MIL-101 Cr Metal-organic Framework Research Articles

Anion-exchanged and quaternary ammonium functionalized MIL-101-Cr metal-organic framework (MOF) for ReO4−/TcO4− sequestration from groundwater

There are few effective technologies for the sequestration of highly water-soluble pertechnetate (TcO4−) from contaminated water despite the urgency of environmental and public health concerns. In this work, anion exchanged and cetyltrimethylammonium bromide (CTAB) functionalized MIL-101-Cr-NO3 were investigated for perrhenate (ReO4−), a surrogate of TcO4−, sequestration from artificial groundwater. Cl−, I−, and CF3SO3− exchanged MIL-101-Cr proved more effective at ReO4− removal than the parent MIL-101-Cr-F. Compared to the parent framework, CTAB functionalized MIL-101-Cr-NO3 increased ReO4− removal capacity from 39 to 139 mg/g, improved the reaction kinetics from ~30 to <10 min to reach full adsorption capacity and the selectivity for ReO4− over competing NO3−, CO32−, SO42−, and Cl−. Spectroscopic data indicated that the chemical speciation of Re in the exchanged MIL-101-Cr remained ReO4−, indicating synergistic sequestration through both anion exchange and non-ion exchange binding with the positively charged ligand of CTAB. These studies foreshadow potential applications of MOFs for the remediation of 99TcO4− from contaminated environments.

Low grade heat driven adsorption system for cooling and power generation using advanced adsorbent materials

Globally there is abundance of low grade heat sources (around 150°C) from renewables like solar energy or from industrial waste heat. The exploitation of such low grade heat sources will reduce fossil fuel consumption and CO2 emissions. Adsorption technology offers the potential of using such low grade heat to generate cooling and power. In this work, the effect of using advanced adsorbent materials like AQSOA-Z02 (SAPO-34) zeolite and MIL101Cr Metal Organic Framework (MOF) at various operating conditions on power and cooling performance compared to that of commonly used silica-gel was investigated using water as refrigerant. A mathematical model for a two bed adsorption cooling cycle has been developed with the cycle modified to produce power by incorporating an expander between the desorber and the condenser. Results show that it is possible to produce power and cooling at the same time without affecting the cooling output. Results also show that for all adsorbents used as the heat source temperature increases, the cooling effect and power generated increase. As for increasing the cold bed temperature, this will decrease the cooling effect and power output except for SAPO-34 which shows slightly increasing trend of cooling and power output. As the condenser cooling temperature increases, the cooling effect and power output will decrease while for the chilled water temperature, the cooling load and power generated increased as the temperature increased. The maximum values of average specific power generation (SP), specific cooling power (SCP) and cycle efficiency are 73W/kgads, 681W/kgads (using SAPO-34) and 67% (using Silica-gel) respectively. However, MIL101Cr can generate SP and SCP of 95W/kgads and 1367W/kgads respectively, but this case cannot consider to be practical operating conditions, because of using relatively low cooling source temperature, but this material still offers potential of generating power.