Micro-supercapacitors Research Articles

All-solid-state flexible micro-supercapacitors with enhanced electrochemical performance obtained by hybridizing mxene with butterfly graphite

Abstract All-solid-state flexible micro-supercapacitors (MSCs) have the advantages of large energy storage capacity, small size, and good flexibility, which can be used as micro power sources. A 2D titanium carbide (MXene) has metallic conductivity, good hydrophility, and excellent processing properties, showing its great potential in flexible MSCs. However, the self-packing of MXene sheets hinders charge transfer and ion transport, limiting its electrochemical capacity. Herein, MSCs were prepared from a composite material of butterfly-like graphite (BTG) and MXene. BTG was inserted into the MXene layer to prevent its overs tacking, which promotes the diffusion of electrolytes and improves the electrochemical capacity of MSCs. As a result, MXene/BTG MSCs exhibit a large capacitance of 177.9 mF cm−2 at 5 mV s−1. In addition, the specific capacitance retention of MXene/BTG-30% MSCs can reach 80.4% in 0.1 -1 mA cm−2.

Photon-beam-inducing synthesis of a tunable porous graphene/Ti3C2T x heterostructure for energy conversion-storage system

Flexible electronic device requires a novel micro-supercapacitors (MSCs) energy conversion-storage system based on two-dimensional (2D) materials to solve the problems of stiffness and complexity. Herein, we report a novel catalytic introduction method of graphene with adjustable porosity by high-energy photon beam. The graphene/Ti3C2T x heterostructure was constructed by electrostatic self-assembly, has a high cycle life (98% after 8000 cycles), energy density (11.02 mWh cm−3), and demonstrate excellent flexible alternating current line-filtering performance. The phase angle of −79.8° at 120 Hz and a resistance-capacitance constant of 0.068 ms. Furthermore, the porous graphene/Ti3C2T x structures produced by multiple catalytic inductions allowed ions to deeply penetrate the electrode, thereby increasing the stacking density. The special ‘pore-layer nesting’ graphene structure with adjustable pores effectively increased the specific surface area, and its superior matching with electrolyte solutions greatly improved surface-active site utilization. This work offers an alternative strategy for fabricating a 2D heterostructure for an MSC.

Ultra-Wide Interlayered WxMo2xSy Alloy Electrode Patterning through High-Precision Controllable Photonic-Synthesis.

Ultra-thin 2D materials have great potential as electrodes for micro-supercapacitors (MSCs) because of their facile ion transport channels. Here, a high-precision controllable photonic-synthesis strategy that provided 1inch wafer-scale ultra-thin film arrays of alloyed WxMo2xSy with sulfur vacancies and expanded interlayer (13.2Å, twice of 2H MoS2) is reported. This strategy regulates the nucleation and growth of transition metal dichalcogenides (TMDs) on the picosecond or even femtosecond scale, which induces Mo-W alloying, interlayer expansion, and sulfur loss. Therefore, the diffusion barrier of WxMo2xSy is reduced, with charge transfer and ion diffusion enhancing. The as-prepared symmetric MSCs with the size of 100×100µm2 achieve ultrahigh specific capacitance (242.57mFcm-2 and 242567.83Fcm-3), and energy density (21.56Whcm-3 with power density of 485.13Wcm3). The established synthesis strategy fits numerous materials, which provides a universal method for the flexible synthesis of electrodes in microenergy devices.

All-printed 3-dimensional micro-supercapacitors with homogeneous Ag interface: Achieving precision on curved surfaces through Electrohydrodynamic jet printing

Despite advancements in manufacturing techniques for micro-supercapacitors (MSCs), significant challenges remain in achieving on-chip miniature devices that conform to complex surfaces, which is crucial for the seamless integration in advanced electronic systems. This study utilizes direct electrohydrodynamic (EHD) 3-dimensional (3D) printing to fabricate all-printed MSCs on planar and curved surfaces, employing Ag as a base material for both current collectors and electrodes to ensure homogeneous interfaces throughout the printed structures. Our approach uniquely manipulates the applied nozzle voltage in the EHD 3D printing process to achieve finely controlled and uniform 3D structures on both flat and curved surfaces. The high-precision EHD jet printer produces MSCs with notably narrow electrode linewidths of approximately 144μm. A 3D MSC cell is then fabricated with 15 EHD 3D-printed stacked layers to achieve a remarkable electrode-line height/width (h/w) ratio of 4.2, which exhibits exceptional electrical performance with an areal capacitance of 763.1 mF cm−2 and energy density of 256.6 μWh cm−2. Additionally, multiple MSCs are EHD 3D-printed on a curved substrate to successfully energize an LED. These findings verify that EHD 3D printing can be utilized to fabricate scalable energy storage devices that can be easily integrated with the next generation electronic systems.

