North China Plain Region Research Articles

Development and application of a twin open-top chambers method to measure soil HONO emission in the North China Plain

HONO (nitrous acid) is a crucial precursor for tropospheric OH radicals, and its sources are not well understood. In the past decade, soil was proven to be a potential source for HONO. However, more field measurements of soil HONO emission flux are needed to explore the mechanism and its impact on regional air quality. Here, we developed a system based on twin open-top chambers (OTCs) and wet chemical methods to measure HONO emission flux from agricultural soil in the North China Plain (NCP). The performance of the OTC system was tested under laboratory and field measurement conditions. The results showed that the system could reflect the strength (>90%) and variation of gas emission with an average residence time of 4–5 min. The greenhouse effect and chemical reaction interference in the chamber was proven to have no significant influence on the HONO flux measurement. Field measurement revealed that agricultural soil before fertilization was an important source of HONO. The emission flux showed radiation-dependent or temperature-dependent variation, with a peak of 3.21 ng m−2 s−1 at noontime that could account for approximately 67 pptv h−1 of the missing HONO source under an assumed mixing layer height of 300 m. Fertilization substantially accelerated HONO emission, which was rationally attributed to biological processes including nitrification. Considering the high fertilization rate in the NCP and other similar regions in China, HONO emission from agricultural soil likely has enormous impact on regional photochemistry and air quality, suggesting that more research should be conducted on this aspect.

Impact of the Horizontal Heat Flux in the Mixed Layer on an Extreme Heat Event in North China: A Case Study

Extreme heat over the North China Plain is typically induced by anomalous descending flows associated with anticyclonic circulation anomalies. However, an extreme heat event that happened in the North China Plain region on 12–13 July 2015, with maximum temperature higher than 40°C at some stations, was characterized by only a weak simultaneous appearance of an anomalous anticyclone and descending flow, suggesting that some other factor(s) may have induced this heat event. In this study, we used the forecast data produced by the Beijing Rapid Updated Cycling operational forecast system, which predicted the heat event well, to investigate the formation mechanism of this extreme heat event. We calculated the cumulative heat in the mixed-layer air column of North China to represent the change in surface air temperature. The cumulative heat was composed of sensible heat flux from the ground surface and the horizontal heat flux convergence. The results indicated that the horizontal heat flux in the mixed layer played a crucial role in the temporal and spatial distribution of high temperatures. The horizontal heat flux was found to be induced by distinct distributions of air temperatures and horizontal winds at low levels during the two days, implying a complexity of the low-level atmosphere in causing the extreme heat.

Underreported coal in statistics: A survey-based solid fuel consumption and emission inventory for the rural residential sector in China

Solid fuel consumption and associated emissions from residential use are highly uncertain due to a lack of reliable statistics. In this study, we estimate solid fuel consumption and emissions from the rural residential sector in China by using data collected from a new nationwide field survey. We conducted a field survey in 2010 which covered ∼17,000 rural residential households in 183 counties in China, to obtain data for solid fuel consumption and use patterns. We then developed a Generalized Additive Model (GAM) to establish the relationship between solid fuel consumption and heating degree days (HDD), income, coal production, coal price, and vegetation coverage, respectively. The GAM was used to estimate solid fuel consumption in rural households in China at the county level. We estimated that, in 2010, 179.8Tg of coal were consumed in Chinese rural households for heating and cooking, which is 62% higher than that reported in official energy statistics. We found that large quantities of rural residential coal consumption in the North China Plain were underreported in energy statistics. For instance, estimated coal consumption in rural households in Hebei (one of most polluted provinces in China) was 20.8Tg in 2010, which is twice as high as government statistics indicate. In contrast, modeled national total consumption of crop residues (used as fuels) we found to be ∼50% lower than reported data. Combining the underlying data from the survey, the GAM and emission factors from literature, we estimate emissions from China’s rural residential sector in 2010 to be: 3.3Tg PM2.5, 0.6Tg BC, 1.2Tg OC, 2.1Tg VOC, 2.3Tg SO2, 0.4Tg NOx, 43.6Tg CO and 727.2Tg CO2, contributing to 29%, 35%, 38% and 26% of national total PM2.5, BC, OC, and CO emissions respectively. This work reveals that current emission inventories in China likely underestimate emissions from coal combustion in rural residential households due to missing coal consumption in official statistics, especially for the heavily polluted North China Plain (NCP) region. Per capita income appears to be the driving factor that results in the difference between surveyed data and official data. Residents with high income prefer commercial energy and have a higher per capita fuel consumption than lower income residents. Therefore, rural residential coal combustion may contribute even more to regional air pollution than the large contributions previously identified.

