Nano Titanium Research Articles

Flexocatalysis of nanoscale titanium dioxide

Piezocatalysis emerges as a distinctive approach for producing free radicals to drive catalysis. However, the piezoelectric effect exclusively manifests in non-centrosymmetric materials, which largely constraints the use of materials with centrosymmetry. To address this challenge, the concept of flexocatalysis is explored to bypass the structural constraints of materials by harnessing strain-gradient-induced polarization, taking advantage of universality of flexoelectricity. As an exemplar of flexocatalysis, centrosymmetric rutile titanium dioxide (TiO2) nano particles are selected due to its high permittivity, non-toxicity, biocompatibility, and wide-ranging utility. The effectiveness of flexocatalysis in generating free radicals (·H, and ·OH) is validated through hydrogen generation (∼2380 μmolg−1h−1 in pure water) and Rhodamine B dye degradation. Additionally, the size effect on flexoelectricity is examined both experimentally and theoretically, revealing that materials at nanoscale exhibit greatly enhanced flexoelectricity that can rival the traditional piezoelectricity. This work endows TiO2 with novel capabilities and broadens material’s selection in mechanochemistry applications.

Titanium Dioxide and Calcium Sulfate Whiskers Are Used for the Preparation of High Performance Polypropylene and Reduce White Pollution.

The anti-aging agent TiO2-polyacrylonitrile (PAN) and the mechanical strengthening agent CSW-PAN were prepared by radical polymerization using rutile nano-titanium dioxide (TiO2) and anhydrous calcium sulfate whisker (CSW) as raw materials. The structures of TiO2-PAN and CSW-PAN were characterized using Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Simultaneously, the mechanical properties, aging properties, and thermal stability of TiO2-PAN/CSW-PAN/polypropylene (PP) composites were studied, and the results showed that the surfaces of nano-titanium dioxide and calcium sulfate whiskers were successfully grafted with acrylonitrile. Owing to the introduction of new elements, such as acrylonitrile, nano-titanium dioxide and calcium sulfate whiskers have anti-aging properties. In comparison of the impact strength and tensile strength of TiO2-PAN/PP and TiO2-PAN/CSW-PAN/PP before aging, it can be proven that adding CSW-PAN can significantly enhance the mechanical properties of TiO2-PAN/CSW-PAN/PP. After 1000 h of aging, the tensile strength of the ternary composite TiO2-PAN/CSW-PAN/PP was 19.88 MPa when the addition amount of TiO2-PAN and CSW-PAN was 3%. Moreover, the impact strength of the ternary composite material TiO2-PAN/CSW-PAN/PP after 1000 h of aging is even better than that of non-aging pure PP materials, proving that the service life of improved PP products is extended, unnecessary waste and environmental pollution can be relieved, and the needs of specific engineering fields can be met.

Development and analysis of the physical and electrochemical characteristics of a nano titanium (IV) tungstomolybdate supported on polyethersulfone composite cation exchange membrane

In this study, a series of novel composite membranes were synthesized utilizing polyethersulfone (PES), sulfonated polyethersulfone (SPES) as base polymer and titanium tungstomolybdate (TWM) as an inorganic ion exchange resin. The membranes were fabricated through the solution casting technique. The composite membranes exhibited enhanced thermal and chemical stability, as well as improved oxidative stability. All the composite membranes demonstrated higher hydrophilicity, with the SPES-TWM composite membranes displaying the lowest contact angle of 65°. The composite membranes also displayed favorable water uptake (up to 26% for SPES-TWM) and lower methanol uptake (maximum 12% for SPES-TWM) and better mechanical stability (maximum of 40 MPa for SPES-TWM). The SPES-TWM composite membranes exhibited the maximum ion exchange capacity of 1.32 meq.g−1. The transport number of 0.95 was obtained for SPES-TWM, which is comparable to the Nafion-117 membrane. The proton conductivity of both membranes increased as the temperature increased. The maximum proton conductivity of 6.3 mScm−1 was observed for SPES-TWM at 60 °C.

