Molecular Hydrogen Absorption Research Articles

Collisional line-shape effects in accurate He-perturbed H[formula omitted] spectra

We investigate collisional line-shape effects that are present in highly accurate experimental spectra of the 3-0 S(1) and 2-0 Q(1) molecular hydrogen absorption lines perturbed by helium. We clearly distinguish the influence of six different collisional effects (i.e.: collisional broadening and shift, their speed dependencies and the complex Dicke effect) on the shapes of H2 lines. We demonstrate that only a very specific combination of these six contributions, determined from our ab initio calculations, gives unprecedentedly good agreement with experimental spectra. If any of the six contributions is neglected, then the experiment-theory comparison deteriorates at least several times. We also analyze the influence of the centrifugal distortion on our ab initio calculations and we demonstrate that the inclusion of this effect slightly improves the agreement with the experimental spectra.

Hydrogen interactions with low-index surface orientations of tungsten

We report on density functional theory calculations that have been performed to systematically investigate the hydrogen-surface interaction as a function of surface orientation. The interactions that were analyzed include stable atomic adsorption sites, molecular hydrogen dissociation and absorption energies, migration pathways and barriers on tungsten surfaces, and the saturation coverage limits on the (1 1 1) surface. Stable hydrogen adsorption sites were found for all surfaces. For the reconstructed W(1 0 0), there are two primary adsorption sites: namely, the long-bridge and short-bridge sites. The threefold hollow site (3F) was found to be the most stable for W(1 1 0), while the bond-centered site between the first and second layer was found to be most stable for the W(1 1 1) surface. No bound adsorption sites for H2 molecules were found for the W surfaces. Hydrogen (H) migration on both the (1 0 0) and (1 1 0) surfaces is found to have preferred pathways for 1D motion, whereas the smallest migration barrier for net migration of H on the W(1 1 1) surface leads to 2D migration. Although weaker H interactions are predicted for the W(1 1 1) surface compared to the (1 0 0) or (1 1 0) surfaces, we observe higher H surface concentrations of Θ = 4.0 at zero K, possibly due to the corrugated surface structure. These results provide insight into H adsorption, surface saturation coverage and migration mechanisms necessary to describe the evolution from the dilute limit to concentrated coverages of H.

Signatures of Hot Molecular Hydrogen Absorption from Protoplanetary Disks. I. Non-thermal Populations

Abstract The environment around protoplanetary disks (PPDs) regulates processes that drive the chemical and structural evolution of circumstellar material. We perform a detailed empirical survey of warm molecular hydrogen (H2) absorption observed against H i-Lyα (Lyα: λ1215.67) emission profiles for 22 PPDs, using archival Hubble Space Telescope ultraviolet (UV) spectra to identify H2 absorption signatures and quantify the column densities of H2 ground states in each sightline. We compare thermal equilibrium models of H2 to the observed H2 rovibrational level distributions. We find that, for the majority of targets, there is a clear deviation in high-energy states (T exc ≳ 20,000 K) away from thermal equilibrium populations (T(H2) ≳ 3500 K). We create a metric to estimate the total column density of non-thermal H2 (N(H2)nLTE) and find that the total column densities of thermal (N(H2)) and N(H2)nLTE correlate for transition disks and targets with detectable C iv-pumped H2 fluorescence. We compare N(H2) and N(H2)nLTE to circumstellar observables and find that N(H2)nLTE correlates with X-ray and far-UV luminosities, but no correlations are observed with the luminosities of discrete emission features (e.g., Lyα, C iv). Additionally, N(H2) and N(H2)nLTE are too low to account for the H2 fluorescence observed in PPDs, so we speculate that this H2 may instead be associated with a diffuse, hot, atomic halo surrounding the planet-forming disk. We create a simple photon-pumping model for each target to test this hypothesis and find that Lyα efficiently pumps H2 levels with T exc ≥ 10,000 K out of thermal equilibrium.

