Multifunctional Architectures Research Articles

Engineering of Thermally Converted 3D-NiO[sbnd]Co3O4/Ni//3D-ϒ-Fe4N[sbnd]C@Ni/SS Porous Electrodes for High-performance Supercapatteries

The designing of higher dimensional multifunctional architecture is an attractive feature to boost the electrochemical performance of the electrodes. Herein, bimetallic 3D-NiOCo3O4/Ni positive electrode is prepared via a facile electrodeposition route followed by a post-annealingmethod. Likewise, the 3D porous ϒ-Fe4NC@Ni/SS negative electrode is successfully developed through vapour phase growth process. The as-prepared 3D-NiOCo3O4/Ni demonstrate a high specific capacity of 98.92 mC cm−2 than 30.92 and 22 mC cm−2 of NiO and Co3O4, respectively. Furthermore, the 3D-ϒ-Fe4NC@Ni/SS electrode is delivered an areal capacitance of 125 mF cm−2. Moreover, enhanced electrochemical performance is observed for the assembled 3D-NiOCo3O4/Ni//3D-ϒ-Fe4NC@Ni/SS supercapattery enactment of individual electrodes. It is demonstrated a maximum energy density of 100.47 mWh cm−3 at a power density of 14.69 W cm−3 and 87% capacitance retention combined with 100% coulombic efficiency after 20,000 operation cycles. The attained results are witnessed the successful fabrication of 3D porous template with bimetallic involvement as well as the 3D-ϒ-Fe4NC nanostructure, easy ion penetration, and shorter diffusion path length. Additionally, the present outcome reveal the binder-free growth of both the battery-type and capacitive electrodes for the next-generation energy storage devices.

Molecular polymer bottlebrushes in nanomedicine: therapeutic and diagnostic applications.

Molecular polymer bottlebrushes are densely grafted, individual macromolecules with nanoscale proportions. The last decade has seen an increased focus on this material class, especially in nanomedicine and for biomedical applications. This Feature Article provides an overview of major developments in this area to highlight the many opportunities that these polymer architectures bring to nano-bio research. The article covers aspects of bottlebrush synthesis and summarises their use in drug and gene delivery, imaging, as theranostics and as prototype materials to correlate nanoparticle structure and composition to biological function and behaviour. Areas for future research in this area are discussed.

Electrically switchable valley polarization, spin/valley filter, and valve effects in transition-metal dichalcogenide monolayers interfaced with two-dimensional ferromagnetic semiconductors

Electron valleys in transition-metal dichalcogenide monolayers drive novel physics and allow designing multifunctional architectures for applications. We propose to manipulate the electron valleys in these systems for spin/valley filter and valve devices through band engineering. Instead of the magnetic proximity effect that has been extensively used in previous studies, in our strategy, the electron valleys are directly coupled to the spin-polarized states of the two-dimensional ferromagnets. We find that this coupling results in a valley-selective gap opening due to the spin-momentum locking in the transition-metal dichalcogenide monolayers. This physics gives rise to a variety of unexpected electronic properties and phenomena including halfmetallicity, electrically switchable valley polarization, spin/valley filter and valve effects in the transition-metal dichalcogenide monolayers. We further demonstrate our idea in MoTe$_2$/CoCl$_2$ and CoCl$_2$/MoTe$_2$/CoCl$_2$ van der Waals heterojunctions based on first-principles calculations. Thus, our study provides a way of engineering the electron valleys in transition-metal dichalcogenide monolayers for new-concept devices.

Tunable Electrocatalytic Behavior of Sodiated MoS2 Active Sites toward Efficient Sulfur Redox Reactions in Room-Temperature Na-S Batteries.

Room-temperature (RT) sodium-sulfur (Na-S) batteries hold great promise for large-scale energy storage due to the advantages of high energy density, low cost, and resource abundance. The research progress on RT Na-S batteries, however, has been greatly hindered by the sluggish kinetics of the sulfur redox reactions. Herein, an elaborate multifunctional architecture, consisting of N-doped carbon skeletons and tunable MoS2 sulfiphilic sites, is fabricated via a simple one-pot reaction followed by in situ sulfurization. Beyond the physical confinement and chemical binding of polarized N-doped carbonaceous microflowers, the MoS2 active sites play a key role in catalyzing polysulfide redox reactions, especially the conversion from long-chain Na2 Sn (4 ≤ n≤ 8) to short-chain Na2 S2 and Na2 S. Significantly, the electrocatalytic activity of MoS2 can be tunable via adjusting the discharge depth. It is remarkable that the sodiated MoS2 exhibits much stronger binding energy and electrocatalytic behavior compared to MoS2 sites, effectively enhancing the formation of the final Na2 S product. Consequently, the S cathode achieves superior electrochemical performance in RT Na-S batteries, delivering a high capacity of 774.2 mAh g-1 after 800 cycles at 0.2 A g-1 , and an ultrahigh capacity retention with a capacity decay rate of only 0.0055% per cycle over 2800 cycles.