INVESTIGATING ALOFT AEROSOLS OVER CENTRAL-EASTERN CHINA USING CALIPSO MEASUREMENTS

Abstract. The rapid development of China in the last decade has brought about serious environmental problems, among which the air quality has attracted much attention. Especially in the winter, haze events with PM2.5 as the primary pollutant frequently occur, which has a huge strike on people's health. Such cumulative anthropogenic aerosols at surface over haze pollution regions could be lifted upwards by vertical turbulent mixing forming elevated haze layers that subsequent transport to distant regions. This paper attempts to analyze layer top altitude, ratio of anthropogenic source and optical properties by counting events occurring in aloft aerosols layer. CALIPSO satellite instruments are used for statistical analysis by screening layer data over central-eastern China from 2007 to 2016. In the most economically active and polluted areas of China, the North China Plain (NCP) and the Yangtze River Delta (YRD) are compared to analyze trend variations over ten years. Results shows that the frequency of occurrence of aloft layer in South China are higher than in North China, indicating that heat has a strong lifting effect on the planetary boundary layer (PBL). Further, the NCP has a unique high frequency value at 2.5 km, while the YRD has two peaks, 3.5 km and 2 km respectively. Moreover, in the past five years in the NCP (2011–2016) and YRD (2012–2016) regions, the anthropogenic source of pollutants dominated by smoke showed a downward trend year by year. In addition, monthly proportion of smoke and polluted dust are analyzed in NCP and YRD winter. Finally, the volume depolarization ratio is almost distributed within 0.2, indicating that the shape of the particles is irregular. The particulate color ratio has a sharp peak near 0.4–0.7 suggesting that smaller particles dominate the size distribution during the winter months.

Effects of aerosol-radiation feedback and topography during an air pollution event over the North China Plain during December 2017

The online coupled Weather Research and Forecasting-Chemistry (WRF-Chem) model was used to investigate a regional haze event, which occurred over the North China Plain (NCP) from 27 to 30 December 2017. Modeling scenarios with and without aerosol-radiation feedback within the planetary boundary layer (PBL) were investigated. By adding aerosol-radiation feedback to the model, we captured the spatial and temporal characteristics of the observed temperature and relative humidity (RH), as well as surface PM2.5, SO2, and NO2 concentrations during this event. The primary meteorological driver of this event was stable meteorological conditions, namely, a low PBL, strong temperature inversion, high RH, and a weak wind field. Aerosol-radiation feedback mechanisms affected these meteorological fields, causing reductions in maximum surface solar radiation, the surface energy budget, PBL height, surface 2-m temperature and middle atmosphere RH, while increasing surface 2-m RH, middle atmosphere temperature, and atmospheric stability. Changes in meteorological variables in turn affected air pollutant distributions and concentrations, with PM2.5 increasing by more than 20 μg/m3 over the NCP during this event. Another sensitivity experiment was carried out over the Taihang and Yanshan mountain areas, in which topography was flattened to a 30-m height to explore the impacts of topography on air pollution in the NCP region. Modeling revealed various topographic effects on meteorological variables related to these two mountains, including a lowered PBL height, reduced wind speed, blocked uniform surface winds, and more intense temperature inversion. Consequently, surface air pollutant concentrations increased unevenly over the NCP in this experiment. Implementation of more detailed PBL processes, as well as radiosonde and satellite data products into the WRF-Chem model would improve simulations of haze formation over the NCP.

