Relaxor ferroelectrics have large dielectric constant maximum with broad phase transition regions due to the complex perovskite structure. Lead zinc niobate Pb(Zn1/3Nb2/3)O3 (PZN), a member of ABO3 structural family, where A = mono or divalent ions, B = tri, tetra or pentavalent ions, has a complex perovskite structure in which Zn2+ and Nb2+ are disordered at the B-site, which results in composition variations and corresponding fluctuations in the phase transition temperature from region to region [1, 2]. As a result the phase transition is broad and occurs over a range of temperatures called the Curie region. The Curie region for PZN occurs near 140 ◦C (crystal form) and shows many desired dielectric and piezoelectric properties for multilayer capacitor, transducer and actuator applications [3–6]. This is due to its larger electrostrictive strains, which are of an order of magnitude larger than those of BaTiO3 based ceramics and piezoelectric PZT ceramics [7, 8]. The formation of the compound in the perovskite structure should satisfy the charge neutrality and tolerance factor, t [9] as
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