Neutral Components Research Articles

Investigating the effect of volatility on the hygroscopicities of acetate nanoparticle aerosols by surface plasmon resonance microscopy

Under high relative humidity (RH) conditions, the release of volatile components (such as acetate) has a significant impact on the aerosol hygroscopicity. In this work, one surface plasmon resonance microscopy (SPRM) measurement system was introduced to determine the hygroscopic growth factors (GFs) of three acetate aerosols separately or mixed with glucose at different RHs. For Ca(CH3COO)2 or Mg(CH3COO)2 aerosols, the hygroscopic growth trend of each time was lower than that of the previous time in three cyclic humidification from 70% RH to 90% RH, which may be due to the volatility of acetic acid leading to the formation of insoluble hydroxide (Ca(OH)2 or Mg(OH)2) under high RH conditions. Then the third calculated GF (using the Zdanovskii-Stokes-Robinson method) for Ca(CH3COO)2 or Mg(CH3COO)2 in bicomponent aerosols with 1:1 mass ratio were 3.20% or 5.33% lower than that of the first calculated GF at 90% RH. The calculated results also showed that the hygroscopicity change of bicomponent aerosol was negatively correlated with glucose content, especially when the mass ratio of Mg(CH3COO)2 to glucose was 1:2, the GF at 90% RH only decreased by 4.67% after three cyclic humidification. Inductively coupled plasma atomic emission spectrum (ICP-AES) based measurements also indicated that the changes of Mg2+concentration in bicomponent was lower than that of the single-component. The results of this study reveal thatduring the efflorescence transitions of atmospheric nanoparticles, the organic acids diffusion rate may be inhibited by the coating effect of neutral organic components, and the particles aging cycle will be prolonged.

Room-Temperature One-Pot Synthesis of pH-Responsive Pyridine-Functionalized Carbon Surfaces.

Carbon surfaces (glassy carbon, graphite, and boron-doped diamond) were functionalized with layers composed of linked pyridinium and pyridine moieties using simple electrochemical reduction of trifluoroacetylpyridinium. The pyridinium species was generated in situ in solution by the reaction of trifluoroacetic anhydride and pyridine precursors and underwent electrochemical reduction at -1.97 V vs Fc/Fc+, as determined by cyclic voltammetry. The pyridine/pyridinium films were electrodeposited at room temperature, on a timescale of minutes, and were characterized using X-ray photoelectron spectroscopy. The as-prepared films have a net positive charge in aqueous solution at pH 9 and below due to the pyridinium content, confirmed by the electrochemical response of differently charged redox molecules at the functionalized surfaces. The positive charge can be enhanced further through protonation of the neutral pyridine component by controlling the solution pH. Moreover, the nitrogen-acetyl bond can be cleaved through base treatment to purposefully increase the neutral pyridine proportion of the film. This results in a surface that can be "switched" from functionally near neutral to a positive charge by treatment in basic and acidic solutions, respectively, through manipulation of the protonation state of the pyridine. The functionalization process demonstrated here is readily achievable at a fast timescale at room temperature and hence can allow for rapid screening of surface properties. Such functionalized surfaces present a means to test in isolation the specific catalytic performance of pyridinic groups toward key processes such as oxygen and CO2 reduction.

In Vitro Anti-inflammatory Activity of Three Inula Species Essential Oils in Lipopolysaccharide-Stimulated RAW 264.7 Macrophages

In the face of the undesirable effects induced by anti-inflammatory drugs, there has been a return, nowadays, to the search for active ingredients based on plants. Herein, for the first time we study the anti-inflammatory activity of essential oils of three species of the genus Inula: Inula viscosa, Inula graveolens and Inula crithmoides in lipopolysaccharide (LPS)-activated macrophages. Essential oils have shown excellent preventive anti-inflammatory potential by causing inhibition of nitric oxide (NO) production in LPSactivated RAW264.7 macrophages with IC50s ranging between 15 and 35 µg mL− 1. On the other hand, the major acidic compounds, more precisely α- and β-costic acids, have been isolated from Inula viscosa and Inula graveolens essential oils and evaluated for their anti-inflammatory effect. These compounds appear to have a moderate preventive inhibitory effect on NO production relative to the significant effect generated by the neutral minority components present in the oils such as borneol, bornyl acetate, (E)-nerolidol, caryophyllene oxide, T-cadinol and eugenol. Therefore, we can deduce that the studied essential oils could be used as anti-inflammatory agents for the treatment of various inflammatory pathologies.