Inter‐annual variation of the spring haze pollution over the North China Plain: Roles of atmospheric circulation and sea surface temperature

Haze pollution is a serious air quality issue in China. Previous studies over the North China Plain (NCP) mainly focused on analysing the haze during boreal winter. However, the variation in haze during spring and the related factors remain unclear. This study investigates inter‐annual variation of the spring haze, which is represented by the humidity‐corrected dry extinction coefficient (DEC) over the NCP. During high DEC years, pronounced positive DEC anomalies appear over the NCP and its surrounding regions. Correspondingly, a notable anticyclonic anomaly is observed over Northeast Asia, inducing significant southeasterly wind anomalies over the NCP. The anomalous southeasterly winds reduce wind speed and increase relative humidity, which provides favourable meteorological conditions for accumulation and growth of aerosol pollutants. Further analysis shows that the North Atlantic Oscillation (NAO) contributes to the formation of anticyclonic anomalies over Northeast Asia via downstream propagating atmospheric wave trains. Additionally, positive sea surface temperature (SST) anomalies over the subtropical northeastern Atlantic Ocean may also impact the DEC variation. The linear barotropic model experiment further confirms the important role of subtropical northeastern Atlantic SST anomalies in contributing to the anomalous anticyclone over Northeast Asia and southerly wind anomalies over the NCP region, which are triggered via eastwards propagating atmospheric wave trains. This study gives support to the idea that the NAO and the North Atlantic SST may be potential predictors for the frequently observed springtime NCP haze variation.

Carbon Footprint Analyses and Potential Carbon Emission Reduction in China’s Major Peach Orchards

An excess of material input in fruit orchards has brought serious environmental problems, particularly in China. However, studies on the estimation of greenhouse gas (GHG) emissions in peach orchards are limited. In this study, based on questionnaire surveys in major peach-producing regions, including the North China Plain (n = 214), as well as northwest (n = 22) and southwest (n = 33) China, the carbon footprints (CFs) of these orchards were calculated by the life cycle assessment. The potential emission reduction in each region was estimated by combining the GHG emissions and CFs with plantation areas and fruit yields. The results showed that the average GHG emissions in the North China Plain, northwest, and southwest regions were 15,668 kg CO2-eq ha−1, 10,386 kg CO2-eq ha−1, and 5580 kg CO2-eq ha−1, with corresponding CFs of 0.48 kg CO2-eq ha−1, 0.27 kg CO2-eq ha−1, and 0.20 kg CO2-eq kg−1, respectively. The main contribution source of GHG emissions in these three regions was fertilizer (77–95%), followed by electricity, pesticides, and diesel. By adopting advanced farming practices with high yield and a high partial factor productivity of fertilizer, the GHG emissions could be reduced by ~13–35%, with the highest potential reduction in the North China Plain. In conclusion, the GHG emissions and their CFs were impressively high in China’s major peach-producing regions, but these GHG emissions could be substantially decreased by optimizing nutrients and irrigation management, including the rational selection of fertilizer rates and types with water-saving irrigation systems or practices (e.g., mulching) for increasing fertilizer and water use efficiency, and maintaining a sustainable peach production in China or similar countries.

Summertime fine particulate nitrate pollution in the North China Plain: increasing trends, formation mechanisms and implications for control policy

Abstract. Nitrate aerosol makes up a significant fraction of fine particles and plays a key role in regional air quality and climate. The North China Plain (NCP) is one of the most industrialized and polluted regions in China. To obtain a holistic understanding of the nitrate pollution and its formation mechanisms over the NCP region, intensive field observations were conducted at three sites during summertime in 2014–2015. The measurement sites include an urban site in downtown Jinan – the capital city of Shandong Province –, a rural site downwind of Jinan city, and a remote mountain site at Mt. Tai (1534 m a.s.l.). Elevated nitrate concentrations were observed at all three sites despite distinct temporal and spatial variations. Using historical observations, the nitrate ∕ PM2.5 and nitrate ∕ sulfate ratios have statistically significantly increased in Jinan (2005–2015) and at Mt. Tai (from 2007 to 2014), indicating the worsening situation of regional nitrate pollution. A multiphase chemical box model (RACM–CAPRAM) was deployed and constrained by observations to elucidate the nitrate formation mechanisms. The principal formation route is the partitioning of gaseous HNO3 to the aerosol phase during the day, whilst the nocturnal nitrate formation is dominated by the heterogeneous hydrolysis of N2O5. The daytime nitrate production in the NCP region is mainly limited by the availability of NO2 and to a lesser extent by O3 and NH3. In comparison, the nighttime formation is controlled by both NO2 and O3. The presence of NH3 contributes to the formation of nitrate aerosol during the day, while there is slightly decreasing nitrate formation at night. Our analyses suggest that controlling NOx and O3 is an efficient way, at the moment, to mitigate nitrate pollution in the NCP region, where NH3 is usually in excess in summer. This study provides observational evidence of a rising trend of nitrate aerosol as well as scientific support for formulating effective control strategies for regional haze in China.

