Marine Ecotoxicity Research Articles

Environmental assessment of gasification and green hydrogen potential role in waste management decarbonization

Achieving sustainability involves implementing a circular economy model and decarbonizing the waste management sector. The development of innovative technologies that enable the reduction of emissions and resource recovery is one of the sector's greatest challenges. From this perspective, the waste-to-methanol (WtM) process represents a viable prospect, the potential environmental impacts of which have never been studied from a life-cycle perspective. A cradle-to-grave LCA analysis was conducted, studying WtM technology and its potential implementation of green hydrogen (WtM-GH) in the process, through a comparison with traditional waste-to-energy (WtE).The results showed that WtM-GH performs best for global impacts, with a global warming potential of 3.52·107 kgCO2eq instead of 1,04·108 kgCO2eq proper of the WtE. Positive effects take place also for the fossil resource scarcity. Looking for non-toxic regional/local impacts WtE represents the best scenario, with the best performance on water consumption (7.96·107 m3) and ionising radiation (2.82·107 kBq Co-60eq). Cumulative impact results, obtained through the normalization, found that WtM is the best scenario, thanks to the less toxic impact compared to the other two, especially for freshwater ecotoxicity (5.26·106 kg 1,4-DCB) and marine ecotoxicity (6.73·106 kg 1,4-DCB).WtM-GH allows the production of 1366 kg of methanol per ton of Refuse Derived Fuel, thanks to the conversion of the entire CO2 contained in the waste, enhancing the value of by-products and carbon credits on the market and making the process more economically sustainable.

Environmental and economic assessment of mixed plastic waste pelletization in the Gulf Cooperation Council region

Pelletizing mixed plastic wastes (MPW) has gained interest as an upcycling technology and an alternative to conventional recycling. To investigate its potential, we conducted a cost analysis and life-cycle assessment (LCA) for a conceptual pelletization facility designed to produce 1 kg of pellets per batch of MPW (comprising polyethylene—PE and polypropylene—PP). This work has the following merits: (i) evaluating environmental impact (EI), cost analysis, and mechanical strength based on actual experimental data and its comparison with local and international manufacturers; (ii) enabling the evaluation of LCA impacts of MPW pellets; and (iii) emphasizing the significance of waste management in reducing EIs. The following ten EIs were assessed: climate change (CC), net energy, particulate matter formation, natural land transformation, metal depletion, marine ecotoxicity, ionising radiation, freshwater ecotoxicity, freshwater eutrophication, and terrestrial ecotoxicity. The CC of the as-synthesized pellets is 1.26 kg CO2 eq., significantly lower than the data obtained from the Gulf Petrochemicals and Chemicals Association (GPCA) and an actual plant in Gulf Cooperation Council (GCC) countries. Additionally, the net energy required for the production of 1 kg of pellets is 54.1 MJ, while the cost is around 0.55 USD. The tensile strength of MPW pellets (24.63 MPa) falls between that of PE virgin pellets (21.12 MPa) and PP virgin pellets (28.12 MPa). This suggests that the MPW pellets exhibit competitive strength characteristics, warranting its consideration for applications where moderate strength is required. Overall, the competitive cost, coupled with the reduced EIs, demonstrates the potential of pelletization as a sustainable and economically viable waste management solution.

Life Cycle Assessment of Extraction of Cellulose from Date Palm Biomass Using Natural Deep Eutectic Solvent (NaDES) via Microwave-Assisted Process

This study investigates the extraction of cellulose from Saudi Arabia-based date palm biomass utilizing a natural deep eutectic solvent (NaDES) integrated with a microwave-assisted process. A comprehensive life cycle assessment (LCA) was conducted in accordance with the ISO 14040 standard, encompassing four key stages: goal and scope definition, life cycle inventory analysis (LCI), life cycle impact assessment (LCIA) and interpretation. The analysis was confined to a gate-to-gate boundary in which two impact assessment methods, namely, ReCiPe Midpoint (H) 2016 and ILCD 2011 Midpoint, were used to assess the environmental impacts. The OpenLCA software (version 2.1.1) with the European Life Cycle Database 3.2 (ELCD 3.2) was used in the study. The ReCiPe method identified impact categories such as fossil resource scarcity, terrestrial ecotoxicity, freshwater ecotoxicity, water consumption, human carcinogenic toxicity and marine ecotoxicity. Conversely, the ILCD method identified freshwater ecotoxicity, water resource depletion, mineral, fossil and resource depletion, human toxicity and cancer effects. The results indicate that freshwater ecotoxicity presents the most substantial environmental impact across both assessment methods, surpassing other categories. Fossil resource scarcity, even though originally appearing impactful, demonstrated a relatively lower normalized score compared to freshwater ecotoxicity. Terrestrial ecotoxicity and water consumption were found to be negligible in their impact. Our findings provide important insights into sustainable material science and waste management, affording potential applications for biomass utilization in the Gulf region.

