Minerals In Sediments Research Articles

Impact of water loss on sustainability of the Mississippi River channel in its deltaic reach

AbstractThe Mississippi River channel from New Orleans to the Gulf of Mexico (GOM) is a key deep draft navigation channel and an active deltaic lobe. Natural and engineered lateral exits from this reach into adjacent receiving basins historically has provided mineral sediment for wetland accretion in the face of rising relative sea level and supported estuarine‐coastal food webs. However, our analysis indicates water losses from the channel have increased by 25% since 2004 due to (1) bank failures during large floods since 2012 that have created several large exit channels downriver of the flood protection levee, and (2) the opening of an engineered diversion at West Bay in 2004. This has resulted in a 60%–80% loss in stream power in the lowermost navigation channel that is accompanied by net shoaling between 2012 and 2022 and an increased dredging need. Our 2022 survey in the GOM exit passes indicates that only 20% of the freshwater, 5% of the total suspended sediment (2% of the sand) at New Orleans now reaches the GOM: this supports previous research indicating the delta front is retreating after centuries of progradation. Together these results indicate that (1) river containment and the sustainability of the navigation channel is threatened, (2) sediment load reaching the seaward end of the delta may be insufficient to avoid major degradation, and (3) the increased freshwater flux into adjacent shallow coastal water bodies has unknown implications for coastal hypoxia and food webs, including commercial species (e.g., oysters) and marine mammals. Future acceleration in sea level rise rates and tropical storm frequency/intensity would likely worsen these trends.

Characterizing Flocculated Mineral Sediments with Acoustic Backscatter, Using Solid and Hybrid Scattering Models.

This study investigated the performance of an acoustic backscatter system (ABS) for the in situ particle characterization of complex wastes. Two sediments were used: a fine, milled calcite that was flocculated with anionic polyacrylamide and naturally flocculated pond sludge. Particles were initially measured independently by light-based techniques to gain size, the coefficient of variation (COV), and fractal dimensions. For acoustic experiments, a bespoke, high-fidelity ABS was employed with 1, 2.25, and 5 MHz probes and a recirculating mixing tank. Initially, the concentration independent attenuation and backscatter coefficients were measured for each system using a robust calibration procedure at multiple concentrations. Comparisons of the total scattering cross-section (χ) and form function (f) were made between the experimental data and two semiempirical models: a Solid Scattering model and a Hybrid model (where the effects of bound fluid are incorporated). Experimental data compared more closely to the Solid Scattering model, as it was assumed scattering was dominated by small, bound "flocculi" rather than the macroscopic structure. However, if the COV was used as a fit parameter, the hybrid model could give equally accurate fits for a range of input aggregate sizes, highlighting that important size and structure information can be gained from the acoustic models if there is some a priori system data. Additionally, dual-frequency inversions were undertaken to measure concentration profiles for various frequency pairs. Here, the lowest frequency pair gave the best performance (with accurate measurements in the range of 2-35 g·L-1) as interparticle scattering was lowest.

Cadmium contamination in cacao farms of Piura, North Peru: A comprehensive assessment of geogenic and anthropogenic sources and implications for future production

Cadmium (Cd) is a heavy metal that poses a threat to food safety via the ingestion of food products with Cd. The uptake of Cd by the cacao tree (Theobroma cacao) has gained attention after the European Union set limits for Cd in chocolate products, the main commodity produced from cacao beans. In this study, we analyzed levels of Cd in soils and plant tissues across five cacao farms in the Piura region of Peru to identify the origins of Cd accumulation, and the natural and human factors controlling its concentration. Our results show that Cd levels varied in the order: leaves (1.25 mg kg−1) > beans (0.78 mg kg−1) > soils at 5 cm (0.68 mg kg−1) > soils at 20 cm (0.6 mg kg−1). Our findings suggest that the higher concentration of Cd in plant tissues and surface soils can be explained by readily available Cd from fertilizers and a litter layer being absorbed, cycled, and accumulated by the plant. Moreover, even when fertilizers are within regulatory limits, their continuous application, combined with the biocycling of Cd, may lead to high Cd concentrations in beans and leaves. Conversely, farms on alluvial soils and more stable topographic positions display higher soil and plant Cd concentrations. Likewise, farms located at lower altitudes, with higher contributing areas are more likely to receive Cd transported through sediments and water in the river network. Our results also suggest that variations in the underlying geology and soil mineralogy may be a source of potentially Cd bearing sediments. Overall, this study indicates that the high levels of Cd in plants in the study area are the result of a combined mechanism involving plant bioaccumulation and high Cd in fertilizers for the most part, with a minor contribution from potential Cd bearing minerals in sediments of alluvial soils.