Constraint on a varying proton-to-electron mass ratio from H2and HD absorption atzabs≃ 2.34

Molecular hydrogen absorption in the damped Lyman-alpha system at z = 2.34 towards quasar Q1232+082 is analyzed in order to derive a constraint on a possible temporal variation of the proton-to-electron mass ratio, mu, over cosmological timescales. Some 106 H2 and HD transitions, covering the range 3290-3726 \AA, are analyzed with a comprehensive fitting technique, allowing for the inclusion of overlapping lines associated with hydrogen molecules, the atomic hydrogen lines in the Lyman-alpha forest as well as metal lines. The absorption model, based on the most recent and accurate rest wavelength for H2 and HD transitions, delivers a value of dmu/mu = (19 +/- 9 +/- 5)x 10^(-6). An attempt to correct the spectrum for possible long-range wavelength distortions is made and the uncertainty on the distortion correction is included in the total systematic uncertainty. The present result is an order of magnitude more stringent than a previous measurement from the analysis of this absorption system, based on a line-by-line comparison of only 12 prominent and isolated H2 absorption lines. This is consistent with other measurements of dmu/mu from 11 other absorption systems in showing a null variation of the proton-to-electron mass ratio over a look-back time of 11 Gyrs.

Estimation of physical conditions in the cold phase of the interstellar medium in the sub-DLA system at z = 2.06 in the spectrum of the quasar J 2123–0050

An independent analysis of the molecular hydrogen absorption system at z = 2.059 in the spectrum of the quasar J2123-0050 is presented. The H_2 system consists of two components (A and B) with column densities log N^A(H_2) = 17.94+/-0.01 and log N^B(H_2) = 15.16+/-0.02. The spectrum exhibits the lines of HD molecules (log N^A(HD) = 13.87+/-0.06) and the neutral species C I and Cl I associated with the H_2 absorption system. For the molecular hydrogen lines near the quasar's Ly_beta and O VI emission lines, we detect a nonzero residual flux, ~3% of the total flux, caused by the effect of partial coverage of the quasar's broad-line region by an H_2 cloud. The uniqueness of the system being investigated is manifested in a high abundance of the neutral species H_2 and C I at the lowest H I column density, log N(H I) = 19.18+/-0.15, among the high redshift systems. The N(HD)/2N(H_2) ratio for component A has turned out to be also unusually high, (4.26+/-0.60)x10^{-5}. We have investigated the physical conditions in components A and B. Component A represents the optically thick case; the gas has a low number density (n~30 cm^{-3}) and a temperature T~140 K. In component B, the medium is optically thin with n<100 cm^{-3} and T<100 K. The ultraviolet (UV) background intensity in the clouds exceeds the mean intensity in our Galaxy by almost an order of magnitude. A high gas ionization fraction, n(H+)/n(H)~10^{-2}, which can be the result of partial shielding of the system from hard UV radiation, is needed to describe the high HD and C I column densities. Using our simulations with the PDR Meudon code, we can reconstruct the observed column densities of the species within the model with a constant density n(H)=40 cm^{-3}. A high H_2 formation rate (higher than the mean Galactic value by a factor of 10-40) and high gas ionization fraction and UV background intensity are needed in this case.

Constraint on a varying proton-to-electron mass ratio from molecular hydrogen absorption towards quasar SDSS J123714.60+064759.5

Molecular hydrogen transitions in the sub-damped Lyman α absorber at redshift zabs ≃ 2.69, towards the background quasar SDSS J123714.60+064759.5, were analysed in order to search for a possible variation of the proton-to-electron mass ratio μ over a cosmological time-scale. The system is composed of three absorbing clouds where 137 H2 and HD absorption features were detected. The observations were taken with the Very Large Telescope/Ultraviolet and Visual Echelle Spectrograph with a signal-to-noise ratio of 32 per 2.5 km s−1 pixel, covering the wavelengths from 356.6 to 409.5 nm. A comprehensive fitting method was used to fit all the absorption features at once. Systematic effects of distortions to the wavelength calibrations were analysed in detail from measurements of asteroid and ‘solar twin’ spectra, and were corrected for. The final constraint on the relative variation in μ between the absorber and the current laboratory value is Δμ/μ = (−5.4 ± 6.3stat ± 4.0syst) × 10−6, consistent with no variation over a look-back time of 11.4 Gyr.

