NIRSpec Instrument Research Articles

H2 Fluorescent Emission from the Diffuse Interstellar Medium

Near-IR spectroscopy, which can now be performed at unprecedented sensitivity with the NIRSpec instrument on JWST, can offer a novel probe of diffuse clouds through the observation of H2 fluorescent emissions. Whereas previous observations of interstellar H2 fluorescent emissions were primarily confined to dense clouds lying close to a source of UV radiation, JWST opens the possibility of detecting such emissions from diffuse molecular clouds exposed to the average radiation field in the Galaxy. A simple analytic model is presented to predict the near-IR H2 fluorescent line intensities emitted by diffuse interstellar clouds with a Plummer density profile. It is applicable to sightlines where the column densities of H and H2 have been measured and the peak gas density can be estimated.

The NIRSpec Wide GTO Survey

The Near-infrared Spectrograph (NIRSpec) on the James Webb Space Telescope is uniquely suited to studying galaxies in the distant Universe with its combination of multi-object capabilities and sensitivity over a large range in wavelength (0.6 − 5.3 μm). Here we present the NIRSpec Wide survey, part of the NIRSpec Instrument Science Team’s Guaranteed Time Observations, using NIRSpec’s microshutter array to obtain spectra of more than 3200 galaxies at z > 1 at both low and high resolution (R ≈ 100 and 2700) for a total of 105 hours. With 31 pointings covering ≈320 arcmin2 across the five CANDELS fields with exquisite ancillary photometry from the Hubble Space Telescope, the NIRSpec Wide survey represents a fast and efficient way of probing galaxies in the early Universe. Pointing centers are determined to maximize the observability of the rarest, high-value sources. Subsequently, the microshutter configurations are optimized to observe the maximum number of “census” galaxies with a selection function based primarily on HST/F160W magnitude, photometric or slitless grism redshift, and predicted Hα flux tracing the bulk of the galaxy population at cosmic noon (zmed = 2.0). We present details on the survey strategy, the target selection, an outline of the motivating science cases, and discuss upcoming public data releases to the community.

Assigning the CH stretch overtone spectrum of benzene and naphthalene with extension to anthracene and tetracene using 2- and 3-quanta anharmonic quantum chemical computations.

The CH stretch overtone region (5750-6300 cm-1) of benzene and naphthalene is assigned herein using anharmonic quantum chemical computations, and the trend of how this extends to larger polycyclic aromatic hydrocarbons (PAHs) is established. The assignment of all experimental bands to specific vibrational states is performed for the first time. Resonance polyads and the inclusion of 3-quanta vibrational states are both needed to compute accurate vibrational frequencies with the proper density-of-states to match the experimental band shape. Hundreds of 3-quanta states produce the observed band structure in naphthalene, anthracene, and tetracene, and this number is expected to increase drastically for larger PAHs. The width and shape of the main peak are consistent from naphthalene to anthracene, necessitating further exploration of this trend to confirm whether it is representative of all PAHs in the CH stretch overtone region. Understanding observations of PAH sources in the 1-3 μm region from the NIRSpec instrument aboard JWST requires new computational data, and this study provides a benchmark and foundation for their computation.

LHS 1140 b Is a Potentially Habitable Water World

LHS 1140 b is a small planet orbiting in the habitable zone of its M4.5V dwarf host. Recent mass and radius constraints have indicated that it has either a thick H2-rich atmosphere or substantial water by mass. Here we present a transmission spectrum of LHS 1140 b between 1.7 and 5.2 μm, obtained using the NIRSpec instrument on JWST. By combining spectral retrievals and self-consistent atmospheric models, we show that the transmission spectrum is inconsistent with H2-rich atmospheres with varied size and metallicity, leaving a water world as the remaining scenario to explain the planet’s low density. Specifically, a H2-rich atmosphere would result in prominent spectral features of CH4 or CO2 on this planet, but they are not seen in the transmission spectrum. Instead, the data favor a high mean molecular weight atmosphere (possibly N2 dominated with H2O and CO2) with a modest confidence. Forming the planet by accreting C- and N-bearing ices could naturally give rise to a CO2- or N2-dominated atmosphere, and if the planet evolves to or has the climate-stabilizing mechanism to maintain a moderate-size CO2/N2-dominated atmosphere, the planet could have liquid-water oceans. Our models suggest CO2 absorption features with an expected signal of 20 ppm at 4.2 μm. As the existence of an atmosphere on TRAPPIST-1 planets is uncertain, LHS 1140 b may well present the best current opportunity to detect and characterize a habitable world.