Generation of Post Sunset E Region Electron Density Stratifications at the Magnetic Equator: An Analysis Using In Situ Measurements and Theoretical Estimations

AbstractMeasurements of electron density/irregularities and ion drift velocity/neutral wind were undertaken with Electron Density and Neutral Wind (ENWi) payload on‐board an RH300 flight on 6 April 2018 as part of the Sounding Rocket Experiment (SOUREX1). The presence of a clearly structured ENWi measured electron density profile is an interesting feature observed on this day. Concurrently electron density/irregularities are measured by a Langmuir probe payload which confirmed the presence of stratifications in electron density. The neutral wind measurements by ENWi also reveal a structured pattern. The hodograph analysis of the neutral wind components reveals clockwise rotation indicating downward phase propagation characteristics associated with the gravity waves. Analysis of the requisite ion convergence at the magnetic equator for occurrence of electron density stratifications using the observed electron density structures during the post sunset hours in relation to the ion convergence due to gravity wave winds is performed according to earlier theoretical simulations. This analysis reveals that conditions favoring the formation of stratification related ion convergence are present therein. Thus the present study for first time uses actual measurements of neutral winds and electron densities from same instrument to demonstrate the role of gravity wave induced winds in producing ion convergence at the magnetic equatorial region Trivandrum in the post sunset hours.

Increased brick ratio in urban substrates has a marginal effect on tree saplings

From construction and demolition of buildings, brick wastes accumulate in large quantities and are difficult to recycle. Re-using bricks as planting substrate could partly substitute gravel or other raw materials, and would reduce deposition of bricks in landfills. High water-holding capacity and a high specific surface of such substrates are beneficial for plant growth, while high pH could be a disadvantage. This study focuses on potential effects of brick-based substrates on survival, growth and functional traits of two urban trees (Acer platanoides, Tilia cordata). We compared the effects of brick quantity (5 vs. 30%), pre-treatment with phosphoric acid, nutrient-poor vs. -rich soil, and mycorrhiza inoculation upon saplings in two greenhouse experiments. There were no effects on survival, while a high brick ratio slightly reduced growth of A. platanoides and its branching in nutrient-rich soil, and tend to increase the root-to-shoot ratio in both species. The acid pre-treatment caused negative effects on relative growth rate of A. platanoides. Mycorrhiza inoculation had a tendency for a positive effect on growth in T. cordata, but only with 5% brick ratio. Overall, the brick-based substrates have no clear effect on the study species. Thus, bricks can be recommended as a neutral component within constructed Technosols, and can be used to modify grain size distribution without negative effects on survival, growth and performance, while further studies are needed on bricks with cement and gypsum contaminations.

Observation of Scintillation Enhancements and Large‐Scale Structures Within the Equatorial Ionization Anomaly During a Sudden Stratospheric Warming Event

