Mineral Residues Research Articles

Ecological and Economic Aspects of Phosphogypsum Safety Management at the Former Uranium Production Site “Pridniproivsky Chemical Plant”

Purpose: Justification the possibility of safe re-use and recycling of the residues of Uranium-containing raw material processing as an element of the remediation strategy for bringing the site of the former "Prydniprovsky Chemical Plant" (PChP)to a safe state. Methods: Site specific field studies and analytical methods for determining of the radionuclides of Uranium-Thorium series, as well as useful mineral elements in the residues of Uranium production, assessment of safe management and possible options for its re-use and recycling. Results: According to the results of monitoring studies on the radionuclide and hydrochemical composition of groundwater at the PChP industrial site for the period from 2009 to 2021 year, a high content of sulfates and an increased content of uranium in groundwater under the body of the Dniprovske tailing dump, which has a phosphogypsum coating on its surface, was revealed. Phosphogypsum is considered, on the one hand, as a source of groundwater pollution, and on the other, as a potential resource for its possible reuse and processing. The results of experimental studies of the content of natural radionuclides and the elemental composition of mineral residues of ore production at the site of the former uranium ore processing plant "PChP" are also provided, as well as an safety assessment of their handling and the options of their possible processing as an element of the strategy for bringing the site to a safe state. Conclusions: The possibility and necessity of safe processing of phosphogypsum on the surface of the tailings "Dniprovske" with its simultaneous replacement by a new soil cover is proved.

Nanostructured and Advanced Designs from Biomass and Mineral Residues: Multifunctional Biopolymer Hydrogels and Hybrid Films Reinforced with Exfoliated Mica Nanosheets.

Transforming potential waste materials into high-value-added sustainable materials with advanced properties is one of the key targets of the emerging green circular economy. Natural mica (muscovite) is abundant in the mining industry, which is commonly regarded as a byproduct and gangue mineral flowing to waste rock and mine tailings. Similarly, chitin is the second-most abundant biomass resource on Earth after cellulose, extracted as a byproduct from the exoskeleton of crustaceans, fungal mycelia, and mushroom wastes. In this study, exfoliated mica nanosheets were individualized using a mechanochemical process and incorporated into regenerated chitin matrix through an alkali dissolution system (KOH/urea) to result in a multifunctional, hybrid hydrogel, and film design. The hydrogels displayed a hierarchical and open nanoporous structure comprising an enhanced, load-bearing double-cross-linked polymeric chitin network strengthened by mica nanosheets possessing high stiffness after high-temperature curing, while the hybrid films (HFs) exhibited favorable UV-shielding properties, optical transparency, and dielectric properties. These hybrid designs derived from industrial residues pave the way toward sustainable applications for many future purposes, such as wearable devices and tissue engineering/drug delivery.

Nutritional and quality changes in piglet concentrate affected by formulation and storage

ABSTRACT The aim of this study was to evaluate the variations in the stability and nutrient concentration in concentrates for piglet feeding. Five treatments were established: T1 - Control, standard concentrate formulation (SCF); T2 - PXMore5, SCF with more 5% vitamin-mineral premix (VMP); T3 - PXLess5, SCF with less 5% VMP. All these three treatments used 400kg batches in an INTECNIAL mixer; T4 - FeedMixer, SCF using a 4,000kg batch in an IMOTO mixer; T5 - PremixMixer, SCF using a 1,200kg batch in an MUYANG mixer. For each treatment, bags of 20kg were stored in three storage places for four months where room temperature and relative humidity was recorded daily. The concentration of nutrients was evaluated through centesimal and mineral analysis. The water activity of concentrate was affected by temperature and relative air humidity in different storage places. The greatest variation in concentration of crude protein, mineral residue, copper, zinc, and selenium was due to the PremixMixer treatment. Regarding the guaranteed levels, the critical value was verified only for the chrome concentration.

