Nuclear energy is essential in addressing the problem of climate change and energy crisis. Liquid metal mixing phenomenon at the core outlet of liquid metal fast reactors is an important issue in Gen-IV nuclear systems. In this paper, the experimental and numerical analysis of the liquid metal mixing process in complex jets were carried out based on the structure of fuel assembly heads in sodium-cooled fast reactors. The liquid metal mixing characteristics were obtained in the experiment. And a high fidelity LES model was developed and validated experimentally. The impact of different head structures on the mixing process was analyzed and an index of liquid metal temperature mixing degree was newly proposed and compared with previous formulas. Result shows that, the temperature mixing region can be divided into five zones along the flow direction. Compared to other three structures, the three-sided outlet head with offset hedge has the lowest fluctuations of velocity and temperature in the upstream of the mixing flow. Also, the three-sided outlet head with offset hedge has the best temperature mixing ability, and the index is two times larger than that of the prototype. The three-sided outlet head with offset hedge proved to be the optimal structure.