AbstractTotal electron content (TEC) and L‐band scintillations measured by several networks of GPS and GNSS receivers that operate in South and Central America and the Caribbean region are used to observe the morphology of the equatorial ionization anomaly (EIA), examine the evolution of plasma bubbles, and investigate the enhancement of L‐band scintillations that occurred on February 12 and 13, 2016. A few weak and short magnetic storms developed these days, and a minor sudden stratospheric warming (SSW) event was initiated a few days before. During these unusual conditions, TEC maps reported a split of the otherwise continuous crests of the EIA and the formation of a large‐scale (thousands of kilometers) almost‐circular structure. The western part of the southern crest faded, and a north‐south aligned segment developed near the center of the South American continent, joining the north and south crests of the EIA, forming an anomaly that resembled a closed loop on the eastern side of the continent. Concurrently with the anomaly events, several GPS stations reported increases in the L‐band scintillation index from 0.4 to values greater than 1. We analyzed TEC values from receivers between ±6° from the magnetic equator to identify and follow TEC depletions associated with plasma bubbles when they reach different stations. Although the magnetic activity was moderate (Kp = 3°), we believe that the anomaly redistribution and the scintillation enhancements are not related to a prompt penetration electric field but to enhancing the semidiurnal lunar tide propitiated by the onset of the minor SSW event. We found that depending on the lunar tide phase cycle, the neutral wind's meridional component can augment sub‐km scale irregularities and enhance L‐band scintillations through the wind gradient instability when U·n < 0 or the action of wind gradients (U) within the bubbles. Our observations imply that the SSW event enables prominent changes in the thermosphere wind system at F‐region altitudes.

Treatment of sewage sludge hydrothermal carbonization aqueous phase by Fe(II)/CaO2 system: Oxidation behaviors and mechanism of organic compounds

The Fe(II)/CaO2 system with a stable oxidant and a low-cost homogeneous activating agent has been considered as a prospective process for the disposal of wastewater. The system was constructed to treat sewage sludge hydrothermal carbonization aqueous phase (HTC-AP) in this study. As the hydrothermal temperature increased, the organics in the HTC-AP were first decomposed and then cyclized, while the Maillard reaction occurs throughout the stage. The oxidation efficiency of the Fe(II)/CaO2 system was related to the composition of organics in HTC-AP, and the removal of dissolved organic carbon (DOC) by the system was 38.56 % in the HTC-AP obtained by hydrothermal treatment at 220 °C. Redundancy analysis showed that the low molecular weight organics, hydrophobic acids, and hydrophobic neutral components were beneficial to DOC removal, while Maillard products and cyclization products were hard to be oxidized to CO2 and H2O. The CN functional group of the protein facilitated DOC removal, and some organics in HTC-AP were oxidized to acids and phenols. The energy input to remove DOC in Fe(II)/CaO2 system was 27.74 MJ per kg carbon. This study provides a low-energy consumption Fe(II)/CaO2 system for the post-treatment of HTC-APs and explores the applicability of the system.

Seebeck, Peltier, and Soret effects: On different formalisms for transport equations in thermogalvanic cells.

Thermogalvanic cells convert waste heat directly to electric work. There is an abundance of waste heat in the world and thermogalvanic cells may be underused. We discuss theoretical tools that can help us understand and therefore improve on cell performance. One theory is able to describe all aspects of the energy conversion: nonequilibrium thermodynamics. We recommend to use the theory with operationally defined, independent variables, as others have done before. These describe well-defined experiments. Three invariance criteria serve as a basis for any description: of local electroneutrality, entropy production invariance, and emf's independence of the frame of reference. Alternative formalisms, using different sets of variables, start with ionic or neutral components. We show that the heat flux is not the same in the two formalisms and derive a new relationship between the heat fluxes. The heat flux enters the definition of the Peltier coefficient and is essential for the understanding of the Peltier heat at the electrode interfaces and of the Seebeck coefficient of the cell. The Soret effect can occur independently of any Seebeck effect, but the Seebeck effect will be affected by the presence of a Soret effect. Common misunderstandings are pointed out. Peltier coefficients are needed for the interpretation and design of experiments.