Characteristic and distribution of grain sizes and minerals in sediments from the Vietnamese Gulf of Tonkin

Grain sizes and minerals of sediments from the Gulf of Tonkin were evaluated from 30 surface samples and 50 samples from two cores. The distribution of grain sizes and minerals from these samples were determined to help understand sediment characteristics, origins, and environmental dynamics. There were five sediment types: fine and very fine sands, very coarse, coarse, and medium silts. Minerals in the sediment were identified as decreasing in terms of the content of quartz, illite, kaolinite, chlorite, feldspar, goethite, halite, calcite, gibbsite, aragonite, and montmorillonite. Contents of major minerals such as quartz, illite, kaolinite, and chlorite varied from nearshore to offshore; quartz was higher nearshore than offshore; illite, kaolinite, and chlorite from nearshore were lower than offshore; calcite and aragonite were low nearshore and higher in the offshore; goethite was lower offshore and higher nearshore; and, finally, halite was high offshore and low nearshore. Surface sediments were divided into three groups based on sedimentary environment characteristics: Group 1 was distributed nearshore with strong dynamics, Group 2 in bays and nearshore with weak dynamics, and Group 3 was distributed offshore with quiet dynamics. The origin of the sediments was weathering and erosion from the mainland and islands under the river and sea processes in the Gulf of Tonkin with quartz, illite, kaolinite, feldspar, chlorite, and montmorillonite found present in the sediment. Geochemical processes produced goethite, gibbsite, halite, and pyrite in the sediments while biological substances produced calcite and aragonite.

Evaluation of Maturity (Late Diagenesis) in Source Rocks of Jaisalmer Basin in Rajasthan, India using 57Fe Mössbauer Spectroscopy

Abstract The potential of a source rock for hydrocarbon generation depends on several factors such as the amount, type and maturity level of the organic matter present in it as well as the redox conditions in which the sediments containing the source rocks were deposited. Organic-rich sediments deposited in reducing environment have better prospects for a good quality source rock as compared to those deposited in oxidizing environments. The information about the oxidizing/reducing environment at the time of deposition can be obtained from the presence or absence of certain iron-bearing minerals in sediments. The presence of oxide minerals goethite (α-FeOOH) and/or hematite (α-Fe2O3) indicates that sediments were deposited in an oxidizing environment. Therefore the study of iron-bearing minerals in sediments can be used to understand the qualities of the source rocks. Sedimentary samples were collected from different depths of three wells BT-3, DND-1 and LNR-1 located in different structures of the Jaisalmer basin were investigated to understand the chemical state of iron by using Mössbauer spectroscopy. In most of the samples, iron was found mainly in the form of pyrite (FeS2), siderite (Fe, Mg) CO3, 2:1 layer silicates in high spin Fe3+ and high spin Fe2+ state and (Ca, Fe, Mg) carbonates. In the samples from Lathi and Shumarwali formations that belong to the lower Jurassic and Triassic sequences, α-Fe2O3 (hematite) was indeed observed. It was present in a narrow sedimentary depth interval in the wells BT-3 and DND-1 and in a much broader thickness in well LNR-1. The other sedimentary sequences younger than the Lower Jurassic sediments have not shown the presence of any oxide mineral. The present study indicates that oxidizing environment was present in the entire basin in the Lower Jurassic era at least for some duration. However, the degree of oxidation was not uniform as evident from the distribution pattern of iron oxide mineral (α-Fe2O3). Mössbauer studies of source rocks can also be used as a fingerprint to get information about the thermal history (Palaeo-temperature) of sedimentary sequence which is crucial in hydrocarbon prospecting.