Exoplanet transit spectroscopy with JWST NIRSpec: diagnostics and homogeneous case study of WASP-39 b

ABSTRACT The JWST has ushered in a new era of exoplanet transit spectroscopy. Among the JWST instruments, the Near-Infrared Spectrograph (NIRSpec) has the most extensive set of configurations for exoplanet time-series observations. The NIRSpec Prism and G395H grating represent two extremes in NIRSpec instrument modes, with the Prism spanning a wider spectral range (0.6–5.3 µm) at lower resolution (R ∼ 100) compared to G395H (2.87–5.14 µm; R ∼ 2700). In this work, we develop a new data reduction framework, JexoPipe, to conduct a homogeneous assessment of the two NIRSpec modes for exoplanet spectroscopy. We use observations of the hot Saturn WASP-39 b obtained as part of the JWST Transiting Exoplanet Early Release Science programme to assess the spectral quality and stability between the two instrument modes at different epochs. We explore the noise sources, effect of saturation, and offsets in transmission spectra between the different instrument modes and also between the two G395H NRS detectors. We find an inter-detector offset in G395H of ∼40–50 ppm, consistent with recent studies. We find evidence for correlated noise in the Prism white light curve. We find the G395H spectrum to be of higher precision compared to the Prism spectrum at the same resolution. We also compare the JexoPipe spectra with those reported from other pipelines. Our work underscores the need for robust assessment of instrument performance and identification of optimal practices for JWST data reduction and analyses.

Detection of a 2.85 μm Feature on Five Spinel-rich Asteroids from JWST

Ground-based observations of “Barbarian” L-type asteroids at 1–2.5 μm indicate that their near-infrared spectra are dominated by the mineral spinel, which has been attributed to a high abundance of calcium-aluminum inclusions (CAIs)—the first solids to condense out of the protoplanetary disk during the formation of the solar system. However, the spectral properties of these asteroids from 2.5–5 μm, a wavelength region that covers signatures of hydrated minerals, water, and organics, have not yet been explored. Here, we present 2–5 μm reflectance spectra of five spinel-rich asteroids obtained with the NIRSpec instrument on the James Webb Space Telescope. All five targets exhibit a ∼2.85 μm absorption feature with a band depth of 3%–6% that appears correlated in strength with that of the 2 μm spinel absorption feature. The shape and position of the 2.85 μm feature are not a good match to the 2.7 μm feature commonly seen in carbonaceous CM meteorites or C-type asteroids. The closest spectral matches are to the Moon and Vesta, suggesting commonalities in aqueous alteration across silicate bodies, infall of hydrated material, and/or space weathering by solar wind H implantation. Lab spectra of CO/CV chondrites, CAIs, as well as the minerals cronstedtite and spinel, also show a similar feature, providing clues into the origin of the 2.85 μm feature.

Ionised gas kinematics and dynamical masses of z ≳ 6 galaxies from JADES/NIRSpec high-resolution spectroscopy

We explore the kinematic gas properties of six 5.5 < z < 7.4 galaxies in the JWST Advanced Deep Extragalactic Survey (JADES), using high-resolution JWST/NIRSpec multi-object spectroscopy of the rest-frame optical emission lines [OIII] and Hα. The objects are small and of low stellar mass (∼1 kpc; M* ∼ 107 − 9 M⊙), less massive than any galaxy studied kinematically at z > 1 thus far. The cold gas masses implied by the observed star formation rates are about ten times higher than the stellar masses. We find that their ionised gas is spatially resolved by JWST, with evidence for broadened lines and spatial velocity gradients. Using a simple thin-disc model, we fit these data with a novel forward-modelling software that accounts for the complex geometry, point spread function, and pixellation of the NIRSpec instrument. We find the sample to include both rotation- and dispersion-dominated structures, as we detect velocity gradients of v(re)∼100 − 150 km s−1, and we find velocity dispersions of σ0 ∼ 30 − 70 km s−1 that are comparable to those at cosmic noon. The dynamical masses implied by these models (Mdyn ∼ 109 − 10 M⊙) are higher than the stellar masses by up to a factor 40, and they are higher than the total baryonic mass (gas + stars) by a factor of ∼3. Qualitatively, this result is robust even if the observed velocity gradients reflect ongoing mergers rather than rotating discs. Unless the observed emission line kinematics is dominated by outflows, this implies that the centres of these galaxies are dominated by dark matter or that star formation is three times less efficient, leading to higher inferred gas masses.