CHOUX PASTRY SEMI-FINISHED PRODUCTS WITH FILLERS: TECHNOLOGY AND QUALITY

Background. Theproblem of expanding the range of flour products of high nutritional and biological value for healthy nutrition with the use of new types of protein and mineral supplements, products of complex processing of fish and plant raw materials remains relevant. The development of technology of choux pastry products using dry fish and plant semi-finished product (NRVGL) and carrot filler (CF) is proposed. The aim of this article is to study the influence of dry fish and plant semi-finished products on the structural and mechanical properties and quality indicators of choux pastry products, to justify the rational recipe composition and to determine the nutritional value of choux pastry semi-finished products using NRVGL and CF. Materials and methods. The semi-finished fish and plant semi-finished product from hydrolyzed fish heads with wheat bran and flax seed fiber (NRVGL), which is made from dry fish and plant semi-finished products (SRRN) according to the TU U 10.2-40220843-003: 2016; boiled carrot puree with a dry matter content of 10 %; model sys­tems and baked semi-finished products from choux pastryis explored. Organoleptic indicators of baked products were evaluated according to DSTU 4683: 2006 [12]. Viscosity was measured on a rotary viscometer VPN-0.2, the total mois­ture content was determined by drying to constant weight, ash - by burning a sample with calcination of the mineral residue in a muffle furnace, fat –by extraction-weight method, protein –by modified Kieldal method according to GOST 7636–85, mass fraction of car­bohydrates –by the calculation method, mineral composition –on the atomic absorption spectrophotometer AAS-30. Results. The influence of dry and hydrated fish and plant semi-finished products on the structural and mechanical, functional technological and organoleptic properties of model systems from choux pastrydough has been established by experimental methods. It was found that the use of hydrated in milk NRVGL during brewing flour improves the techno­logical properties of choux pastry dough. The influence of CF on the structure of choux pastrydough and the quality of baked semi-finished products with NRVGL has been studied. The mechanism of action of these additives is studied, the stage of their intro­duction and rational mass fraction in the choux pastrysystem are substantiated. It is established that when using 20 % NRVGL from flour weight and 10 % CF from the mass of egg mix during the brewing of flour, the necessary plasticization of the dough structure is achieved. At the same time there is an improvement of organoleptic characteristics and quality indicators of products. Custard semi-finished products contain­ning NRVGL and CF contain 15.1 % less fat, their nutrient composition improves, in particular, the content of Calcium, Phosphorus, fiber, easily hydrolyzed polysaccharides and soluble pectin substances increases compared to the control. Conclusion. The complex of experimental researches enabled the development of the recipe composition and technology of production of baked choux pastrysemi-finished products with the use of dry fish and plant semi-finished product NRVGL and carrot filler. Choux pastrysemi-finished product is recommended for using in the production of culinary products with improved nutrient composition –profiteroles, filled with pate and fish paste, which are served as cold or banquet snacks.

Review about the effect of chemical activation of industrials waste which is rich by SiO2 and CaO

Most previous research on the term of alkaline and thermal activation, applied in the presence of cement as a main constituent, mixed with industrial waste like (fly ash, slag, glass…) by certain percentages to give a geopolymers or alkali-activated materials for studying the chemical and physical, as well as mechanical behaviour. These methods carried out by chemical solutions such as (NaOH, KOH, Na2CO3…) by different concentrations to facilitate the solubility of the aluminates-silicates, it’s depending on the nature of (CaO-SiO2-Al2O3) system in mineral residues, also there is the thermal method cured at a differents temperature between (20 °C and 100 °C) for 24 h that according to studies and researchers, all these methods to protect the environment from the emission of gaseous pollutants into the atmosphere.

Nutritional and quality changes in piglet concentrate affected by the mix

ABSTRACT The aim of this study was to evaluate the reasons of quality deviation of a concentrate from a predefined standard. Five treatments were established: T1 - Control, standard concentrate formulation (SCF); T2 - PXMore5, SCF with more 5% vitamin-mineral premix (VMP); T3 - PXLess5, SCF with less 5% VMP. All three treatments used a 400kg batches in an INTECNIAL mixer; T4 - FeedMixer, SCF using a 4,000kg batch in an IMOTO mixer; T5 - PremixMixer, SCF using a 1,200kg batch in an MUYANG mixer. For each treatment, bags of 20 kg were stored in three storage places for four months. Water activity of concentrate was affected by temperature and air relative humidity in different storage places. Regarding the kind of mixer, the greatest variation in concentration of crude protein, mineral residue, copper, zinc, and selenium was observed in the PremixMixer. Adjustments are imperative in the handling and use procedures of this kind of mixer to meet the quality requirements required in the concentrate production. Analyzing the effect of the mineral-vitamin premix level, no difference could be defined with the evaluated parameters.

