Metamorphic Zircon Research Articles

Magmatic and metamorphic evolution of a layered gabbro-anorthosite complex from the Coorg Block, southern India: Implications for Mesoarchean suprasubduction zone process

As one of the oldest crustal blocks in Southern Peninsular India, the Coorg Block has been the focus of investigations related to crustal evolution in the early history of the Earth with implications on Mesoarchean plate tectonic processes. The Coorg Block is dominantly composed of arc magmatic rocks and bordered on the north by the Mercara Suture Zone, a Mesoproterozoic subduction-collision zone hosting extruded high-pressure and ultra-high temperature metapelitic and meta-mafic rocks. Here, we report the occurrence of a dismembered gabbro-anorthosite complex corresponding to a layered intrusion from the northern margin of the Coorg Block. We present results from an integrated study on the petrology, mineral chemistry, P-T phase equilibria, whole-rock geochemistry, and zircon and monazite U–Pb geochronology to understand the magmatic and metamorphic evolution of the layered intrusion and associated rocks. The geochemical data suggest that the parental magma was generated within a suprasubduction zone setting. Phase equilibrium modelling of garnet-bearing metagabbro from the Coorg Block suggests metamorphic P–T range of 10.5–11 kbar at 1000–1100 °C corresponding to ultra-high temperature conditions. The zircon U-Pb data from the various rock types of the mafic–ultramafic suite yield weighted mean ages at 3176 Ma, 3174 Ma, 3143 Ma, and 3124 Ma whereas the associated charnockite shows a slightly older age of 3319 ± 12 Ma. Metamorphic zircon from charnockite yield an age of 3101 Ma, close to the monazite age of 3110 ± 24 Ma from the same rock, constraining the timing of metamorphism as Mesoarchean, and marking the collisional event between the Coorg Block and the Dharwar Craton along the Mercara Suture Zone. We propose a tectonic model involving southward subduction of the Western Dharwar Block beneath the northern margin of the Coorg Block that can explain the extensive arc magmatism and suprasubduction zone rock suites, followed by ocean closure and collision along the Mercara Suture Zone, accompanied by high P-T metamorphism.

Metamorphic PT path, U-Pb zircon dating and tectonic implications of High-pressure Pelitic Granulites from the Kharta region, Southern Tibet, China

HP pelitic granulites associated with eclogites from the Kharta Gneiss are found in the Thongmön area, central Himalaya, which provides significant constraints for the tectonic evolution of the Himalayan orogeny. Three generations of garnets are identified in pelitic granulites (DR15P15). The first generation of garnet is core sections of euhedral to subhedral porphyroblasts (Grt-I core) followed by growth of Grt-I mantle during the heating stage. The third generation of garnet is represented by thin rims of Grt-I and small grains (Grt-II) in the matrix, which likely nucleated and grew in response to peritectic reaction during exhumation. Petrographic evidence and P–T pseudosection calculation reveal a four-stages metamorphic evolution: 1) a prograde metamorphic stage (M1) represented by Grt-I core and its mineral inclusions rutile, ilmenite and quartz with metamorphic conditions of 740–760 °C and 13–16 kbar; 2) a near isobaric heating stage with slightly decompression to HP granulite-facies (M2, 820–840 °C, 13–14 kbar) indicated by the composition of Grt-I mantle and the increase of Zr concentrations of rutile in it; 3) a heating decompression stage (M3) supported by a decrease in grossular content in the Grt-I rim and higher XAn in plagioclase, yielding T > 860 °C and P = 10–11 kbar in the sillimanite stability field; 4) a final decompression stage followed by cooling (M4, T ~ 800 °C and P = 6–8 kbar) indicated by biotite replacing sillimanite and lower Ti content in biotite in the matrix. Based on the zircon trace element geochemistry, zircon inclusions, and the REE partitioning between garnet and zircon, the metamorphic zircon rims with middle Miocene age (16–13 Ma) probably grew during Grt-I rim/Grt-II formation at granulite facies stage (M3). The P–T history of the pelitic granulites of the Kharta Gneiss indicates that they were subducted beneath the Asian plate and exhumed to middle-lower crustal depths prior to 14–13 Ma due to the activity of STDS.

Bulk inclusion micro‐zircon U–Pb geochronology: A new tool to date low‐grade metamorphism