Strong ozone production at a rural site in theNorth China Plain: Mixed effects of urban plumesand biogenic emissions

Regional ozone (O3) pollution has drawn increasing attention in China over the recent decade, but the contributions from urban pollution and biogenic emissions have not been clearly elucidated. To better understand the formation of the regional O3 problem in the North China Plain (NCP), intensive field measurements of O3 and related parameters were conducted at a rural site downwind of Ji'nan, the capital city of Shandong province, in the summer of 2013. Markedly severe O3 pollution was recorded, with the O3 mixing ratios exceeding the Chinese national ambient air quality standard on 28 days (a frequency of 78%) and with a maximum hourly value of 198 ppbv. Extensive regional transport of well-processed urban plumes to the site was identified. An observation-constrained chemical box model was deployed to evaluate in situ photochemical O3 production on two episodes. The results show that the in situ formation accounted for approximately 46% of the observed O3 accumulation, while the remainder (~54%) was contributed by regional transport of the O3-laden urban plumes. The in situ ozone production was in a mixed controlled regime that reducing either NOx or VOCs would lead to a reduction of ozone formation. Biogenic VOCs played an important role in the local ozone formation. This study demonstrates the significant mixed effects of both anthropogenic pollution from urban zones and biogenic emission in rural areas on the regional O3 pollution in the NCP region, and may have general applicability in facilitating the understanding of the formation of secondary pollution over China.

Potential source regions of air pollutants at a regional background station in Northern China

ABSTRACTUnderstanding the potential source regions of air pollutants and their relative contribution from surrounding areas are of great importance for air pollution control strategies in Northern China. Six years of measurement of air pollutants was conducted from 2005 to 2010 in Shangdianzi (SDZ) regional background station. During the study period, the annual average concentrations of sulfur dioxide (SO2), carbon monoxide (CO), nitrogen dioxide and ozone (Ox), and fine particle matter less than or equal to 2.5 μm (PM2.5) range from 15.7 to 20.0 μg/m3, 577.7 to 856.0 μg/m3, 90.4 to 101.8 μg/m3, and 39.8 to 62.4 μg/m3, respectively. In this work, Potential Source Contribution Function (PSCF) and Trajectory Sector Analysis (TSA) methods are applied to identify locations of sources and their relatively contribution of air pollutants at SDZ. PSCF analysis shows that central Inner Mongolia, north Shanxi, west and south Hebei, and west Liaoning are all potential sources of SO2. The North China Plain (NCP) region, especially south Hebei and north Shandong, are major potential source regions for CO, Ox, and PM2.5. Therefore, reducing anthropogenic emissions from the coal industry, biomass burning, agricultural activities, and vehicles in these areas could be an effective way of controlling air pollution at SDZ. Based on the TSA results, the contributions of SO2, CO, Ox, and PM2.5 from long-distance transport are 5.5 μg/m3, 301.4 μg/m3, 14.8 μg/m3, and 25.8 μg/m3, accounting for approximately 22.6%, 32.3%, 13.1%, and 37.5% of the respective air pollutant concentrations at SDZ.

Changes in soil organic carbon fractions in response to different tillage practices under a wheat‐maize double cropping system