High‐Resolution Patterned Functionalization of Slippery “Liquid‐Like” Brush Surfaces via Microdroplet‐Confined Growth of Multifunctional Polydopamine Arrays

AbstractSlippery omniphobic covalently attached liquids enable smooth, transparent, pressure‐ and temperature‐resistant, and liquid‐repellent coatings. Patterned functionalization of such surfaces would drive technology developments and fundamental understandings in broad applications from biosensors to sustainable smart surfaces. Herein an additive microcontact printing approach in combination with the microdroplet‐confined synthesis is developed to functionalize slippery surfaces tethered with “liquid‐like” linear poly(dimethylsiloxane) by multifunctional polydopamine (PDA) arrays. Using glycerol and non‐ionic surfactant Tween‐20, microdroplet arrays containing dopamine monomers are printed onto the slippery surfaces and serve as microreactors for the in situ growth of PDA micropatterns. The confined growth approach enables tunable feature size, height, and morphology of the patterns, through which sub‐micrometer PDA dot arrays over centimeter‐square patterning area can be reliably achieved. Furthermore, the reactive and hydrophilic PDA micropatches allow further functionalization of the slippery surfaces with a diverse variety of materials, meanwhile the anti‐fouling and dynamically dewetting “liquid‐like” brushes permit minimum background contamination. Proof‐of‐concept demonstrations include PDA‐initiated photografting for stimuli‐responsive polymer functionalization, protein immobilization for microarray‐based immunoassays, as well as sliding‐induced selective dewetting of organic solutions to pattern photoluminescent perovskite microcrystals and nanoparticles. The current approach illustrates the potential for applying patterned slippery surfaces with multifunctional architectures in many fields.

Tough metal-ceramic composites with multifunctional nacre-like architecture

The brick-and-mortar architecture of biological nacre has inspired the development of synthetic composites with enhanced fracture toughness and multiple functionalities. While the use of metals as the “mortar” phase is an attractive option to maximize fracture toughness of bulk composites, non-mechanical functionalities potentially enabled by the presence of a metal in the structure remain relatively limited and unexplored. Using iron as the mortar phase, we develop and investigate nacre-like composites with high fracture toughness and stiffness combined with unique magnetic, electrical and thermal functionalities. Such metal-ceramic composites are prepared through the sol–gel deposition of iron-based coatings on alumina platelets and the magnetically-driven assembly of the pre-coated platelets into nacre-like architectures, followed by pressure-assisted densification at 1450 °C. With the help of state-of-the-art characterization techniques, we show that this processing route leads to lightweight inorganic structures that display outstanding fracture resistance, show noticeable magnetization and are amenable to fast induction heating. Materials with this set of properties might find use in transport, aerospace and robotic applications that require weight minimization combined with magnetic, electrical or thermal functionalities.

Graphene-based tunable hyperbolic microcavity

Graphene-based hyperbolic metamaterials provide a unique scaffold for designing nanophotonic devices with active functionalities. In this work, we have theoretically demonstrated that the characteristics of a polarization-dependent tunable hyperbolic microcavity in the mid-infrared frequencies could be realized by modulating the thickness of the dielectric layers, and thus breaking periodicity in a graphene-based hyperbolic metamaterial stack. Transmission of the tunable microcavity shows a Fabry–Perot resonant mode with a Q-factor > 20, and a sixfold local enhancement of electric field intensity. It was found that by varying the gating voltage of graphene from 2 to 8 V, the device could be self-regulated with respect to both the intensity (up to 30%) and spectrum (up to 2.1 µm). In addition, the switching of the device was considered over a wide range of incident angles for both the transverse electric and transverse magnetic modes. Finally, numerical analysis indicated that a topological transition between elliptic and type II hyperbolic dispersion could be actively switched. The proposed scheme represents a remarkably versatile platform for the mid-infrared wave manipulation and may find applications in many multi-functional architectures, including ultra-sensitive filters, low-threshold lasers, and photonic chips.