AbstractDating low‐grade metamorphism is challenging since such rocks commonly lack suitable target minerals for acquiring pressure–temperature–time–deformation (P–T–t–d) data. Herein a new geochronological method termed ‘bulk inclusion dating’ is applied to a chloritoid‐bearing schist from the Staufen‐Höllengebirge Nappe (SHN, Austroalpine Unit, Eastern Alps, Austria) for which Cretaceous metamorphism is imprecisely constrained. Thermodynamic modelling of the phase relations and mineral chemistry predicts the stability of the equilibrium assemblage in a P–T field between 450–490℃ and 0.5–0.7 GPa, which agrees with peak temperature constraints ~490℃ derived from Raman spectroscopy of carbonaceous material. Chemical zoning of, and the zonation of inclusions within, chloritoid confirm porphyroblast growth at these conditions. High‐resolution imaging reveals thousands of minute (length: 0.1–3 µm), euhedral micro‐zircon crystals included in chloritoid porphyroblasts and in the matrix. The morphological and microstructural characteristics of micro‐zircon as well as the crystal size distributions indicate that it nucleated and grew at greenschist facies conditions most likely from a Zr‐saturated fluid. In situ laser ablation inductively coupled plasma mass spectroscopy bulk inclusion dating of metamorphic zircon in the chloritoid rim using a laser spot diameter of 120 μm yields a U–Pb age of 116.7 ± 9.1 Ma (MSWD: 1.5, n: 79). We interpret zircon precipitation and progressive coarsening coeval with chloritoid growth during prograde metamorphism and thus link the age to the late prograde part of the P–T evolution. The contribution of other U‐bearing phases (apatite, epidote, rutile) does not significantly disturb the U–Pb age. The data provide clear evidence for Early Cretaceous metamorphism in the SHN and indicates that metamorphism started at least 20 m.y. before the formation of eclogites in the Austroalpine Unit. The method introduced here allows integration between metamorphic conditions and age constraints in low‐grade metamorphic rocks and opens up new potential applications in petrochronology.

Petrogenesis and tectonic significance of Neoarchean (~2.6 Ga) alkaline ultrapotassic granitic gneisses from the southeastern margin of the North China Craton: Constraints from U-Pb dating, Hf isotope and petrogeochemistry

The Wuhe complex (WC), exposed at the southeastern margin of the North China Craton (NCC), is an important constituent of the Eastern Block of the NCC. In order to better understand the Precambrian crustal composition and evolution of this region, a comprehensive investigation on zircon geochronology and Hf isotopes, as well as whole-rock geochemistry and Sr-Nd-Pb isotopes was conducted on alkaline ultrapotassic granitic gneisses from the WC at Mashan. These gneisses are considered as meta-igneous rocks based on geochemical and mineralogical criteria (with special reference to zircon cathodoluminescence images). They are characterized by modally abundant alkali feldspar (more than 60%) and quartz (more than 30%) while plagioclase is rare. Mafic minerals are sodic amphiboles such as arfvedsonite and eckermannite, aegirine and rare biotite. Minor constituents are rutile, muscovite, apatite and barite. Major elements geochemistry shows high SiO2 (69.85%–74.51%) and K2O + Na2O (9.67%–12.17%) contents, high K2O/Na2O (7.41–22.53) ratios, and relatively low MgO (0.37%–0.87%) and CaO (0.10%–0.23%) contents. Trace elements geochemistry shows significant depletions of Nb, Y, Ce, Ga, and REE (rare earth elements) relative to anorogenic granites. These features suggest that the magmatic protoliths of the studied gneisses belong to ultrapotassic silica-saturated alkaline series from an extensional background, perhaps in a subduction-related rifting environment. As concerning isotope geochemistry, their 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios are 16.6297–17.1877, 15.4454–15.5066, and 36.6036–38.0304, respectively, and εNd(t) values vary from −1.7 to +9.1. Two samples yielded zircon 207Pb/206Pb ages of 2615 ± 4 Ma and 2617 ± 5 Ma, respectively, representing their precursor ages. The zircon igneous core domains exhibit oscillatory growth zoning with positive εHf (t) values (+2.5 − +6.6). These data, coupled with chondrite-normalized and primitive-mantle-normalized element patterns, suggest that the precursors of the studied granitic gneisses were mainly derived from a subduction-modified ultrapotassic syenitic parental magma, and may be considered as a particular group of A-type granites, involved in an important crustal growth and reworking event at ~2.6 Ga. These rocks experienced a granulite-facies metamorphic stage accompanied by partial melting, as testified by clinopyroxene + rutile + K-feldspar + spinel + quartz + apatite inclusions in zircon metamorphic domains which were dated at ~2.5 Ga. The occurrence of this metamorphic stage is also supported by the lower ΣREE contents, negative Eu anomalies, and high Ti-in-zircon temperatures (>800 °C) of metamorphic zircon mantles dated at ~2.5 Ga. Eventually, the studied rocks suffered a later ~1.85 Ga metamorphic overprinting, possibly related to the Paleoproterozoic collisional orogeny recorded in the region.

Age and tectonic setting of the Quinebaug-Marlboro belt and implications for the history of Ganderian crustal fragments in southeastern New England, USA

