Let $(M^n,g)$ be a complete simply connected $n$-dimensional Riemannian manifold with curvature bounds $\Sect_g\leq \kappa$ for $\kappa\leq 0$ and $\Ric_g\geq(n-1)Kg$ for $K\leq 0$. We prove that for any bounded domain $\Omega \subset M^n$ with diameter $d$ and Lipschitz boundary, if $\Omega^*$ is a geodesic ball in the simply connected space form with constant sectional curvature $\kappa$ enclosing the same volume as $\Omega$, then $\sigma_1(\Omega) \leq C \sigma_1(\Omega^*)$, where $\sigma_1(\Omega)$ and $ \sigma_1(\Omega^*)$ denote the first nonzero Steklov eigenvalues of $\Omega$ and $\Omega^*$ respectively, and $C=C(n,\kappa, K, d)$ is an explicit constant. When $\kappa=K$, we have $C=1$ and recover the Brock-Weinstock inequality, asserting that geodesic balls uniquely maximize the first nonzero Steklov eigenvalue among domains of the same volume, in Euclidean space and the hyperbolic space.
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