Ti3C2Tx MXene: from dispersions to multifunctional architectures for diverse applications.

The exciting combination of high electrical conductivity, high specific capacitance and colloidal stability of two-dimensional Ti3C2Tx MXene (referred to as MXene) has shown great potential in a wide range of applications including wearable electronics, energy storage, sensors, and electromagnetic interference shielding. To realize its full potential, recent literature has reported a variety of solution-based processing methodologies to develop MXenes into multifunctional architectures, such as fibres, films and aerogels. In response to these recent critical advances, this review provides a comprehensive analysis of the diverse solution-based processing methodologies currently being used for MXene-architecture fabrication. A critical evaluation of the processing challenges directly affecting macroscale material properties and ultimately, the performance of the resulting prototype devices is also provided. Opportunities arising from the observed and foreseen challenges regarding their use are discussed to provide avenues for new designs and realise practical use in high performance applications.

Museum and center for contemporary art: design principles and functional features

The article discusses the topical issue of the establishment of museum and center for contemporary art. The objective of the research is to analyze the historical background of contemporary art museums; to review the world design practice of them according to urban planning, functional, architectural and expositional criteria; to reveal functional features’ trends and to identify the design principles of an advanced center for contemporary art. We collected more than 45 leading examples to compile a matrix using classification and analysis methods. As a result, we reached the museums’ functional features: administrative, exhibition, educational, recreational are fixed functions; storage and research functions are optional; cultural and entertainment are particularly additional functions. At first, art museums and centers are focused on adaption to visitors and intersection with them, secondly, on the exhibit. To sum up, we define the design principles of the ideal architectural model on the basis of urban planning, architectural, sociocultural and technological radicals. In conclusion, it is revealed that contemporary art centers have absorbed most of the historical functions of the museum and today are one of the developed types of the multifunctional architecture.

Advancements in Therapeutics via 3D Printed Multifunctional Architectures from Dispersed 2D Nanomaterial Inks.

2D nanomaterials (2DNMs) possess fascinating properties and are found in multifarious devices and applications including energy storage devices, new generation of battery technologies, sensor devices, and more recently in biomedical applications. Their use in biomedical applications such as tissue engineering, photothermal therapy, neural regeneration, and drug delivery has opened new horizons in treatment of age-old ailments. It is also a rapidly developing area of advanced research. A new approach of integrating 3D printing (3DP), a layer-by-layer deposition technique for building structures, along with 2DNM multifunctional inks, has gained considerable attention in recent times, especially in biomedical applications. With the ever-growing demand in healthcare industry for novel, efficient, and rapid technologies for therapeutic treatment methods, 3DP structures of 2DNMs provide vast scope for evolution of a new generation of biomedical devices. Recent advances in 3DP structures of dispersed 2DNM inks with established high-performance biomedical properties are focused on. The advantages of their 3D structures, the sustainable formulation methods of such inks, and their feasible printing methods are also covered. Subsequently, it deals with the therapeutic applications of some already researched 3DP structures of 2DNMs and concludes with highlighting the challenges as well as the future directions ofresearch in this area.

High-Throughput Tailoring of Nanocellulose Films: From Complex Bio-Based Materials to Defined Multifunctional Architectures.

This paper demonstrates a high-throughput approach to fabricate nanocellulose films with multifunctional performance using conventionally existing unit operations. The approach comprises cast-coating and direct interfacial atmospheric plasma-assisted gas-phase modification along with the microscale patterning technique (nanoimprint lithography, NIL), all applied in roll-to-roll mode, to introduce organic functionalities in conjunction with structural manipulation. Our strategy results in multifunctional cellulose nanofibrils (CNF) films in which the high optical transmittance (∼90%) is retained while the haze can be adjusted (2–35%). Concomitantly, the hydrophobic/hydrophilic balance can be tuned (50–21 mJ/m2 with the water contact angle ranging from ∼20 up to ∼120°), while intrinsic hygroscopicity of CNF films is not significantly compromised. Therefore, a challenge to produce multifunctional bio-based materials with properties defined by various high-performance applications conjoined to the lack of efficient processing strategies is elucidated. Overall, economically and ecologically viable strategy, which was realized by facile and upscalable unit operations using the R2R technology, is introduced to expand the properties’ spaces and thus offer a vast variety of interesting applications for CNF films.

Broadband detection of multiple spin and orbital angular momenta via dielectric metasurface.