Abstract Crustal fragments underlain by high-grade rocks represent a challenge to plate reconstructions, and integrated mapping, geochronology, and geochemistry enable the unravelling of the temporal and spatial history of exotic crustal blocks. The Quinebaug-Marlboro belt (QMB) is an enigmatic fragment on the trailing edge of the peri-Gondwanan Ganderian margin of southeastern New England. SHRIMP U-Pb geochronology and geochemistry indicate the presence of Ediacaran to Cambrian metamorphosed volcanic and intrusive rocks dated for the first time between ca. 540–500 Ma. The entire belt may preserve a cryptic, internal stratigraphy that is truncated by subsequent faulting. Detrital zircons from metapelite in the overlying Nashoba and Tatnic Hill Formations indicate deposition between ca. 485–435 Ma, with provenance from the underlying QMB or Ganderian crust. The Preston Gabbro (418 ± 3 Ma) provides a minimum age for the QMB. Mafic rocks are tholeiitic with trace elements that resemble arc and E-MORB sources, and samples with negative Nb-Ta anomalies are similar to arc-like rocks, but others show no negative Nb-Ta anomaly and are similar to rocks from E-MORB to OIB or backarc settings. Geochemistry points to a mixture of sources that include both mantle and continental crust. Metamorphic zircon, monazite, and titanite ages range from 400 to 305 Ma and intrusion of granitoids and migmatization occurred between 410 and 325 Ma. Age and chemistry support correlations with the Ellsworth terrane in Maine and the Penobscot arc and backarc system in Maritime Canada. The arc-rifting zone where the Mariana arc and the Mariana backarc basin converge is a possible modern analog.

Geochronology, petrography and Sr-Nd-Hf isotopes of Mbalizi carbonatite, southwestern Tanzania

The Mbalizi carbonatite is located in the middle of the Paleoproterozoic Ubendian Mobile Belt and the western branch of East Africa Rift, southwestern Tanzania. Calcite, dolomite, phlogopite, pyrochlore and apatite are found in the sample. Mineral chemistry studies have shown that the carbonatite phlogopite is linked to mantle-derived magmatism. The apatite is fluorapatite, means they are of magmatic origin. The analyses on two crystals of pyrochlore show high concentrations of Nb2O5, and therefore the Nb-oxide is classified as pyrochlore subspecies. Three types of zircon have been obtained from the Mbalizi carbonatite, including xenocrysts zircon, igneous zircon and metamorphic zircon. Zircon in-situ LA-ICP-MS U–Pb dating in this contribution indicates that the Mbalizi carbonatite was crystallized at ca. 116.0 ± 1.8 Ma. The εHf(t) values of igneous zircon ranging from −13.9 to +5.7, indicates that the carbonatite parental magma was originated from the sub-continental lithospheric mantle, and evolves toward HIMU and EM. The whole-rock Sr–Nd isotopic data suggest more contribution of the HIMU and EMⅠ material. We propose that the complex evolutionary history of the Ubendian Mobile Belt has stored the subduction oceanic crust which has the EMⅠ and HIMU components, forming the compositional heterogeneity mantle beneath the Ubendian Mobile Belt. At 116.0 ± 1.8 Ma, with the extension stress field, deep faults cause the pressure reduction, resulting in reactive of the upwelling of the HIMU and EMⅠ components. This provides the metamorphic conditions to induce the isotopic resetting and may result in large scatter of initial 176Hf/177Hf ratios of carbonatite melts.

Zircon U–Pb Dating and Lu-Hf Isotope of the Retrograded Eclogite from Chicheng, Northern Hebei Province, China

We report zircon U–Pb ages and Lu-Hf isotopic data from two sample of the retrograded eclogite in the Chicheng area. Two groups of the metamorphic zircons from the Chicheng retrograded eclogite were identified: group one shows characteristics of depletion in LREE and flat in HREE curves and exhibit no significant Eu anomaly, and this may imply that they may form under eclogite facies metamorphic condition; group two is rich in HREE and shows slight negative Eu anomaly indicated that they may form under amphibolite facies metamorphic condition. Zircon Lu-Hf isotopic of εHf from the Chicheng eclogite has larger span range from 6.0 to 18.0, which suggests that the magma of the eclogite protolith may be mixed with partial crustal components. The peak eclogite facies metamorphism of Chicheng eclogite may occur at 348.5–344.2 Ma and its retrograde metamorphism of amphibolite fancies may occur at ca. 325.0 Ma. The Hongqiyingzi Complex may experience multistage metamorphic events mainly including Late Archean (2494–2448 Ma), Late Paleoproterozoic (1900–1734 Ma, peak age = 1824.6 Ma), and Phanerozoic (495–234 Ma, peak age = 323.7 Ma). Thus, the metamorphic event (348.5–325 Ma) of the Chicheng eclogite is in accordance with the Phanerozoic metamorphic event of the Hongqiyingzi Complex. The eclogite facies metamorphic age of the eclogite is in accordance with the metamorphism (granulite facies or amphibolite facies) of its surrounding rocks, which implied that the tectonic subduction and exhumation of the retrograded eclogite may cause the regional metamorphism of garnet biotite plagioclase gneiss.