Partial covering of the emission regions of Q 0528−250 by intervening H2 clouds

We present an analysis of the molecular hydrogen absorption system at z$_{\rm abs}$ = 2.811 in the spectrum of the blazar Q0528-250. We demonstrate that the molecular cloud does not cover the background source completely. The partial coverage reveals itself as a residual flux in the bottom of saturated H_2 absorption lines. This amounts to about (2.22$\pm$0.54)% of the continuum and does not depend on the wavelength. This value is small and it explains why this effect has not been detected in previous studies of this quasar spectrum. However, it is robustly detected and significantly higher than the zero flux level in the bottom of saturated lines of the Ly-alpha forest, (-0.21$\pm$0.22)%. The presence of the residual flux could be caused by unresolved quasar multicomponents, by light scattered by dust, and/or by jet-cloud interaction. The H$_2$ absorption system is very well described by a two-component model without inclusion of additional components when we take partial coverage into account. The derived total column densities in the H$_2$ absorption components A and B are logN(H$_2$)[cm$^{-2}$] = 18.10$\pm$0.02 and 17.82$\pm$0.02, respectively. HD molecules are present only in component B. Given the column density, logN(HD)= 13.33$\pm$0.02, we find N(HD)/2N(H$_2$)=(1.48$\pm$0.10)x10$^{-5}$, significantly lower than previous estimations. We argue that it is crucial to take into account partial coverage effects for any analysis of H$_2$ bearing absorption systems, in particular when studying the physical state of high-redshift interstellar medium.

The Magellan uniform survey of damped Lyman α systems – II. Paucity of strong molecular hydrogen absorption★

We present the first large, blind and uniformly selected survey for molecular hydrogen (H_2) in damped Lyman alpha systems (DLAs) with moderate-to-high resolution spectra. 86 DLAs were searched for absorption in the many Lyman and Werner H_2 transitions, with approximately 79% completeness for H_2 column densities above N(H_2)=10^17.5 cm^-2 for an assumed Doppler broadening parameter b=2 km s^-1. Only a single strong H_2 absorber was found -- a system detected previously in VLT/UVES spectra. Given our distribution of N(H_2) upper limits, this ~1% detection rate is smaller than expected from previous surveys at 99.8% confidence. Assuming the N(H_2) distribution shape from previous surveys, our detection rate implies a covering factor of ~1% for N(H_2) >= 10^17.5 cm^-2 gas in DLAs (<6% at 95% confidence). We obtained new Magellan/MagE spectra for 53 DLAs; 8 km s^-1 -resolution spectra were available for 27 DLAs. MagE's moderate resolution (~71 km s^-1) yields weaker N(H_2) upper limits and makes them dependent on the assumed Doppler parameter. For example, half the (relevant) previous H_2 detections have N(H_2) >= 10^18.1 cm^-2, a factor of just 3 higher than our median upper limit. Nevertheless, several tests suggest our upper limits are accurate, and they would need to be increased by 1.8 dex to bring our detection rate within 95% confidence of previous surveys.

Molecular hydrogen absorption systems in Sloan Digital Sky Survey

We present a systematic search for molecular hydrogen absorption systems at high redshift in quasar spectra from the Sloan Digital Sky Survey (SDSS)-II Data Release 7 and SDSS-III Data Release 9. We have selected candidates using a modified profile fitting technique taking into account that the Lyα forest can effectively mimic H2 absorption systems at the resolution of SDSS data. To estimate the confidence level of the detections, we use two methods: a Monte Carlo sampling and an analysis of control samples. The analysis of control samples allows us to define regions of the spectral quality parameter space where H2 absorption systems can be confidently identified. We find that H2 absorption systems with column densities log NH2 > 19 can be detected in only less than 3 per cent of SDSS quasar spectra. We estimate the upper limit on the detection rate of saturated H2 absorption systems (NH2 > 19) in damped Lyα (DLA) systems to be about 7 per cent. We provide a sample of 23 confident H2 absorption system candidates that would be interesting to follow up with high-resolution spectrographs. There is a 1σ r − i colour excess and non-significant AV extinction excess in quasar spectra with an H2 candidate compared to standard DLA-bearing quasar spectra. The equivalent widths of C ii, Si ii and Al iii (but not Fe ii) absorptions associated with H2 candidate DLAs are larger compared to standard DLAs. This is probably related to a larger spread in velocity of the absorption lines in the H2-bearing sample.

