Optical Profiles Research Articles

568: A Fibre Optic Beam Profile and Dose Monitor for Ultrahigh Dose Rate (FLASH) Beams

568: A Fibre Optic Beam Profile and Dose Monitor for Ultrahigh Dose Rate (FLASH) Beams

Exploring synthesis and annealing influence on WS2 (tungsten disulfide): Structural, morphological, optical, and magnetic profiles

The resurgence of interest in Transition Metal Dichalcogenides (TMDCs) stems from their remarkable magnetic and optical properties, reminiscent of graphene. TMDCs like MoS2, MoSe2, WS2, and WSe2 exhibit substantial bandgaps that shift from indirect to direct in single layers. This characteristic enables diverse applications such as solar cells, transistors, photodetectors, and electroluminescent devices, without the direct use of graphene. In this study, polycrystalline WS2 powder was synthesized via the solid-state reaction method. We systematically investigated the structural, morphological, optical, and magnetic properties concerning the synthesized WS2 and its variants annealed at different temperatures. Through X-ray powder diffraction (XRD) analysis, we confirmed the hexagonal structure of the as-synthesized compound, with a space group of P 63/mmc. Interestingly, no structural transitions were observed in the annealed samples. Morphological examination revealed a plate-like structure across all samples. The determination of the optical bandgap was facilitated by UV-DRS absorption spectrum analysis. Our findings showcased the ferromagnetic behavior of the synthesized WS2, corroborated by magnetic measurements and electron paramagnetic resonance (EPR) analysis. These insights contribute to a deeper understanding of TMDCs and pave the way for their tailored utilization in advanced technological applications.

Investigation of the milled surface quality of SiCp/Al composite materials with a moderate SiCp volume fraction

Silicon carbide particle–reinforced aluminum matrix (SiCp/Al) composite materials are challenging to machine, leading to significant surface quality issues arising during milling. In this study, a single-factor experiment was conducted using carbide-coated tools to mill SiCp/Al composite materials with a 45% volume fraction of silicon carbide particles (SiCps). Scanning electron microscopy, roughness measuring instruments, and a three-dimensional optical profiler were employed to investigate the formation mechanisms of the machined surface morphologies, as well as the effects of milling parameters (milling speed, feed per revolution, and milling depth) on the surface micro-morphology of the SiCp/Al composite materials. This study assessed the suitability of various roughness characterization parameters for evaluating the milled surface of SiCp/Al composite materials, including the two-dimensional profile arithmetic mean deviation (Ra), profile root mean square deviation (Rq), and microscopic surface roughness 10-point height (Rz), as well as the three-dimensional arithmetic mean deviation of the surface profile (Sa), and root mean square deviation of the surface profile (Sq) roughness characterization parameters to evaluate the milled surface of the SiCp/Al composite materials. The findings suggest that the three-dimensional roughness characterization parameters more accurately reflected the changes in the surface roughness than the two-dimensional ones. When the milling speed increased from 0.05 to 1.2 mm/rev, Sa first decreased from 0.514 to 0.498 µm and then increased to 0.537 µm, while Sq first decreased from 0.637 to 0.616 µm and then increased to 0.658 µm. Ra, Rz, and Rq all increased with higher values of feed per revolution and milling depth.

Improvement of AISI 316L laser cladding properties by high-frequency vibration process

In the present paper, a unique laser cladding-assisted high-frequency vibration device was applied to prepare the AISI 316L cladding layer by laser cladding on the surface of the AISI 316L stainless steel substrate. The macroscopic morphology, microstructure, microhardness, and wear resistance of the cladding layer were analyzed by optical microscope, scanning electron microscope, Vickers microhardness tester, friction and wear tester, and three-dimensional optical profiler. The laser cladding-assisted high-frequency vibration device uses a high-frequency oscillator with a fixed frequency (20 KHz) to transfer vibration energy through the probe in contact with the substrate and close to the molten pool. This paper explores the effect of different laser powers on the dilution rate of the cladding layer, compares and observes the cross-sectional morphology and microstructure of the cladding layer with and without high-frequency vibration, and analyzes the reasons for the different results.