U–Pb detrital zircon dating applied to metavolcano-sedimentary complexes of the São Gabriel Terrane: New constraints on the evolution of the Dom Feliciano Belt

The Tonian to Cryogenian São Gabriel Terrane located at the northwestern portion of Dom Feliciano Belt, in southern Brazil, provides sedimentation and magmatism records associated with the Rodinia supercontinent and its subsequent deformation and metamorphism during the West Gondwana assembly. It is composed by a succession of arc-related associations including metavolcano-sedimentary and orthogneisses complexes, accretionary prism associations with mafic-ultramafic complexes (ophiolites) and passive margin metasedimentary associations. New U–Pb analyses by LA-ICPMS on detrital zircon from the supracrustal metamorphic complexes in its type-area indicate two distinct times of deposition, sources and tectonic settings. Arc-related complexes occur as parallel bodies interleaved with the metaplutonic associations- of the Passinho (0.9–0.85 Ga) and São Gabriel (0.78–0.72 Ga) arcs. These complexes have detrital zircon data ranging between 0.94 and 0.70 Ga and depositional age constrained at 0.68 Ga. Passive margin complexes constitute a long and continuous belt located at the eastern and southern borders of the São Gabriel Terrane and were deposited over the Paleoproterozoic basement. These complexes show a wide range of detrital zircon ages, between 3.6–1.62 Ga, and a maximum depositional age of 1.58 Ga. The regional mixed sources and the geological context are consistent with accumulation in a passive margin basin situated on the border of an ancient continental plate represented by the Rio de la Plata Craton. Metamorphic zircon overgrowths indicate that the arc-related complexes were accreted during a Cryogenian (0.71–0.70 Ga) collisional event. The contact between the São Gabriel Terrane and the Paleoproterozoic basement units located to the east and south is tectonic. The distinct geological and geophysical features of this boundary characterize it as a suture zone and emphasize its allochthonous and exotic character.

Petrogenesis and tectonic implications of TTG granitoids from the Daqingshan Complex of the Khondalite Belt, North China Craton

Located in the Western Block of the North China Craton, the Khondalite Belt is one of the three Paleoproterozoic tectonic belts that were linked to the final assembly of the craton. At present, a popular model is that the Khondalite Belt was formed by the collision between the Yinshan and Ordos blocks at ∼1.95 Ga. However, the initiation of oceanic subduction and its related arc magmatism and accretionary process before the collisional event were poorly constrained. The Daqingshan Complex is located in the middle East part of the Khondalite Belt, and contains highly deformed and metamorphosed rock assemblages, and thus represents a key area to decipher the above issue. In this study, we carried out petrological, geochemical and geochronological analysis on the TTG granitoids of the Daqingshan Complex. Zircon U-Pb results from three typical TTG samples yielded upper intercept ages of 2545 ± 50 Ma, 2484 ± 68 Ma and 2452 ± 32 Ma, indicating that the TTG granitoids were emplaced in the late Neoarchean. Metamorphic zircons from two samples gave ²⁰⁷Pb/²⁰⁶Pb weighted mean ages of 1892 ± 53 Ma and 1906 ± 27 Ma, respectively, recording the timing of a continent-to-continent collisional event. Thirteen TTG granitoid samples are geochemically low-, medium- and high-K calc-alkaline, with metaluminous to peraluminous trends and are enriched in large-ion lithophile elements (LILEs) such as Rb, Ba, La, Ce, Nd, and depleted in high field strength elements (HFSEs) such as Nb and Ta. Chondrite-normalized rare earth element (REE) patterns show fractionation with (La/Yb) _N ratios ranging from 8.20 to 27.47, with weak Eu negative anomalies (δEu = 0.50 – 0.98). In addition, TTG granitoids of the Daqingshan Complex belong to I-type granitoids, and their igneous protoliths were intimately related to a subduction-related magmatic arc environment. New results of this study reveal that the initial oceanic lithosphere subduction operated since ∼2.55 Ga along the southern margin of the Yinshan Block, and generated the coeval arc-related TTG granitoids. Closure of the ocean led to the final collision between the Yinshan and Ordos blocks and the amalgamation of the Western Block at 1.95 to 1.85 Ga.

U–Pb Dating of Apatite, Titanite and Zircon of the Kingash Mafic–Ultramafic Massif, Kan Terrane, Siberia: from Rodinia Break-up to the Reunion with the Siberian Craton

Abstract The initial stage of Rodinia supercontinent break-up occurred at about 750 Ma. It preceded formation of the Irkutsk and Franklin large igneous provinces (LIPs) at 712 ± 2 to 739 ± 8 Ma. These LIPs were emplaced within the formerly connected Laurentian and Siberian cratons. The Kingash massif is located in the Precambrian Kan terrane in direct contact with the Siberian Craton at its southwestern boundary. It has been linked to an important suite of mafic–ultramafic intrusions that border the southern margin of the Siberian craton, and that have been inferred to belong to the Irkutsk LIP. The massif is also significant, because it hosts platinum group element (PGE)–Cu–Ni-rich mineralization and is the only large deposit in the region. However, despite numerous dating attempts, the age of the massif had not been resolved. A significant difficulty is post-magmatic recrystallization at amphibolite facies that affected the rocks of the massif. In this study we used U–Pb dating of zircon, titanite and apatite from rocks of the Kingash massif and cross-cutting granite and monzonite veins. The oldest igneous zircon grain of the Kingash massif analysed by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) yields an age of c. 750 Ma, taken as a tentative age of magmatism. Dating of multiple grains of metamorphic zircon by chemical abrasion isotope dilution thermal ionization mass spectrometry yielded 564·8 ± 2·2 Ma, which is in agreement with LA-ICP-MS titanite ages of 557 ± 19, 565 ± 35 and 551 ± 17 Ma. Apatite of two different samples showed ages of 496·4 ± 7·9 and 497·0 ± 1·8 Ma (LA-ICP-MS), which are interpreted as the time when the terrane cooled below the closure temperature of apatite. Using our new data we suggest that at the time of the Irkutsk–Franklin LIP event the Kan terrane was a part of Rodinia, then it separated from either Siberia or Laurentia during the break-up of Rodinia and finally collided with Siberia at 560 Ma, the time of regional amphibole-facies metamorphism.