Medium-resolution 0.97–5.3 μm Spectra of Very Young Benchmark Brown Dwarfs with NIRSpec on Board the James Webb Space Telescope

Spectra of young benchmark brown dwarfs with well-known ages are vital to characterize other brown dwarfs, for which ages are in general not known. These spectra are also crucial to test atmospheric models, which have the potential to provide detailed information about the atmospheres of these objects. However, to test atmospheric models optimally, medium-resolution, long-wavelength-coverage spectra with well-understood uncertainties are ideal, such as the spectra provided by the NIRSpec instrument on board the James Webb Space Telescope. In this paper, we present medium-resolution JWST/NIRSpec spectra of two young brown dwarfs, TWA 28 (M9.0) and TWA 27A (M9.0), and one planetary-mass object, TWA 27B (L6.0), members of the TW Hydrae Association (age ∼ 10 Myr). We show the richness of the atomic lines and molecular bands present in the spectra. All objects show signs of a circumstellar disk, via a near-infrared excess and/or via emission lines. We matched a set of cloudless atmospheric spectra (ATMO), and cloudy atmospheric spectra (BT-Settl) to our NIRSpec spectra, and analyzed which wavelength ranges and spectral features both models reproduce best. Both models derive consistent parameters for the three sources, and predict the existence of CH4 at 3.35 μm in TWA 27B. Nonetheless, in contrast to other slightly older objects with similar spectral type, like PSO 318.5–22 and VHS 1256b, this feature is not present in the spectrum of TWA 27B. The lack of the CH4 feature might suggest that the L–T transition of very young dwarfs starts at later spectral types than for older brown dwarfs.

Water‐Ice Dominated Spectra of Saturn's Rings and Small Moons From JWST

AbstractJWST measured the infrared spectra of Saturn's rings and several of its small moons (Epimetheus, Pandora, Telesto, and Pallene) as part of Guaranteed Time Observation program 1247. The NIRSpec instrument obtained near‐infrared spectra of the small moons between 0.6 and 5.3 microns, which are all dominated by water‐ice absorption bands. The shapes of the water‐ice bands for these moons suggests that their surfaces contain variable mixes of crystalline and amorphous ice or variable amounts of contaminants and/or sub‐micron ice grains. The near‐infrared spectrum of Saturn's A ring has exceptionally high signal‐to‐noise between 2.7 and 5 microns and is dominated by features due to highly crystalline water ice. The ring spectrum also confirms that the rings possess a 2%–3% deep absorption at 4.13 microns due to deuterated water ice previously seen by the Visual and Infrared Mapping Spectrometer onboard the Cassini spacecraft. This spectrum also constrains the fundamental absorption bands of carbon dioxide and carbon monoxide and may contain evidence for a weak aliphatic hydrocarbon band. Meanwhile, the MIRI instrument obtained mid‐infrared spectra of the rings between 4.9 and 27.9 microns, where the observed signal is a combination of reflected sunlight and thermal emission. This region shows a strong reflectance peak centered around 9.3 microns that can be attributed to crystalline water ice. Since both the near and mid‐infrared spectra are dominated by highly crystalline water ice, they should provide a useful baseline for interpreting the spectra of other objects in the outer solar system with more complex compositions.