Nano-Additives in Asphalt Binder: Bridging the Gap between Traditional Materials and Modern Requirements

This research delves into the realm of asphalt technology, exploring the potential of nano-additives to enhance traditional asphalt binder properties. Focusing on Nano-Titanium Dioxide (NT), Nano-Aluminum Oxide (NA), and Nano-Silica Oxide (NS), this study investigates the effects of incorporating these nanomaterials at varying dosages, ranging from 0% to 8%, on the asphalt binder’s performance. This study employs a series of experimental tests, including consistency, storage stability, rotational viscosity, mass loss due to aging, and rheological properties, to assess the impact of nano-additives on asphalt binder characteristics. The findings indicate a substantial improvement in the consistency of the asphalt binder with the addition of nanomaterials, particularly NS, which shows a 41% reduction in penetration at an 8% content and a notable increase in the softening point. The storage stability tests reveal that NS-modified asphalt exhibits superior stability compared to NT and NA, with a significantly lower ΔT increase. Furthermore, the investigation into rotational viscosity suggests that NS, despite increasing the binder’s viscosity, does not exceed the AASHTO M320 threshold, ensuring the binder’s workability. Aging tests demonstrate that NT, at lower concentrations, acts as an effective anti-aging agent, whereas NA and NS tend to increase the mass loss, impacting thermal stability. This study concludes that while each nanomaterial uniquely influences the asphalt binder’s properties, NS stands out in terms of enhancing the high-temperature performance and storage stability. Optimal dosages of 6% for NT and NA and 4% for NS are recommended based on the Overall Desirability analysis. This research bridges the gap between traditional asphalt materials and modern requirements, highlighting the transformative impact of nano-additives in advancing asphalt pavement technology.

Effects of Modified Distillers' Grains Biochar on Cadmium Forms in Purple Soil and Cadmium Uptake by Rice

Biochar and modified biochar have been widely used as remediation materials in heavy metal-contaminated agricultural soils. In order to explore economical and effective materials for the remediation of cadmium (Cd)-contaminated acidic purple soil, distillers 'grains were converted into distillers' grains biochar (DGBC) and modified using nano-titanium dioxide (Nano-TiO2) to produce two types of modified DGBCs:TiO2/DGBC and Fe-TiO2/DGBC. A rice pot experiment was used to investigate the effects of different biochar types and application rates (1%, 3%, and 5%) on soil properties, nutrient content, Cd bioavailability, Cd forms, rice growth, and Cd accumulation. The results showed that:① DGBC application significantly increased soil pH, cation exchange capacity (CEC), and nutrient content, with TiO2/DGBC and Fe-TiO2/DGBC exhibiting better effects. ② DGBC and modified DGBCs transformed Cd from soluble to insoluble forms, increasing residual Cd by 1.22% to 18.46% compared to that in the control. Cd bioavailability in soil decreased significantly, with available cadmium being reduced by 11.81% to 23.67% for DGBC, 7.64% to 43.85% for TiO2/DGBC, and 19.75% to 55.82% for Fe-TiO2/DGBC. ③ DGBC and modified DGBCs increased rice grain yield, with the highest yields observed at a 3% application rate:30.60 g·pot-1 for DGBC, 37.85 g·pot-1 for TiO2/DGBC, and 39.10 g·pot-1 for Fe-TiO2/DGBC, representing 1.13, 1.40, and 1.44 times the control yield, respectively. Cd content in rice was significantly reduced, with grain Cd content ranging from 0.24 to 0.30 mg·kg-1 for DGBC, 0.16 to 0.26 mg·kg-1 for TiO2/DGBC, and 0.14 to 0.24 mg·kg-1 for Fe-TiO2/DGBC. Notably, Cd content in rice grains fell below the food safety limit of 0.2 mg·kg-1 (GB2762-2022) at 5% for TiO2/DGBC and 3% and 5% for Fe-TiO2/DGBC. In conclusion, Nano-TiO2 modified DGBC effectively reduced the bioavailability of soil Cd through its own adsorption and influence on soil Cd forms distribution, thus reducing the absorption of Cd by rice and simultaneously promoting rice growth and improving rice yield. It is a type of Cd-contaminated soil remediation material with a potential application prospect. The results can provide scientific basis for farmland restoration and agricultural safety production of Cd-contaminated acidic purple soil.