AbstractTo understand the turnover of soil organic carbon (SOC) and the improvement of soil quality in response to tillage practices, it is important to identify changes in labile SOC fractions, for example, permanganate oxidizable organic carbon (POxC) and particulate organic carbon (POC). Five tillage treatments were initially undertaken in a winter wheat (Triticum aestivum L., mid‐October to early‐June)–summer maize (Zea mays L., mid‐June to early‐October) system in the North China Plain in 2008 with changes being examined in 2012–2013. These treatments included plough tillage with residue removed, plough tillage with residue incorporation, no tillage with residue mulching, subsoiling with residue incorporation, and rotary tillage (tillage with a rotary tiller) with residue incorporation for the winter wheat season; summer maize was only managed with the NTM treatment. The greatest POxC and POC concentrations at the 0–5‐cm depth were observed under RTR and NTM treatments (p < .05), respectively. Both STR and RTR recorded larger POxC and POC concentrations at the 5–10‐cm depth (p < .05). Both POxC and POC concentrations for STR treatment were significantly higher than those under RTR, NTM, and PT0 treatments in the 20–50‐cm soil profile. The POC concentrations in each soil layer of 0–30‐cm showed a significant response to residue amount, temperature, and precipitation; and POxC concentrations did not record similar responses. Therefore, subsoiling with residue incorporation could be a potential tillage practice to manage labile SOC pool in top soil (0–50‐cm) in the North China Plain region.

Nitrate-driven urban haze pollution during summertime over the North China Plain

Abstract. Compared to the severe winter haze episodes in the North China Plain (NCP), haze pollution during summertime has drawn little public attention. In this study, we present the highly time-resolved chemical composition of submicron particles (PM1) measured in Beijing and Xinxiang in the NCP region during summertime to evaluate the driving factors of aerosol pollution. During the campaign periods (30 June to 27 July 2015, for Beijing and 8 to 25 June 2017, for Xinxiang), the average PM1 concentrations were 35.0 and 64.2 µg m−3 in Beijing and Xinxiang. Pollution episodes characterized with largely enhanced nitrate concentrations were observed at both sites. In contrast to the slightly decreased mass fractions of sulfate, semivolatile oxygenated organic aerosol (SV-OOA), and low-volatility oxygenated organic aerosol (LV-OOA) in PM1, nitrate displayed a significantly enhanced contribution with the aggravation of aerosol pollution, highlighting the importance of nitrate formation as the driving force of haze evolution in summer. Rapid nitrate production mainly occurred after midnight, with a higher formation rate than that of sulfate, SV-OOA, or LV-OOA. Based on observation measurements and thermodynamic modeling, high ammonia emissions in the NCP region favored the high nitrate production in summer. Nighttime nitrate formation through heterogeneous hydrolysis of dinitrogen pentoxide (N2O5) enhanced with the development of haze pollution. In addition, air masses from surrounding polluted areas during haze episodes led to more nitrate production. Finally, atmospheric particulate nitrate data acquired by mass spectrometric techniques from various field campaigns in Asia, Europe, and North America uncovered a higher concentration and higher fraction of nitrate present in China. Although measurements in Beijing during different years demonstrate a decline in the nitrate concentration in recent years, the nitrate contribution in PM1 still remains high. To effectively alleviate particulate matter pollution in summer, our results suggest an urgent need to initiate ammonia emission control measures and further reduce nitrogen oxide emissions over the NCP region.

Air quality and climate change, Topic 3 of the Model Inter-Comparison Study for Asia Phase III (MICS-Asia III) – Part 1: Overview and model evaluation

Abstract. Topic 3 of the Model Inter-Comparison Study for Asia (MICS-Asia) Phase III examines how online coupled air quality models perform in simulating high aerosol pollution in the North China Plain region during wintertime haze events and evaluates the importance of aerosol radiative and microphysical feedbacks. A comprehensive overview of the MICS-Asia III Topic 3 study design, including descriptions of participating models and model inputs, the experimental designs, and results of model evaluation, are presented. Six modeling groups from China, Korea and the United States submitted results from seven applications of online coupled chemistry–meteorology models. Results are compared to meteorology and air quality measurements, including data from the Campaign on Atmospheric Aerosol Research Network of China (CARE-China) and the Acid Deposition Monitoring Network in East Asia (EANET). The correlation coefficients between the multi-model ensemble mean and the CARE-China observed near-surface air pollutants range from 0.51 to 0.94 (0.51 for ozone and 0.94 for PM2.5) for January 2010. However, large discrepancies exist between simulated aerosol chemical compositions from different models. The coefficient of variation (SD divided by the mean) can reach above 1.3 for sulfate in Beijing and above 1.6 for nitrate and organic aerosols in coastal regions, indicating that these compositions are less consistent from different models. During clean periods, simulated aerosol optical depths (AODs) from different models are similar, but peak values differ during severe haze events, which can be explained by the differences in simulated inorganic aerosol concentrations and the hygroscopic growth efficiency (affected by varied relative humidity). These differences in composition and AOD suggest that future models can be improved by including new heterogeneous or aqueous pathways for sulfate and nitrate formation under hazy conditions, a secondary organic aerosol (SOA) formation chemical mechanism with new volatile organic compound (VOCs) precursors, yield data and approaches, and a more detailed evaluation of the dependence of aerosol optical properties on size distribution and mixing state. It was also found that using the ensemble mean of the models produced the best prediction skill. While this has been shown for other conditions (for example, the prediction of high-ozone events in the US (McKeen et al., 2005)), this is to our knowledge the first time it has been shown for heavy haze events.