In Operando Study of Microsupercapacitors with Gel Electrolytes Using Nano‐Beam Synchrotron X‐ray Diffraction

AbstractSynchrotron radiation X‐ray diffraction (XRD) with nanoscale beam size was used here for in situ and in operando study of micro‐supercapacitors (MSC) with gel electrolyte and MXene Ti3C2Tx electrodes. The electrode structure was characterized as a function of applied voltage and distance from the gap separating electrodes using microscopic cells with cylindrical shape designed for transmission mode XRD. The devices with gel electrolytes based on H2SO4 (with H2O/PVA and DMSO/PVA) showed stable performance with no changes in MXene structure under voltage swaps between positive and negative values. Experiments with KI‐based electrolytes demonstrated changes of MXene structure correlated with decrease of energy storage parameters under conditions of increased operation voltage starting from 0.8 V. The optimal performance of the MSCs was observed when the MXene structure remained unchanged upon switching the applied voltage polarity. The changes of inter‐layer distance of MXene upon swap of applied voltage correlate with decrease of device performance and are undesirable for stable operation of MSC's. We also tested feasibility of X‐ray fluorescence (XRF) for characterization of electrolyte ion migration in MSCs using 2D element mapping. Irreversible sorption of iodine by MXene was found using XRF mapping of charged electrodes using standard in‐plane MSC device and KI electrolyte.

Sputtered thin film deposited laser induced graphene based novel micro-supercapacitor device for energy storage application

Pioneering flexible micro-supercapacitors, designed for exceptional energy and power density, transcend conventional storage limitations. Interdigitated electrodes (IDEs) based on laser-induced graphene (LIG), augmented with metal-oxide modifiers, harness synergies with layered graphene to achieve superior capacitance. This study presents a novel one-step process for sputtered plasma deposition of HfO2, resulting in enhanced supercapacitance performance. Introducing LIG-HfO2 micro-supercapacitor (MSC) devices with varied oxygen flow rates further boosts supercapacitance performance by introducing oxygen functional groups. FESEM investigations demonstrate uniform coating of HfO2 on LIG fibers through sputtering. Specific capacitance measurements reveal 6.4 mF/cm2 at 5 mV/s and 4.5 mF/cm2 at a current density of 0.04 mA/cm2. The LIG-HfO2 devices exhibit outstanding supercapacitor performance, boasting at least a fourfold increase over pristine LIG. Moreover, stability testing indicates a high retention rate of 97% over 5000 cycles, ensuring practical real-time applications.

Chitosan Oligosaccharide Laser Lithograph: A Facile Route to Porous Graphene Electrodes for Flexible On-Chip Microsupercapacitors.

In this study, a convenient chitosan oligosaccharide laser lithograph (COSLL) technology was developed to fabricate laser-induced graphene (LIG) electrodes and flexible on-chip microsupercapacitors (MSCs). With a simple one-step CO2 laser, the pyrolysis of a chitosan oligosaccharide (COS) and in situ welding of the generated LIGs to engineering plastic substrates are achieved simultaneously. The resulting LIG products display a hierarchical porous architecture, excellent electrical conductivity (6.3 Ω sq-1), and superhydrophilic properties, making them ideal electrode materials for MSCs. The pyrolysis-welding coupled mechanism is deeply discussed through cross-sectional analyses and finite element simulations. The MSCs prepared by COSLL exhibit considerable areal capacitance of over 4 mF cm-2, which is comparable to that of the polyimide-LIG-based counterpart. COSLL is also compatible with complementary metal-oxide-semiconductor (CMOS) and micro-electro-mechanical system (MEMS) processes, enabling the fabrication of LIG/Au MSCs with comparable areal capacitance and lower internal resistance. Furthermore, the as-prepared MSCs demonstrate excellent mechanical robustness, long-cycle capability, and ease of series-parallel integration, benefiting their practical application in various scenarios. With the use of eco-friendly biomass carbon source and convenient process flowchart, the COSLL emerges as an attractive method for the fabrication of flexible LIG on-chip MSCs and various other advanced LIG devices.