Environmental benefits of valorising food waste into bio-based polyols for the production of polyurethane rigid foams

Under the global pursuit of sustainable development, waste streams are being recognised as renewable feedstocks to produce value-added products. Given this, food waste (FW) was explored to synthesise bio-based polyols to further develop polyurethane rigid foams (PURF). However, relevant environmental aspects are yet to be examined to support this biorefinery scheme as a green and sustainable solution. In this work, we examined the environmental performance associated with the production of PURF using polyols derived from a FW biorefinery scheme by life cycle assessment (LCA). Analysis was first conducted at the polyol level. Different allocation and offset options were examined to configure the LCA model. Based on mass allocation, compared with fossil-based production, the production of FW-derived polyols achieved reductions of 24.30 % and 34.19 % in global warming potential (GWP) and cumulative energy demand (CED), respectively. At the midpoint level, FW-derived polyols had reduced impacts on human carcinogenic toxicity, freshwater eutrophication, and fossil resource scarcity but caused additional burdens on freshwater and marine ecotoxicity. Key environmental hotspots at this level included diethylene glycol, ion exchange resin (epoxidation catalyst), and hydrogen peroxide. The lipid content in FW also played a significant role. It was demonstrated that reducing the use of enzymes for FW hydrolysis to a cost-effective level remarkably mitigated the overall impacts of FW-derived polyol production. At the next level, we examined the production of FW-derived PURF using the obtained polyols. When 70 % of the polyols were replaced with bio-based products, the resultant PURF production achieved a GWP and CED of 5.67 kg CO2eq and 110.66 MJ/kg, respectively. In general, FW-derived PURF leads to environmental benefits compared to fossil-based ones. However, isocyanate used for foam formulation was the dominant contributor, causing almost two-thirds of the total impacts. The flame retardant also caused considerable impacts. Through the systematic examination of FW-derived polyols and PURF, this study demonstrated that FW-derived PURF could benefit the sustainable development of FW biorefineries and bio-based plastic industries, while the identified environmental hotspots need to be further studied and replaced with greener substitutes.

Solar cells combined with geothermal or wind power systems reduces climate and environmental impact

This research investigates the environmental sustainability of three integrated power cycles: combined geothermal-wind, combined solar-geothermal, and combined solar-wind. Here, a promising solar technology, the perovskite solar cell, is considered and analysed in conjunction with another renewable-based cycle, evaluating 17 scenarios focusing on improving the efficiency and lifespan. Among the base cases, combined solar-wind had the lowest ozone depletion impact, while combined geothermal-wind had the lowest freshwater ecotoxicity and marine ecotoxicity impacts. The study shows that extending the perovskite solar cell lifespan from 3 to 15 years reduces CO2 emissions by 28% for the combined solar-geothermal and 56% for the combined solar-wind scenario. The most sustainable cases in ozone depletion, marine ecotoxicity, freshwater ecotoxicity, and climate change impacts are combined solar-wind, combined solar-geothermal, and combined geothermal-wind, respectively, among all evaluated scenarios. This research suggests investing in the best mix of integrated power cycles using established and emerging renewable technologies for maximum environmental sustainability.

Life Cycle Assessment of Bioethanol Produced from Banana Peduncle

Abstract Biofuel production has been promoted in part to reduce dependency on fossil fuels in transportation due to fewer environmental emissions. Feedstocks for biofuels include agricultural waste and non-edible crops, suggesting that large amounts of waste can be used to produce biofuels such as bioethanol, which is currently being blended with gasoline in the Philippines as transportation fuel. However, shifting from non-renewable fuels to bioethanol and other biofuels as the dominant transportation fuel must consider aspects other than fuel usage. The objectives of this study are to perform cradle-to-grave life cycle analysis on bioethanol produced from banana peduncle and determine the contributions of each stage in the life cycle to different environmental impacts and compare the results with those of other transport fuels. The contributions of each stage in the life cycle of bioethanol are modelled in openLCA software with the ReCiPe impact assessment method. It was identified that electricity use in simultaneous saccharification and fermentation, and sulfuric acid consumption are the main contributors to the different environmental impacts. Comparison of the results of banana peduncle bioethanol production stage to those of the first-generation bioethanol production showed that most of the emissions were lower except for those pertaining to freshwater ecotoxicity, human toxicity, marine ecotoxicity, and metal depletion. Comparing fuel use, environmental impacts of conventional gasoline were slightly lower than those of a 10% mix with bioethanol. But impacts of the 85% mix with bioethanol in climate change and marine eutrophication are higher by 29% and 37%, respectively, than those of conventional gasoline. Overall, increasing the ethanol concentration would reduce the emissions during fuel usage but impacts of production will increase. Potential process improvements for environmental performance of bioethanol from banana peduncle are in the pre-treatment methods and fermentation set-up in bioethanol production, use of renewable power, and ethanol blending concentrations with gasoline.