The 3D Kinematics of the Orion Nebula Cluster. II. Mass-dependent Kinematics of the Inner Cluster

We present the kinematic analysis of 246 stars within 4′ from the center of Orion Nebula Cluster (ONC), the closest massive star cluster with active star formation across the full mass range, which provides valuable insights in the formation and evolution of star cluster on an individual-star basis. High-precision radial velocities and surface temperatures are retrieved from spectra acquired by the NIRSPEC instrument used with adaptive optics (NIRSPAO) on the Keck II 10 m telescope. A 3D kinematic map is then constructed by combining with the proper motions previously measured by the Hubble Space Telescope Advanced Camera for Surveys/WFPC2/WFC3IR and Keck II NIRC2. The measured root-mean-squared velocity dispersion is 2.26 ± 0.08 km s−1, significantly higher than the virial equilibrium’s requirement of 1.73 km s−1, suggesting that the ONC core is supervirial, consistent with previous findings. Energy equipartition is not detected in the cluster. Most notably, the velocity of each star relative to its neighbors is found to be negatively correlated with stellar mass. Low-mass stars moving faster than their surrounding stars in a supervirial cluster suggests that the initial masses of forming stars may be related to their initial kinematic states. Additionally, a clockwise rotation preference is detected. A weak sign of inverse mass segregation is also identified among stars excluding the Trapezium stars, although it could be a sample bias. Finally, this study reports the discovery of four new candidate spectroscopic binary systems.

The brighter-fatter effect in the JWST MIRI Si:As IBC detectors

Context. The Mid-Infrared Instrument (MIRI) on board the James Webb Space Telescope (JWST) uses three Si:As impurity band conduction (IBC) detector arrays. The output voltage level of each MIRI detector pixel is digitally recorded by sampling up the ramp. For uniform or low-contrast illumination, the pixel ramps become nonlinear in a predictable way, but in areas of high contrast, the nonlinearity curve becomes much more complex. The origin of the effect is poorly understood and currently not calibrated out of the data. Aims. We provide observational evidence of the brighter-fatter effect (BFE) in MIRI conventional and high-contrast coronagraphic imaging, low-resolution spectroscopy, and medium-resolution spectroscopy data, and we investigate the physical mechanism that gives rise to the effect on the MIRI detector pixel raw voltage integration ramps. Methods. We used public data from the JWST/MIRI commissioning and Cycle 1 phase. We also developed a numerical electrostatic model of the MIRI detectors using a modified version of the public Poisson_CCD code. Results. We find that the physical mechanism behind the BFE manifesting in MIRI data is fundamentally different to that of charge-coupled devices and photodiode arrays such as the Hawaii-XRG near-infrared detectors used by the NIRISS, NIRCam, and NIRSpec instruments on board JWST. Observationally, the BFE makes the JWST MIRI data yield 10–25% larger point sources and spectral line profiles as a function of the relative level of de-biasing of neighboring detector pixels. This broadening impacts the MIRI absolute flux calibration, time-series observations of faint companions, and point spread function modeling and subtraction. We also find that the intra-pixel 2D profile of the shrinking Si:As IBC detector depletion region directly impacts the accuracy of the pixel ramp nonlinearity calibration model.

First Detection of CO2 Emission in a Centaur: JWST NIRSpec Observations of 39P/Oterma

Centaurs are minor solar system bodies with orbits transitioning between those of trans-Neptunian scattered disk objects and Jupiter-family comets (JFCs). 39P/Oterma (39P) is a frequently active centaur that has recently held both centaur and JFC classifications and was observed with the JWST NIRSpec instrument on 2022 July 27 UTC while it was 5.82 au from the Sun. For the first time, CO2 gas emission was detected in a centaur, with a production rate of = (5.96 ± 0.80) × 1023 molecules s−1. This is the lowest detection of CO2 of any centaur or comet. CO and H2O were not detected down to constraining upper limits. Derived mixing ratios of Q CO/Q ≤ 2.03 and /Q ≥ 0.60 are consistent with CO2 and/or CO outgassing playing large roles in driving the activity, but not water, and show a significant difference between the coma abundances of 29P/Schwassmann–Wachmann 1, another centaur at a similar heliocentric distance, which may be explained by thermal processing of 39P’s surface during its previous JFC orbit. To help contextualize the JWST data we also acquired visible CCD imaging data on two dates in 2022 July (Gemini-North) and September (Lowell Discovery Telescope). Image analysis and photometry based on these data are consistent with a point-source detection and an estimated effective nucleus radius of 39P in the range of R nuc = 2.21–2.49 km.