Light beams carrying spin angular momentum (SAM) and orbital angular momentum (OAM) have created novel opportunities in the areas of optical communications, imaging, micromanipulation and quantum optics. However, complex optical setups are required to simultaneously manipulate, measure and analyze these states, which significantly limits system integration. Here, we introduce a novel detection approach for measuring multiple SAM and OAM modes simultaneously through a planar nanophotonic demultiplexer based on an all-dielectric metasurface. Coaxial light beams carrying multiple SAM and OAM states of light upon transmission through the demultiplexer are spatially separated into a range of vortex beams with different topological charge, each propagating along a specific wavevector. The broadband response, material dispersion and momentum conservation further enable the demultiplexer to achieve wavelength demultiplexing. We envision the ultracompact multifunctional architecture to enable simultaneous manipulation and measurement of polarization and spin encoded photon states with applications in integrated quantum optics and optical communications.

Molecular Springs: Integration of Complex Dynamic Architectures into Functional Devices.

Molecular/supramolecular springs are artificial nanoscale objects possessing well-defined structures and tunable physicochemical properties. Like a macroscopic spring, supramolecular springs are capable of switching their nanoscale conformation as a response to external stimuli by undergoing mechanical spring-like motions. This dynamic action offers intriguing opportunities for engineering molecular nanomachines by translating the stimuli-responsive nanoscopic motions into macroscopic work. These nanoscopic objects are reversible dynamic multifunctional architectures which can express a variety of novel properties and behave as adaptive nanoscopic systems. In this Minireview, we focus on the design and structure-property relationships of supramolecular springs and their (self-)assembly as a prerequisite towards the generation of novel dynamic materials featuring controlled movements to be readily integrated into macroscopic devices for applications in sensing, robotics, and the internet of things.

Molecular Springs: Integration of Complex Dynamic Architectures into Functional Devices

AbstractMolecular/supramolecular springs are artificial nanoscale objects possessing well‐defined structures and tunable physicochemical properties. Like a macroscopic spring, supramolecular springs are capable of switching their nanoscale conformation as a response to external stimuli by undergoing mechanical spring‐like motions. This dynamic action offers intriguing opportunities for engineering molecular nanomachines by translating the stimuli‐responsive nanoscopic motions into macroscopic work. These nanoscopic objects are reversible dynamic multifunctional architectures which can express a variety of novel properties and behave as adaptive nanoscopic systems. In this Minireview, we focus on the design and structure–property relationships of supramolecular springs and their (self‐)assembly as a prerequisite towards the generation of novel dynamic materials featuring controlled movements to be readily integrated into macroscopic devices for applications in sensing, robotics, and the internet of things.

Images of "Soviet" and "Sovietness" in the Cultural Landscape of Vinnytsia Region (Based on Field Ethnographic Materials)

The purpose of the article is to analyze the images of "Soviet" and "Sovietness" in visual objects of the cultural landscape of Vinnitsia region on the basis of field ethnographic materials collected in the process of collective and individual expeditions by students of the Faculty of History, Law and Public Administration and teachers of the Department of History of Ukraine Vinnytsia Mykhailo Kotsiubynskyi State Pedagogical University in 2018-19. The methodology of the research is based on the combination of general scientific (analysis, synthesis, generalization) methods with the principles of historicism, systematicity, scientificity and verification and is carried out in the interdisciplinary plane - in the context of "cultural landscaping" (in the context of anthropology of space) and memory discourses and methodology of visual anthropology. The scientific novelty of the work is to try to breed the concepts of "Soviet" and "Sovietness". Through the analysis of visual objects of cultural landscape, the author traced the organic combination of objects of material culture (toponymy, symbolism, multifunctional architecture, vehicles, memorial sites, etc.) with varieties of human practices (daily, ritual, symbolic, artistic, etc.) focusing on the connection of visualization with a cognitive form of cognition that emphasizes sociocultural features in the creation and understanding of these visual images. The researcher also touched upon the difficulties of (not)reading the images of "Soviet" and "Sovietness" in the visual space, their (im)perception and (not)rethinking by different generations. Conclusions. The perspective of the outlined topic is important not only in the scientific but also in the public area, reflecting its applied vector. Since the main purpose of the visual in Soviet times was to achieve homogeneity and unification of society in all its spheres, therefore, the key tasks of modern "cultural landscaping" discourse is the transformation of the cultural landscape towards the construction of its "face" with a clear local identity of its inhabitants and express "individualization" space to represent sociocultural heterogeneity. This should become an active mode of formation, first of all, its tourist attraction for "others" and comfort for "self".