Developing sediment provenance discrimination tracers using major elements in East China Sea mud deposits

Discriminating shelf sediment provenances using sediment trace metal and rare earth element (REE) concentration and isotope ratios and clay mineral contents has several unavoidable hurdles, such as the effect of sediment grain size on metal concentrations, ubiquitous inclusion of REE-rich heavy minerals in sediments, and meager and inconsistent compositional differences. Furthermore, to date, no study has analyzed and determined a convincing tracer that can differentiate between Huanghe (HH) and Changjiang (CJ) sediment provenances, especially quantitatively. In this study, we quantitatively discriminated the provenances of the southwestern Cheju Island mud deposit (SWCIM) in the northern East China Sea (ECS) shelf, using seven major elements (Si, Al, Fe, K, Na, Ca, and Mg), and further determined the spatial variations of the contributions from the HH and CJ rivers to the northern ECS sediments. The results indicate that the SiO2/Al2O3 and Fe2O3/Al2O3 ratios of the HH, CJ, and Korean (KR) river sediments can be considered as reliable tracers for differentiation of the northern ECS shelf sediment provenance. Furthermore, the quantitative contributions of HH, CJ, and KR to the northern ECS sediment budget were approximately 80, 20, and 0%, respectively. The systematic spatial variations of the HH and CJ river contributions to the sediment provenances in the study area, such as the significant contributions of the HH river in the northwestern part of the SWCIM and the CJ river in the southwestern part, support the availability and applicability of the Fe2O3/Al2O3 ratio as a sediment provenance discrimination tracer. We propose that these major element concentration ratios can be applied to distinguish other siliciclastic shelf sediment provenances.

Incised valleys on the Algarve inner shelf, northern Gulf of Cadiz margin: Stratigraphic architecture and controlling factors in a low fluvial supply setting

A network of cross-shelf paleovalleys has been recognized over the paleo-inner shelf off the Gilão-Almargem Estuary, a small fluvial drainage system that presently receives minor sediment supply in the eastern Algarve shelf, northern margin of the Gulf of Cadiz (SW Iberian Peninsula). This study is aimed at determining the driving controls that triggered substantially different paleohydrological conditions and sedimentary dynamics of ancient fluvial systems in this margin. We focus on evidences of secondary controls on valley genesis and evolution, superimposed to primary glacio-eustatic control such as antecedent geology, low fluvial supply and changing hydrodynamic regimes. The architecture and spatial distribution of these paleovalleys were interpreted based on a grid of seismic profiles with different resolutions. Likewise, a sediment core obtained in a distal position of the paleovalley system provided information about sedimentary processes during the most recent stage of valley infilling. The chronostratigraphic framework was constructed based on regional seismic horizons defined in previous studies and complemented with two AMS 14C dates obtained from bivalve shells.The inner shelf paleovalley system is composed of several incised valley features which exhibit a remarkable similar internal architecture. These inner valley features exhibit two major incision phases (from oldest to youngest; IP 2 and IP 1) that are thought to constitute a simple paleovalley system formed during the last glacial cycle. The origins of the incision are considered to be different. The older one is related to fluvial incision during the sea-level fall leading into the Last Glacial Maximum, whereas the recent one is interpreted as the result of tidal scour during the postglacial transgression. Their corresponding infillings are interpreted, respectively, as estuarine bay-fill deposits and estuary-mouth sands. Overlying the paleovalley infilling, a distinctive reflective unit is in agreement with the generation of coastal barriers and related depositional systems.The formation of the paleo-inner-shelf paleovalley system was strongly conditioned by antecedent geology, which strongly limited the generation of wide incised valleys and determined the amount of incision landward of a well-defined break of slope. Its postglacial infilling was mainly estuarine in nature, likely involving the development of a dendritic system, with numerous barriers interrupted by tidal inlets and channels in a mixed estuarine system with low fluvial supply.

Geochemical and mineralogical evaluations of coal, shale, and mine waste overburden from Makum coalfield of the Northeast India

The Cenozoic-age Makum coal from northeastern India offers numerous research opportunities because of its diverse geochemical and geological characteristics. Due to its high sulfur content, the coal has been found to be less useful for industrial purposes. It can, however, serve as a hub for ongoing research on coal-based derivative products. The aim of this research work is to investigate the mineralogical and geochemical compositions of the coal, mine overburden (MOB) and shale samples taken from the Makum coal field and also on establishing a mutual relationship between them. To characterize the geochemical controlling factors of the Makum coal field, the study employs coal petrography, FTIR, mineralogical, and geochemical analysis. According to X-ray diffraction analysis, the major minerals like quartz, kaolinite, haematite, illite, pyrite, and calcite are present in coal and MOB. Pyrite is observed by SEM–EDS analysis as cubic-shaped particles that are smaller than a few µm in size. The presence of sulfide minerals represents a phase of pyrite mineralization. The petrography study was used to better understand the environment that existed during the formation of the plant material, which aids us in determining the quantity of detrital mineral sediment contained in the coal. According to the ICP-MS analysis, the samples indicate significant levels of rare earth elements including yttrium. The present study reveals higher concentrations of potential hazardous elements in the coal samples, with V, Cr, Ni, Cu, and Zn content in coal being considerably enriched compared to world-average concentrations. The correlation analysis reveals that the potential hazardous elements like Co, Ni, As, and Cu are associated with pyrite as they have strong affinity towards pyrite. Thus, numerous minerals and rare earth elements (REEs) exist, opening up a fresh avenue for more research in the area. This study also assists researchers in understanding the significance of Makum coal and provides numerous ideas for coal characterization.