Reutilization of pyrite-rich alkaline leaching tailings as sorbent must consider the interplay of sorption and desorption

Sustainable schemes favor the reutilization of waste over direct disposal. In the case of mine waste from mineral processing (tailings), the reutilization of such waste as sorbents of contaminants in water can be advantageous, considering that tailings have already a plan for disposal. In this article, a methodology to evaluate the convenience of using residual minerals as sorbents is presented. The sorption ability of pyrite-based tailings using synthetic solutions containing copper ions (Cu+2) is followed and contrasted to the sorption ability of minerals before processing (feed). In the case of as-received samples, tailings show a higher capacity for copper removal in batch tests (1.3 vs. 0.4 mg Cu/g for tailings and feed, respectively). This large difference is associated with (a) the smaller particle size distribution for tailings, and (b) the ability of tailings to increase the pH and favor precipitation of metals. Interestingly, tailings were found also to release smaller amounts of undesired elements such as arsenic and cadmium. Tests using defined particle sizes for feed and tailings demonstrate that copper removal was around 0.45 mg Cu/g in batch experiments and 0.68 mg Cu/g in recirculation experiments. In all cases, copper sorption follows pseudo-second-order kinetics, suggesting a mechanism where copper is chemisorbed, forming copper sulfides according to X-ray photoelectron spectroscopy (XPS) measurements. More importantly, sorption experiments were complemented with simultaneous measurements of metal ion release from the minerals into solution. The metals released during batch sorption are mainly Pb and Zn, in the respective amounts of 0.79 and 0.32 mg/g (feed) and 0.75 and 2.19 mg/g (tailing). Thus, even though the use of mineral residues as sorbents is possible, the metal release should be considered to determine the overall convenience of the process.

Supercritical water oxidation of chlorinated waste from pulp and paper mill

The article presents the research results of the oxidation of watered toxic waste from the pulp and paper industry (sludge-lignin, the empirical formula of organic matter CH1.51N0.05S0.03Cl0.01O0.54) in supercritical water-oxygen (SCW/O2) fluid. The experiments were carried out using a flow tube reactor at a pressure of 25 MPa, temperature gradient along its vertical axis (from top to bottom: 390–600 °C), sludge-lignin flow rate of 9.5–14.5 g/min, oxygen ratio OR = 0.73–2.52, using NaOH (1.6 wt%) as a catalyst. Employing gas chromatography – mass spectrometry, polychlorophenols were identified in the composition of sludge-lignin, in which 2,4,6-trichlorophenol was the main component. The total yield of extracted phenols and chlorophenols per sludge-lignin organic matter was 20.82 and 2.88 μg/g, respectively. It is revealed that the conversion rate of sludge-lignin in SCW/O2 fluid is limited by heterogeneous oxidation of the carbonized residue, and is determined by the O2 content in the reaction mixture. At OR ≥ 1.16, only CO2, CO, N2, and N2O were detected in the volatile oxidation products. An increase in OR from 0.73 to 2.52 leads to a decrease in the total content of phenols (from 45540.1 to 129.3 μg/dm3) and chlorophenols (from 51.4 to 2.2 μg/dm3) in the water collected at the reactor outlet. It is shown that 2,6-dichlorophenol and 2-chlorophenol are the most resistant to oxidation. From the analysis of the initial sludge-lignin and mineral residues, it follows that the bulk of the chlorine contained in its organic matter is converted into NaCl in the course of oxidation.