Formation of optical soliton wave profiles of nonlinear conformable Schrödinger equation in weakly non-local media: Kudryashov auxiliary equation method

Formation of optical soliton wave profiles of nonlinear conformable Schrödinger equation in weakly non-local media: Kudryashov auxiliary equation method

Dynamical analysis and optical soliton wave profiles to GRIN multimode optical fiber under the effect of noise

Dynamical analysis and optical soliton wave profiles to GRIN multimode optical fiber under the effect of noise

Laser-induced ultrasound in multiple thin layers-An analytical solution.

Laser-induced ultrasound is based on the thermo-elastic conversion of absorbed short light pulses to pressure pulses. In the work presented here, laser-induced ultrasound in a planar structure of interconnected layers with variations in optical, thermal, and mechanical properties is studied. Layered structures can be used for generating wideband ultrasonic pulses specific to a chosen application. An analytical time-domain solution is derived for the resulting pressure transmitted from the layered structure. The solution is derived for an arbitrary number of layers with an arbitrary optical absorption profile. Free space Green's functions with image sources are used to derive the solution. A solution employing the Beer-Lambert law is also proposed. The simplification with reflections only at the boundaries is in agreement with previous published results. The spectral properties of the generated pulse are derived, where the effects of optical absorption coefficients and layer thicknesses are shown. The analytical solution is compared to one-dimensional (1D) simulations and a three-dimensional (3D) simulation, realised as a two-dimensional (2D) axially symmetric case, using the matlab toolbox k-Wave. The 3D simulation on-axis pressure agrees well with the 1D analytical solution when the diameter of the laser beam is larger by approximately 1 order of magnitude than the thickness of the planar layered structure.

Norbornadiene-Quadricyclane Photoswitches with Enhanced Solar Spectrum Match.

Herein, we report monomeric and dimeric norbornadiene-quadricyclane molecular photoswitch systems intended for molecular solar thermal applications. A series of six new norbornadiene derivatives conjugated with benzothiadiazole as the acceptor unit and dithiafulvene as the donor unit were synthesized and fully characterized. The photoswitches were evaluated by experimentally and theoretically measuring optical absorption profiles and thermal conversion of quadricyclane to norbornadiene. Computational insight by density functional theory calculations at the M06-2X/def2-SVPD level of theory provided geometries, storage energies, UV-vis absorption spectra, and HOMO-LUMO levels that are used to describe the function of the molecular systems. The studied molecules exhibit absorption onset ranging from 416 nm to 595 nm due to a systemic change in their donor-acceptor character. This approach was advantageous due to the introduction of benzothiadiazole and the dimeric nature of molecular structures. The best-performing system has a half-life of 3 days with quantum yields over 50 %.

Enhancing Charge Generation in Nonfullerene Interdigitated Heterojunction Organic Solar Cells

Interdigitated heterojunction (IHJ) structures have recently been investigated as an alternatives to bulk heterojunction (BHJ) structures due to their better film morphology stability, reproducibility, and contact selectivity. Herein, the electrical and optical properties of a nonfullerene IHJ structure are investigated using drift diffusion and Maxwell equations and compared with other conventional structures. Based on simulation results, the IHJ structure demonstrates electrical advantages such as enhanced charge transport pathways and reduced nonradiative recombination and exhibits superior optical absorption profiles compared to the BHJ structure, owing to its photonic crystal‐like structure. A method is also proposed to further enhance the optical absorption of this structure by introducing a third organic material with absorption capabilities in the near‐infrared range, increasing the solar cell power conversion efficiency from 18.42% to over 19.5%.

