Corrosion is a challenge for the conservation of musical instruments when metal parts are exposed to organic materials of the instrument's body. In long-term observations in the Norwegian Museum of Music, Ringve and Rockheim (Museums of Southern Trøndelag), local contact corrosion was documented on metal strings of plucked instruments when mounted close to cellulose nitrate (CN). The investigated strings were iron-based alloys, in some cases covered with a tin coating. In the gas mixture emitted from CN, the presence of corrosive compounds such as NO2 and carboxylic acids was confirmed by an electrochemical NO2-sensor and gas chromatography-mass spectrometry. The corrosion product on the strings consisted of iron oxide nitrate hydroxide hydrate, Fe2(NO3)O(OH)3(H2O), and goethite, α-FeOOH, detected with X-ray diffraction (XRD), Raman and infrared spectroscopy (IR). X-ray photoelectron spectroscopy (XPS), used to investigate the surface of tin-coated corrosion products, showed the presence of adsorbed organic nitrogen. The formation of corrosion products is dominated by organic acids and moisture. The presence of nitrate in the corrosion product proved the involvement of nitrogen oxides in the corrosion mechanism. This analytical study highlights a dilemma for preserving material combinations in musical instruments and provides a basis for further researchfor conservation practice.
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