Metallic Carbon Nanotubes Research Articles

1D-2D Synergistic MXene-Nanotubes Hybrids for Efficient Perovskite Solar Cells.

Incorporation of 2D MXenes into the electron transporting layer (ETL) of perovskite solar cells (PSCs) has been shown to deliver high-efficiency photovoltaic (PV) devices. However, the ambient fabrication of the ETLs leads to unavoidable deterioration in the electrical properties of MXene due to oxidation. Herein, sorted metallic single-walled carbon nanotubes (m-SWCNTs) are employed to prepare MXene/SWCNTs composites to improve the PV performance of PSCs. With the optimized composition, a power conversion efficiency of over 21% is achieved. The improved photoluminescence and reduced charge transfer resistance revealed by electrochemical impedance spectroscopy demonstrated low trap density and improved charge extraction and transport characteristics due to the improved conductivity originating from the presence of nanotubes as well as the reduced defects associated with oxygen vacancies on the surface of the SnO2 . The MXene/SWCNTs strategy reported here provides a new avenue for realizing high-performance PSCs.

Radius dependence of the electrical conductivity of zigzgag carbon nanotubes

The radius dependence of the electrical conductivity of metallic and semiconducting zigzag carbon nanotubes (CNTs) is theoretically studied. The investigation was done semiclassically by solving the Boltzmann transport equation to derive current density as a function of a homogenous axial dc field and radius of the tube. The analysis was numerically carried out by varying the radius of the materials at a constant temperature. Plots of the normalized current density versus dc field applied along the axis of both materials are presented. We observed that in the case of the metallic zigzag CNTs as the radius increases, the electrical conductivity decreases. On the other hand, in the semiconducting zigzag CNT there was an increase as radius increases. This research shows that thinner metallic zigzag CNTs and thicker semiconducting zigzag CNTs are better conductors of electricity. This investigation therefore offers way of obtaining higher electrical conductivity in both materials without doping. This study therefore shows applications in the development of current conducting nano-devices for scientific systems.

Recent advances in nano-engineered approaches used for enzyme immobilization with enhanced activity

Enzyme immobilization has been achieved on various functional nanostructures to increase their shelf-life, enhancement of productivity, stability, reusability and develop a biocatalyst or biosensor. Current review is ascribing the recent advances in the art of immobilization with great efficiency by adopting logistic and sensible nano-engineering approaches i.e nanoparticles, nanoliposomes, nanotubes, fibers and membranes, beads, sol–gel, metal–organic frameworks, DNA nanostructures, nanowires, nanostars, nanocystals, nanoflowers and nanocages. The activity of various immobilized enzyme i.e. lipase, glucose oxidase, laccase, alcohol dehydrogenase and many more on these newer nanostructures are discussed here demonstrating interaction of biomacromolecules with these nanostructures. Taking Glucose oxidase as an example, it’s immobilization on metallic nanoparticles, nano-liposomes, gold nanostars, carbon nanotubes, hydrogel and hybrid nanoparticles to develop a nano-biocatalyst/biosensor has also been discussed. This review will provide a great insight in the selection of nanostructure with different morphologies and composition so that it can be extended for the multi-enzyme immobilization with multi-functionality, stability and reusability for industrial and clinical translation.

PN junction and band to band tunneling in carbon nanotube transistors at room temperature

We demonstrate band to band tunneling (BTBT) in a carbon nanotube (CNT) field effect transistor. We employ local electrostatic doping assisted by charged traps within the oxide to produce an intramolecular PN junction along the CNT. These characteristics apply for both metallic (m-CNTs) and semiconducting (SC-CNTs) CNTs. For m-CNTs we present a hysteretic transfer characteristic which originates from local electrostatic doping in the middle segment of the CNT. This controlled doping is reversible and results in formation and destruction of a PN junction along the CNT channel. For SC-CNTs we observe BTBT, and analysis based on the WKB approximation reveals a very narrow depletion region and high transmission probability at the optimal energy bands overlap. These results may assist in developing a non-volatile one-dimensional PN junction memory cell and designing a tunneling based field effect transistor.

