This paper presents a broadband vibration energy harvester (VEH) which consists of a monostable Duffing oscillator connected to an electromagnetic generator via a mechanical motion rectifier. The mechanical motion rectifier converts the bidirectional vibratory motion of the oscillator induced by ambient environment vibrations into unidirectional rotation of the generator and causes the harvester to periodically switch between a large- and small-inertia system, resulting in nonlinearity in inertia. By means of analytical and numerical methods, this inertia nonlinearity is shown to have two advantages. First, it allows for more stiffness nonlinearity without inducing nonuniqueness of energy branches and enhances bandwidths of energy harvesting. The effect of mitigating nonuniqueness of energy branches occurs to steady-state and transient responses of the harvester and is experimentally verified by a prototype. The experimental results show a nearly 50% increase in the half power bandwidth via mechanical motion rectification (MMR). Second, it enlarges the basin of attraction of the high-energy branch when multiple energy branches are present. A numerical example shows that a more than 50% increase in the basin area can be achieved via MMR.