Possible New Heat Transfer Fluid: The IoNanofluid of 1-Ethyl-3-methylimidazolium Dicyanamide + Nano-Titanium Oxide─Studying Its Thermal Conductivity and Viscosity

Possible New Heat Transfer Fluid: The IoNanofluid of 1-Ethyl-3-methylimidazolium Dicyanamide + Nano-Titanium Oxide─Studying Its Thermal Conductivity and Viscosity

Physical, rheological and micro characteristics of ARA/Nano-TiO2 composite modified asphalt before and after short-term aging

This paper aims to investigate the composite application of nanomaterials and natural asphalt in order to enhance the road performance of asphalt pavement. The objective is to develop high-performance modified asphalt that improves the durability, reliability, and load resistance of asphalt roads while reducing resource waste and environmental pollution. The composite modified asphalt was prepared by adding different blends of Albanian natural rock asphalt (ARA) and 1% of nano titanium dioxide (Nano-TiO2), and the basic properties and rheological properties of the asphalt before and after aging were tested by using basic performance tests and temperature scanning tests. Subsequently, the microscopic morphological characteristics of the asphalt were observed by scanning electron microscope and atomic force microscope, and the number of bee structures, the area share of bee structures, root mean square roughness Rq, and arithmetic mean roughness Ra were used as microscopic quantitative indexes. The results indicate that the complex modulus and rutting coefficient of ARA/Nano-TiO2 composite-modified asphalt increase with an increase in ARA dosage when the dosage of Nano-TiO2 is 1%. The asphalt modified with Nano-TiO2 composite blended with 15% ARA exhibits higher residual needle penetration, composite modulus ratio, rutting coefficient ratio and lower softening point increment compared to 70# asphalt. The bitumen modified with titanium dioxide nanocomposite blended with 15% ARA exhibits higher Rq and Ra and a more stable phase structure before and after aging. 15% of ARA/Nano-TiO2 composite-modified asphalt has higher Rq and Ra before and after aging, and its phase structure is more stable. The results show that ARA/Nano-TiO2 composite-modified asphalt has better high-temperature deformation resistance and aging resistance than 70# and that 15% ARA is recommended as the optimum amount of composite-modified asphalt.

Effect of titanium dioxide on fresh and mechanical properties of Mortar: A review

Nanotechnology-based engineering approaches are rapidly developing throughout the world. Modern, cutting-edge nanotechnology has proven useful in a variety of technical applications. In emerging and developed countries, increasing infrastructure needs a considerable amount of cement, which has a significantly impact on the environment and human health, resulting in greenhouse gas emissions and severe acute respiratory illnesses (asthma and silicosis, respectively). To overcome such difficulties, cement consumption in building materials must be reduced. Several novel extra materials have lately been introduced to improve the performance of mortar. Nano-titanium dioxide (NT) in cement mortar is widely used in green building construction because NT capable to the degradation of air pollution, self-cleaning, and enhancing mechanical, microstructural, and durability properties. In this paper, the effect of NT on fresh and hardened properties of cement mortar has been discussed. For the collection, screening and implementation of data for review paper PRISMA analysis and VOSviewer technique was used. Existing literature indicates that the reduction in workability 15% − 20% whereas improvement in compressive strength (CS) up to 15% and tensile strength up to 45% was noted with NT in mortar. Current research supports using NT as a cement replacement in mortar. Aside from the key findings, some identified gaps, problems, and future scope challenges have been presented in order to develop NT based mortar as a sustainable material in the building sector.