Cretaceous Nb-enriched basalts in the western Gan-Hang belt, South China: A response to slab window opening during the Paleo-Pacific ridge subduction

The role of recycled slab-mantle interaction in the formation of mantle-derived rocks during the Paleo-Pacific subduction remains to be tested. In this study Nb-enriched basalts (NEBs) are identified in Shanggao, western part of the Gan-Hang belt, South China. These volcanic rocks have 40Ar/39Ar ages of ∼90 Ma. They are tholeiitic to calc-alkaline in composition and have low SiO2 (50.1–53.4 wt%), high MgO (5.86–7.10 wt%), and Nb (10.7–14.3 ppm) contents. These NEBs have high Nb/La (0.91–0.99) and Nb/U (14.8–21.0) ratios and chondrite-normalized patterns with slightly enriched light rare earth elements (LREEs) ((La/Yb)N = 5.32–6.52). Their primitive mantle-normalized patterns are similar to E-MORB-like characteristics. These features indicate that these NEBs were derived from a mixed source between the asthenospheric mantle and slab-derived adakitic components in the garnet stability field. Their Sr-Nd-Pb-Hf isotopic compositions also reflect the contribution of the subducted oceanic crust including minor sediments in the source. These NEBs are spatially associated with adakitic rocks, A-type granites, and related mineral deposits in the Gan-Hang belt, clearly supporting a tectonic model in which the Cretaceous ridge subduction and slab window opening occurred during the enhanced slab rollback of the Paleo-Pacific plate. The melting of residual eclogites caused by episodic upwelling of the asthenospheric mantle can account for the formation of the NEBs in a back­arc extensional setting.

Geochemical discrimination of pyrite in diverse ore deposit types through statistical analysis and machine learning techniques

Abstract Pyrite is a ubiquitous mineral in many ore deposits and sediments, and its trace element composition is mainly controlled by temperature, oxygen fugacity, pH, compositions of fluids, and host rock composition. A discriminant analysis (DA), based on multi-element compositions of pyrite, distinguishes iron oxide-apatite (IOA), iron oxide copper-gold (IOCG), skarn Cu-(Fe), porphyry Cu-Mo, orogenic Au, volcanic-hosted massive sulfide (VMS), sedimentary exhalative (SEDEX) deposits, and barren sedimentary pyrite. Testing of the DA classifier yields an accuracy of 98% for IOA, 96% for IOCG, 91% for skarn Cu-(Fe), 94% for porphyry Cu-Mo, 87% for orogenic Au, 84% for VMS, 96% for SEDEX, and 85% for barren sedimentary pyrite. Furthermore, neural network, support vector machine, and random forest, were performed for selecting the optimum classifier more accurately. In these three techniques, the support vector machine yielded the highest overall accuracy (98% for IOA, IOCG, skarn Cu-Fe, and porphyry Cu-Mo, and 97% for orogenic Au, VMS, SEDEX, and barren sedimentary pyrite) and thus is an appropriate technique in predicting pyrite types.

Impact of Sedimentary Conditions and Relative Distribution of Sand Sedimentary Minerals in Iraqi Soils

