ABSTRACT Historically, asphalt rheology has been described in terms of a colloidal model, which depicts asphalts as dispersions of asphaltenes in petrolenes (maltenes). The model leads to a classification of asphalts into sol, gel, or intermediate categories. Sol and gel type asphalts exhibit differences in physical and chemical behavior. Sol asphalts also are described as compatible, while gel asphalts are described as non-compatible. The relative viscosity of an asphalt, defined as the quotient of the viscosity of the whole asphalt divided by the viscosity of the n-heptane soluble maltene fraction at a given temperature and rate of shear is one measure of asphalt compatibility. Based on this definition of compatibility, asphalts with low values of relative viscosity are designated as compatible and higher values of relative viscosity are designated as incompatible. Asphalt compatibility is also related to the asphaltene content, where asphalts with low asphaltene content are designated as compatible. It is claimed that the Heithaus parameters also are measures of asphalt compatibility. Therefore there should be a relationship between relative viscosities (πrel), Heithaus parameters, and n-heptane asphaltene volume fractions ( φn-heptane)- Such a relationship has been derived assuming that the Heithaus pa parameter is numerically equivalent to α in the Pal-Rhodes equation.
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