Surface modification of TiO2 with MPS and its effects on the wettability and physical properties of Kawayan Kiling (Bambusa vulgaris Schrad ex. Wendl) handsheets

The need for hydrophobic papers has steadily increased over past years. These papers are often sought after as packaging materials and have high demand in the food industry and medicine. In this study, various concentrations of surface-modified TiO2-MPS were added to Kawayan Kiling (B. vulgaris) pulp at the wet-end section of handsheet formation. Surface-modified TiO2-MPS was made from nano-titanium (IV) oxide using 3-(trimethoxysilyl)propyl methacrylate as a coupling agent. The wettability of handsheets and physical properties were tested using various standard methods. Results reveal that the handsheets without surface-modified TiO2-MPS had the lowest water contact angle (WCA), while the handsheet with 12.34% (w/w) surface-modified TiO2-MPS had the highest WCA. At 17% (w/w) surface-modified TiO2-MPS, the WCA rapidly declined. Handsheets with surface-modified TiO2-MPS have a rougher surface compared to the handsheets without chemicals and handsheets with unmodified TiO2. This roughness made the handsheet hydrophobic. The handsheet with 12.34% (w/w) unmodified TiO2 has a smoother surface than the control handsheet. Energy-dispersive X-ray spectroscopy (EDS) analysis shows that the handsheet with 12.34% (w/w) unmodified TiO2 contained titanium, while the handsheet with 12.34% (w/w) surface-modified TiO2-MPS contained both titanium and silicon. Generally, the physical properties of handsheets improved with surface-modified TiO2-MPS, especially grammage, bulk thickness, tensile index, and water absorptiveness, which showed statistically sig-nificant differences across treatments. The tear index did not differ between treatments.

Research progress in preparation technology of micro and nano titanium alloy powder

Abstract Titanium alloys have excellent properties and are widely used in aerospace, medicine, chemical industry, and other fields. With the rapid development of the powder metallurgy and 3D printing industries, the demand for ultra-fine titanium alloy powders has increased significantly. It should be noted that the particle size of titanium alloy powders determines the application process. However, the high melting point of titanium and titanium alloys and the limitation of many factors, such as the prepared powders being easily contaminated by secondary pollution, make the preparation cost higher, which restricts their promotion and application. In this study, the research progress of micro and nano titanium alloy powder preparation process is described, and the existing problems of various processes are analyzed and discussed, and it is proposed that the direct reduction in TiO2 to obtain micro and nano titanium alloy powder is the key research direction in the future. In particular, the preparation of micro and nano titanium alloy powder by “calciothermic self-propagation process” has great industrial potential.

Nanotechnology and high-performance concrete: Evaluating mechanical transformations

The High-performance concrete (HPC) is defined by the attained strength and durability that are superior to conservative techniques. The features of ordinary concrete that are achieved at certain times and locations, used to establish the standards for HPC. The use of nanotechnology in HPC is attracted significant attention globally because of its small particle sizes, filling capacities, enormous surface areas and strong macro quantum tunnel property. By adding nanotechnology to HPC, it increases the whole diameters of the cementations matrix, improves cement hydration and raises matrix density. This study provides a review of current developments in HPC and assesses the effects of different nanotechnology on HPC characteristics, to provide an in-depth understanding of the potential of nanotechnology reinforced in HPC. This review evaluates the mechanical characteristics of HPC containing compressive strength (CS) by applying nano calcium carbonate, nano silicon dioxide, nano titanium dioxide and carbon nano tubes. According to findings in this review, introducing different nanotechnology enhances HPC's mechanical properties while decreasing its flexibility. While integrating nanotechnology into HPC for the greatest possible outcomes in construction, review contributes to expand the collection of information in the area of building materials. To provide a low-impact construction material and an ecologically friendly solution, more consideration is required given to nanoparticles' antibacterial, self-cleaning, air depolluting and air-cooling properties. By increasing the reactivity of various fillers, including nanoparticles with other mineral admixtures reduces the quantity of cement needed in concrete.