Bifunctional polyoxometalate clusters-modified single-walled carbon nanotubes for high-energy–density micro-supercapacitors

The rapid advancement of wearable electronics has pushed the urgent demand for flexible power sources with high energy density and fast integrations. Herein, we created high-energy–density micro-supercapacitors (MSCs) based on phosphomolybdic acid (PMo12) clusters anchored single-walled carbon nanotubes (SWCNTs) via the electrostatic assembly. The SWCNT microelectrodes for MSCs were directly fabricated by an aerosol process without any solvent-based treatment. The PMo12 clusters were found to not only increase the electrical conductivity of SWCNT thin-film electrodes, but also offer significant pseudo-capacitance of MSCs. The MSCs based on PMo12-modified SWCNTs demonstrated an areal capacitance of 10.2 mF cm−2 when scanned at 5 mV s−1, coupled with a notable energy density of 0.71 μWh cm−2 at a power density of 7 μW cm−2, being much higher than the one without PMo12 modification. The density functional theory simulation further reveals the enhancement of electrical conductivity and areal capacitance induced by PMo12 modifications. Moreover, our strategy is highly scalable for integrations via series or parallel connections, which could deliver higher voltage output or areal capacitance. This work demonstrates great potential for high-performance MSCs toward wearable electronics applications.

A Fabric-Based Strain Sensor with a Microbridge Structure and the Supercapacitor-Powered Integrated Sensing System.

Developing fabric-based strain sensors with high sensitivity and stability is in high demand for wearable electronics. Herein, carbon nanotubes (CNTs) and polypyrrole (PPy) are coated on a thermoplastic polyurethane (TPU) fabric as strain sensors. A microbridge structure, in which CNT bridges the stretching-induced cracks, has been designed for the TPU-CNT-PPy strain sensor. The microbridge structure can significantly enhance the electrical resilience, ensuring the improved sensitivity and stability of strain sensors. As a result, our TPU-CNT-PPy strain sensors deliver high sensitivity (GF = 231.5) with a broad working range (150%) and fast response and recovery time (166/195 ms). In addition, our TPU-CNT-PPy could also be used as flexible electrodes of the microsupercapacitors (MSCs) as a power supplier for the integrated sensing system. The TPU-CNT-PPy-based MSCs exhibit a high specific capacitance (460.3 mF cm-2 at 0.5 mA cm-2) and excellent cycling stability (96.69% capacitance retention for 10,000 charge/discharge cycles). Finally, we demonstrated an integrated sensing system using TPU-CNT-PPy as both MSCs and strain sensors, where the current signals of the sensors could be well detected via Bluetooth. This study offers a microbridge strategy to fabricate strain sensors with high sensitivity and stability and develops an integrated sensing system for the actual applications of wearable electronics.

Printing pillar array structure of electrodes facilitating ion diffusion and electron transport for high-performance asymmetric microsupercapacitors

The asymmetric microsupercapacitors (MSCs) are appealing power sources for miniaturized electronic devices owing to their high capacitance and wider working voltage window. However, the sluggish ion diffusion and poor electron transport in pseudocapacitive electrodes result in confined electrochemical performance of devices. In this work, we propose the pillar array structure of electrodes via 3D printing V2O5 (VN) nanosheets and graphene composite inks to boost the electrochemical performance of asymmetric MSCs. The V2O5 (VN) nanosheets and graphene sandwich each other can deliver a high electrical conductivity. The pillar array structure of electrodes shortens ion diffusion pathway to endow the electrodes with fast kinetics. The asymmetric MSCs achieve an impressive energy density of 44.86 μWh cm−2 and power density of 1.78 mW cm−2, powering a pressure sensor for 20 000 s. This strategy developed here is very helpful to promote the practical applications of MSCs.