Regional zircon U-Pb geochronology for the Maniitsoq region, southwest Greenland

Zircon U-Pb geochronology places high-temperature geological events into temporal context. Here, we present a comprehensive zircon U-Pb geochronology dataset for the Meso- to Neoarchean Maniitsoq region in southwest Greenland, which includes the Akia Terrane, Tuno Terrane, and the intervening Alanngua Complex. The magmatic and metamorphic processes recorded in these terranes straddle a key change-point in early Earth geodynamics. This dataset comprises zircon U-Pb ages for 121 samples, including 46 that are newly dated. A principal crystallization peak occurs across all three terranes at ca. 3000 Ma, with subordinate crystallization age peaks at 3200 Ma (Akia Terrane and Alanngua Complex only), 2720 Ma and 2540 Ma. Metamorphic age peaks occur at 2990 Ma, 2820–2700 Ma, 2670–2600 Ma and 2540 Ma. Except for one sample, all dated metamorphic zircon growth after the Neoarchean occurred in the Alanngua Complex or within 20 km of its boundaries. This U-Pb dataset provides an important resource for addressing Earth Science topics as diverse as crustal evolution, fluid–rock interaction and mineral deposit genesis.

U-Pb-Hf isotopic systematics of zircons from granites and metasediments of southern Ouaddaï (Chad), implications for crustal evolution and provenance in the Central Africa Orogenic Belt

We present the first combined U-Pb ages and Lu-Hf isotope data of zircon grains from the southern Ouaddaï area in Eastern Chad in the Central Africa Orogenic Belt. Zircon xenocrysts from granites and detrital zircons from quartzites of the Ouaddaï document crustal accretion from depleted mantle sources at 3.0 ± 0.5 Ga, rarely up to 3.8 Ga, and for subsequent reworking during four magmatic events, during the Neoarchean at ca. 2.6 Ga (εHft = −7.0 to 4.6), Paleoproterozoic at ca. 1.9–2.1 Ga (εHft = −17.7 to 5.3), Mesoproterozoic at ca. 1.1 Ga (εHft = −15.3 to 5.9), and Neoproterozoic/early Cambrian at 635–540 Ma (εHft = −31.1 to 1.4). Superchondritic εHft values point to new crust addition during all four events. Metamorphic zircon rims yield a Concordia age of 600 ± 2 Ma, and provide evidence that greenschist to amphibolite-facies metamorphism affecting the quartzites occurred between syn-tectonic (635 Ma) and post-kinematic (540 Ma) granite intrusions. Our new set of zircon data, combined with field relationships, also indicate that the quartzite precursor rocks were deposited between 1045 and 635 Ma, possibly after 670 Ma in a basin that subsequently became the Central Africa Orogenic Belt. The detritus was supplied from surrounding cratons, although the sources of the Mesoproterozoic zircons remain ambiguous. Comparison of age-εHft data from worldwide sources suggests sediment supply from the Irumide, Katanga and Mozambique belts, located to the south-east of the Congo Craton. Paleogeographic reconstructions further require sediment transport prior to final closure of several oceanic basins surrounding Central and Northern Africa during the Neoproterozoic, comprising the Khomas and Mozambique oceans

Identification of continental-type eclogites in the Paleo-Tethyan Changning–Menglian orogenic belt, southeastern Tibetan Plateau: Implications for the transition from oceanic to continental subduction

As a record of ancient subduction, eclogites preserve critical information for exploring geodynamic processes at convergent plate boundaries. The Changning–Menglian orogenic belt (CMOB) in the southeastern Tibetan Plateau is situated between the Gondwana-derived Baoshan–Tengchong Block and the Eurasia-derived Lanping–Simao Block. The belt has long been accepted as a typical cold subduction–accretion belt associated with the closure of the main Paleo-Tethys Ocean, owing to the development of oceanic-type lawsonite-bearing eclogites. However, this viewpoint is challenged by the presence of newly discovered continental-type eclogites hosted by metasedimentary rocks in the CMOB. The continental-type eclogites are depleted in high field-strength elements (e.g., Nb, Ta, and Zr), enriched in Th and U, and preserve highly negative ɛNd(t) values varying from −15.26 to −13.04, indicating derivation from continental mafic protoliths that underwent extensive crustal contamination. Inherited zircons from both the continental-type eclogites and their host schists have characteristic detrital age distributions, with dominant Pan-African age peaks at 630–505 Ma that match well with those in the Baoshan–Tengchong Block. Combined with published age data, our new geochemical and geochronological data provide convincing evidence for the presence of significant volumes of subducted continental fragments derived from the Baoshan–Tengchong Block. Thermodynamic modeling of the continental-type eclogites indicates a clockwise P–T path with a steep prograde path consistent with a geothermal gradient of 5–8 °C/km, which was followed by near-isothermal decompression. Calculations suggest the eclogite-facies assemblage of garnet + omphacite + glaucophane ± talc ± lawsonite ± phengite records peak conditions of 28.5–29.6 kbar and 580–594 °C, equivalent to depths of 85–90 km. U–Pb dating of metamorphic zircon rims from the eclogites gives an age of 234–233 Ma, which is interpreted to reflect the timing of continental subduction. The continental-type eclogites show mineral associations, paragenetic sequences and metamorphic P–T–t evolutions similar to those of low-temperature oceanic-type eclogites in the CMOB. As a result, we propose that rapid, cold subduction of continental crust, and its subsequent rapid exhumation, occurred shortly after the closure of the dense and long-lived Paleo-Tethys oceanic lithosphere. The discovery of continental-type eclogites imparts significant insights into the dynamics of Gondwana–Eurasia convergence in the Paleo-Tethyan domain. The CMOB provides a well-exposed example of the tectonic transformation from final oceanic subduction to the onset of continental subduction and collision in a cold geothermal regime.