Nano-titanium dioxide exacerbates the harmful effects of perfluorooctanoic acid on the health of mussels

Exposing marine organisms to contemporary contaminants, such as perfluorooctanoic acid (PFOA) and nano-titanium dioxide (nano-TiO2), can induce multifaceted physiological consequences. Our investigation centered on the responses of the mussel, Mytilus coruscus, to these agents. We discerned pronounced disruptions in gill filament connections, pivotal structures for aquatic respiration, suggesting compromised oxygen uptake capabilities. Concurrently, the respiratory rate exhibited a marked decline, indicating a respiratory distress. Furthermore, the mussels' clearance rate, a metric of their filtration efficacy, diminished, suggesting the potential for bioaccumulation of deleterious substances. Notably, the co-exposure of PFOA and nano-TiO2 exhibits interactive effects on the physiological performance of the mussels. The mussels' digestive performance waned in the face of heightened PFOA and nano-TiO2 concentrations, possibly hampering nutrient assimilation and energy accrual. This was mirrored in the noticeable contraction of their energy budget, suggesting long-term growth repercussions. Additionally, the dysregulation of the gut microbiota and the reduction in its diversity further confirm alterations in intestinal homeostasis, subsequently impacting its physiological functions and health. Collectively, these findings underscore the perils posed by escalated PFOA and nano-TiO2 levels to marine mussels, accentuating the need for a deeper understanding of nanoparticle-pollutant synergies in marine ecosystems.

Effect of Mechanical Properties of Concrete Using Nano Titanium Dioxide and Partial Replacement of Fly Ash in Cementitious Material

Effect of Mechanical Properties of Concrete Using Nano Titanium Dioxide and Partial Replacement of Fly Ash in Cementitious Material

Novel chitosan-based smart bio-nanocomposite films incorporating TiO2 nanoparticles for white bread preservation

Chitosan (CS)-based bio-nanocomposite food packaging films were prepared via solvent-casting method by incorporating a unique combination of additives and fillers, including polyvinyl alcohol (PVA), glycerol, Tween 80, castor oil (CO), and nano titanium dioxide (TiO2) in various proportions to enhance film properties. For a comprehensive analysis of the synthesized films, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), tensile testing, field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), and UV–vis spectrophotometry were employed. Furthermore, the antimicrobial efficacy of the films against S. aureus, E. coli, and A. niger was examined to assess their potential to preserve food from foodborne pathogens. The results claimed that the inclusion of castor oil and TiO2 nanoparticles considerably improved antimicrobial properties, UV–vis light barrier properties, thermal stability, optical transparency, and mechanical strength of the films, while reducing their water solubility, moisture content, water vapor and oxygen permeability. Based on the overall analysis, CS/PVA/CO/TiO2–0.3 film can be selected as the optimal one for practical applications. Furthermore, the practical application of the optimum film was evaluated using white bread as a model food product. The modified film successfully extended the shelf life of bread to 10 days, surpassing the performance of commercial LDPE packaging (6 days), and showed promising attributes for applications in the food packaging sector. These films exhibit superior antimicrobial properties, improved mechanical strength, and extended shelf life for food products, marking a sustainable and efficient alternative to conventional plastic packaging in both scientific research and industrial applications.

Adsorption mechanism and influencing factors of selenium under the coexistence of nanoparticles and microplastics