The spatial representativeness of mixing layer height observations in the North China Plain

To investigate the spatial representativeness of mixing layer height (MLH) observations in the North China Plain (NCP), we performed several successive MLH measurements with ceilometers from 2013 to 2017, and the MLH observation data were analyzed at different measurement scales. Daytime MLH differences among stations increased with increasing observation scale. The relative coefficient (R) and the coefficient of variation (CV) of the hourly daytime MLH decreased and increased from 0.87 and 18.7% to 0.57 and 27.9%, respectively, by enlarging the observation domain from the urban scale (0–20 km) to the synoptic scale (100–300 km). At inter-station distances of <25 km, the daytime MLH values between two sites are highly consistent. At inter-station distances >25 km but <60 km, the daytime MLH values at any two sites exhibit obvious differences. Additionally, at inter-station distances >60 km, the daytime MLH measurements effectively capture the regional MLH distribution characteristics. Therefore, inter-station distances within the range of 25–60 km are useful for detecting whether obvious differences in daytime MLH exist among stations, and an inter-station distance >60 km is sufficient to obtain daytime MLH observations that represent the regional distribution pattern. Our research results have instructive significance for MLH observation station layouts within the NCP region.

Potential co-benefits of electrification for air quality, health, and CO2 mitigation in 2030 China

Electrification with decarbonized electricity is a central strategy for carbon mitigation. End-use electrification can also reduce air pollutant emissions from the demand sectors, which brings public health co-benefits. Here we focus on electrification strategies for China, a country committed to both reducing air pollution and peaking carbon emissions before 2030. Considering both coal-intensive and decarbonized power system scenarios for 2030, we assess the air quality, health and climate co-benefits of various end-use electrification scenarios for the vehicle and residential sectors relative to a non-electrified coal-intensive business-as-usual scenario (BAU). Based on an integrated assessment using the regional air pollution model WRF-Chem and epidemiological concentration–response relationships, we find that coal-intensive electrification (75% coal) does not reduce carbon emissions, but can bring significant air quality and health benefits (41,000–57,000 avoided deaths in China annually). In comparison, switching to a half decarbonized power supply (∼50% coal) for electrification of the transport and/or residential sectors leads to a 14–16% reduction in carbon emissions compared to BAU, as well as greater air quality and health co-benefits (55,000–69,000 avoided deaths in China annually) than coal intensive electrification. Furthermore, depending on which end-use sector is electrified, we find different regional distributions of air quality and health benefits. While electrifying the transport sector improves air quality throughout eastern China, electrifying the residential sector brings most benefits to the North China Plain region in winter where coal-based heating contributes substantially to air pollution.

Air pollution over the North China Plain and its implication of regional transport: A new sight from the observed evidences.

High concentrations of the fine particles (PM2.5) are frequently observed during all seasons over the North China Plain (NCP) region in recent years. In NCP, the contributions of regional transports to certain area, e.g. Beijing city, are often discussed and estimated by models when considering an effective air pollution controlling strategy. In this study, we selected three sites from southwest to northeast in NCP, in which the concentrations of air pollutants displayed a multi-step decreasing trend in space. An approach based on the measurement results at these sites has been developed to calculate the relative contributions of the minimal local emission (MinLEC) and the maximum regional transport (MaxRTC) to the air pollutants (e.g., SO2, NO2, CO, PM2.5) in Beijing. The minimal influence of local emission is estimated by the difference of the air pollutants' concentrations between urban and rural areas under the assumption of a similar influence of regional transport. Therefore, it's convenient to estimate the contributions of local emission from regional transport based on the selective measurement results instead of the complex numerical model simulation. For the whole year of 2013, the averaged contributions of MinLEC (MaxRTC) for NO2, SO2, PM2.5 and CO are 61.7% (30.7%), 46.6% (48%), 52.1% (40.2%) and 35.8% (45.5%), respectively. The diurnal variation of MaxRTC for SO2, PM2.5 and CO shows an increased pattern during the afternoon and reached a peak (more than 50%) around 18:00, which indicates that the regional transport is the important role for the daytime air pollution in Beijing.