This study investigated the relative distribution of sand-separating minerals and the effect of sedimentary and climatic conditions on their distribution in some soils from northern and southern Iraq. The samples were collected from four Iraqi governorates: Erbil (included the soils from areas of Shaqlawa, Soran, and Juman), Sulaymaniyah (included the soils from Dokan, Sayed Sadeq, and Halabja), Maysan (included the soils of Al-Kahla, Ali Al-Sharqi, Awasha, Kumit, Ali Al-Gharbi, and Al-Tayyib), and Wasit Governorate (included the soils of Zurbatiya, Badra, Jassan, Al-Muwafiqiyah, Al-Numaniyah, and Zubaidiyah). The results indicated that the percentages of light sand minerals were higher than the percentages of heavy sand minerals in all the soils of the study sites. It is attributed to the nature of the mineral composition and the intensity of the weathering factor’s influence on the sedimentation sites or during transportation. The results also indicated the dominance of the quartz group, followed by the group of carbonate rock pieces and the group of feldspar minerals in terms of dominance within the light part of sand minerals in all soil samples in southern Iraq (Wasit and Maysan). The rock-cut minerals group was dominant, followed by the quartz and feldspar minerals group in all soil samples in northern Iraq (Erbil and Sulaymaniyah). The other light minerals of the group were found in varying proportions and distribution in all soil samples, which included (mudstone, lime, evaporites, igneous and metamorphic rocks, clay-coated grains, and other minerals). The results showed that the percentages of the opaque minerals were higher in all soil samples than the group of non-opaque minerals, which included minerals (zircon, tourmaline, rutile, strolite, epidote, and kyanite) with irregularity and a significant difference in the proportions as the large percentages indicate that they bear transportation over long distances and their resistance to weathering processes. These ratios were more evident in the northern regions of Erbil and Sulaymaniyah, which indicate the intensity of weathering processes (wet climate) compared to the soils of Wasit and Maysan in southern Iraq. The low percentages appeared in the soil samples due to the short transportation distance and the diversity of the source rocks.

Electronic-Level Insight into the Adsorption and Surface Diffusion Kinetics of a Simplified Glyphosate Model on a Goethite Surface.

The diffusive processes that occur in minerals involve chemical and physical surface phenomena of great interest that allow for understanding the mobility of different anions of environmental importance. One of them is glyphosate, which is widely used as a pesticide. In this work, we performed Hubbard-corrected density functional theory (DFT + U) calculations to study the adsorption and surface diffusion of methylphosphonic acid (MPA), as a model of glyphosate, on the (010) plane of goethite (GOT), one of the most important Fe(III) minerals in soils and sediments. In particular, the MPA adsorption was studied at the GOT-water interface, finding a strong covalent character in the bond. We also corroborated the occurrence of double proton transfer (MPA to GOT and GOT to GOT). Finally, activation energy barriers were calculated to estimate the half-lives for molecular diffusion, showing that MPA moves almost 3000 times slower than water at the GOT surface.

Effect of Karst Geomorphology on the Sedimentary Mineralization and Geochemical Distribution of Bauxite: An Example from the Xiaoyuan Area in Qingzhen, Guizhou Province

Bauxite, in central Guizhou, is predominantly karst bauxite, but there is insufficient research on the effect of karst paleogeomorphology on bauxite development. Xiaoyuan bauxite is also a karst bauxite, and high- and low-iron bauxite deposits exist in the study area. This study conducts geological modeling of karst bauxite using controlled-source audio-frequency magnetotelluric (CSAMT) data and drill core data. The effects of karst paleogeomorphology on bauxite deposition and mineralization are evaluated by assessing karst paleogeomorphology, conducting a mineralogical analysis of drill cores at different locations, and determining the geochemical distribution characteristics of the elements in the horizontal and vertical directions. Combined with previous research results, we propose two metallogenic processes of high-iron and low-iron bauxite. The findings are significant for understanding the mechanism of bauxite formation.

The formation of authigenic phosphorus minerals in cold-seep sediments from the South China Sea: Implications for carbon cycling below the sulfate-methane transition

The formation of authigenic phosphorus (P) minerals near the sulfate-methane transition (SMT) represents an important pathway of P burial in marine sediments. However, our current understanding of the coupling between the formation of authigenic phosphate and carbon and iron (Fe) cycling is insufficient. In this study, a piston core recovered from the Haima cold seeps of the Qiongdongnan basin, northern South China Sea, was used to analyze pore-water parameters and solid-phase Fe and P speciation. Results from a previous study indicate that the current SMT is located at approximately 1 m below the seafloor (mbsf) and a fossil SMT located at approximately 6.5 mbsf. Dissolved phosphate concentrations and solid-phase iron oxide (FeOx) contents are found to decrease with depth, while Fe-bound P (PFe) and authigenic phosphate (PAuth) contents increase with depth in the zone between the current and fossil SMTs where gas hydrate is present, suggesting that vivianite and authigenic apatite formed in this zone. Gas hydrate below the current SMT will dissociate once methane is undersaturated, which could persistently provide dissolved methane to prevent the downward shift of the current SMT where methane is continually consumed. Such a methane-rich environment maintained by gas hydrate may favor the persistent reduction of FeOx and the formation of vivianite. Dissolved phosphate concentrations are high, but decrease rapidly with depth at the fossil SMT. Combined with higher FeOx and PAuth contents and lower PFe contents and lower POrg/total organic carbon (TOC) ratios, these results suggest the formation of authigenic apatite at the fossil SMT. The high dissolved phosphate concentration and low POrg/TOC ratios at the fossil SMT are interpreted to reflect preferential release of P during the degradation of organic matter generated by methanotrophic microorganisms. Overall, our study shows that P speciation in methane-rich sediments provides insight into the formation processes of authigenic P minerals near the SMT and associated carbon and Fe cycling processes.