Taming semi-empirical methods for PAHs and vibrational spectra

Semi-empirical methods offer a cost-effective means of computing explicit, anharmonic vibrational frequencies for large molecules, such as polycyclic aromatic hydrocarbons (PAHs), but their default parameters produce insufficiently accurate results for comparison to experiment, especially in the hydride stretching region where the NIRSpec instrument on JWST is most effective. This work delivers several reparameterized variants of the PM6 semi-empirical method trained to reproduce the experimental vibrational frequencies of 5 small hydrocarbon molecules. When benchmarked on the experimental frequencies of benzene and naphthalene, these reparameterized methods match the empirical values to within 38.7 cm−1 on average. Combining these values with the default PM6 frequencies below 3000 cm−1 brings the average deviation below 22 cm−1 for naphthalene, comparing favorably with the existing state of the art in B3LYP/4-31G, for a two order of magnitude decrease in the computational cost. As such, the present work offers a promising means of extending the computation of explicit, anharmonic vibrational frequencies to PAHs larger than those that can be examined anharmonically via B3LYP. Such large and accurate data sets are necessary to disentangle the unidentified spectral features observed around myriad astronomical bodies and the influx of observational data from JWST.

Emission-line properties of IllustrisTNG galaxies: from local diagnostic diagrams to high-redshift predictions for JWST

ABSTRACT We compute synthetic, rest-frame optical and ultraviolet (UV) emission-line properties of galaxy populations at redshifts from z ≈ 0 to = 8 in a full cosmological framework. We achieve this by coupling, in post-processing, the cosmological IllustrisTNG simulations with new-generation nebular-emission models, accounting for line emission from young stars, post-asymptotic giant branch (PAGB) stars, accreting black holes (BHs) and, for the first time, fast radiative shocks. The optical emission-line properties of simulated galaxies dominated by different ionizing sources in our models are largely consistent with those expected from classical diagnostic diagrams and reflect the observed increase in [O iii]/Hβ at fixed [N ii]/Hα and the evolution of the Hα, [O iii]λ5007, and [O ii] λ3727 luminosity functions from z ≈ 0 to ∼ 2. At higher redshift, we find that the emission-line galaxy population is dominated by star-forming and active galaxies, with negligible fractions of shock- and PAGB-dominated galaxies. We highlight 10 UV-diagnostic diagrams able to robustly identify the dominant ionizing sources in high-redshift galaxies. We also compute the evolution of several optical- and UV-line-luminosity functions from z = 4 to 7, and the number of galaxies expected to be detectable per field of view in deep, medium-resolution spectroscopic observations with the NIRSpec instrument on board the JWST. We find that 2-h-long exposures are sufficient to achieve unbiased censuses of Hα and [O iii]λ5007 emitters, while at least 5 h are required for Hβ, and even 10 h will detect only progressively smaller fractions of [O ii] λ3727, O iii] λ1663, C iii] λ1908, C iv λ1550, [N ii]λ6584, Si iii] λ1888, and He ii λ1640 emitters, especially in the presence of dust.

Carbon-bearing Molecules in a Possible Hycean Atmosphere

The search for habitable environments and biomarkers in exoplanetary atmospheres is the holy grail of exoplanet science. The detection of atmospheric signatures of habitable Earth-like exoplanets is challenging owing to their small planet–star size contrast and thin atmospheres with high mean molecular weight. Recently, a new class of habitable exoplanets, called Hycean worlds, has been proposed, defined as temperate ocean-covered worlds with H2-rich atmospheres. Their large sizes and extended atmospheres, compared to rocky planets of the same mass, make Hycean worlds significantly more accessible to atmospheric spectroscopy with JWST. Here we report a transmission spectrum of the candidate Hycean world K2-18 b, observed with the JWST NIRISS and NIRSpec instruments in the 0.9–5.2 μm range. The spectrum reveals strong detections of methane (CH4) and carbon dioxide (CO2) at 5σ and 3σ confidence, respectively, with high volume mixing ratios of ∼1% each in a H2-rich atmosphere. The abundant CH4 and CO2, along with the nondetection of ammonia (NH3), are consistent with chemical predictions for an ocean under a temperate H2-rich atmosphere on K2-18 b. The spectrum also suggests potential signs of dimethyl sulfide (DMS), which has been predicted to be an observable biomarker in Hycean worlds, motivating considerations of possible biological activity on the planet. The detection of CH4 resolves the long-standing missing methane problem for temperate exoplanets and the degeneracy in the atmospheric composition of K2-18 b from previous observations. We discuss possible implications of the findings, open questions, and future observations to explore this new regime in the search for life elsewhere.