High-voltage (> 3 V) energy storage device based on sputter-grown TiCrN microelectrodes towards miniaturized applications

In this work, we report sputter-grown micro-patterns of titanium chromium-based bimetallic nitride (TiCrN) over Si/SiO2 substrate. The highly stable TiCrN-micro pattern is tested electrochemically and used to construct an efficient microsupercapacitor (MSC) device. To achieve a stable and high-voltage window, a non-aqueous gel polymer electrolyte (GPE) of TEABF4/EC/PC/PVDF is optimized. At room temperature, the GPE exhibits high ionic conductivity of ~10.58 mS cm−1 with exceptional mechanical stability. A symmetric supercapacitor based on TiCrN sandwich structure (TiCrN-SS) is fabricated with TEABF4 GPE for practical application. The TiCrN-SS device works on a high voltage of 3.1 V and exhibits good electrochemical properties. The device shows a high energy density of 1.9 μWh cm−2 (5.9 Wh kg−1) at a power density of 109 μW cm−2 (0.34 kW kg−1). To utilize the excellent performance of TiCrN-SS as a miniaturized power source, an on-chip MSC is subsequently fabricated by patterning planar interdigitated TiCrN-microelectrodes. The constructed on-chip TiCrN microsupercapacitor (TiCrN-MSC) works on a wide voltage window of 0–3.1 V while maintaining an optimum areal capacitance of ~500 μF cm−2 at 0.07 mA cm−2 current density. The device exhibits an areal energy density of ~0.7 μWh cm−2 with an optimum 169.02 μW cm−2 power density. This remarkable electrochemical performance and exceptionally wide voltage window of TiCrN-based MSC makes it a potential candidate for direct use as a miniaturized power source in microelectronic devices.

High Capacitance Porous Ruthenium Nitride Films with High Rate Capability for Micro-Supercapacitors.

The demand for high-performance energy storage devices to power Internet of Things applications has driven intensive research on micro-supercapacitors (MSCs). In this study, RuN films made by magnetron sputtering as an efficient electrode material for MSCs are investigated. The sputtering parameters are carefully studied in order to maximize film porosity while maintaining high electrical conductivity, enabling a fast charging process. Using a combination of advanced techniques, the relationships among the morphology, structure, and electrochemical properties of the RuN films are investigated. The films are shown to have a complex structure containing a mixture of crystallized Ru and RuN phases with an amorphous oxide layer. The combination of high electrical conductivity and pseudocapacitive charge storage properties enabled a 16µm-thick RuN film to achieve a capacitance value of 0.8Fcm-2 in 1m KOH with ultra-high rate capability.

Stable 3D porous N-MXene/NiCo2S4 network with Ni–O atomic bridging for printed hybrid micro-supercapacitors

The vision of “Internet of Everything” marked by wearable and multi-functional microelectronics technology has a profound impact on our lives, and the requirements for micro-supercapacitors (MSCs) are also constantly increasing. Compared to traditional super capacitors, there is still a lack of systematic investigation on regulating the morphology and internal structure of microelectrodes. Herein, we achieved the inkjet printing of intricate structures, a novel 3D N-MXene/NiCo2S4 porous network, and applied it to long-life hybrid MSCs. A new bridging mechanism of Ni atoms and O atoms is demonstrated by XPS. DFT calculations reveal that the O atoms of N-MXene can capture electrons from Ni atoms of NiCo2S4, resulting in charge redistribution in the interfacial region of 3D N-MXene/NiCo2S4, thereby realizing enhanced structural stability of the composite material. Due to the gradual release of active sites within the porous network, its capacitance retention rate can be as high as 99.1 % after 25,000 charge and discharge tests. With a wide voltage window of 1.6 V, a volumetric capacitance of 983.9 F cm−3, and an energy density of 342.4 mWh cm−3, the MSCs perform better than previously reported inkjet-printed MSCs. Our work demonstrates a new strategy to regulate the surface morphology and internal structure of the microelectrodes by high-precision inkjet printing to improve the performance of the MSCs.

Printed flexible solid-state microsupercapacitor with highly-stable aqueous cobalt-based inks

Cobalt-based nanomaterials are among the most noticed candidates for manufacturing supercapacitive electrodes. Inkjet-printing is an emerging technique for fabricating miniaturized devices. In this work, highly flexible microsupercapacitors (MSCs) are manufactured, using a pseudocapacitive (C = 900 F‌ g−1 at 1 A g−1) Co-oxide-hydroxide water-based and ultra-stable (up to 12 months) ink on paper. The synthesized capacitive active material consists of cobalt-oxide nanocubes and cobalt-hydroxide hexagonal nanoflakes. Conductive (Rs = 13 Ω/□) silver nanowire networks serve as current collectors, and the morphology of cobalt oxide-hydroxide structures and the developed ink features, allow for printing well-detailed and homogeneous patterns. The inkjet-printed symmetric and asymmetric devices show notable areal specific capacitances of 35.68 mF cm−2 and 23.60 mF cm−2 at a current density of 0.1 mA cm−2, respectively. The asymmetric devices deliver impressive energy and power densities of 2.76 μW h cm−2 (4.10 W h kg−1) and 646 μW cm−2 (959 W kg−1), respectively. A thorough study on the cyclic and mechanical stability of the flexible devices resulted in perfect capacitance maintenance of 94.3 % after 10,000 charge and discharge cycles and retention of over 80 % even after 1000 cycles of successive bending and folding. The extensive study of capacitance retention following folding under various obtuse and reflex angles, which can be regarded as an important step toward characterizing flexible devices suitable for being utilized in wearable electronics, is carried out for the first time to the best of our knowledge. The findings of this study clearly illustrate the prospects of using the inkjet-printing technique to fabricate high-performance MSC devices appropriate for integration with flexible and wearable electronics.