Physico-chemical and electrostatic surface characterisation of mica mineral and its applicability on the adsorption of Safranin Orange and Reactive Black 5 dyes

ABSTRACT The combined approach of specific surface area (SSA), porosity, microprobe analysis (EMPA), transmission electron microscopy (TEM), scanning electron microscopy (SEM) equipped with EDX and infrared spectroscopy (FTIR) provided the mica mineral physico-chemical and morphological characterisation. The electrostatic surface properties were assessed through the determination of the Point of Zero Charge (pHPZC) by the drift method and the electrokinetic mica mineral features represented by the Isoelectric Point (pHIEP) which was carried out through zeta potential measurements. Adsorption tests were performed to correlate the surface charge behaviour of the mica mineral and its influence on the adsorption efficiency of two different dyes, namely: Safranin Orange (SO), as a cationic dye and Reactive Black 5 (RB5), as an anionic dye. The higher adsorption capacity SO dye was observed at pH 9 and achieved almost 83% of removal, while RB5 dye adsorption on mica surface had the highest result, about 45% of removal efficiency, on pH of 3. In both cases, the main mechanism identified that drove this results is the electrostatic force of attraction between the adsorbent edge surface charge (pH-dependent) and the ionic nature (anionic or cationic) of the pollutant dyes particles. The preliminary adsorption experiments demonstrated that the raw grounded mica mineral has a greater potential associated with its application on cationic dye removal in wastewater. The present study aimed to detail the main characteristics of the mica mineral in order to evaluate the potential use of such mineral residues in the removal efficiency of contaminated wastewater.

Sustainable process to co-synthesize nano carbon dots, nano hydroxyapatite and nano β-dicalcium diphosphate from the fish scale

The conventional protocols for the extraction of biological hydroxyapatite employ the prior removal of organic material using severe chemical treatment, which quite often limit the purity and crystalline properties of synthesized hydroxyapatite. The present study describes a process to co-synthesize four high value nano products from scale of Labeo rohita, viz. nano carbon dots, nano hydroxyapatite, nano β-dicalcium diphosphate and nano carbon dot—hydroxyapatite composite. In the process, the organic matter in fish scale is converted to nano carbon dots by a hydrothermal process using acetic acid (1:1) and the mineral residue precipitated was converted to hydroxyapatite, following a sintering protocol. The acetic acid not only functioned as a medium to release the mineral—organic linkage but also acted as a base to hydrolyze the collagenous proteins linked with calcium phosphate in the fish scales. The hydrolyzed collagenous protein was in turn transformed into fluorescent nano carbon dots. β-Dicalcium diphosphate was seen attached over carbon dots, which was separated by crystallization followed by high temperature sintering. Hydroxyapatite: carbon dot composite was synthesized through a hydrothermal method. The spectral and morphological studies of the composite showed strong interaction between carbon dot and hydroxyapatite. All the synthesized materials were characterized using ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, powder X-ray diffraction, atomic force microscope, transmission electron microscope and electrochemical impedance techniques. The study proposes a sustainable method for the complete utilization of fish scale by converting into high value nano products.

The quality of roasted and ground brazilian coffee: Chemical analysis of the effect of fixed mineral residue e different types of packaging on moisture content

The agricultural production of national coffee faces controversy regarding the quality of roasted and ground coffee, being susceptible to quality loss because of oxygen and humidity exposure and high storage temperatures. In light of the importance of coffee to the Brazilian economy and consumption, a survey was made of the main brands of coffee sold in establishments in the city of São Luís, observing the presence or absence of the ABIC quality seal, the category (traditional, extra-strong, superior, gourmet), and the most common packaging types (pillow and vacuum-sealed bags). Then, two purity parameters established by ABIC – humidity and fixed mineral residue – were determined quantitatively in the eight representative samples. The analyses were performed following the procedures described by the Adolf Lutz Institute (2008). The survey revealed that the superior and gourmet categories of coffee are not easily found, while traditional and extra-strong coffee is very accessible, both in pillow and vacuum-sealed bags. The moisture level results showed two brands (A2 and A3) within the standards established by INMETRO for coffee in both pillow and vacuum-sealed bags. Of the samples of fixed mineral residue that were collected, brand A1 was observed to be in conformity with legislation, for coffee packaged in both pillow and vacuum-sealed bags, and brand A4 showed results for pillow bags within the given parameters. Statistical design was applied to verify the effect of packaging (pillow and vacuum-sealed bag) on moisture levels between different brands using analysis of variance (ANOVA). The results showed that despite displaying the ABIC seal attesting to the quality of the product, without fraud and free of impurities, 50% of the samples analyzed showed alterations in moisture level and 62.5% showed fixed mineral residue levels above the standards established by Brazilian legislature.

