We study the existence and properties of solutions and free boundaries of the one-phase Stefan problem with fractional diffusion posed in [Formula: see text]. In terms of the enthalpy [Formula: see text], the evolution equation reads [Formula: see text], while the temperature is defined as [Formula: see text] for some constant [Formula: see text] called the latent heat, and [Formula: see text] stands for the fractional Laplacian with exponent [Formula: see text]. We prove the existence of a continuous and bounded selfsimilar solution of the form [Formula: see text] which exhibits a free boundary at the change-of-phase level [Formula: see text]. This level is located at the line (called the free boundary) [Formula: see text] for some [Formula: see text]. The construction is done in 1D, and its extension to [Formula: see text]-dimensional space is shown. We also provide well-posedness and basic properties of very weak solutions for general bounded data [Formula: see text] in several dimensions. The temperatures [Formula: see text] of these solutions are continuous functions that have finite speed of propagation, with possible free boundaries. We obtain estimates on the growth in time of the support of [Formula: see text] for solutions with compactly supported initial temperatures. Besides, we show the property of conservation of positivity for [Formula: see text] so that the support never recedes. On the contrary, the enthalpy [Formula: see text] has infinite speed of propagation and we obtain precise estimates on the tail. The limits [Formula: see text], [Formula: see text], [Formula: see text] and [Formula: see text] are also explored, and we find interesting connections with well-studied diffusion problems. Finally, we propose convergent monotone finite-difference schemes and include numerical experiments aimed at illustrating some of the obtained theoretical results, as well as other interesting phenomena.