Microplastics (MPs), as a common “vector” of pollutants in the aquatic environment, have a significant impact on the migration and transformation of heavy metals. In order to explore the mechanism and the influencing factors of the adsorption behavior of microplastics (MPs) on selenium (Se) in aqueous solution under the coexistence of nanoparticles, polystyrene microplastics (PS), nano-titanium dioxide particles (TiO2) and their coexisting compounds (PS+TiO2) were used as adsorbents to investigate the adsorption kinetics, isotherms and thermodynamic processes of Se. The effects of pH, humic acid concentration and coexisting ions on the adsorption behavior of Se(VI) were also analyzed. The results showed that the adsorption process of Se(VI) by PS and PS+TiO2 could be well fitted by pseudo-second-order kinetic model and Freundlich isotherm model, and it was an endothermic reaction with increased entropy. The adsorption capacity of Se(VI) by PS, TiO2, and PS+TiO2 were decreased with the increase of solution pH. Humic acid and Ca2+ promoted the adsorption of Se(VI), while PO43- significantly inhibited the adsorption of Se(VI) in the above three systems. The main adsorption mechanism of PS on Se(VI) was electrostatic adsorption and hydrogen bonding. The TiO2 adsorbed on the surface of PS mainly affected the adsorption behavior of PS on Se(VI) through hydrogen bonding.

The synergistic mechanism of hydration regulation and carbonation curing on the carbon sequestration and impermeability enhancement of cementitious materials

Carbonation curing, as a novel curing method, gradually plays an important role in the reduction of carbon emissions and the improvement of durability for cementitious materials. This study considers the intervention of carbonation at different ages of hydration and investigates the synergistic effect of nano-titanium dioxide (NT) regulating cement hydration and 20% CO2 carbonation curing on the enhancement of carbon sequestration and durability performance of cement mortar. The results show that early-age carbonation curing and the addition of NT increase the unit area carbon sequestration of cement mortar at the age of 28 days by 242.75% (0.41 kg/m2); meanwhile, some micro-nano-sized calcite crystals and NT jointly play a nucleation and filling role during hydration, optimizing the pore structure. As a result, the unit area capillary water absorption coefficient and gas permeability coefficient decrease by 70.55% and 91.89%, respectively, inhibiting the continuous diffusion of CO2 and achieving controlled surface carbonation. Based on the pore characteristics of the carbonated surface, this study also proposes a “Sieve filter” structure hypothesis model, which suggests a negative correlation between pore structure and surface depth under the synergistic mechanism. This can provide innovative ideas for the cement industry to enhance the durability performance of reinforced concrete prefabricated components using carbon sequestration technology.

Evaluation of antibacterial activity and biocompatibility of nano-titanium dioxide coatings prepared by atomic layer deposition for dental titanium abutments

To reduce the adhered bacteria on the dental titanium (Ti) abutments and the risk of peri‑implantitis, an antibacterial nanometer titanium dioxide (nano-TiO2) coating was developed by atomic layer deposition (ALD). The effects of the nano-TiO2 coatings on surface characteristics, antibacterial efficacy, biocompatibility, and corrosion resistance of Ti abutment materials were investigated. Specifically, the colors of Ti samples were changed from silver-gray to blue, yellow, and purple corresponding to the coating thicknesses were 50 nm, 100 nm, and 150 nm, respectively. Moreover, these coatings with different thicknesses all presented uniform morphologies with anatase TiO2 phases and hydrophobic characteristics. Simultaneously, the prepared coatings exhibited strong antibacterial effects against Staphylococcus aureus (S. aureus), Streptococcus mutans (S. mutans), and Porphyromonas gingivalis (P. gingivalis), which were independent of coating thicknesses. Additionally, Ti substrates coated with 100 nm nano-TiO2 demonstrated exceptional cell compatibility and corrosion resistance. In conclusion, these antibacterial and biocompatible nano-TiO2 coatings prepared by ALD possess great potential in dental aesthetic restorative materials.