Paleoproterozoic medium to high pressure metamorphism in the Wanzi supracrustal association, Trans-North China Orogen: New insights from the gedrite-bearing gneiss, gedrite-free gneiss, and amphibolite

The Wanzi supracrustal association locates in the Fuping Complex, middle Trans-North China Orogen, and it was generally considered before as a lithological unit that underwent medium pressure metamorphism. The newly discovered gedrite-bearing gneiss, gedrite-free gneiss, and amphibolite of the Wanzi supracrustal association show abundant mineral assemblages with complex reaction textures, which are critical clues to retrieve the metamorphic evolution of this area. Gedrite-bearing/free gneiss samples mainly consist of garnet porphyroblast plus matrix minerals including biotite, kyanite, sillimanite, staurolite, ±gedrite, plagioclase, quartz, as well as accessory minerals such as ilmenite, magnetite, apatite, monazite, and zircon. Amphibolite samples are generally composed of garnet porphyroblast plus matrix minerals amphibole, ±biotite, plagioclase, quartz, as well as accessory minerals including ilmenite, magnetite, and zircon. Two to four generations of metamorphic mineral assemblages formed at the prograde (M1), peak (M2), and retrograde (M3-M4) stages have been identified from these samples, recording clockwise P-T paths including sequential near-isothermal decompression (ITD) and near-isobaric cooling (IBC) segments, indicative of convergence tectonic settings. The peak P-T conditions of these samples are different, ranging from 8.2 to 13 kbar and 695 to 822 °C. SIMS/SHRIMP U-Pb dating of metamorphic zircon yields 207Pb/206Pb age of 1838–1821 Ma, representing the metamorphic event. Combined with the previous data, the Wanzi supracrustal association is inferred to have undergone middle to high pressure metamorphism during 1.84–1.82 Ga, which was involved in the subduction and/or collision event between the Western and Eastern Blocks and led to the final assembly of the North China Craton.

Constraining the provenance and evolution of the Western Alps Molasse Basin by detrital zircon U–Pb geochronology

Molasse basin is one of the best-preserved pieces of evidence of the Alpine orogeny. Molasse and flysch sequences deposited during the convergence between the Adriatic and the European continents recorded various geological processes. However, detailed provenance analysis of the foreland basin in the Western Alps is still in need of precise data for molasse strata. This paper provides new detrital zircon U–Pb geochronology results from five sandstone samples to constrain the provenance of the Molasse Basin in the Western Alps. The main populations in zircon age spectra correspond to the four tectonothermal events defined in the Alpine domain: the late Neoproterozoic to early Cambrian magmatic event, the pre-Variscan rifting event, the Variscan orogeny, and the Permian extensional event, respectively. Two magmatic zircons (100 ± 2 Ma and 130 ± 5 Ma) and one metamorphic zircon grain (116 ± 3 Ma) yield Cretaceous age. The metamorphic one was probably originated in the Internal zone. A contribution of the Valaisan unit as part of the source terrane is possible to account for the Cretaceous magmatic zircons. Comparing our results with published detrital zircon age data using multidimensional scaling, we infer that the Austroalpine unit was an essential provenance of the Western Alps Molasse Basin during the late Oligocene and the middle Miocene. During the middle Miocene, the deposition of the Molasse Basin was strongly influenced by the exhumation of the External Massifs and the propagation of the subalpine fold-and-thrust belt. Meanwhile, the French Massif Central was also possible to provide a limited proportion of the material for the basin.