Redshift Evolution of Electron Density in the Interstellar Medium at z ∼ 0–9 Uncovered with JWST/NIRSpec Spectra and Line-spread Function Determinations

We present electron densities n e in the interstellar medium (ISM) of star-forming galaxies at z = 4–9 observed by the JWST/NIRSpec GLASS, Early Release Observations, and CEERS programs. We carefully evaluate the line-spread functions of the NIRSpec instrument as a function of wavelength with the calibration data of a planetary nebula taken on board, and obtain secure [O ii] λ λ3726, 3729 doublet fluxes for 14 galaxies at z = 4.02–8.68 falling on the star formation main sequence with the NIRSpec high- and medium-resolution spectra. We thus derive the electron densities of singly ionized oxygen nebulae with the standard n e indicator of the [O ii] doublet, and find that the electron densities of the z = 4–9 galaxies are n e ≳ 300 cm−3 significantly higher than those of low-z galaxies at a given stellar mass, star formation rate (SFR), and specific SFR. Interestingly, the typical electron densities of the singly ionized nebulae increase from z = 0 to z = 1−3 and z = 4–9, which is approximated by the evolutionary relation of n e ∝ (1 + z) p with p ∼ 1–2. Although it is not obvious that the ISM property of n e is influenced by global galaxy properties, these results may suggest that the nebula densities of high-z galaxies are generally high due to the compact morphologies of high-z galaxies evolving by (r vir ∝ (1 + z)−1) for a given stellar (halo) mass whose inverse square corresponds to the p ∼ 2 evolutionary relation. The p ∼ 1−2 evolutionary relation can be explained by a combination of the compact morphology and the reduction of n e due to the high electron temperature of high-z metal-poor nebulae.

Confirmation of Subsolar Metallicity for WASP-77Ab from JWST Thermal Emission Spectroscopy

We present the dayside thermal emission spectrum of WASP-77Ab from 2.8 to 5.2 μm as observed with the NIRSpec instrument on the James Webb Space Telescope (JWST). WASP-77Ab was previously found to have a subsolar metallicity and a solar carbon-to-oxygen (C/O) ratio from H2O and CO absorption lines detected using high-resolution spectroscopy. By performing atmospheric retrievals on the JWST spectrum assuming chemical equilibrium, we find a subsolar metallicity [M/H] = and C/O ratio . We identify H2O and CO and constrain their abundances, and we find no CO2 in the spectrum. The JWST and high-resolution spectroscopy results agree within ∼1σ for the metallicity and within 1.8σ for the C/O ratio. However, our results fit less well in the picture painted by the shorter wavelength spectrum measured by Hubble Space Telescope Wide Field Camera 3. Comparing the JWST thermal emission spectra of WASP-77Ab and HD 149026b shows that both hot Jupiters have nearly identical brightness temperatures in the near-infrared but distinctly different atmospheric compositions. Our results reaffirm high-resolution spectroscopy as a powerful and reliable method to measure molecular abundances. Our results also highlight the incredible diversity of hot Jupiter atmospheric compositions.

