Organic-rich carbonate mudstones have emerged as a significant unconventional play globally, particularly the Middle Jurassic carbonate mudstones of the Arabian plate. Despite their importance, these mudstones are highly heterogeneous, composed of organic-lean and organic-rich deposits, and often exhibit similar reservoir quality, making them challenging to characterize. While most studies have attributed the reservoir quality of these mudstones to the organic-related pores, little attention has been paid to the origin of the pore structure and network of the organic-lean counterparts. To address these issues, we performed high-resolution quantitative pore characterization and modeling by coupling micro-computed tomography and focused ion beam scanning electron microscopy to gain insight into the matrix-related pore structure, size, and networks on the organic-lean mudstones. Our study showed that in the organic-lean mudstones micropores are present but isolated, while the nanoscale pore structure appears to be well-connected, hence higher permeability. The pore-network model result has a median pore radius of 189–226 nm and a median throat radius of 91–112 nm, rarely exceeding 1000 nm and 500 nm, respectively. The frequency plots demonstrate positively skewed distributions indicating that large pores and throats are anomalous. Our study highlights that the organic-lean mudstone nanoscale pores are comparable to previously reported nanopores in the organic-rich zone and other mudstone plays around the globe. It emphasizes coexisting organic and matrix-related nanopores, suggesting the significance of matrix-bound nanopores' influence on carbonate mudstones unconventional play. The findings can enhance our understanding of the nano-scale pore structure and provide insights to evaluate and build development strategies of carbonate mudstones in the Arabian Intrashelf Basin and elsewhere.
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