Optical, physical, mechanical, structural, and radiation shielding investigations of B2O3–TeO2-GeO2-MgO-PbO for ionizing protection and optical transmission application

This study aims to investigate a new heavy glass system's potential use in the radiation shielding and optical transmission applications. Glass former like borate is replaced in this work by heavy metal oxides like lead oxide in the following glass system: (35-x) B2O3–20TeO2-10GeO2-35MgO-xPbO (where x = 2.5, 5, 7.5, and 10 mol%). Through the melt-annealing process, four transparent glasses were synthesized. A number of physical properties were reported, namely the boron–boron separation x 10−8 m, field strength x 1018 (cm2), inter nuclear distance x 10−8 m, ion concentration (N) x 1023 (ion cm3), molar volume (cm3/mol), molecular weight (g/mol), and polaron radius x 10−9 m. Moreover, the following mechanical and structural properties of the synthesized glasses were explored: bulk modulus (B, GPa), dissociation energy (kcal/cm3), fractal bond connectivity (d), longitudinal modulus (L, GPa), hardness (H, GPa), oxygen packing density, packing density (Vt), oxygen molar volume, packing factor (Vi), shear modulus (S, GPa), Poisson radius (σ), and Young modulus (Y, GPa). To study the bulk glasses' nature, the X-ray diffraction was examined. Optical absorption along with optical transmission profile have been recorded to extract various optical properties, as well as the direct and indirect band gap. The transmittance spectra of the prepared glass samples' FTIR were investigated within the 400–2000 cm−1 range. This allowed for the examination of molecular structural groups and vibrational modes. Radiation shielding parameters have been calculated and studied using XCOM software and MCNP-5 algorithm.

Random Forest Model-Based Inversion of Aerosol Vertical Profiles in China Using Orbiting Carbon Observatory-2 Oxygen A-Band Observations

Aerosol research is important for the protection of the ecological environment, the improvement of air quality, and as a response to climate change. In this study, a random forest (RF) estimation model of aerosol optical depth (AOD) and extinction coefficient vertical profiles was, respectively, established using Orbiting Carbon Observatory-2 (OCO-2) oxygen-A band (O2 A-band) data from China and its surrounding areas in 2016, combined with geographical information (longitude, latitude, and elevation) and viewing angle data. To address the high number of OCO-2 O2 A-band channels, principal component analysis (PCA) was employed for dimensionality reduction. The model was then applied to estimate the aerosol extinction coefficients for the region in 2017, and its validity was verified by comparing the estimated values with the Cloud-Aerosol Lidar Infrared Pathfinder Satellite Observations (CALIPSO) Level 2 extinction coefficients. In the comprehensive analysis of overall performance, an AOD model was initially constructed using variables, achieving a correlation coefficient (R) of 0.676. Subsequently, predictions for aerosol extinction coefficients were generated, revealing a satisfactory agreement between the predicted and the actual values in the vertical direction, with an R of 0.535 and a root mean square error (RMSE) of 0.107 km−1. Of the four seasons of the year, the model performs best in autumn (R = 0.557), while its performance was relatively lower in summer (R = 0.442). Height had a significant effect on the model, with both R and RMSE decreasing as height increased. Furthermore, the accuracy of aerosol profile inversion shows a dependence on AOD, with a better accuracy when AOD is less than 0.3 and RMSE can be less than 0.06 km−1.

Modulation instability and optical wave profiles for the conformable Schrödinger–Poisson dynamical system

This manuscript studies the exact solitary wave profiles for the conformable Schrödinger–Poisson dynamical system. This system has a significant role in gravity’s quantum state operation approximates the interaction between quantum mechanics and gravitation. The diverse exact solitary wave profiles are constructed by using the Khater method. The different closed-form solutions are obtained such as dark, singular, hyperbolic, periodic, and plane waves. Moreover, the modulation instability is also discussed for this dynamical system. To, show the physical significance of desired results we plot the 3D and 2D plots along with the related contour graphs, which are also drawn. The constraint criteria for the exact solutions are also exposed.

The comparison of an optical and X-ray counterpart of subparsec supermassive binary black holes

In this paper, we study and compare the optical and X-ray counterparts of subparsec supermassive black hole binaries (SMBHBs). With that aim, we simulated the profiles of optical spectral lines emitted from the broad line region (BLR) as well as X-ray spectral lines emitted from the relativistic accretion disks around both black holes and compared them with each other. The obtained results showed that SMBHBs could cause a specific, but different variability of the lines from the optical part and Fe Kα line, leaving potentially detectable imprints in their profiles. Since these imprints depend on the orbital phase of the system, they could be used for reconstructing the Keplerian orbits of the components in the observed SMBHBs. Moreover, such signatures in the optical and X-ray line profiles of the observed SMBHBs could be used as a tool for the detection of these objects as well as for studying their properties.