Long-Term Impact of Historical Mining on Water Quality at Mount Lyell, Western Tasmania, Australia

During the twentieth century, inadequate management of mine waste at the Mount Lyell Copper Mine affected the ecology of the Queen–King Rivers and Macquarie Harbour, western Tasmania, Australia. Over the past two decades, the water quality of the river system has been measured semi-annually to investigate the long-term hydrochemical and environmental impacts caused by these historical mine practices and the waste associated with the Mount Lyell mine to the Queen–King Rivers. At sample sites below the confluence of Haulage Creek, the water pH was below pH 3.5, remaining below pH 5 across all sites to Macquarie Harbour. Local baseline rivers ranged from pH 4.0 to 8.4. Elemental concentrations of dissolved metals in water samples downstream of Haulage Creek were above the Australian and New Zealand Environment and Conservation Council (ANZECC) water quality guidelines. Copper, Fe, and Zn were not attenuated along the length of the river, with concentrations remaining elevated to the King River Delta. Mineralogical analyses demonstrated secondary minerals in sediments at Haulage Creek and pyrite concentrated at the King River Delta. Static tests on mining-affected sediments indicated risk of AMD and metal(loid) leaching in the river system. Since 2016, after flooding of the Prince Lyell mine, dissolved metal levels in the Queen–King Rivers have decreased; however, concentrations remain above guidelines. Almost three decades after legacy mine waste disposal ended, it still poses a long-term risk to the downstream environment, implying that without effective management of these historical mine wastes, the Queen–King Rivers will continue to be severely impacted.Graphical

RECONSTRUCTION OF SEDIMENT RUNOFF FORMATION FEATURES IN THE LAKE KHORLAKEL (NORTH CAUCASUS) CATCHMENT FOR THE LAST 8 THOUSAND YEARS (ACCORDING TO GEOMORPHOLOGICAL AND LITHOSTRATIGRAPHIC DATA)<a href="#FN2"><sup>2</sup></a>

The change in sediment yield is an important indicator of the natural environment dynamics, depending on the combination of landscape, tectonic and climatic conditions. Assessment of sediment yield often based on the results of studying the bottom sediments of mountain lakes with relatively compact catchments. However, for correct reconstructions, in addition to analyzing lake sediments, it is necessary to study the causes and mechanizm of sediment redistribution in their catchments, to identify sediment delivery pathways to the reservoir and their possible changes over different time windows. The drainless Lake Khorlakel, located at the altitude of 2045.0 m above sea level on the northern macroslope of the Greater Caucasus. It is a suitable testing ground for complex research: on the one hand, the relict reservoir is an ideal sedimentation trap, and on the other, it is located with in an area of intensive exogenous processes and tectonic activity. The two boreholes were drilled in 2017 in the deepest (≈8 m) part of the lake and 17 samples collected taken from the cores for radiocarbon dating, which made it possible to build an age model for the range from 8000 to 500 yr. BP. Complex geological and geomorphological studies were carried out in 2021 to interpret the obtained data. It was found that sedimentation in the lake is associated with runoff and sediment redistribution in the Elbashi creek catchment. A number of episodes of proluvial activation with the formation of an outflow cone, followed by lake accumulation, have been traced for the last 8 kyr. The connection between lake and catchment ceased only in the last 1 kyr. BP. Two main stages of lake sedimentation with a boundary of 3 kyr. BP and 10 episodes, that are characterized by different proportions of mineral and organic components in bottom sediments were established. Some of the lithostratigraphic boundaries correlate with strong earthquakes that occurred in the Elbrus region, and some – with climatic events.