METALLICITIES, DUST, AND MOLECULAR CONTENT OF A QSO-DAMPED Lyα SYSTEM REACHING logN(H I) = 22: AN ANALOG TO GRB-DLAs

We present the elemental abundance and H2 content measurements of a Damped Lyman-{\alpha} (DLA) system with an extremely large H i column density, log N(H i) (cm-2) = 22.0+/-0.10, at zabs = 3.287 towards the QSO SDSS J 081634+144612. We measure column densities of H2, C i, C i^*, Zn ii, Fe ii, Cr ii, Ni ii and Si ii from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 +/- 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of \approx 52 km s-1) in rotational levels up to J = 3. We derive a total H2 column density of log N(H2) (cm-2) = 18.66 and a mean molecular fraction of f = 2N(H2)/[2N(H2) + N(H i)] = 10-3.04+/-0.37, typical of known H2-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the Interstellar Medium (ISM) of this galaxy, with a enhanced abundance in the H2-bearing clouds. However, the total amount of dust along the line of sight is not large and does not produce any significant reddening of the background QSO. The physical conditions in the H2-bearing clouds are constrained directly from the column densities of H2 in different rotational levels, C i and C i^* . The kinetic temperature is found to be T = 75 K and the particle density lies in the range nH = 50-80 cm-3 . The neutral hydrogen column density of this DLA is similar to the mean H i column density of DLAs observed at the redshift of {\gamma}-ray bursts (GRBs). We explore the relationship between GRB-DLAs and high column density end of QSO-DLAs finding that the properties (metallicity and depletion) of DLAs with log N(H i) > 21.5 in the two populations do not appear to be significantly different.

Constraint on a variation of the proton-to-electron mass ratio from H2 absorption towards quasar Q2348−011

Molecular hydrogen (H2) absorption features observed in the line-of-sight to Q2348-011 at redshift zabs = 2.426 are analysed for the purpose of detecting a possible variation of the proton-to-electron mass ratio mu=mp/me. By its structure Q2348-011 is the most complex analysed H2 absorption system at high redshift so far, featuring at least seven distinctly visible molecular velocity components. The multiple velocity components associated with each transition of H2 were modeled simultaneously by means of a comprehensive fitting method. The fiducial model resulted in dmu/mu = (-0.68 +/- 2.78) x 10^-5, showing no sign that mu in this particular absorber is different from its current laboratory value. Although not as tight a constraint as other absorbers have recently provided, this result is consistent with the results from all previously analysed H2-bearing sight-lines. Combining all such measurements yields a constraint of dmu/mu < 10^-5 for the redshift range z = (2--3).

HST /COS SPECTRA OF DF Tau AND V4046 Sgr: FIRST DETECTION OF MOLECULAR HYDROGEN ABSORPTION AGAINST THE Lyα EMISSION LINE

We report the first detection of molecular hydrogen (H$_{2}$) absorption in the Lyman-$\alpha$ emission line profiles of two classical T Tauri stars (CTTSs), DF Tau and V4046 Sgr, observed by \emph{HST}/COS. This absorption is the energy source for many of the Lyman-band H$_{2}$ fluorescent lines commonly seen in the far-ultraviolet spectra of CTTSs. We find that the absorbed energy in the H$_{2}$ pumping transitions from a portion of the Lyman-$\alpha$ line significantly differ from the amount of energy in the resulting fluorescent emission. By assuming additional absorption in the H I Lyman-$\alpha$ profile along our light of sight, we can correct the H$_{2}$ absorption/emission ratios so that they are close to unity. The required H I absorption for DF Tau is at a velocity close to the radial velocity of the star, consistent with H I absorption in the edge-on disk and interstellar medium. For V4046 Sgr, a nearly face-on system, the required absorption is between +100 km/s and +290 km/s, most likely resulting from H I gas in the accretion columns falling onto the star.

