Number Of TiO2 Nanoparticles Research Articles

Determination of Titanium (IV) Oxide Nanoparticles Released from Textiles by Single Particle – Inductively Coupled Plasma – Mass Spectrometry (SP-ICP-MS)

Monitoring TiO2 nanoparticles (NPs) that are released from functional textiles is significant for assessing the potential risk to consumers. However, determining the size distribution of TiO2 NPs is still a challenge due to agglomeration. The present study employed single particle–inductively coupled plasma–mass spectrometry (SP-ICP-MS) to quantify TiO2 NPs released from functional textiles. Through screening dispersants and validating the standard samples, an accurate method for determining the size and number of TiO2 NPs was developed. The validated procedure was successfully used to determine the release of TiO2 NPs from yarn in sweat and water media throughout the day. The result revealed that the yarn decorated with TiO2 NPs released approximately the same particle size distribution from 60 to 260 nm in both media. The released particle concentration was 0.094 µg/mL with a mean size of 136 nm in water and a particle concentration of 0.120 µg/mL with a mean size of 133 nm in sweat. Additionally, based upon transmission electron microscopy, anatase TiO2 NPs were identified. It is expected that this work is significant in the evaluation of the toxicological effects of multifunctional textiles modified by TiO2 NPs on human health.

Removal Mechanism of Oxide Layer on the Surface of Sn-0.4Ti Alloy for Quartz Glass Sealing

The oxide layer on the surface of Sn-0.4Ti alloy and its removal mechanism were investigated by coalitional analyses, using XPS and TEM technologies. The results show that a compact SnO1.65 oxide layer of less than 4 nm in thickness exists on the surface of Sn-0.4Ti alloy. A large number of TiO2 nanoparticles with scale of several to tens of nanometers were grown in Sn-0.4Ti matrix by depleting SnO1.65 while welding at 800 °C. These nanoparticles were adhered to the interfacial layer between Sn-0.4Ti alloy and quartz glass, which was formed by the reaction of Sn-0.4Ti and SiO2 after SnO1.65 removal from the Sn-0.4Ti. This work may promote further works on Sn-Ti design to further improve the welding quality between Sn-Ti alloy and quartz glass, and also provide a feasible research idea to remove the oxide layer on the surfaces of solders.

Optimized TiO2 nanoparticle packing for DSSC photovoltaic applications

Different synthesis protocols have been developed to control TiO2 anatase nanoparticle packing. The diameter of TiO2 packing aggregate varies from 13nm to a few 100nm. Efficiency of dye-sensitized solar cells (DSSC) fabricated with the obtained TiO2 packing aggregate films was reported to depend on the size of the packing aggregate. It increases with the increase of the aggregate size (number of TiO2 nanoparticles) to a maximum of 4.3% and then it decreases. This effect was discussed in terms of a balance between the incident light scatterings, adsorbing amount of dye molecules, cracks free and the efficiency of electron transfer (reduction of recombination process).