Wideband study of the brightest black hole X-ray binary 4U 1543−47 in the 2021 outburst: signature of disc-wind regulated accretion

ABSTRACT A comprehensive wideband spectral analysis of the brightest black hole X-ray binary 4U 1543−47 during its 2021 outburst is carried out for the first time using NICER, NuSTAR, and AstroSat observations by phenomenological and reflection modelling. The source attains a super-Eddington peak luminosity and remains in the soft state, with a small fraction ($\lt 3{{\ \rm per\ cent}}$) of the inverse-Comptonized photons. The spectral modelling reveals a steep photon index (Γ ∼ 2–2.6) and relatively high inner disc temperature (Tin ∼ 0.9–1.27 keV). The line-of-sight column density varies between (0.45–0.54) × 1022 cm−2. Reflection modelling using the RELXILL model suggests that 4U 1543−47 is a low-inclination system (θ ∼ 32°–40°). The accretion disc is highly ionized (log ξ > 3) and has super solar abundance (3.6–10 AFe,⊙) over the entire period of study. We detected a prominent dynamic absorption feature between ∼8 and 11 keV in the spectra throughout the outburst. This detection is the first of its kind for X-ray binaries. We infer that the absorption of the primary X-ray photons by the highly ionized, fast-moving disc winds can produce the observed absorption feature. The phenomenological spectral modelling also shows the presence of a neutral absorption feature ∼7.1–7.4 keV, and both ionized and neutral absorption components follow each other with a delay of a typical viscous time-scale of 10–15 d.

A retrospective study of articular surface mounting computer-assisted total knee arthroplasty in alignment, knee function, and survival

Background Hong Kong Chinese exhibits a greater varus lower limb mechanical axis and coronal bowing when compared to Caucasians. This anatomical difference may affect the accuracy of bone cuts in total knee arthroplasty (TKA) using western anatomy-based intramedullary TKA cutting jigs. Use of computer navigation may avoid suboptimal cuts due to altered anatomy. This is the first study evaluating clinical function, radiological alignment and long-term survival of computer-assisted TKA amongst Hong Kong Chinese patients. Methods Retrospective study comparing articular surface mounting computer-assisted TKA (ASM-CATKA) and conventional TKA performed in a single centre from 2008 to 2010. Patients were followed up for ​assessment of clinical parameters including range of motion, Knee Society Knee score, and radiological parameters such as limb alignment, component alignment, and survival. Results Seventy-five patients were included in this study. Baseline clinical and radiological data were similar between groups. The computer-navigated group had superior radiological mechanical alignment ( p < 0.001), tibial component alignment ( p = 0.016) and femoral component alignment ( p < 0.01) when compared to conventional TKA. There were no differences in knee scores ( p = 0.488), range of motion ( p = 0.432) and survival at 117 months ( p = 0.986) between the two groups. Conclusion This retrospective study showed that ASM-CATKA was more accurate in achieving neutral mechanical axis and component alignment amongst Hong Kong Chinese. Clinical outcomes and implant survival were comparable.

Mass exchange in two-layer medium moving through the narrow cylindrical channel

This work further develops previous studies devoted to numerical modeling of diffuse mass transfer in narrow pore channels. The problem of diffusion in a two-layer liquid moving through narrow cylindrical channel, into which a neutral component, which does not interact with heterogeneous inclusions, diffuses, is considered. The dispersion carrier fluid moves close to the wal, while a reologically complicated two-phase medium occupies most of the channel. During the flow of a fine-dispersed concentrated suspension in a quasi-balanced condition, the reological properties of the medium were accepted as parameters of some homogenous liquid, which can be deemed an adequate approximation. This model can be used for some situations of flow in the chanal of fluid bodies which are capillary-porous and broken, such as those that contain muddy or clay inclusions. Similar mathematical models can be applied to paste sliding flows because of poor capillary fluid fixation. In this paper, two cases are considered. In the first scenario, a portion of the channel midsection is exceeded by the diffusing component. In the second, this component in the same location exits the channel. The non-stable problem is numerically solved before the creation of the stationary state. The installation procedure was monitored up to the fifth decimal digit. The resulting solution determines the concentration fields of the diffuse component. It is demonstrated that distribution of the diffuse component concentration in the working area is influenced by the rate of the medium speed; diffuse flow through the wall, and effective diffusion coefficient. In this work, the case is considered when there is no interaction between the diffusing component and the dispersed medium. However, the interaction of these components of the medium in soils, biological systems, and natural layers containing organic inclusions is of great interest. Therefore, accounting of adsorption properties of the dispersed medium in relation to the elements involved in mass exchange can be in the focus of future study. Taking into account large-scale metabolic processes, such as those in blood in the veins, is crucial in many practically significant circumstances.

