Magneto-photoluminescence in a single type-II broken-gap n-Ga0.94In0.06As0.13Sb0.87/p-InAs heterostructure with a 2D electron channel at the heterointerface containing two occupied electron subbands has been studied in the spectral range 0.3–0.8 eV in high magnetic fields of up to 10 T at low temperatures (T = 7 K). At photon energies in the range 0.5–0.8 eV, bulk photoluminescence from the layer of the n-GaInAsSb alloy was observed. In the low-energy part of the spectrum (0.3–0.45 eV), three narrow emission bands with photon energies hνa = 0.419 eV, hνb = 0.404 eV, and hνc = 0.384 eV and full widths at half-maximum FWHM = 4–7 meV were observed. These bands are due to radiative transitions of 2D electrons localized in the quantum well on the InAs side near the type-II heterointerface. The electron effective mass in the occupied subband E2 was estimated to be m2 = 0.027m0, which is close to the effective mass at the bottom of the InAs conduction band.
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