FUSEMEASUREMENTS OF FAR-ULTRAVIOLET EXTINCTION. III. THE DEPENDENCE ONR(V) AND DISCRETE FEATURE LIMITS FROM 75 GALACTIC SIGHTLINES

We present a sample of 75 extinction curves derived from FUSE far-ultraviolet spectra supplemented by existing IUE spectra. The extinction curves were created using the standard pair method based on a new set of dereddened FUSE+IUE comparison stars. Molecular hydrogen absorption features were removed using individualized H_2 models for each sightline. The general shape of the FUSE extinction (8.4 micron^-1 < lambda^-1 < 11 micron^-1) was found to be broadly consistent with extrapolations from the IUE extinction (3.3 micron-1 < lambda^-1 < 8.6 micron^-1) curve. Significant differences were seen in the strength of the far-UV rise and the width of the 2175 A bump. All the FUSE+IUE extinction curves had positive far-UV slopes giving no indication that the far-UV rise was turning over at the shortest wavelengths. The dependence of A(lambda)/A(V) versus R(V)^-1 in the far-UV using the sightlines in our sample was found to be stronger than tentatively indicated by previous work. We present an updated R(V) dependent relationship for the full UV wavelength range (3.3 micron^-1 <= lambda^-1 <= 11 micron^-1). Finally, we searched for discrete absorption features in the far-ultraviolet. We found a 3 sigma upper limit of ~0.12 A(V) on features with a resolution of 250 (~4 A width) and 3 sigma upper limits of ~0.15 A(V) for lambda^-1 < 9.6 micron^-1 and ~0.68 A(V) for lambda^-1 > 9.6 micron^-1 on features with a resolution of 10^4 (~0.1 A width).

DIRECT EVIDENCE OF COLD GAS IN DLA 0812+32B

We present the first direct evidence for cold gas in a high redshift DLA galaxy. We measured several multiplets of weak neutral carbon (CI) transitions in order to perform a curve of growth analysis. A delta chi-squared test constrains the best fit Doppler parameter, b = 0.33_{-0.04}^{+0.05} km/s, and logN(CI) = 13.30 +- 0.2 cm^-2. This Doppler parameter constrains the kinetic temperature of the gas to T <= 78 K (T <= 115 K, 2 sigma). We used the associated CI fine structure lines to constrain the volume density of the gas, n(HI) ~ 40 - 200 cm^-3 (2 sigma), resulting in a lower limit on the cloud size of approximately 0.1 - 1 parsec. While it is difficult to determine the metallicity of the cold component, the absence of Cr II indicates that the cold cloud suffers a high level of dust depletion. Additionally, the large amount of Lyman and Werner-band molecular hydrogen absorption (log N(H2)_{total} = 19.88 cm^-2, f_{H_2} >= 0.06) with an excitation temperature of T_{ex} = 46 K as determined by the rotational J = 0 and J = 1 states, is consistent with the presence of cold gas. We propose that this cloud may be gravitationally confined and may represent a transition gas-phase from primarily neutral atomic gas, to a colder, denser molecular phase that will eventually host star formation.

AN OBSERVATIONAL DETERMINATION OF THE PROTON TO ELECTRON MASS RATIO IN THE EARLY UNIVERSE

In an effort to resolve the discrepancy between two measurements of the fundamental constant mu, the proton to electron mass ratio, at early times in the universe we reanalyze the same data used in the earlier studies. Our analysis of the molecular hydrogen absorption lines in archival VLT/UVES spectra of the damped Lyman alpha systems in the QSOs Q0347-383 and Q0405-443 yields a combined measurement of a (Delta mu)/mu value of (-7 +/- 8) x 10^{-6}, consistent with no change in the value of mu over a time span of 11.5 gigayears. Here we define (Delta mu) as (mu_z - mu_0) where mu_z is the value of mu at a redshift of z and mu_0 is the present day value. Our null result is consistent with the recent measurements of King et al. 2009, (Delta mu)/u = (2.6 +/- 3.0) x 10^{-6}, and inconsistent with the positive detection of a change in mu by Reinhold et al. 2006. Both of the previous studies and this study are based on the same data but with differing analysis methods. Improvements in the wavelength calibration over the UVES pipeline calibration is a key element in both of the null results. This leads to the conclusion that the fundamental constant mu is unchanged to an accuracy of 10^{-5} over the last 80% of the age of the universe, well into the matter dominated epoch. This limit provides constraints on models of dark energy that invoke rolling scalar fields and also limits the parameter space of Super Symmetric or string theory models of physics. New instruments, both planned and under construction, will provide opportunities to greatly improve the accuracy of these measurements.