Evaluation of using magnetic nanoparticle attached phosphorus species as supplemental phosphorous source in broiler diet

Aluminum doped magnetite (Fe 3 O 4 ) magnetic nanoparticle ( MNP ) has been used as an effective sorbent to remove phosphorus ( P ) species in poultry processing wastewaters. It was found that spent MNP contains approximately 13% of P by weight. A study was conducted to evaluate the potential of using spent MNP as a P source. A total of 240 one-day-old male broilers were randomly allocated to four dietary treatments and six replicate each for 18 days. Treatments consisted of 1) positive control ( PC ) with 0.45% nonphytate-P ( nPP ); 2) negative control ( NC ) with a reduction of 0.15% nPP; 3) NC with additional 0.075% of P from magnetic nanoparticle ( NC + 0.075% P-MNP ); and 4) NC with additional 0.15% of P from magnetic nanoparticle ( NC + 0.15% P-MNP ). Body weight and feed intake were recorded at day 7, 14, and 18. Three birds were randomly selected from each cage for Dual-energy X-ray Absorptiometry ( DXA ) scanning at d18. The liver, heart, and spleen were collected and analyzed for mineral content. Ileal digesta were collected from the rest of the birds for P digestibility analysis. Data were subjected to SAS using one-way ANOVA model with GLM procedure. The birds fed with additions of 0.075% and 0.15% P from MNP had an increased ( P = 0.017) body weight gain at d8 to d14 compared to those with NC diet. Significant lower ( P ≤ 0.008) body mineral density and body mineral content were observed in the birds with NC diet compared to those with PC, NC + 0.075% P- magnetic nanoparticle, and NC + 0.15% P- magnetic nanoparticle diets. In addition, the birds with NC + 0.075% P- magnetic nanoparticle and NC + 0.15% P- magnetic nanoparticle had similar body mineral contents and body mineral densities compared to the PC-fed birds, indicating P from spent magnetic nanoparticle has incorporated into the bone mineralization. No significant differences were found between the treatments for mineral residues (Al and Fe) in liver, heart and spleen samples. The ileal P digestibility of dry matter and P was not influenced by the presence of magnetic nanoparticle in diets. In conclusion, 0.15% P from spent magnetic nanoparticle could be efficiently and safely used to replace the same amount P from dicalcium phosphate in the diets for broilers.

Building of the Al-containing Secondary Raw Materials Registry for the Production of Low CO2 Mineral Binders in South-Eastern European Region

The bottleneck in the process for increasing production of low CO2 mineral binders, based on BCSA (belite sulfoaluminate) clinkers, is the availability of Al-rich raw materials. For that purpose, a new registry of Al-containing secondary mineral residues (industrial and mine waste) has been developed and is presented in this paper. The methodology of creating the registry consists of three main steps: Gathering ideas, consolidation of ideas, and implementation. In order to achieve this, the following methodology was adopted: Analysis of similar registries by potential end-users and seeking potential solutions and tools to be used, and conducting 3 rounds of stakeholder consultations via workshops in order to determine crucial parameters and features the registry needs to contain. The key discussion points were about which data the registry needs to contain, who shall be the potential users, and what are the stakeholder’s expectations from the registry’s portal. Potential individual registry variables were identified as being relevant/irrelevant or available/unavailable, and potential solutions for the registry’s sustainability were explored. Each Al-rich waste/residue data entry is divided into 10 slots, describing legal status, location, quantities, chemical (REE included), mineralogical, physical and radiological properties, life-cycle assessment, additional data, and data relevancy. The registry will act as a matchmaking tool between producers/holders of Al-rich secondary raw materials and potential producers of cement clinkers.