Carboniferous high‐P metamorphism and deformation in the Belledonne Massif (Western Alps)

AbstractThe age and P–T conditions of Variscan high‐P(HP) metamorphism in the Palaeozoic basement of the western Alps remain poorly constrained, but is nevertheless crucial to build a consistent tectonic scenario for the southeastern domain of the Variscan Belt. We report here the results of a structural, petrological, thermobarometric, and geochronological investigation of an eclogite‐bearing unit exposed in the northeastern part of the Belledonne Massif (France). This unit is mostly composed of metasediments that are locally migmatized and contain decametre‐ to hectometre‐scale lenses of orthogneiss and amphibolites. SIMS U–Pb dating of magmatic zircon cores in two retrogressed ecogites yields ages at 456 ± 4 Ma and 448 ± 6 Ma, which are interpreted to date the emplacement of the magmatic protoliths. The peak pressure stage in the retrogressed eclogites is estimated to be >1.4 GPa at 690–740°C, and was followed by decompression from 1.4 to ca. 1.0 GPa at 700–800°C. By contrast, the investigated migmatitic metasediment does not present any trace of HP metamorphism, but instead preserves prograde evolution from sub‐solidus conditions (ca. 0.8–1.1 GPa and 600–700°C) to supra‐solidus conditions (1.1–1.4 GPa and 700–780°C). A later stage of retrogression below ca. 0.5–0.8 GPa and 570–610°C is recorded in both lithologies, and is taken to indicate cooling and exhumation to upper crustal levels. Metamorphism was roughly coeval in the retrogressed eclogites and in the migmatitic metasediment. Metamorphic zircon rims yield U–Pb dates scattering between 340 and 310 Ma in both lithologies. In the migmatitic metasediment, a distinct younger age at 306 ± 3 Ma is interpreted to represent late stages of melt crystallization. In the retrogressed eclogites, zircon zoning and chemical composition (Th/U and REE) indicate initial crystallization of the rims during the HP stage followed by protracted growth during decompression to granulitic/amphibolitic conditions. Rutile U–Pb dating in one eclogite sample yields an age of 340 ± 11 Ma similar to the oldest zircon ages and is interpreted to approximate the age of the peak pressure metamorphism. Retrogression in the amphibolite facies is correlated with the development of a penetrative, N30° subvertical mylonitic S2 foliation. Regionally, this deformation occurs in a dextral transpressive corridor interpreted to represent a crustal‐scale shear zone active during the mid‐late Carboniferous. We therefore suggest that this structure has driven the exhumation of eclogites from the lower crust and their mixing with mid‐crustal felsic lithologies devoid of HP assemblages.

Reconstructing the metamorphic evolution of the Araçuaí orogen (SE Brazil) using in situ U–Pb garnet dating and P–T modelling

AbstractThe Araçuaí orogen of SE Brazil consists of a suite of deformed, metamorphosed, and partly migmatitic sedimentary rocks and granitoid batholiths that predominantly formed during collision of the São Francisco and Congo cratons during West Gondwana assembly in the late Neoproterozoic. While widespread anatexis and a prolonged magmatic record are well‐established, insufficient information exists about the extensive exposure of metamorphic rocks along the Araçuaí orogen. Combining information from a wide range of these metamorphic rocks is essential to reconstruct mountain‐building processes and heat sources that operate in convergent tectonic settings. New petrographic observations, mineral chemistry, and phase equilibria modelling were used to constrain peak metamorphic conditions of amphibolite facies metasedimentary rocks from the central domain of the orogen at 580–620°C and 7–9 kbar. We applied in situ low‐U (<1 µg/g) garnet U–Pb geochronology, which yielded ages in the range of 590–565 Ma, interpreted as the timing of bulk garnet growth during prograde metamorphism, and consistent with previously established monazite ages for the peak metamorphic event. Metamorphic zircon ages of c. 630 Ma are related to a cryptic terrane accretion event prior to the orogeny, whereas garnet U–Pb ages record the main orogenic event as revealed by disequilibrium rare earth element partitioning between the two minerals. A compilation of our results with previously reported metamorphic conditions defines a clockwise P–T evolution for the Araçuaí orogeny, characterized by slow burial to depths of 26–30 km, followed by nearly isothermal decompression from ~10 to 6 kbar. Substantial differences of peak temperatures in various domains of the orogen are consistent with the presence of different protoliths in the crustal sections. The higher concentration of heat‐producing elements (HPEs) in lithologies from the anatectic domains may have triggered partial melting of metasedimentary rocks. This suggests that HPEs were a significant heat source for crustal reworking during West Gondwana convergent tectonics.

Chicheng high-pressure granulites record the paleoproterozoic tectonic evolution in the northern North China Craton

High-pressure (HP) mafic granulites are widely distributed along the Trans-North China Orogen (TNCO), and they provide important insights into the timing and tectonic processes involved in the formation of the TNCO. We discovered three types of HP granulite, including mafic, intermediate, and felsic granulites, exposed in Chicheng area, in the northern segment of the TNCO. Their mineral assemblages of prograde, peak, and post-peak metamorphic stages were identified based on petrographic investigations. SIMS U-Pb zircon analyses yielded an upper intercept age of 2547 ± 38 Ma and a lower intercept age of 1916 ± 100 Ma for one HP mafic granulite and a discordant 207Pb/206Pb age of 2479 Ma with a weighted mean 207Pb/206Pb age of 1905 ± 9 Ma for the other HP mafic granulite. For the HP intermediate granulite, an upper intercept age of 2544 ± 20 Ma was obtained. The HP felsic granulite yielded an upper intercept age of 2524 ± 23 Ma and a concordant 207Pb/206Pb age of 1906–1907 Ma. These results reveal that the protoliths of HP granulites were formed at ~ 2.5–2.55 Ga and underwent high pressure granulite facies metamorphism at ~ 1.9 Ga. The elevated Hf isotopic compositions of the metamorphic zircons from two granulite samples indicate that metamorphic fluids that have high 176Hf/ 177Hf ratios but low 176Lu/177Hf ratios were involved in their metamorphism. The low 18O isotopic features of the zircons from the intermediate granulite suggest alteration by δ18O-depleted seawater or meteoric fluids at high temperatures. By integrating geochronological data from previous studies, we infer that the formation of the TNCO may have begun as early as ~ 1.9 Ga and lasted until ~ 1.8 Ga, supporting the hypothesis that it was formed by a long-lived tectono-metamorphic event