Revisiting optical absorption power density of inhomogeneous plane waves

We review the analytical expressions for the complex Poynting’s vector in the case of arbitrary plane-waves in a lossy isotropic medium. We demonstrate how these expressions can be used to recover the optical absorption power density Q, considering the divergence of the time-averaged Poynting vector. This quantity, proportional to the imaginary part of the dielectric function and the field intensity, i.e. Q∝|E|2ɛ”, is usually established for harmonic fields, using the Poynting’s identity. The derivation from the complex Poynting vector expression is more direct for TE-polarized homogeneous waves, but the derivation encompasses the other cases like inhomogeneous TM plane waves. As an application, the optical absorption profile Q(x) within 1D multilayers is detailed using matrix transfer method for both TE and TM plane waves, including the evanescent case.

A Novel High-Fidelity Simulation for Finishing Operations: Hybrid Image Mosaic and Wavelet Decomposition.

In finishing simulations, achieving accurate results can be challenging due to the minimal amount of material removal and the limited measurement range of surface micro-topography instruments. To overcome these limitations, a novel high-fidelity modeling method combining image mosaic and wavelet decomposition technologies is proposed in this paper. We achieve the stitching of narrow field and high pixel micro morphology images through four steps: image feature extraction, overlapped feature matching, feature fusion, and stitching effect evaluation. On this basis, the wavelet decomposition method is employed to separate detection signals based on their respective frequencies, allowing the establishment of a datum plane and a roughness surface. The point cloud model undergoes a transformation into a continuous geometric model via the Poisson reconstruction algorithm. In the case study, four sample images of an aluminum alloy sheet after barrel finishing were collected using the ZeGage Plus optical profiler. Each image has an actual size of 834.37 μm × 834.37 μm. Subsequently, a comparison was carried out between the physical and simulation experiments. The results clearly indicate that the proposed method has the potential to enhance the accuracy of the finishing simulation by over 30%. The error between the resulting model and the actual surface of the part can be controlled within 1 μm.

Estimation of net accumulation and removal of fluorescent dissolved organic matter in different Baltic Sea water masses

This study aimed to detect non-conservative processes that affect the distribution of fluorescent dissolved organic matter (FDOM) in the Baltic Sea. An extensive data set comprised of 408 FDOM data, optical and physical profiles, and the development of a water masses balance model allowed us to ascertain the sources of mixing anomalies. These were seen as second-order deviations in the FDOM distribution as a function of salinity in three layers: surface water, Baltic Sea Winter Water, and deep water. The difference between modeled and measured FDOM values at three different excitation/emission wavelengths allowed to show the strength of non-conservative processes, such as photochemical and microbial decomposition (negative residual values) or extracellular release of dissolved organic matter from phytoplankton, heterotrophic uptake and release from anoxic sediments (positive residual values). Humic-like FDOM fractions displayed positive residuals in all seasons for intermediate and deep layers and negative residuals in surface waters. Largest accumulation rates of humic-like fractions were reached in the Gulf of Gdańsk during summer in intermediate and deep layers, while the greatest removal in surface waters was observed during spring in the Bornholm and Gotland Basins and during summer in the Gulf of Gdańsk, probably due to photodegradation. Positive residuals of the protein-like fraction were observed at the surface in summer and autumn in the Gulf of Gdańsk, probably linked to the abundance of phytoplankton and also due to the low molecular weight by-products of photodegradation of humic-like components. Spatial transects revealed an increase in humic-like residuals with depth and a strong correlation with apparent oxygen utilization, increasing with higher fluorescence and exhibiting an asymptotic trend. A relationship was found between the protein-like fractions and phytoplankton biomass proxies. A generalized concept for FDOM cycling in the Baltic Sea was proposed, highlighting photobleaching as the dominant non-linear process determining the efficiency of humic-like FDOM removal. The protein-like component was found to be more efficiently taken up by aerobic prokaryotes at the surface. Microbial utilization and reworking of organic matter, release from sediments, and a decade-long stagnation of bottom water masses, all contribute to the observed accumulation of FDOM in mesohaline deep waters below the permanent pycnocline in the Baltic Sea.