Reaction behaviors of Pb and Zn sulfates during reduction roasting of Zn leaching residue and flotation of artificial sulfide minerals

To evaluate the feasibility of recovering Pb and Zn sulfides and Ag-containing minerals from Zn leaching residue by the process of reduction roasting followed by flotation, the reaction behaviors of Pb and Zn sulfates during this process were investigated. Chemical analysis showed that the transformation ratios of PbSO4 and ZnSO4 could reach 65.51% and 52.12%, respectively, after reduction roasting, and the introduction of a sulfidation agent could improve the transformation ratios of these sulfates. scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) revealed that temperature obviously affects the particle size, crystal growth, and morphology of the artificial Pb and Zn sulfide minerals. Particle size analysis demonstrated that the particle size of the materials increases after roasting. Flotation tests revealed that a flotation concentrate composed of 12.01wt% Pb, 27.78wt% Zn, and 6.975 × 10−2wt% Ag with recoveries of 60.54%, 29.24%, and 57.64%, respectively, could be obtained after roasting.

Physical, chemical, sensory and mineral characterization of salty muffins enriched with Tetragonia tetragonoides

Abstract The preparation of bakery products is expanding, mainly due to the possibility of adding other ingredients, in order to enrich them nutritionally. Spinach (Tetragonia tetragonoides) is a vegetable widely used, although its stem that has great potential for use, is still considered a waste and discarded. Based on the aforementioned information, this work aims to elaborate and characterize physical, chemical, sensory and minerals of salty muffins enriched with T. tetragonoides. Four formulations of salty muffins were prepared as following: Standard Formulation (F1); Formulation with addition of spinach leaves (F2); Formulation with addition of spinach stems (F3); Formulation with addition of spinach leaves and stems (F4). The physical and chemical characterization of the leaves and stems of T. tetragonoides was done by quantifying the moisture, residue mineral fixed, proteins, color and minerals. Muffins were characterized by analyzing moisture, fixed mineral residue, protein, total reducing sugars and instrumental analysis of color and texture; sensory and minerals. The muffins showed a predominant green color, due to the addition of spinach. However, stems, leaves and muffins have a high content of minerals, especially calcium and iron. The incorporation of vegetables in the formulations provided an increase in protein content, in addition to expressive sensory acceptance. Feasibility is observed in the production of savory muffins with the addition of leaves and stems, thus using the entire vegetable and avoiding food waste.