Metamorphic evolution and Petrogenesis of garnet–corundum silica–undersaturated metapelitic granulites: A new case study from the Mianlüe Tectonic Zone of South Qinling, Central China

Newly identified garnet–corundum silica-undersaturated pelitic granulites in the Mianlüe Tectonic Zone of the South Qinling belt, central China, preserve a distinct mineral assemblage of garnet + corundum + biotite + plagioclase ± kyanite + sillimanite + staurolite and are therefore useful for deciphering the metamorphic evolution of the zone. Most of the garnet porphyroblasts preserve prominent major- and trace-element zoning, which provides evidence for two stages of garnet growth, under subsolidus conditions and then fluid-absent conditions, during prograde metamorphism. The distinctive yttrium annuli in garnet grains are most likely the result of the breakdown of xenotime. Four stages in the pressure–temperature (P–T) evolution of the granulites are inferred from the results of P–T pseudosection analysis together with petrographic observations. The first stage records the early prograde evolution, comprising isobaric heating at ~7 kbar from 580 to ~700 °C, and the later-stage prograde evolution with increasing pressure and temperature to the peak-pressure stage. The second stage is marked by the maximum XGrs in the garnet mantle, indicating the peak conditions in the high-P–high-T granulite facies of 830 °C at ~11.7 kbar. The third stage is characterized by a continued increase in pyrope in the garnet rim, suggesting decompression with slight heating from the peak pressure to reach the peak temperature at ~9.4 kbar and ~850 °C. The late retrograde cooling stage is represented by further decompression after the peak temperature, accompanied by the growth of staurolite. 7–13 mol% melt was produced during prograde metamorphism via the reaction sill + bi + pl → g + crn + melt. Although later melt loss reduced the bulk-rock Si and Al, the low-Si and high-Al–Fe bulk compositions of restite were inherited mainly from the protolith, which comprised high-Fe sediments (bauxites) derived from weathering of adjacent mafic rock. U–Pb dating of metamorphic zircon rims yielded two age clusters: ~227 Ma represents the timing close to peak-pressure conditions, and 222–217 Ma represents the timing of post-Tmax cooling to the solidus. Monazite U–Pb ages of 212–206 Ma are interpreted as the timing of further retrograde cooling under the solidus. The geochronological data and clockwise P–T paths indicate the garnet–corundum pelitic granulites record a complete metamorphic P–T–t history, including crustal thickening during continental collision/subduction and subsequent exhumation and cooling during the early Mesozoic. Combined with recent high-precision early Neoproterozoic data, we proposed that the MTZ was formed as a result of Grenvillian oceanic plate subduction and the assembly of Rodinia during the early Neoproterozoic and that it also records processes related to continental collision/subduction during the early Mesozoic.

An Improved In Situ Zircon U‐Pb Dating Method at High Spatial Resolution (≤ 10 μm Spot) by LA‐MC‐ICP‐MS and its Application

In situ small‐spot U‐Pb geochronology is essential for measuring zircon crystals containing micrometre‐scale heterogeneities, abundant inclusions, inevitable cracks and narrow growth zones, all of which are especially common in metamorphic zircons. We present a high spatial resolution (≤ 10 μm diameter) laser ablation‐multi‐collector‐inductively coupled plasma‐mass spectrometry (LA‐MC‐ICP‐MS) U‐Pb dating method using a Nu Plasma II mass spectrometer coupled with a GeoLas HD laser ablation system, which is capable of analysing zircon crystals with a wide range of U contents through two analytical modes (mixed‐mode for 10 μm ablation and IC‐mode for 5 μm ablation). We examined Pb/U down‐hole fractionation (DHF) as a function of different laser settings under small‐spot ablation, and how it controls the accuracy and precision of U‐Pb ages of zircon reference materials. After DHF correction using Iolite software (version 3.71), five measurement sessions (with different laser fluence and/or laser pulse settings) for the two analytical modes yielded accurate and precise U‐Pb ages for four zircon reference materials (Plešovice, 91500, GJ‐1 and Temora‐2). Further determinations of U‐Pb ages of three metamorphic zircon samples (~ 14 to 2000 Ma) from the Himalaya, North China Craton and North Qaidam were conducted, the results of which confirm the effectiveness and feasibility of this small‐spot ablation method for natural zircons with multiple growth zones.