Unlocking Maximum Synergy: Screen-Printing Fabrication of Heterostructured Microsupercapacitor Stacks.

A cost-effective and scalable approach for the fabrication of heterostructured microsupercapacitors (MSCs) employing screen-printing followed by sequential electrochemical and microspray deposition techniques has been demonstrated. The microsupercapacitor electrode (MSC) that composed of stacked layers of mesoporous carbon, polyaniline (PANI), and MXene hold significant promise for wearable electronics. By adjusting the deposition and spray cycles, the MSC can be readily coated with PANI and MXene. The sequentially stacked two layers of MXene and PANI on the mesoporous carbon spheres (PMPM-MSC) yielded a specific capacitance of 1003 mF cm-2 at 0.5mA cm-2, surpassing the performance of PANI/mesoporous carbon electrode by 1.6 times (771 mF cm-2). After 10,000 cycles of charge and discharge, PMPM-MSCs retained more than 86% of their initial capacitance. In-situ Raman spectroscopy confirmedthe synergistic effects between MXene and PANI within the heterostructured stacked PMPM-MSC electrodes, including enhanced electronic conductivity and improved electrolyte ion dissociation, which aligned with the electrochemical measurement results, such as fast charge/discharge rates and reduced internal and mass transport resistance. This study demonstrates the potential of screen-printed heterostructured MSC stacks with maximum electrochemical synergy for portable and wearable energy storage devices.

Green Fabrication of Stackable Laser‐Induced Graphene Micro‐Supercapacitors under Ambient Conditions: Toward the Design of Truly Sustainable Technological Platforms

AbstractExtensive research into green technologies is driven by the worldwide push for eco‐friendly materials and energy solutions. The focus is on synergies that prioritize sustainability and environmental benefits. This study explores the potential of abundant, non‐toxic, and sustainable resources such as paper, lignin‐enriched paper, and cork for producing laser‐induced graphene (LIG) supercapacitor electrodes with improved capacitance. A single‐step methodology using a CO2 laser system is developed for fabricating these electrodes under ambient conditions, providing an environmentally friendly alternative to conventional carbon sources. The resulting green micro‐supercapacitors (MSCs) achieve impressive areal capacitance (≈7–10 mF cm−2) and power and energy densities (≈4 μW cm‐2 and ≈0.77 µWh cm−2 at 0.01 mA cm−2). Stability tests conducted over 5000 charge–discharge cycles demonstrate a capacitance retention of ≈80–85%, highlighting the device durability. These LIG‐based devices offer versatility, allowing voltage output adjustment through stacked and sandwich MSCs configurations (parallel or series), suitable for various large‐scale applications. This study demonstrates that it is possible to create high‐quality energy storage devices based on biodegradable materials. This development can lead to progress in renewable energy and off‐grid technology, as well as a reduction in electronic waste.

Direct laser writing of MnOx decorated laser-induced graphene on paper for sustainable microsupercapacitor fabrication

Laser-induced graphene (LIG) on paper is a popular choice for fabricating flexible micro-supercapacitors (MSCs) as it is a simple and sustainable process. However, carbon-based MSC electrodes have limited energy densities. To address this challenge, this study presents a highly reproducible and cost-effective method for decorating manganese oxide (MnOx) on interdigital LIG MSC electrodes, fabricated via a single-step direct laser writing (DLW) process on paper substrates. The paper fibers embedded with MnOx precursors are transformed into graphene through laser processing while reducing the salt, resulting in the formation of MnOx-LIG. The resulting MnOx-LIG-MSC exhibits a specific capacitance of 12.30 mF cm−2 (0.05 mA cm−2) with a 60 % retention at 1000 bending cycles (30°), due to the pseudocapacitive contribution of MnOx. Furthermore, the devices exhibit high electrochemical stability, retaining 190 % of the initial specific capacitance after 10,000 cycles, and a high energy density of 2.6 μWh cm−2 (at a power of 0.109 mW cm−2). The study demonstrates that manganese oxide-based LIG-MSCs have the potential to be used as energy storage devices for portable, low-cost, and flexible paper electronics.