Structures of LaH10, EuH9, and UH8 superhydrides rationalized by electron counting and Jahn-Teller distortions in a covalent cluster model.

The superconducting hydrides LaH10, EuH9 and UH8 are studied using chemically intuitive bonding analysis of periodic and molecular models. We find trends in the crystallographic and electronic structures of the materials by focusing on chemically meaningful building blocks in the predicted H sublattices. Atomic charge calculations, using two complementary techniques, allow us to assign oxidation states to the metals and divide the H sublattice into neutral and anionic components. Cubic [H8]q- clusters are an important structural motif, and molecular orbital analysis of this cluster in isolation shows the crystal structures to be consistent with our oxidation state assignments. Crystal orbital Hamilton population analysis confirms the applicability of the cluster model to the periodic electronic structure. A Jahn-Teller distortion predicted by MO analysis rationalises the distortion observed in a prior study of EuH9. The impact of this distortion on superconductivity is determined, and implications for crystal structure prediction in other metal-hydrogen systems are discussed. Additionally, the performance of electronic structure analysis methods at high pressures are tested and recommendations for future studies are given. These results demonstrate the value of simple bonding models in rationalizing chemical structures under extreme conditions.

A Component of the Smith High-velocity Cloud Now Crossing the Galactic Plane

We have identified a new structure in the Milky Way: a leading component of the Smith high-velocity cloud that is now crossing the Galactic plane near longitude 25°. Using new 21 cm H i data from the Green Bank Telescope (GBT), we measured the properties of several dozen clouds that are part of this structure. Their kinematics is consistent with that of the Smith Cloud with a V LSR exceeding that permitted by circular rotation in their direction. Most of the clouds in the leading component show evidence that they are interacting with disk gas allowing the location of the interaction to be estimated. The leading component crosses the Galactic plane at a distance from the Sun of 9.5 kpc, about 4.5 kpc from the Galactic Center. Its H i mass may be as high as 106 M ⊙, comparable to the mass of the neutral component of the Smith Cloud, but only a fraction of this is contained in clouds that are resolved in the GBT data. Like the Smith Cloud, the leading component appears to be adding mass and angular momentum to the interstellar medium in the inner Galaxy. We suggest that the Smith Cloud is not an isolated object, but rather part of a structure that stretches more than 40° (∼7 kpc) across the sky, in two pieces separated by a gap of ∼1 kpc.

The concept Muslim: discourses in Bosnian, Croatian, German and Serbian webcorpora

The aim of this contribution is to examine the meaning of the word musliman or German Muslim and to answer the question whether the meaning of this word in a dictionary can be mapped by means of classical distributional analysis, and whether further meanings can be captured by this method. In addition, a simple method for a distributional semantic analysis is presented. The basis of the investigation is the assumption common in corpus–based semantics and lexicography that the meaning of words can be interpreted from the context and thus polysemy and synonymy can be recognized. The article examines four web corpora for Bosnian, Croatian, Serbian and German. First, the context is analysed, assuming that the syntactic structures in the context are themselves inherently meaningful. Specifically, adjective attributes are used to analyse properties of the keyword, coordination partners as indicators for relevant categories, verbs with the keyword as subject and accusative object as indicators for typical actions the keyword performs or is target of. In a second step, the lexemes that occur in these four contexts are clustered and the semantic dimensions of the keyword are determined. The results suggest that the distributional method can in principle map dictionary definitions well. However, this is mainly true for contexts which involve attributes and coordination but not for action–related syntactic configurations. Overall, the most salient semantic dimensions of the lexeme are those pertaining to members of a religious community, members of a regional ethnic group, and experienced or induced aggression. Here, the four corpora differ considerably: while German usage almost exclusively focuses on religion–related aspects, the other corpora also contain ethnic/regional components, as well as the discourse of aggression. This aggression is mainly verbal in German, but physical in the other corpora. Neutral meaning components for the word musliman are salient only in the Bosnian corpus.

