Measurements of the volume extinction coefficient employing a Laser transmission path through the atmospheric boundary layer of the city of Leipzig are presented. Working conditions of a long path measurement and the calibration are discussed. To compare the extinction coefficient with other atmospheric quantities the influence of relative humidity on the extinction coefficient is eliminated by a humidity correction. The humidity corrected extinction coefficient is shown to be a measure of atmospheric loading. Based on changes of concentration of aerosol particles the results of measurements are classified in terms of heating or non-heating period and in terms of different air masses. For the empirical relation between the humidity corrected extinction coefficient and the concentration of particulate matter the specific extinction is introduced. With the help of this quantity conclusions are drawn about the shape of the size distribution of atmospheric particles.
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