Methyl esters production from Waste Cooking Oil catalysed by iron oxides supported on CaO: Cost and environmental impacts

It was the objective of this work, to assess the midpoint environmental impacts of the catalyst synthesis stage and biodiesel production from waste cooking oil (WCO) as feedstock, depending on the catalyst source, i.e. Fe2O3 or Fe(NO3)3⋅9H2O, lime or waste clam shells, to produce the applied bifunctional catalyst based on iron and CaO. The cost of biodiesel production depending on the catalyst was also established. In the catalyst synthesis stage, the use of clam shells contributed the most to the midpoint environmental categories, mainly terrestrial ecotoxicity, freshwater ecotoxicity, marine ecotoxicity and human non-carcinogenic toxicity. In the stage of biodiesel production (esterification-transesterification reaction), the scenario contributing the lowest (20.95–22.16 %) to the midpoint environmental impacts is when using Fe(NO3)3·9H2O and CaO as iron and lime precursors, respectively. Using waste clam shells increases the environmental impacts. Regarding costs, the clam shells lead to the most expensive process ($0.08 USD/MJ). The source of energy to conduct the biodiesel production was also assessed and it was found that the use of wind turbines leads to the lowest global warming potential (GWP), 11.6 g CO2 eq·MJ-1, with the catalyst prepared with the iron salt and with the CaO from lime. The presented results were obtained with the commercial software SimaPro® version 9.6 PhD. For the inventory, experimental data obtained at laboratory scale and previously published were used.It was concluded that based on environmental impacts and costs, it is recommended to use lime instead of clam shells waste as precursor of CaO and Fe(NO3)3·9H2O as precursor of iron.

Life Cyle Assessment of Activated Carbon from Waste Materials as an Adsorbent in Wastewater Treatment

Activated Carbon (AC) has been a great alternative to reduce the cost of the process in wastewater treatment plants (WWTP) but they also have several hidden impacts on the environment. The impact assessment on the waste materials from coconut shells and wood will be identified using the Life Cycle Assessment (LCA) software approach. Through the “Cradle-to-gate” approach, activated carbon made from waste materials is produced and consumed, and its eighteen environmental effects which are fine particulate matter formation, fossil resource scarcity, freshwater ecotoxicity, freshwater eutrophication, global warming, human carcinogenic toxicity, human non-carcinogenic toxicity, ionizing radiation, land use, marine ecotoxicity, marine eutrophication, mineral resource scarcity, human health, terrestrial ecosystem, stratospheric ozone depletion, terrestrial acidification, terrestrial ecotoxicity and water consumption are assessed using the LCA software. This study aims to discover whether the choice of waste material precursors from the Activated Carbon (AC) can help to minimise environmental impacts. The study evaluates the potential benefits of using waste-derived activated carbon in wastewater treatment by comparing the environmental performance of activated carbon obtained from coconut, wood, and coal. This study is based on past studies all around the world. In thirteen of the eighteen impact categories, wood has the greatest environmental impact. Coconut shells on the other hand, has the lowest total environmental impacts, ranking first or second in fifteen among the eighteen environmental categories. The findings help in making choices for environmentally friendly wastewater treatment methods by illuminating the effects of employing waste products as an alternative source of adsorbents.

Intensification of valorization of cooked rice water through energy-efficient synthesis of drop-in biofuel (butyl levulinate): engine performance, emission profile, and environmental impact assessments.