Measurements of Ca ii absorption, metals and dust in a sample ofz≃ 1 DLAs and subDLAs★

We present observations of Ca ii, Zn ii and Cr ii absorption lines in 16 damped Lyman alpha (DLA) systems and six subDLAs at redshifts 0.6 < zabs < 1.3, obtained for the dual purposes of (i) clarifying the relationship between DLAs and absorption systems selected from their strong Ca ii lines, and (ii) increasing the still limited sample of Zn and Cr abundance determinations in this redshift range. We find only partial overlap between current samples of intermediate redshift DLAs (which are drawn from magnitude-limited surveys) and strong Ca ii absorbers: approximately 25 per cent of known DLAs at these redshifts have an associated Ca iiλ3935 line with a rest-frame equivalent width greater than 0.35 A, the threshold of the Sloan Digital Sky Survey sample assembled by Wild and her collaborators. The lack of the strongest Ca ii systems (with equivalent widths greater than 0.5 A) is consistent with these authors' conclusion that such absorbers are often missed in current DLA surveys because they redden and dim the light of the background quasi-stellar objects. We rule out the suggestion that strong Ca ii absorption is associated exclusively with the highest column density DLAs. Furthermore, we find no correlation between the strength of the Ca ii lines and either the metallicity or degree of depletion of refractory elements, although the strongest Ca ii absorber in our sample is also the most metal-rich DLA yet discovered, with [Zn/H]≃ solar. We conclude that a complex mix of parameters must determine the strengths of the Ca ii lines, including the density of particles and ultraviolet photons in the interstellar media of the galaxies hosting the DLAs. We find tentative evidence (given the small size of our sample) that strong Ca ii systems may preferentially sample regions of high gas density, perhaps akin to the DLAs exhibiting molecular hydrogen absorption at redshifts z > 2. If this connection is confirmed, strong Ca ii absorbers would trace possibly metal rich, H2 bearing columns of cool, dense gas at distances up to tens of kpc from normal galaxies.

The Molecular Hydrogen Deficit in Gamma‐Ray Burst Afterglows

Recent analysis of five gamma-ray burst (GRB) afterglow spectra reveals the absence of molecular hydrogen absorption lines, a surprising result in light of their large neutral hydrogen column densities and the detection of H2 in similar, more local star-forming regions such as 30 Doradus in the Large Magellanic Cloud (LMC). Observational evidence further indicates that the bulk of the neutral hydrogen column in these sight lines lies more than 100 pc from the GRB progenitor and that H2 was likely absent prior to the burst, suggesting that direct flux from the star, FUV background fields, or both suppressed its formation. We present one-dimensional radiation hydrodynamical models of GRB host galaxy environments, including self-consistent radiative transfer of both ionizing and Lyman-Werner (L-W) photons, nine-species primordial chemistry with dust formation of H2, and dust extinction of UV photons. We find that a single GRB progenitor is sufficient to ionize neutral hydrogen to distances of 50-100 pc, but that a galactic L-W background is required to dissociate molecular hydrogen in the ambient ISM. Intensities of 0.1-100 times the Galactic mean are necessary to destroy H2 in the cloud, depending on its density and metallicity. The minimum radii at which neutral hydrogen will be found in afterglow spectra is insensitive to the mass of the progenitor or the initial mass function (IMF) of its cluster, if present.

Excitation mechanisms in newly discovered H2-bearing damped Lyman-αclouds: systems with low molecular fractions