A Spectroscopic Thermometer: Individual Vibrational Band Spectroscopy with the Example of OH in the Atmosphere of WASP-33b

Individual vibrational band spectroscopy presents an opportunity to examine exoplanet atmospheres in detail, by distinguishing where the vibrational state populations of molecules differ from the current assumption of a Boltzmann distribution. Here, retrieving vibrational bands of OH in exoplanet atmospheres is explored using the hot Jupiter WASP-33b as an example. We simulate low-resolution spectroscopic data for observations with the JWST's NIRSpec instrument and use high-resolution observational data obtained from the Subaru InfraRed Doppler instrument (IRD). Vibrational band–specific OH cross-section sets are constructed and used in retrievals on the (simulated) low- and (real) high-resolution data. Low-resolution observations are simulated for two WASP-33b emission scenarios: under the assumption of local thermal equilibrium (LTE) and with a toy non-LTE model for vibrational excitation of selected bands. We show that mixing ratios for individual bands can be retrieved with sufficient precision to allow the vibrational population distributions of the forward models to be reconstructed. A fit for the Boltzmann distribution in the LTE case shows that the vibrational temperature is recoverable in this manner. For high-resolution, cross-correlation applications, we apply the individual vibrational band analysis to an IRD spectrum of WASP-33b, applying an “unpeeling” technique. Individual detection significances for the two strongest bands are shown to be in line with Boltzmann-distributed vibrational state populations, consistent with the effective temperature of the WASP-33b atmosphere reported previously. We show the viability of this approach for analyzing the individual vibrational state populations behind observed and simulated spectra, including reconstructing state population distributions.

GOALS-JWST: Pulling Back the Curtain on the AGN and Star Formation in VV 114

We present results from the James Webb Space Telescope Director’s Discretionary Time Early Release Science program 1328 targeting the nearby, luminous infrared galaxy, VV 114. We use the MIRI and NIRSpec instruments to obtain integral-field spectroscopy of the heavily obscured eastern nucleus (V114E) and surrounding regions. The spatially resolved, high-resolution spectra reveal the physical conditions in the gas and dust over a projected area of 2–3 kpc that includes the two brightest IR sources, the NE and SW cores. Our observations show for the first time spectroscopic evidence that the SW core hosts an active galactic nucleus as evidenced by its very low 6.2 μm and 3.3 μm polycyclic aromatic hydrocarbon equivalent widths (0.12 and 0.017 μm, respectively) and mid- and near-IR colors. Our observations of the NE core show signs of deeply embedded star formation including absorption features due to aliphatic hydrocarbons, large quantities of amorphous silicates, as well as HCN due to cool gas along the line of sight. We detect elevated [Fe ii]/Pfα consistent with extended shocks coincident with enhanced emission from warm H2, far from the IR-bright cores and clumps. We also identify broadening and multiple kinematic components in both H2 and fine structure lines caused by outflows and previously identified tidal features.

A JWST NIRSpec Phase Curve for WASP-121b: Dayside Emission Strongest Eastward of the Substellar Point and Nightside Conditions Conducive to Cloud Formation

We present the first exoplanet phase-curve measurement made with the JWST NIRSpec instrument, highlighting the exceptional stability of this newly commissioned observatory for exoplanet climate studies. The target, WASP-121b, is an ultrahot Jupiter with an orbital period of 30.6 hr. We analyze two broadband light curves generated for the NRS1 and NRS2 detectors, covering wavelength ranges of 2.70–3.72 μm and 3.82–5.15 μm, respectively. Both light curves exhibit minimal systematics, with approximately linear drifts in the baseline flux level of 30 ppm hr−1 (NRS1) and 10 ppm hr−1 (NRS2). Assuming a simple brightness map for the planet described by a low-order spherical harmonic dipole, our light-curve fits suggest that the phase curve peaks coincide with orbital phases 3.°36 ± 0.°11 (NRS1) and 2.°66 ± 0.°12 (NRS2) prior to mideclipse. This is consistent with the strongest dayside emission emanating from eastward of the substellar point. We measure planet-to-star emission ratios of 3924 ± 7 ppm (NRS1) and 4924 ± 9 ppm (NRS2) for the dayside hemisphere and 136 ± 8 ppm (NRS1) and 630 ± 10 ppm (NRS2) for the nightside hemisphere. The latter nightside emission ratios translate to planetary brightness temperatures of 926 ± 12 K (NRS1) and 1122 ± 10 K (NRS2), which are low enough for a wide range of refractory condensates to form, including enstatite and forsterite. A nightside cloud deck may be blocking emission from deeper, hotter layers of the atmosphere, potentially helping to explain why cloud-free 3D general circulation model simulations systematically overpredict the nightside emission for WASP-121b.