LOW-TEMPERATURE GEYSERITE AND EPHEMERAL MINERALS OF THE MOGOYSKY THERMAL SPRING (NORTHERN TRANSBAIKALIA, BAIKAL RIFT ZONE)

During hydrogeochemical testing of the Mogoisky thermal spring in Northern Transbaikalia, 5 samples of modern mineral sediments were taken, in two of which opal is the main component of geyserite, and in the other three carbonates, fluorides and sodium sulfates predominated. Calculations of deep temperatures showed that the formation of geyserite is associated with low-temperature hydrotherms and is explained by a decrease in their temperatures during discharge. Deposits of easily soluble salt minerals occur on the evaporation barrier, during rainy periods they can completely dissolve and disappear.

A New Approach for Investigating Iron Mineral Transformations in Soils and Sediments Using 57Fe-Labeled Minerals and 57Fe Mössbauer Spectroscopy.

Iron minerals in soils and sediments play important roles in many biogeochemical processes and therefore influence the cycling of major and trace elements and the fate of pollutants in the environment. However, the kinetics and pathways of Fe mineral recrystallization and transformation processes under environmentally relevant conditions are still elusive. Here, we present a novel approach enabling us to follow the transformations of Fe minerals added to soils or sediments in close spatial association with complex solid matrices including other minerals, organic matter, and microorganisms. Minerals enriched with the stable isotope 57Fe are mixed with soil or sediment, and changes in Fe speciation are subsequently studied by 57Fe Mössbauer spectroscopy, which exclusively detects 57Fe. In this study, 57Fe-labeled ferrihydrite was synthesized, mixed with four soils differing in chemical and physical properties, and incubated for 12+ weeks under anoxic conditions. Our results reveal that the formation of crystalline Fe(III)(oxyhydr)oxides such as lepidocrocite and goethite was strongly suppressed, and instead formation of a green rust-like phase was observed in all soils. These results contrast those from Fe(II)-catalyzed ferrihydrite transformation experiments, where formation of lepidocrocite, goethite, and/or magnetite often occurs. The presented approach allows control over the composition and crystallinity of the initial Fe mineral, and it can be easily adapted to other experimental setups or Fe minerals. It thus offers great potential for future investigations of Fe mineral transformations in situ under environmentally relevant conditions, in both the laboratory and the field.

An Improved Framework for Estimating Organic Carbon Content of Mangrove Soils Using loss-on-ignition and Coastal Environmental Setting

The use of loss on ignition (LOI) measurements of soil organic matter (SOM) to estimate soil organic carbon (OC) content is a decades-old practice. While there are limitations and uncertainties to this approach, it continues to be necessary for many coastal wetlands researchers and conservation practitioners without access to an elemental analyzer. Multiple measurement, reporting, and verification (MRV) standards recognize the need (and uncertainty) for using this method. However, no framework exists to explain the substantial differences among equations that relate SOM to OC; consequently, equation selection can be a haphazard process leading to widely divergent and inaccurate estimates. To address this lack of clarity, we used a dataset of 1,246 soil samples from 17 mangrove regions in North, Central, and South America, and calculated SOM to OC conversion equations for six unique types of coastal environmental setting. A framework is provided for understanding differences and selecting an equation based on a study region’s SOM content and whether mineral sediments are primarily terrigenous or carbonate in origin. This approach identifies the positive dependence of conversion equation slopes on regional mean SOM content and indicates a distinction between carbonate settings with mean (± 1 S.E.) OC:SOM of 0.47 (0.002) and terrigenous settings with mean OC:SOM of 0.32 (0.018). This framework, focusing on unique coastal environmental settings, is a reminder of the global variability in mangrove soil OC content and encourages continued investigation of broadscale factors that contribute to soil formation and change in blue carbon settings.

L. V. Pustovalov and the establishment of sedimentary research in Russia

This article is dedicated to the role of L.V. Pustovalov in creating the theoretical foundations of sedimentary research in Russia, including determination and substantiation of the most important regularities governing sedimentary processes and their stages. The constituting stages of sedimentary processes, such as weathering, transport, and deposition, were identified and described. These stages lead to the differentiation of sedimentary material and the formation of sedimentary rocks of different composition and structure. The concepts of the stages of diagenesis and epigenesist (catagenesis) were formulated. For the first time, specific features of sedimentary process evolution were outlined, including sedimentation conditions and formation of individual sedimentary minerals and rocks.