Structural electroneutrality in Onsager–Stefan–Maxwell transport with charged species

We present a method to embed local electroneutrality within Onsager–Stefan–Maxwell electrolytic-transport models, circumventing their formulation as differential systems with an algebraic constraint. Flux-explicit transport laws are developed for general multicomponent electrolytes, in which the ionic conductivity, component diffusivities, and transference numbers relate to Stefan–Maxwell coefficients through invertible matrix calculations. A construction we call a ‘salt–charge basis’ implements Guggenheim’s transformation of species electrochemical potentials into combinations describing a minimal set of neutral components, leaving a unique combination associated with electricity. Defining conjugate component concentrations and fluxes that preserve the structures of the Gibbs function and energy dissipation retains symmetric Onsager reciprocal relations. The framework reproduces Newman’s constitutive laws for binary electrolytes and the Pollard–Newman laws for molten salts; we also propose laws for salt solutions in two-solvent blends, such as lithium-ion-battery electrolytes. Finally, we simulate a potentiostatic Hull cell containing a non-ideal binary electrolyte with concentration-dependent properties.

COMPOSITION OF LIPOPHILIC COMPONENTS OF RHODODENDRON ADAMSAY ETHER EXTRACT AND AC-TIVITY AGAINST SARS-COV-2 MAIN PROTEASE

The composition of the lipophilic components of the Adams rhododendron RhododendronadamsiiRehd. Acid and neutral components were identified using gas-liquid chromatography with mass spectrometric detection. Methyl tert-butyl ether (MTBE), which has all the advantages of diethyl ether, but is devoid of its disadvantages, was used as the raw material extractant. It does not form peroxides and does not create increased gas contamination due to its higher boiling point. As a result, comparison with databases identified triterpene, phenolcarboxylic and aliphatic acids with a chain length of 8 to 30 carbon atoms, including saturated, unsaturated and dibasic acids. More than 150 triterpene and aliphatic components of the unsaponifiable residue and acid fractions have been identified. Previously, unsaponifiable residues of lipophilic extracts were practically not studied. Only components of Rh.adamsiiand other species of the genus rhododendron essential oils have been studied in detail. For bioactivity testing, samples of the whole extract and its fractionation products were prepared. Some of the studied samples show inhibitory activity against the main protease of SARS-CoV-2.

Hydrogen-Bonded Chain of Rings Motif in N-(4-Methoxyphenyl)piperazin-1-ium Salts with Benzoate Anions: Supramolecular Assemblies and Their Energy Frameworks

The crystal structures of three salts, namely N-(4-methoxyphenyl)piperazin-1-ium ethoxybenzoate monohydrate (I), N-(4-methoxyphenyl)piperazin-1-ium methoxybenzoate monohydrate (II) and N-(4-methoxyphenyl)piperazin-1-ium hydroxybenzoate monohydrate (III), have been determined and compared. In each of them, the ionic components and the water molecules are linked by a combination of N—H···O and O—H···O hydrogen bonds to form infinite chains of edge-fused centrosymmetric rings running parallel to the [100] direction. The C—H···O, C—H···π(arene) interactions and O—H···O in (III) are responsible for the further propagation of the aforementioned chains into di-periodic layers or tri-periodic networks. From an energetic point of view, all structures are primarily di-periodic; the very strong ionic interactions determine the periodicity. For comparison purposes, quantum chemical calculations were performed to show the difference between the ionic and neutral components. The energy of the hydrogen-bonded ring motifs was also estimated.