Aims. We probe the physical conditions in high-redshift damped Lyman-α systems (DLAs) using the observed molecular fraction and the rotational excitation of molecular hydrogen. Methods. We search for Lyman- and Werner-band absorption lines of molecular hydrogen in the VLT/UVES spectra of background QSOs at the redshift of known DLAs. Results. We report two new detections of molecular hydrogen in the systems at zabs = 2.402 and 1.989 toward, respectively, HE 0027−1836 and HE 2318−1107, discovered in the course of the Hamburg-ESO DLA survey. We also present a detailed analysis of our recent H2 detection toward Q 2343+125. All three systems have low molecular fractions, log f ≤− 4, with f = 2N(H2)/(2N(H2) + N(H i)). Only one such H2 system was known previously. Two of them (toward Q 2343+125 and HE 2318−1107) have high-metallicities, [X/H] > −1, whereas the DLA toward HE 0027−1836 is the system with the lowest metallicity ([Zn/H] = −1.63) among known H2-bearing DLAs. The depletion patterns for Si, S, Ti, Cr, Mn, Fe and Ni in the three systems are found to be very similar to what is observed in diffuse gas of the Galactic halo. Molecular hydrogen absorption from rotational levels up to J = 5 is observed in a single well-defined component toward HE 0027−1836. We show that the width (Doppler parameter) of the H2 lines increases with increasing J and that the kinetic energy derived from the Doppler parameter is linearly dependent on the relative energy of the rotational levels. There is however no velocity shift between lines from different rotational levels. The excitation temperature is found to be 90 K for J = 0t oJ = 2a nd∼500 K for higher J levels. Single isothermal PDR models fail to reproduce the observed rotational excitations. A two-component model is needed: one component of low density (∼50 cm −3 ) with weak illumination (χ = 1) to explain the J ≤ 2 rotational levels and another of high density (∼500 cm −3 ) with strong illumination (χ = 30) for J ≥ 3 levels. However, the juxtaposition of these two PDR components may be ad-hoc and the multicomponent structure could result either from turbulent dissipation or C-shocks.

Metal Absorption Profiles from the Central Star of the Planetary Nebula M27 (NGC 6853, PN G060.8−03.6, the Dumbbell): Photospheric and Nebular Line Identifications

High resolution spectra of the hot central star of the planetary nebula (CSPN) M27, acquired with the Far Ultraviolet Spectroscopic Explorer (\FUSE), have revealed an unusually rich set of narrow molecular hydrogen absorption features. This object is also unique in that the velocity of nebular absorption features are cleanly separated from the velocity of the intervening interstellar medium. These features blend with and in many cases obscure atomic features. We have developed a continuum model of the CSPN including atomic and molecular hydrogen absorption. Using this model we have identified and tabulated the metal lines as arising from either photospheric, nebular and/or non-nebular velocity systems. We find the nebular outflow and ionization balance to be stratified with high ionization states favored at low velocity and low ionization states favored at high velocity. Neutrals and molecules are found at a velocity that marks the transistion between these two regimes. These observations are a challenge to the interacting wind model of PN evolution. Mappings at high resolution of the line profiles for \ion{C}{1} \ion{-}{4}, \ion{N}{1} \ion{-}{3}, \ion{O}{1}, \ion{O}{6}, \ion{Si}{2} \ion{-}{4}, \ion{P}{2} \ion{-}{5}, \ion{S}{2} \ion{-}{4}, \ion{Ar}{1} \ion{-}{2} and \ion{Fe}{2} \ion{-}{3} within the \FUSE and STIS bandpasses are presented. The digitial spectra of the stars and the model are freely available on the H$_2$ools website. They will be useful for photospheric analyses seeking to determine the metallicity of the central star and for absorption line based atomic and molecular abundance determination of the nebular outflow.

Molecular Hydrogen in Infrared Cirrus

We combine data from our recent FUSE survey of interstellar molecular hydrogen absorption toward 50 high-latitude AGNs with COBE-corrected IRAS 100 ?m emission maps to study the correlation of infrared cirrus with H2. A plot of the H2 column density versus IR cirrus intensity shows the same transition in molecular fraction, f, as seen with total hydrogen column density, NH. This transition is usually attributed to H2 self-shielding, and it suggests that many diffuse cirrus clouds contain H2 in significant fractions, f ? 1%-30%. These clouds cover ~50% of the northern sky at b > 30?, at temperature-corrected 100 ?m intensities D ? 1.5 MJy sr-1. The sheetlike cirrus clouds, with hydrogen densities nH ? 30 cm-3, may be compressed by dynamical processes at the disk-halo interface, and they are conducive to H2 formation on grain surfaces. Exploiting the correlation between N and 100 ?m intensity, we estimate that cirrus clouds at b > 30? contain ~3000 M? in H2. Extrapolated over the inner Milky Way, the cirrus may contain 107 M? of H2 and 108 M? in total gas mass. If elevated to 100 pc, their gravitational potential energy is ~1053 ergs.