Electromagnetic properties of a composite medium comprising chains of tunnel-coupled carbon nanotubes

When creating a model of a composite medium based on carbon nanotubes in the gigahertz and subterahertz ranges, it is necessary to take into account the tunnel coupling between nanoparticles. To simplify the consideration, we present a model of a composite medium consisting of the same randomly oriented linear chains of parallel single walled metallic carbon nanotubes connected by tunnel contacts. The problem of scattering of electromagnetic radiation by the chains was solved through the application of the integral equation technique of classical electrodynamics and the Landauer – Buttiker formalism for quantum transport. It is shown that electron tunnelling between the nanotubes leads to the electromagnetic size effects in chains of finite length. In this case, in the gigahertz frequency range, there is a regime in which the comparable in magnitude real and imaginary parts of the effective permittivity of the composite medium decrease with increasing frequency that is often observed in experiments. It has been found that size effects can manifest themselves within small sections of the chain limited by contacts of low conductivity. The obtained results provide an understanding of the physical mechanisms responsible for the frequency dispersion of the permittivity of composite materials based on carbon nanotubes.

An accurate parameter extraction method for small signal model of CNFET

AbstractA new small‐signal model for carbon nanotube field effect transistor (CNFET) is proposed which incorporates the effect of metallic carbon nanotubes (m‐CNTs). The effect of m‐CNTs is comprehensively modeled by contact resistance between m‐CNTs and source/drain (S/D), which also taken into account a parallel RC circuit composed of Cmts, Cmtd, and non‐linear resistance Rdsm. An analytical method is presented to extract model parameters. The model is validated using multi‐tube (MT) CNFET with eight gate fingers of 400 nm length and 50 μm width each manufactured in a 700 nm technology. Excellent agreement is achieved between measured and simulated S‐parameters in the range over 0.6–10.1 GHz.

Metallic carbon nanotube quantum dots with broken symmetries as a platform for tunable terahertz detection

Generating and detecting radiation in the technologically relevant range of the so-called terahertz gap (0.1–10 THz) is challenging because of a lack of efficient sources and detectors. Quantum dots in carbon nanotubes have shown great potential to build sensitive terahertz detectors, usually based on photon-assisted tunneling. A recently reported mechanism combining resonant quantum dot transitions and tunneling barrier asymmetries results in a narrow linewidth photocurrent response with a large signal-to-noise ratio under weak THz radiation. That device was sensitive to one frequency, corresponding to transitions between equidistant quantized states. In this work we show, using numerical simulations together with scanning tunneling spectroscopy studies of a defect-induced metallic zigzag single-walled carbon nanotube quantum dot, that breaking simultaneously various symmetries in metallic nanotube quantum dots of arbitrary chirality strongly relaxes the selection rules in the electric dipole approximation and removes energy degeneracies. This leads to a richer set of allowed optical transitions spanning frequencies from 1 THz to several tens of THz, for a ∼10 nm quantum dot. Based on these findings, we propose a terahertz detector device based on a metallic single-walled carbon nanotube quantum dot defined by artificial defects. Depending on its length and contacts transparency, the operating regimes range from a high-resolution gate-tunable terahertz sensor to a broadband terahertz detector. Our calculations indicate that the device is largely unaffected by temperatures up to 100 K, making carbon nanotube quantum dots with broken symmetries a promising platform to design tunable terahertz detectors that could operate at liquid nitrogen temperatures.

