Abstract This study focused on the X-ray radiation attenuation properties of spark plasma sintered boron carbide-zirconium diboride (B4C-ZrB2) composites against diagnostic X-rays. The ZrB2 amount ranged from 0 to 15 vol%. Diagnostic X-rays were applied using the tube voltages ranging from 50 to 110 kV in 10 kV increments. The radiation attenuation ratios (RARs), the linear and mass attenuation coefficients of the samples were calculated for all tube voltages. Lead equivalent thickness (PbE) values were obtained for all samples. The results indicate that addition of ZrB2 to B4C enhanced the X-ray radiation attenuation capability across all applied tube voltages. Furthermore, increasing the amount of ZrB2 in the samples resulted in higher radiation attenuation coefficients. While one cm thick monolithic B4C had an average PbE of 0.019 mm, one cm thick B4C- %15 ZrB2 had an average PbE of 0.404 mm, which indicates that BZ15 demonstrated approximately 25 times better radiation attenuation performance than monolithic B4C. In addition, a 1 cm thick BZ15 composite provides at least 0.35 mm PbE radiation shielding performance for the studied diagnostic X-rays, which is equivalent to approximately 17.5% of the 2 mm Pb sheets typically used in X-ray protection applications. This result could help to reduce the usage of Pb in such applications which helps the environmentally friendly purposes. In conclusion, ZrB2-added B4C materials exhibit superior radiation attenuation properties compared to monolithic B4C.
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