INFLUENCE OF THE LEVEL OF WATER MINERALIZATION ON THE CONCENTRATION OF HEAVY METALS IN MUSHROOMS

The current ecological condition of forest plantations has been characterized by high anthropogenic load as a result of population activity. The consequences of the human impact have been manifested in the disturbance of natural landscapes, air pollution, hydrosphere, destruction of the lithosphere, uncontrolled depletion of forest resources, resulting in a decrease and extinction of a huge number of species of animals and plants. In the result of various industries’ work chemical compounds have been formed, which have been transformed into the biosphere and enter all living organisms. Therefore, there are serious problems in the relationship between nature and man. The human impact on the environment is extremely powerful and it is obvious that the biosphere as a result of this impact loses the ability to self-regulate and it does not allow it to function properly. One of the current environmental problems that threatens plants, animals and human health and the quality of the environment is heavy metal pollution. These substances gradually enter plants, animals and humans through the air, water and food chain over a period of time [4]. Toxicity of metals has a direct effect on flora, which is an integral part of ecosystems. These effects lead to changes in the biochemical, physiological and metabolic processes that take place in plants that grow directly in areas with high levels of heavy metals. Samples of edible forest mushrooms were taken on the territory of forests of Tyvriv, Vinnytsia and Kalyniv districts in the Forest-Steppe of the Right Bank of Ukraine. Studies of the concentration of heavy metals were performed in the research and measurement agrochemical laboratory of the Department of Ecology and Environmental Protection, Faculty of Agronomy and Forestry on the basis of Vinnytsia National Agrarian University. The concentrations of Cu, Zn, Pb and Cd of the studied fungi were determined by atomic absorption spectrometry after dry mineralization. Studies of the effect of cooking on the concentration of heavy metals in mushrooms were carried out according to the following scheme: 1. control option: mushrooms, cleaned and washed with tap water; 2. option 1: mushrooms soaked for 3 hours in water without mineral residue; 3. mushrooms soaked for 3 hours in water without mineral residue with the addition of salt (1 kg of mushrooms – 1 liter of water and 10 g of salt). The effect of soaking mushrooms in water without mineral residue with the addition of salt was studied. It was found that when soaking mushrooms for 3 hours in water without mineral residue, the concentration of zinc in them decreased: from 1.02 to 1.37 times; copper - from 1.14 to 1.5 times; lead - from 1.09 to 1.13 times; cadmium - from 1.3 to 1.5 times. When soaking mushrooms for 3 hours in water without mineral residue with the addition of salt, the concentration of zinc in them decreased: from 1.23 to 1.28 times; copper - from 1.2 to 1.36 times; lead - from 1.31 to 1.38 times; cadmium - from 1.41 to 1.6 times.

INVESTIGATION OF THE INFLUENCE OF STABILIZERS ON THE VISCOSITY OF THE RECOVERED MIXTURE OF A HYPERTONIC DRINK FOR ATHLETES

When introducing plant and animal protein products, in addition to nutritional value, it is advisable to assess their physicochemical properties and technological indicators, in particular, homogeneity and consistency stability. The aim of research is to determine the effect of consistency stabilizers on the viscosity of a reconstituted hypertonic drink for athletes based on flaxseed cake, sesame seeds and whey protein concentrate. The mass fraction of protein in the model dry mixture of a hypertonic drink, as well as in its individual components by the Kjeldahl method, the mass fraction of fiber – by the gravimetric method, the mass fraction of lipids – by the extraction-gravimetric method, the mass fraction of moisture – by the thermogravimetric method. The mass fraction of ash in the mixtures was carried out by the method of incineration followed by calcining the mineral residue at a temperature of 450 ... 600 °C. The effective viscosity in the reduced samples of mixtures without and with the addition of stabilizers was determined on a rotational viscometer "Rheotest 2". For the planning of the experiment and data processing, mathematical methods were applied using the Microsoft Office Excel 2003 software package. The chemical composition of individual components and a model dry mixture of a hypertonic drink for the nutrition of athletes, including the content of compounds that have a stabilizing effect on the restored product, has been investigated. It has been proved that the effective viscosity of the reconstructed model mixture in comparison with the effective viscosity of the individual components of the mixture nonaditively increases. The mutual influence of the consistency stabilizers (gum arabic (E 414) and carboxymethylcellulose (E 466)) on the value of the effective viscosity of the reconstituted hypertonic drink was investigated. The developed model mixture of a hypertonic drink is recommended to be used for the development of competitive dry mixtures of hypertonic drinks of plant and animal origin for the nutrition of athletes

The Utilitation of Fish Scale Waste as A Chitosan

Fish scales are fishery waste that can still be utilized because many contain chemical compounds such as organic proteins (41–84%), and the rest are mineral residues and inorganic salts. Fish scales are reported to contain proximate, calcium, and chitin. Chitin can be extracted into chitin by the deasetillation process. Chitosan is a biomaterial that can be used as a food preservative, a pharmaceutical ingredient. This research aims to extract chitin from fish scales and find out the comparison of chitin rendemen in different types of fish. The study was conducted from July to September 2020. Samples of fish scales Upeneus mullocensisi, Lethrinus sp., Caesio chrysozona, and Scarus rivulatus were obtained from the Traditional Market and Morotai Culinary Center. The process of making chitosan is carried out in the FPIK Laboratory of Universitas Pasifik Morotai. The extraction of chitosan from fish scales through three stages is deproteination, demineralization, and deasetilation. The results showed the protein and mineral content of fish scales vary, namely Upeneus mullocensisi (67.83% and 29.84%), Lethrinus sp. (36.80% and 15.99%), Caesio chrysozona (51.84% and 22.99%), and Scarus rivulatus (82.96% and 14.31%). The highest chitosan rendemen in Lethrinus sp. (13.22%), followed by Caesio chrysozona (7.74%), Upeneus mullocensisi (0.80%), and Scarus rivulatus (0.05%). Some chitosan characteristics, such as color, shape, and smell, meet commercial chitosan standards.