Alignment dynamics of single-wall carbon nanotubes under electric field in different surfactant solutions

The dynamics of metallic single-wall carbon nanotube (SWCNT) alignment inside various viscous media under electric field is investigated in this simulation work for the manifestation of macroscale aligned SWCNT films. An alternating current (AC) electric field was applied to the liquid solution of several surfactants (DIW, DMF, CHEX, SDS, and DOC) containing SWCNTs. The time required for the SWCNTs to get aligned to the applied AC electric field was simulated for different initial conditions for all the surfactants. An analytical model based on dielectrophoresis induced torque was employed. The model considers the viscosity and conductivity of the surrounding medium. The influence of SWCNT length, SWCNT radius, and frequency of the AC field on the assembly of SWCNTs were studied. Our analysis showed that a longer and narrower SWCNT prompts faster assembly to an aligned SWCNT aggregation. Furthermore, the effect of the concentration of SDS and the effect of electric field strength for DIW surfactant were also investigated. Viscosity plays a significant role in the alignment process. Slower SWCNT alignment is caused by a medium of higher viscosity.

Broadband Metallic Carbon Nanotube Saturable Absorber for Ultrashort Pulse Generation in the 1500–2100 nm Spectral Range

Herein, we report on the possibility of ultrashort laser pulse generation in the broadband spectral range using a saturable absorber based on free-standing metallic carbon nanotube thin film. Erbium, thulium, and holmium-doped all-fiber lasers were mode-locked with a single saturable absorber containing a 300 nm thick material layer. Subpicosecond pulses were generated at 1559, 1938, and 2082 nm. Our work validates the broadband operation of metallic carbon nanotube-based saturable absorbers and highlights the suitable performance of nanomatematerial for ultrafast photonic applications.

Preparation, characterization, and nonlinear optical properties of graphene oxide thin film doped with low chirality metallic SWCNTs

We present non-linear optical properties of graphene oxide (GO) doped with low chirality metallic single walled carbon nanotubes (m-SWCNTs) thin films. The weight percentage of the m-SWCNTs was 5, 10, and 20 wt%. High-resolution transmission electron microscope (HRTEM), high resolution scanning electron microscope (HRSEM), Raman, and UV–vis spectroscopy were used to characterize the prepared samples. We have investigated their nonlinear optical properties using open and closed Z-scan technique at Nd:YAG laser at 1064 nm laser pulses (7 ns, 10 Hz). The nonlinear absorption coefficient β, nonlinear refractive index n2, and third order nonlinear susceptibility χ3 were calculated. The results show that all samples exhibit reverse saturable absorption (RSA) because of increasing metallicity and/or partial reduction of GO during laser illumination. The nonlinearity response of the GO/m-SWCNT films increase as the m-SWCNTs percentage increases. The high non-linear optical parameters of the GO/m-SWCNTs films make them as superior candidates for near-infrared (NIR) laser protection applications.

Simple, cost-efficient and high throughput method for separating single-wall carbon nanotubes with modified cotton

Application of carbon nanotubes (CNT) is hampered by the lack of practical methods for separating the raw production mixtures into species with a given structure and properties. In this work, we propose a new, cost effective separation method, suitable for the industrial scale processing of SWCNTs. The separation is afforded by passing a surfactant solution of unsorted CNTs through a column, filled with chemically modified cotton wool. This yields two fractions, heavily enriched with semiconducting and metallic CNTs, respectively. The as-separated fractions are fully characterized by UV–Vis spectroscopy, PL spectroscopy, Raman spectroscopy, and HRTEM.

Scattering of electromagnetic waves by two crossing metallic single-walled carbon nanotubes of finite length

The scattering theory for two crossing metallic single-walled carbon nanotubes of finite length exposed to an electromagnetic field has been developed based on a synthesis of the quantum transport formalism and classical electrodynamics. The model of the point contact has been developed to be incorporated into the Hall\'en and Pocklington equations for crossing carbon nanotubes. The influence of the contact conductance and position as well as the angle between the tube axes on the tube polarizability has been analyzed in the range of 1 GHz to 10 THz. The physical mechanisms responsible for the electromagnetic interaction between crossing tubes with zero and nonzero intertube contact conductance are shown and discussed. The influence of the coupling between the tubes on the localized plasmon resonance in them has been demonstrated.