Characteristics and formation of typical winter haze in Handan, one of the most polluted cities in China

Handan, a city within the North China Plain (NCP) region, is a typical city influenced by regional particulate matter (PM) pollution. One-year hourly semi-continuous observation was carried out in 2015 in Handan with the aim of identifying the chemical composition and variations in PM2.5. Moreover, the concentration of aerosol precursors, meteorological factors, and secondary transformations are considered. The results demonstrate that the annual average PM2.5 concentration in Handan is 122.35μgm−3, approximately 3.5 times higher than the Chinese National Ambient Air Quality Standard (NAAQS) (35μgm−3), and only 12days were below the guideline. As expected, PM concentrations are highest in winter, especially in December. In addition, we measure the concentrations of five species commonly found in PM, nitrate, sulfate, ammonium, inorganic carbon, and organic carbon. Of these, nitrate and sulfate account for the largest proportion of PM2.5; during periods when the PM2.5 concentration was below 400μgm−3, nitrate dominates, while above this concentration, sulfate dominate. This is likely related to the nitrogen and sulfur oxidation ratios, which are in turn, especially the sulfur oxidation ratio, driven by high relative humidity (>60%). In addition, haze events are driven by other meteorological conditions, wind speed and direction, where low wind speeds from the south and southwest enable pollutant accumulation, which are infrequently interspersed with brief periods with high wind speeds that promote pollutant dispersal. Even though Handan is among the ten most polluted cities in China with regard to air pollution, few studies beyond model simulations have analyzed air pollutant concentrations in this city. Therefore, this study makes a significant contribution to understanding air pollution in Handan, which can further be used to improve our understanding of regional pollution in the highly populated North China Plain. These results have implications for the creation of policies and legislation, as well as other pollution control measures.

Root vertical distribution is important to improve water use efficiency and grain yield of wheat

The winter wheat (Triticum aestivum L.) production of the North China Plain is threatened by increasing water shortages. Therefore, the invention of effective irrigation techniques is crucial to maintain high yields of winter wheat through improved water use efficiency (WUE). In this study, field experiments were carried out in the North China Plain region in 2012–2013 and 2013–2014. Based on the soil moisture regulation at sowing to ensure the normal emergence of the winter wheat, four supplemental irrigation (SI) regimes were set up: no-irrigation after emergence (T1), SI at jointing and anthesis (T2), SI at sowing, jointing and anthesis (T3), and SI at pre-wintering, jointing and anthesis (T4). The results showed that the root length density (RLD), root surface area density (RAD), and root weight density (RWD) in the 0–0.2m soil layer from T2 increased rapidly after jointing and were significantly higher than those from T3 and T4 at anthesis. Those of T2 in the 0.6–0.8m and 0.8–1.0m soil layers were also significantly higher at anthesis. T2 was significantly higher than T1 in the photosynthetic rate (Pn) and instantaneous water use efficiency (WUEleaf) of flag leaves, post-anthesis dry matter accumulation (DMA), contribution of DMA to grain (CDMA), grain yield and WUE, but lower than T1 in the pre-anthesis dry matter remobilization efficiency (DMRE) and contribution of DMR to grain (CDMR). T2 had significantly lower plant populations and dry matter at jointing, Pn and WUEleaf at 28days after anthesis, DMA and CDMA, but higher dry matter increase rate after jointing, tiller survival rate, DMR, DMRE, CDMR and WUE. The combined effect of these differences enabled T2 to have yield that was not significantly different to T4. In summary, SI at joining and anthesis that was based on suitable soil water content at sowing increased the absorbing area of roots in both deep and surface soil layers; accelerated the dry matter accumulation after jointing; increased the Pn and WUEleaf of flag leaves, DMA and DMR; and finally achieved a high grain yield and higher WUE. However, excessive irrigation reduced the WUE by inhibiting the redistribution of dry matter, although the WUEleaf of flag leaves was still increased.

