphibole) was also observed in the Li-bearing systems.Beryllium, Zn and Cs are highly incompatible in all run products with mineral/melt partitioning of mineral/meltDBe between 0.01 and 0.08, mineral/meltDZn between < 0.01 and 0.24 and mineral/meltDCs between <0.01 and 0.19. Gallium is mildly incompatible in mica and feldspars with mica/meltDGa, K-feld/meltDGa and Na-feld/meltDGa of 0.24–0.35, 0.60–0.67 and 0.69–0.72, respectively, whereas Fhlm/meltDGa is nearly 1. Rubidium is characterized by a slight enrichment in mica and K-rich feldspar with respect to melt. Niobium and Ta are highly incompatible in feldspars, while they are compatible in ferroholmquistite. Li-mica crystallization would cause Nb/Ta fractionation with mica/meltDNb and mica/meltDTa of 4.46 and 0.88, respectively. Tungsten is preferentially incorporated in Li-rich mica with mica/meltDW > 22. The strong partitioning of W into Li-rich mica implies that minor Li-rich mica fractionation (>5 %) will strongly deplete W in the residual melt, thus inhibiting transfer to the magmatic fluid at the magmatic-hydrothermal transition. Based on the observed mineral/meltD value, a multi-stage quantitative fractionation model for the behavior of metals during the crystallization of Li-bearing granitic magmas was developed. The results suggest that crystal fractionation is an effective mechanism that could further enrich Be, Ga, Rb, Cs, Nb and Ta in residual melts. Li-rich mica and muscovite are more effective in causing Nb/Ta fractionation as compared with biotite. The very low Nb/Ta ratios found in natural granite may have resulted via extreme, i.e., >99 wt% of fractional crystallization, even if without the precipitation of columbite-group minerals or increasing hydrothermal activity. Due to the very high Li-mica/meltDW value, water saturation in the melt and subsequent magmatic fluid exsolution should occur before Li-mica starts to crystallize to avoid W sequestration in the magma. At 175 MPa, the efficiency of extracting W from Li-poor granitic system is at least 15 % higher than that from Li-rich granitic system. Li-poor granitic systems are thus expected to have a greater W-mineralization potential than Li-rich system, which is consistent with the fact that most parental magmas of large/giant W deposits are Li-poor in composition.

The role of hydrothermal processes and the formation of the J-M reef and associated rocks of olivine-bearing zone I of the Stillwater Complex, Montana

AbstractSeveral lines of evidence, including hydrous melt inclusions and unusually Cl-rich apatite, have been used to suggest that the reappearance of olivine and PGE-sulfide of the J-M Reef in the Stillwater Complex, Montana, is due to fluid infiltration and hydration melting. This study builds upon the hydration melting model using the programs MELTS and PELE with Stillwater bulk rock compositions for the original protolith. Cl-bearing phases are not modeled by MELTS and thus simple oxide mixtures of either a pure H2O or a H2O + Na2O “faux brine” are added to norite, gabbronorite, and melanorite protoliths at 1050 °C at 2 kbar pressure, conditions for which the nominally “dry” protolith is &gt; 95% solid. Incongruent hydration melting results in up to 37% olivine produced in the melanorite. The olivine Fo content is a function of the partial melt retained on cooling, and ranges between 76 and 86, overlapping the natural range of olivine compositions observed in the rocks. Modeling with the PELE program, which includes a silicate liquid Cl component, sulfur species, and a more complex C-O–H-S fluid, suggests that, for CO2-rich fluids, fluid metal concentrations on the order of 25 ppm Pt, 75 ppm Pd, 0.03 wt.% Cu, and 0.20 wt.% Ni at a fluid/rock mass ratio of ~ 0.25 are needed to account for the observed ore grades. Sulfide and ore metals are readily remobilized for more H2O-rich fluids, consistent with heterogeneous distribution of sulfide and regionally variable ore grades.

Deep resistivity geophysics of the San Juan–Silverton caldera complex, San Juan County, Colorado (USA)

Magnetotelluric (MT) and audiomagnetotelluric (AMT) data are used to better understand the subsurface geology and mineral resources in the San Juan–Silverton caldera complex located near Silverton, Colorado, western United States, as part of the extensive southern Rocky Mountains volcanic field that covers much of southwestern Colorado and northern New Mexico. Seven MT and AMT profiles of varying lengths image resistivity structure to depths of ~5 km. The AMT inversion models characterize geophysical responses of near-surface lithologies, structures, and mineralized systems and also help corroborate airborne electromagnetic data at shallow levels. The MT inversion models extend our depth of investigation from near the surface to great depths (~5 km) and help to form hypotheses about roots of the hydrothermal plumbing that fed shallower mineralized systems. Subsurface high resistivities occur beneath intermediate-composition lava flows and Proterozoic units. Subsurface moderate- to low-resistivity values may reflect hydrothermal plumbing that served as flow paths for mineralizing fluids and metallic ore formation. The model interpreta­tions presented in this study could be utilized in remediation planning or mineral resource applications. The methods used could be applied to other watersheds with similar volcanic environments containing acid-generating historical mines or hydrothermally altered and mineralized source rocks.