Nano-Elicitation as an Effective and Emerging Strategy for In Vitro Production of Industrially Important Flavonoids

Flavonoids represent a popular class of industrially important bioactive compounds. They possess valuable health-benefiting and disease preventing properties, and therefore they are an important component of the pharmaceutical, nutraceutical, cosmetical and medicinal industries. Moreover, flavonoids possess significant antiallergic, antihepatotoxic, anti-inflammatory, antioxidant, antitumor, antiviral, and antibacterial as well as cardio-protective activities. Due to these properties, there is a rise in global demand for flavonoids, forming a significant part of the world market. However, obtaining flavonoids directly from plants has some limitations, such as low quantity, poor extraction, over-exploitation, time consuming process and loss of flora. Henceforth, there is a shift towards the in vitro production of flavonoids using the plant tissue culture technique to achieve better yields in less time. In order to achieve the productivity of flavonoids at an industrially competitive level, elicitation is a useful tool. The elicitation of in vitro cultures induces stressful conditions to plants, activates the plant defense system and enhances the accumulation of secondary metabolites in higher quantities. In this regard, nanoparticles (NPs) have emerged as novel and effective elicitors for enhancing the in vitro production of industrially important flavonoids. Different classes of NPs, including metallic NPs (silver and copper), metallic oxide NPs (copper oxide, iron oxide, zinc oxide, silicon dioxide) and carbon nanotubes, are widely reported as nano-elicitors of flavonoids discussed herein. Lastly, the mechanisms of NPs as well as knowledge gaps in the area of the nano-elicitation of flavonoids have been highlighted in this review.

Growth of Semiconducting Single-Walled Carbon Nanotubes Array by Precisely Inhibiting Metallic Tubes Using ZrO2 Nanoparticles.

Synthesis of high-quality single-walled carbon nanotubes arrays with pure semiconducting type is crucial for the fabrication of integrated circuits in nanoscale. However, the naturally grown carbon nanotubes usually have diverse structures and properties. Here the bicomponent catalyst using Au and ZrO2 is designed and prepared. The Au nanoparticle serves as the catalysts for carbon feedstock cracking and facilitating the nucleation of carbon nanotubes, whereas the close-connected ZrO2 forms a localized etching zone around Au by releasing lattice oxygen and to inhibit the nucleation of metallic carbon nanotubes precisely. The obtained single-walled carbon nanotubes array show a high semiconducting content of >96%,on the basis of good performance of field-effect transistor devices. And such building of localized etching zone is compatible with other catalyst systems as a universal and efficient method for the scalable production of semiconducting carbon nanotubes.

Enhanced electron emission from ternary solid solution-MWCNT hybrid with theoretical validation

Coalescence of unique properties of semiconductor and carbon nanotubes (CNTs) produces new advanced materials with exciting properties, which unwraps several new fields. Here, finite element modeling is employed to optimize the diameter of semiconducting zinc cadmium sulfide (Zn0.8Cd0.2S) microspheres on the wall of metallic CNTs to get the improved field emission property. Then, Zn0.8Cd0.2S microspheres are attached on COOH functionalized multiwalled CNTs (MWCNTs) by a simple one step solvothermal method for experimental corroboration. Field emission experiment shows a considerable enhancement of current density with respect to bare microspheres and functionalized CNTs. The turn-on field is found to be as low as 3V/μm at a current density of 10 μΑ/cm2 for the hybrid system. Density functional theory (DFT) calculation is carried out for the model structures of Zn0.8Cd0.2S and CNT-Zn0.8Cd0.2S to calculate the work functions. This improvement in field emission property of the hybrid system is demonstrated in terms of band bending, geometry, high field enhancement factor, low work function and electron affinity. Thus, non-field emitting microspheres with less toxicity have been transformed into a decent field emitter by the contribution of few carbon nanotubes.