Dark matter in a singlet-extended inert Higgs-doublet model

In this work, we consider an extension of the Standard Model with an inert Higgs doublet and a real scalar singlet, in order to address problems around the origin of dark matter (DM). In this model, the lightest among the $CP$-odd and $CP$-even neutral inert components plays the role of a DM candidate, where the model parameters are subject to many theoretical and experimental constraints. These constraints include vacuum stability, perturbativity, LEP negative searches, electroweak precision tests, Higgs diphoton, Higgs invisible and Higgs undetermined decays, DM relic density, and DM direct detection bounds. Using these constraints, we find that the allowed parameter space for these models is quite sizable and could be explored in upcoming collider and astrophysical searches.

Large Ion-neutral Drift Velocities and Plasma Heating in Partially Ionized Coronal Rain Blobs

In this paper we present a numerical study of the dynamics of partially ionized coronal rain blobs. We use a two-fluid model to perform a high-resolution 2D simulation that takes into account the collisional interaction between the charged and neutral particles contained in the plasma. We follow the evolution of a cold plasma condensation as it falls through an isothermal vertically stratified atmosphere that represents the much hotter and lighter solar corona. We study the consequences of the different degrees of collisional coupling that are present in the system. On the one hand, we find that at the dense core of the blob there is a very strong coupling and the charged and neutral components of the plasma behave as a single fluid, with negligible drift velocities (of a few cm s−1). On the other hand, at the edges of the blob the coupling is much weaker and larger drift velocities (of the order of 1 km s−1) appear. In addition, frictional heating causes large increases of temperature at the transition layers between the blob and the corona. For the first time we show that such large drift velocities and temperature enhancements can develop as a consequence of ion-neutral decoupling associated to coronal rain dynamics. This can lead to enhanced emission coming from the plasma at the coronal rain-corona boundary, which possesses transition region temperature.

Effects of Bacillus subtilis subsp. on the microbial community and aroma components of flue-cured tobacco leaves based on metagenome analysis.

To improve the sensory quality of aged flue-cured tobacco (FCT), Bacillus subtilis subsp, H11 was inoculated on aged FCT leaves named Pingdingshan DCFB. The metagenome and thecharacteristic aroma substances of aged FCT with different fermentation times (0h, 12h, 24h, and 36h) were systematically analyzed. The results showed that the content of aroma components and sensory quality of aged FCT were significantly improved when the strain was treated at 35°C with 25% moisture for 24h. The inoculation of H11 had a strong influence on the microbial composition and metabolism of the aged FCT leaf surface. Five microorganisms Pantoea (35.04%, 20.12-56.95%), Enterobacter (22.16, 13.60-39.82%), Pseudomonas (12.12, 3.13-26.17%), Terribacillus (8.00%, 4.65-13.01%) and Bacillus (6.54%, 0.67-16.96%) accounted for the largest proportion during the process of fermentation. The content of most neutral flavor components such as ketones and aldehydes in FCT after fermentation was higher than that priorto fermentation. After 24h fermentation, 3-furfural, 5-methylfurfural, dihydrokiwi lactone and megalotrienone increased by 71.42%, 49.19%, 21.09%, and 10.56%, respectively. Correlation analysis between groups showed that Pseudomonas was significantly correlated with (E, E)-2, 4-heptadienal (P < 0.05), Franconibacter was correlated with damascus ketone (P < 0.05), and Terribacillus was related to the production of β-citral (P < 0.05). GH9 may be involved in the formation of damasone (P < 0.05), and 4-cyclopentene-1, 3-dione was significantly correlated with glycoside hydrolase family 5 (GH5) (P < 0.05). The correlation between 4-oxyisophorone and GH31, GH103, GH73, and GH3 was significant (P < 0.05). Microorganisms and GHs may play important roles in FCT fermentation.