Laser-induced fabrication of porous graphene for flexible planar microsupercapacitors with wide voltage window

Herein, laser-induced graphene (LIG) derived from polyimide (PI) is demonstrated to construct a flexible planar interdigital microsupercapacitors (MSCs) device with wide voltage window through simple laser-direct-writing method. The mechanism study of LIG derived from PI show that the photon energy of the laser is absorbed by the electrons and converted into heat energy, and the rapid energy accumulation produces extremely high temperatures leading to the graphitization of PI film. At the same time, the internal expansion and gas escape from the interior, the graphitized carbon material grows upward, resulting in the formation of porous graphene. As a demonstration of the supercapacitor application, the as-prepared LIG MSCs device show excellent supercapacitance performance, wide voltage window (0–1.8 V) and good mechanical flexibility. When the laser power is 2.75 W, that is, 50 % of the maximum power, the resulting LIG MSCs device has a high specific capacitance of 20.85 mF cm−2, a maximum energy density of 9.38 μWh cm−2, and good cycle stability with a capacitance retention rate of 101.09 % after 15,000 cycles. This work provides a simple method to prepare graphene-based MSCs and demonstrates great potential of the LIG MSCs in flexible wearable electronic devices.

Centrifugal-Gravity-Enforced Deposition of MXene Electrodes for High-Performance and Ultrastable Microsupercapacitors.

Two-dimensional (2D) transition metal carbides, known as MXenes, have captured much attention for their excellent electrical conductivity and electrochemical capability. However, the susceptibility of MXenes to oxidation, particularly Ti3C2Tx transforming into titanium dioxide upon exposure to ambient air, hinders their utilization for extended operational life cycles. This work introduces a simple and straightforward method for producing ultrathin MXene electrode films tailored for energy storage applications, employing centrifugal-gravity force. Our approach significantly suppresses the oxidation phenomenon that arises in MXene materials and also effectively prevents the recrystallization of potentially residual LiF during the film formation. Additionally, the utilization of this MXene electrode in an all-solid-state microsupercapacitor (MSC) with an interdigitated pattern demonstrates an exceptionally improved and stable electrochemical performance. This includes a high volumetric capacitance of approximately 467 F cm-3, an energy density of around 65 mWh cm-3, and impressive long-term cycle stability, retaining about 94% capacity after 10 000 cycles. Moreover, a downsized MSC device exhibits remarkable mechanical durability, retaining over 98% capacity even when folded and sustaining stability over extended periods. Therefore, we believe that this study provides valuable insights for advancing highly integrated energy storage devices, ensuring exceptional electrochemical efficiency and prolonged functionality in diverse environments, whether ambient or humid.

Manufacturing Shape-Controllable Flexible PEDOT/rGO Composite Electrodes for Planar Micro-Supercapacitors.

Flexible electronic products, with their characteristics of flexibility and wearability, have attracted significant attention and have become an important direction in the research and development of the electronics industry. Planar micro-supercapacitors (MSCs) with flexible composite electrodes can provide reliable energy support for these products, propelling their further development. The research employed a quick, effective, and environmentally friendly method of laser scribing to create shape-controllable flexible composite electrodes on composite films of Poly(3,4-ethylenedioxythiophene) and graphene oxide (PEDOT/GO), which were subsequently assembled into MSCs. An analysis of the composite electrode morphology, structure, and elemental distribution was conducted through the utilization of SEM, TEM, and XPS techniques. Following this, a comprehensive evaluation of the electrochemical performance of the flexible MSCs was carried out, which included cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and assessment of cyclic stability. The analysis of the CV results indicated that the MSCs achieved the areal capacitance of 5.78 mF/cm2 at 5 mV/s. After 5000 cycles at a current density of 0.05 mA/cm2, the capacitance retention rate was 85.4%. The high areal capacitance and strong cycle stability of MSCs highlight the potential of PEDOT/reduced graphene oxide (PEDOT/rGO) electrodes in electrode applications.