Combined impacts of nitrous acid and nitryl chloride on lower-tropospheric ozone: new module development in WRF-Chem and application to China

Abstract. Nitrous acid (HONO) and nitryl chloride (ClNO2) – through their photolysis – can have profound effects on the nitrogen cycle and oxidation capacity of the lower troposphere. Previous numerical studies have separately considered and investigated the sources/processes of these compounds and their roles in the fate of reactive nitrogen and the production of ozone (O3), but their combined impact on the chemistry of the lower part of the troposphere has not been addressed yet. In this study, we updated the WRF-Chem model with the currently known sources and chemistry of HONO and chlorine in a new chemical mechanism (CBMZ_ReNOM), and applied it to a study of the combined effects of HONO and ClNO2 on summertime O3 in the boundary layer over China. We simulated the spatial distributions of HONO, ClNO2, and related compounds at the surface and within the lower troposphere. The results showed that the modeled HONO levels reached up to 800–1800 ppt at the surface (0–30 m) over the North China Plain (NCP), the Yangtze River Delta (YRD), and the Pearl River Delta (PRD) regions and that HONO was concentrated within a 0–200 m layer. In comparison, the simulated surface ClNO2 mixing ratio was around 800–1500 ppt over the NCP, YRD, and central China regions and was predominantly present in a 0–600 m layer. HONO enhanced daytime ROx (OH + HO2 + RO2) and O3 at the surface (0–30 m) by 2.8–4.6 ppt (28–37 %) and 2.9–6.2 ppb (6–13 %), respectively, over the three most developed regions, whereas ClNO2 increased surface O3 in the NCP and YRD regions by 2.4–3.3 ppb (or 5–6 %) and it also had a significant impact (3–6 %) on above-surface O3 within 200–500 m. The combined effects increased surface O3 by 11.5, 13.5, and 13.3 % in the NCP, YRD, and PRD regions, respectively. Over the boundary layer (0–1000 m), the HONO and ClNO2 enhanced O3 by up to 5.1 and 3.2 %, respectively, and their combined effect increased O3 by 7.1–8.9 % in the three regions. The new module noticeably improved O3 predictions at ∼ 900 monitoring stations throughout China by reducing the mean bias from −4.3 to 0.1 ppb. Our study suggests the importance of considering these reactive nitrogen species simultaneously into chemical transport models to better simulate the formation of summertime O3 in polluted regions.

Carbonyl compounds at Mount Tai in the North China Plain: Characteristics, sources, and effects on ozone formation

Carbonyl compounds, an important category of volatile organic compounds (VOCs), play important roles in ozone (O3) formation and atmospheric chemistry. To better understand the characteristics and sources of carbonyl compounds and their effects on O3 formation, C1-C8 carbonyls were measured at Mount Tai, the highest mountain in the North China Plain (NCP), in summer 2014. Acetone (3.57±0.55ppbv), formaldehyde (3.48±0.98ppbv) and acetaldehyde (1.27±0.78ppbv) are the three most abundant species, comprising as high as 90% of the total observed compounds. Isovaleraldehyde (0.37±0.17ppbv) presents another important carbonyl compound despite its high reactivity. Comparison with the observations available in China highlights the serious situation of carbonyls pollution in the NCP region. The sources of carbonyls are dominated by photo-oxidation of VOCs during the daytime and regional transport at night. Secondary sources from oxidation of hydrocarbons contribute on average 44% of formaldehyde, 31% of acetone, 85% of acetaldehyde, 78% of benzaldehyde, and 84% of isovaleraldehyde, demonstrating the dominant role of secondary formation in the ambient carbonyl levels. Formaldehyde, acetaldehyde and isovaleraldehyde are the most important contributors to the OH reactivity and O3 production among the measured carbonyls. This study shows that carbonyl compounds contribute significantly to the photochemical pollution in the NCP region and hence understanding their sources and characteristics is essential for developing the science-based O3 pollution control strategies.