Diverse protein assembly driven by metal and chelating amino acids with selectivity and tunability

Proteins are versatile natural building blocks with highly complex and multifunctional architectures, and self-assembled protein structures have been created by the introduction of covalent, noncovalent, or metal-coordination bonding. Here, we report the robust, selective, and reversible metal coordination properties of unnatural chelating amino acids as the sufficient and dominant driving force for diverse protein self-assembly. Bipyridine-alanine is genetically incorporated into a D3 homohexamer. Depending on the position of the unnatural amino acid, 1-directional, crystalline and noncrystalline 2-directional, combinatory, and hierarchical architectures are effectively created upon the addition of metal ions. The length and shape of the structures is tunable by altering conditions related to thermodynamics and kinetics of metal-coordination and subsequent reactions. The crystalline 1-directional and 2-directional biomaterials retain their native enzymatic activities with increased thermal stability, suggesting that introducing chelating ligands provides a specific chemical basis to synthesize diverse protein-based functional materials while retaining their native structures and functions.

Biopositive materials and green technologies in low-rise architecture

Nowadays high quality of life, rational nature management and reduction of negative impact on nature, become some of the leading directions of urban planning policy development in the world. Mass construction of low-rise eco-houses worldwide has been the most relevant. The use of biopositive materials provides great savings on labour costs. From 65 to 89% of the population in Western European and North American countries live in low-rise buildings. By 2020 low-rise construction in Russia will be around 70%, while there will be a transition to the integrated development of territories with its own infrastructure. The article discusses biopositive materials and low-cost renewable “green” technologies that are used in low-rise multi-functional architecture. It is shown that biopositive materials such as whole wood, reed, straw, soil, peat, and many others have a positive effect on human and the correlation of its biofield. Also, “green” technologies save energy and material resources throughout the entire life cycle of a building. The article looks at some of the low-cost renewable “green” technologies such as Rammed Earth, Rammed Clay, Earth Bags, Straw Bale constructions, Zonal discharge and others that increase the construction speed and the environmental quality of low-rise multifunctional building architecture.

Aramid nanofiber-reinforced three-dimensional graphene hydrogels for supercapacitor electrodes

HypothesisSelf-assembled graphene hydrogels are notable in the field of electrochemical energy storage for their unique combination of excellent specific surface area, high porosity, and electrically conductive continuous network. However, graphene hydrogels suffer from poor mechanical integrity compared to layered architectures like graphene buckypapers, limiting their applications in practical devices. We propose the use of high strength, Kevlar®-derived polymeric nanofillers, aramid nanofibers (ANFs) as structural fillers to enhance graphene hydrogel’s shear modulus in the context of multifunctional (mechanical and electrochemical) architectures. ExperimentsGraphene hydrogels are fabricated using sol-gel self-assembly of graphene oxide (GO) nanosheets in presence of ammonium hydroxide. Colloidal dispersion of ANFs and GO are integrated using a novel combination of solvent exchange and dialysis approach to fabricate GO-ANF hydrogels with 0–15 wt.% of ANFs loading (dry weight basis). Shear modulus and electrochemical properties of resulting hydrogel composites are evaluated using rheology and symmetric supercapacitor cell. FindingsThe addition of 2 wt.% ANFs resulted in an 80% improvement in shear modulus compared to neat graphene hydrogel. Addition of ANFs resulted in gradual reduction of specific capacitance, with the specific capacitance of 190 F/g for neat graphene hydrogel, reducing to 128 F/g for an ANF loading of 15 wt.% (dry weight basis). This work shows the broader concept that adding high-strength nanofibers to a nanomaterial gel can add reinforcement provided that the gelation process itself is not disrupted.

High Throughput Screening of 3D Printable Resins: Adjusting the Surface and Catalytic Properties of Multifunctional Architectures

Identification of 3D printable materials is crucial to expand the breadth of physical and chemical properties attainable by additive manufacturing. Stereolithography (SLA), a widespread 3D printing...

Lithium–Sulfur Batteries: A 3D Multifunctional Architecture for Lithium–Sulfur Batteries with High Areal Capacity (Small Methods 6/2018)

Lithium–Sulfur Batteries: A 3D Multifunctional Architecture for Lithium–Sulfur Batteries with High Areal Capacity (Small Methods 6/2018)