Explosive molecule sensing at lattice defect sites in metallic carbon nanotubes

Adsorption of a TNT molecule at a divacancy defect on a metallic single walled carbon nanotube. Carbon atoms corresponding to the defect are highlighted in green.

Mass-produced metallic multiwalled carbon nanotube hybrids exhibiting high N-type thermoelectric performances

Finding a stable n-type flexible thermoelectric (TE) material with a high power factor and mass production is a challenge for wearable TE devices.

Effects of Different Junction Parameters on Junction Conductances of Crossed Metallic Carbon Nanotubes

We have studied the effect of different junction parameters on the junction conductances made of two crossed metallic carbon nanotubes. We have found that because of the intrinsic asymmetries of the junction, forward and backward tunneling between one tube and the other are unequal. Passing a current in one tube leaded to the development of non zero voltage across the other one, a zero field Hall like conductance for the junction was found. We have found that this zero field Hall conductance relates to the contact conductance of the junction. The result also shows that the electronic properties of the junction sensitively depend on the degree of matching between the tube lattices. This matching is controlled by the crossing angel, which resulted in an intertube conductance that varied by an order of magnitude for different angles. We have derived a tunneling matrix element that coupled the low energy electronic states on the two tubes. The magnitude of the coupling was determined by the intertube separation of the crossing angle. We have found that the intrinsic symmetries of the junction created a discrepancy between the forward and backward hopping between the tubes. Using Landauer-Buttiker formalism, we have calculated the different conductances of the four terminal junctions. We have found that the contact conductance scaled inversely with the zero field Hall conductance of the junction. We have also found that the two crucial parameters in determining the conductance are the tube chiralities and the crossing angle. The obtained results were found in good agreement with previously obtained results.

Humidity Effects According to the Type of Carbon Nanotubes

As a new type of one-dimensional nanomaterial, carbon nanotubes (CNTs) have been used as a chemical sensing material due to their excellent electrical, mechanical and chemical properties. Several recent studies have attempted to obtain an electrochemical sensor based on CNTs, and CNT-based humidity sensors have potential applications in industrial, agricultural and medical fields and in smart wearable electronic devices. Although various CNT-based humidity sensors have been reported, in this work, we investigated the humidity effects in depth and the underlying mechanisms according to CNT type, i.e., semiconducting (s-CNT) and metallic (m-CNT) CNTs, which is determined by the chiral vector during CNT growth. For this purpose, we fabricated CNT-based humidity sensors with highly purified, solution-processed 99% single-walled s-CNT and m-CNT network films bridged by palladium (Pd) electrodes. The fabricated sensors exhibited completely different humidity responses, as denoted by the film resistance as a function of the relative humidity (RH), according to the CNT type. In the s-CNT-based sensor, the resistance tended to decrease as the RH increased, while the m-CNT-based sensor showed the opposite tendency. Based on these results, a humidity sensing mechanism according to the CNT type was proposed in this work. We believe that our findings can serve as design guidelines for CNT-based humidity sensors.

Effects of Catalyst Pretreatment on Carbon Nanotube Synthesis from Methane Using Thin Stainless-Steel Foil as Catalyst by Chemical Vapor Deposition Method.

Synthesis of carbon nanotubes (CNTs) was carried out using methane as a carbon source via the chemical vapor deposition (CVD) method. A thin stainless-steel foil was used as catalyst for CNT growth. Our results revealed that pretreatment step of the stainless-steel foil as a catalyst plays an important role in CNT formation. In our experiments, a catalyst pretreatment temperature of 850 °C or 950 °C was found to facilitate the creation of Fe- and Cr-rich particles are active sites on the foil surface, leading to CNT formation. It is noted that the size of metallic particles after pretreatment is closely related to the diameter of the synthesized CNTs. It is interesting that a shorter catalyst pretreatment brings the growth of semiconducting typed CNTs while a longer pretreatment creates metallic CNTs. This finding might lead to a process for improving the quality of CNTs grown on steel foil as catalyst.