ANALYSIS OF THE EFFICIENCY OF USING THE CULINARY PROCESSING OF MUSHROOMS IN ORDER TO REDUCE THE CONCENTRATION OF HEAVY METALS IN THEM

The samples of mushrooms were collected in the forestry of the village Tyvriv and the town of Kalynivka, Vinnytsia and Kalynivka districts, in the conditions of Right-Bank Forest-Steppe of Ukraine. The studies of heavy metals concentration were performed in the scientific agrochemical laboratory of the Department of Ecology and Environmental Protection, the Faculty of Agronomy and Forestry at Vinnytsia National Agrarian University. The concentrations of Cu, Zn, Pb and Cd of the studied mushrooms were determined by the method of atomic absorption spectrometry after the dry mineralization. The research of the effect of culinary processing on the concentration of heavy metals in mushrooms were conducted according to the following scheme: 1. The control: mushrooms, cleaned and washed with tap water; 2. Option 1: mushrooms soaked in tap water for 3 hours and boiled in it; 3. Option 2: mushrooms soaked in the water without mineral residue for 3 hours and boiled in it; 4. Option 3: mushrooms soaked in distilled water for 3 hours and boiled in it. Summarizing the obtained results, it should be noted that the most effective way to reduce the concentration of lead and cadmium in mushrooms was the option of soaking and boiling mushrooms in the water without mineral residue. The most effective way to reduce the concentration of zinc and copper was Option 3, where distilled water was used. The influence of soaking and boiling mushrooms in different types of water is investigated. When soaking and boiling mushrooms in tap water for 3 hours, the concentration of zinc in them was found to decrease from 1.01 to 1.04 times, the concentration of copper – from 1.0 to 1.2 times, the concentration of lead – from 1.09 to 1.16 times and the concentration of cadmium – from 1.08 to 1.2 times. When soaking and boiling mushrooms in the water without mineral residue, the concentration of zinc decreased from 1.01 to 1.04 times, the concentration of copper – from 1.16 to 1.25 times, the concentration of lead – from 1.8 to 2.0 times and the concentration of cadmium – from 1.75 to 2.0 times. When soaking mushrooms and boiling them in distilled water, the concentration of zinc decreased from 1.13 to 1.18 times, the concentration of copper – from 1.2 to 1.29 times, the concentration of lead – from 1.22 to 1.28 times and the concentration of cadmium – from 1.08 to 1.2 times. Key words: mushrooms, concentration, zinc, copper, lead, cadmium, distilled water, water without mineral residue, tap water, boiling of mushrooms.

Concrete for Precast Blocks: Binary and Ternary Combination of Sewage Sludge Ash with Diverse Mineral Residue.

This paper proposes binary and ternary combinations of sewage sludge ash (SSA) with fly ash (FA), marble dust (MD) and rice husk ash (RHA) as partial replacements of Portland cement in concretes with a similar dosage to that used in precast blocks, with very dry consistency. Several physical-mechanical tests were carried out on concrete specimens with curing ages of 28 and 90 days: density, water absorption, capillary water absorption, ultrasonic pulse velocity and compressive strength. The combinations of residues significantly improve the properties of the cementitious systems: 30% replacement of Portland cement provides strength values similar to the reference sample, showing the synergetic effects of the combination of the mineral additions. The significance of this research relies on the combined use of the mineral additions as well as the use of them for the precast block industry. The results show synergies among the additions and even that some of them showed relevant improvements when they are used in combination, performing better than when used individually.