Turbulence-enhanced THz generation by multiple chaotically-distributed femtosecond filaments in air

Remote generation of electromagnetic waves in the terahertz (THz) by the volume of air medium gains increasing scientific interest due to the demand for this spectral range in solving various practical problems including those belonging to the nonlinear atmospheric optics. During self-focusing and filamentation of high-power femtosecond laser pulses in air, the source of THz radiation is the plasma of laser filaments. One of the main challenges of THz generation by a laser filament is increasing the value of optical energy conversion to the long-wavelength band. In this paper, we present the results of our studies on DC-biased THz generation during single-color filamentation in air of focused femtosecond Ti:Sapphire-laser pulses (800 nm, pulse energy up to 40 mJ). The distinctive feature of our study is that a femtosecond optical pulse propagates through a spatially-localized heated air layer containing randomly inhomogeneous refractive index perturbations, which mimics strong air turbulence. For the first time to our knowledge, we show, that the turbulent air layer formed at the beginning of the optical path allows increasing the yield of THz radiation up to 1.5 times due to the formation of multiple chaotically-arranged filaments resulting from random perturbations of the optical beam energy profile that reduces the subsequent THz (re)absorption in the filament plasma.

Exploring structural and optical properties of shock wave-loaded polycrystalline picric acid: implications for molecular engineering applications

Abstract The shock wave impact on hydrogen-bonded organic materials’ structural properties and their responses with respect to their associated functional properties is one of the most prevalent research topics because of the possible emergence of unusual functional properties. Presently, we intend to examine the structural response of the poly-crystalline picric acid samples under shocked conditions. The crystallographic structural responses and the linear optical properties of the test samples have been examined by powder XRD analysis, ultra-violet diffused reflectance spectroscopy (UV-DRS) and Raman spectroscopy, respectively. Under shocked conditions, a considerable modification in the diffraction peak positions and their intensity changes could be witnessed. Notably, linear optical transmittance profiles show remarkable changes according to the number of applied shock pulses, such that the 150-shocked sample has the highest optical transmittance of 53.9 % at 350 nm, whereas the control sample has an optical transmittance of 6.6 %. The Raman spectrum shows the vibrational groups of material that are stable in shocked conditions with similar intensity changes. Based on the obtained XRD, UV-DRS and Raman results, shock wave-induced picric acid samples have remarkably improved characteristics of optical transmittance, which is highly favorable for non-linear optical applications.

Longitudinal Mode Number Estimation of External Cavity Diode Laser Using Dual Periodic Grating for Optical Profiler System.

The concept of an optical profiler based on optical resonance was proposed, highlighting the initial requirements for mode number estimation. We proposed a method for estimating the longitudinal mode number of a laser propagating in an external cavity diode laser with high accuracy, utilizing dual-periodic diffraction gratings. These gratings were fabricated using interference lithography. To estimate the mode number, the wavelengths of two different modes are compared. Therefore, the greater the difference between the wavelengths, the higher the accuracy of the mode number determination. While the mode number difference was approximately 35 when using a conventional diffraction grating, this could be increased by a factor of 20 to around 700 using the dual-periodic grating. The relative accuracy achieved was 1.4 × 10-5.

Fundamental optical constants and anti-reflection coating of melt-grown, polished CsPbBr3 crystals

AbstractLead halide perovskites are notorious for water-sensitivity and low hardness. Consequently, polishing CsPbBr3 crystals to achieve high-quality surfaces is challenging. We present a breakthrough mechanical polishing methodology tailored to the specific needs of these soft, moisture-sensitive semiconductors. Three-dimensional optical surface profiles over ~ 1 mm2 areas demonstrate high-quality surfaces with root-mean-square roughness values (< 10 nm) that are unparalleled for melt-grown CsPbBr3. We additionally delve into the polished wafers’ fundamental optical constants and introduce an anti-reflection coating method, setting new standards for short-wave infrared transparency in CsPbBr3. These pivotal processing guidelines pave the way for advancing halide perovskite applications beyond academic curiosity. Graphical abstract