Improving Efficiency of Heat Pump Dryer Using R32 Refrigerant by Nanofluid

Drying process are important in many areas in the agriculture and food sectors, including increasing shelf life, improving transportability by reducing product weight or adding value to products. However, the main problem in the drying process is the relatively high energy consumption. Therefore, the development of energy-saving dryers is necessary. Based on the above reasons, this research aims to study the performance enhancement of heat pump dryers using R32 refrigerant by using heat recovery and nanofluid. The heat that is exhausted from the refrigerant by a heat exchanger. In this work, a Nano titanium dioxide (Ti2O3) was selected. Pork was dried under the conditions of drying temperature of 45, 50 and 55 °C and water flow rate in the heat exchanger at the front of the drying chamber of 2, 3 and 4 L/min. Criteria for evaluating heat pump dryer performance include drying rate, specific moisture extraction rate, specific energy consumption, heat pump dryer performance coefficient compared to heat pump dryers without nanofluid. The results showed that increasing the drying temperature and water flow rate in heat exchanger increased the drying rate, power and specific moisture extraction rate in the heat pump dryer using nanofluid. Whereas, the specific energy consumption was lower than the case without nanofluid. Increasing the drying temperature and the water flow rate in the heat exchanger had relatively little effect on the coefficient of performance (COP) of the heat pump dryer. Moreover, the study found that the coefficient of performance of heat pump dryer with nanofluid was in the range of 4.33 - 4.42.

Differential intestinal effects of water and foodborne exposures of nano-TiO2 in the mussel Mytilus coruscus under elevated temperature

With the wide use of nanomaterials in daily life, nano-titanium dioxide (nano-TiO2) presents potential ecological risks to marine ecosystems, which can be exacerbated by ocean warming (OW). However, most previous studies have only centered around waterborne exposure, while there is a scarcity of studies concentrating on the impact of trophic transfer exposure on organisms. We investigated the differences in toxic effects of 100 μg/L nano-TiO2 on mussels via two pathways (waterborne and foodborne) under normal (24 °C) and warming (28 °C) conditions. Single nano-TiO2 exposure (waterborne and foodborne) elevated the superoxide dismutase (SOD) and catalase (CAT) activities as well as the content of glutathione (GSH), indicating activated antioxidatant response in the intestine. However, depressed antioxidant enzymes and accumulated peroxide products (LPO and protein carbonyl content, PCC) demonstrated that warming in combination with nano-TiO2 broke the prooxidant-antioxidant homeostasis of mussels. Our findings also indicated that nano-TiO2 and high temperature exhibited adverse impacts on amylase (AMS), trypsin (PS), and trehalase (THL). Additionally, activated immune function (lysozyme) comes at the cost of energy expenditure of protein (decreased protein concentration). The hydrodynamic diameter of nano-TiO2 at 24 °C (1693–2261 nm) was lower than that at 28 °C (2666–3086 nm). Bioaccumulation results (range from 0.022 to 0.432 μg/g) suggested that foodborne induced higher Ti contents in intestine than waterborne. In general, the combined effects of nano-TiO2 and warming demonstrated a more pronounced extent of interactive effects and severe damage to antioxidant, digestive, and immune parameters in mussel intestine. The toxicological impact of nano-TiO2 was intensified through trophic transfer. The toxic effects of nano-TiO2 are non-negligible and can be exerted together through both water- and foodborne exposure routes, which deserves further investigation.

Nano protective membrane coated wheat to resist powdery mildew.

The plant pathogenic fungus Blumeria graminis f. sp. tritici infects wheat and reduces its yield. The policy of reducing fertilizer and biocide use in sustainable agriculture has prompted researchers to develop more green and efficient management strategies. In this study, a novel nanoprotective membrane (kaolin-nano titanium dioxide-liquid paraffin, referred to as KTP) that could effectively prevent powdery mildew of wheat was prepared by using 1 g/L kaolin, 2 g/L nanotitanium dioxide and 8% (v/v) liquid paraffin. The prevention and control effects of KTP spraying in advance in the pot and field experiments were 98.45% and 83.04%, respectively. More importantly, the weight of 1000 grains of wheat pretreated with KTP was 2.56 g higher than that of wheat infected with powdery mildew, significantly improving wheat yield. KTP delayed the germination of powdery mildew spores on the leaf surface, and inhibited the formation of mycelia. In addition, KTP did not affect the growth of wheat or the survival of earthworms. KTP nanoprotective membrane are a green and safe prevention and control materials that are which is expected to be widely used in agriculture to control wheat powdery mildew.