For the first time, an energy-efficient and eco-friendly technology for the conversion of abundantly available kitchen waste, specifically waste cooked rice water (WCRW) to drop-in- biofuels, namely, butyl levulinate (BL), has been explored. The synthesis of BL was accomplished employing butyl alcohol (BA) and WCRW in an energy-efficient UV (5W each UVA and UVB)-near-infrared (100W) irradiation assisted spinning (120rpm) batch reactor (UVNIRSR) in the presence of TiO2-Amberlyst 15 (TA15) photo-acidic catalyst system (PACS). The optimal 95.81% yield of BL (YBL) could be achieved at 10 wt% catalyst concentration, 60°C reaction temperature, 80min time, and 1:10 WCRW: BA concentration as per Taguchi statistical design. Moreover, additional combination of different PACS such as TiO2-Amberlyst 16, TiO2-Amberlyst 36, and TiO2-Amberlite IRC120 H rendered 86.72% YBL, 90.04% YBL, and 93.47% YBL, respectively, proving superior efficacy compared to individual activity of the acidic catalysts and photocatalysts. The heterogeneous reaction kinetics study for TA15 PACS suggested Langmuir-Hinshelwood model to be the best fitted model. A significant 63.33% energy could be saved by UVNIRSR as compared to conventional heated reactor at the optimized experimental condition using PACS TA15. An overall alleviation in environmental pollution with 59.259% reduction in GWP, 15.254% decline in terrestrial ecotoxicity, 18.238% diminution in marine ecotoxicity, 17.25% decrease in ozone formation affecting human health, 5.865% reduction in human non-carcinogenic toxicity, 18.65% diminution in ozone formation affecting terrestrial ecosystem, 55.17% significant decrease in terrestrial acidification, and 25.619% mitigation in fresh water ecotoxicity could be observed. Furthermore, BL-biodiesel-diesel blends (3% BL, 7% biodiesel, and 90% diesel) exhibited significant reduction (25.45% and 36%, respectively, for CO and HC) in harmful engine exhaust emissions demonstrating environmental sustainability of the overall process.

The Utilisation of Rice Husk Ash Leachates for The Synthesis of Eco-Friendly Geopolymers

Geopolymers are inorganic polymers projected as feasible alternatives to Portland cement due to their lower CO2 emissions and high mechanical properties. In recent times, however, their impact on other environmental indices such as abiotic depletion, freshwater toxicity, marine ecotoxicity, terrestrial ecotoxicity, acidification, and human toxicity has become questionable, thus the need to investigate alternative eco-friendly precursors and activators. This work aims to manufacture an eco-efficient geopolymer by utilising biomass ash leachate as an alternative to the conventional alkali silicate solution. The leachate was obtained by soaking the rice husk ash (RHA) in a 10 M concentration of NaOH solution and filtering to obtain a clear solution. The effects of the calcination temperature of the kaolin and the RHA content in the alkaline solution were investigated, and a factorial design of experiments was developed considering three levels of calcination temperature (700°C, 800°C, and 900°C) and five levels of RHA content (0 g, 5 g, 10 g, 15 g, and 20 g). Physical and mechanical tests were performed on the synthesised geopolymer pastes, and chemical analysis was performed using X-ray diffraction and X-ray spectroscopy. The impacts of replacing the synthetic alkali silicates with rice husk ash-based activators were compared. The results showed that the calcination temperature of the kaolin and the content of the RHA both contributed significantly to the flexural and compressive strength at the 0.01 level of significance. A compressive strength of 10.4 MPa was obtained for the MK915 binders, which showed a 100% increase from samples without RHA content. This research proves that utilising RHA-based activators in metakaolin-based geopolymers can be feasible for less critical applications where a very high compressive strength will not be required.Keywords: alkaline activators, biomass, geopolymers, leachates, rice husk ash

Integrated assessment of environmental and economic impact of municipal solid waste incineration for power generation: A case study in China

Municipal solid waste incineration for power generation is significant for reducing and reusing solid waste. The study conducted an integrated assessment of environment and economy on municipal solid waste incineration in China, from a “cradle to grave” perspective using 1 tonne of municipal solid waste incineration as the functional unit. The environmental impacts of each month are also calculated to analyze the dynamic change throughout one year. The results indicate that the environmental impacts are mainly concentrated in marine ecotoxicity, freshwater ecotoxicity, human carcinogenic toxicity, and human non-carcinogenic toxicity. Flue gas purification, waste incineration and transportation are the key processes, which account for 65.61 %, 18.50 %, and 11.93 % of the overall environmental impact, respectively. Urea, activated carbon, chelating agent (EDTA) and diesel fuel for transportation are key factors. The life cycle cost (LCC) is 132.26 RMB/t of waste, of which the initial capital causes the largest economic cost. When considering power generated from municipal solid waste incineration to replace electricity supply from the power grid, it achieves significant environmental benefits and the normalized environmental impact value changes from 0.85 to −12.19. The findings provide references for municipal solid waste treatment to mitigate the environmental impact and reduce the economic burden across the entire life cycle.

Environmental performance of Penaeus vannamei shrimp production in intensive and super-intensive biofloc systems

Shrimp farms worldwide have been responsible for a series of social and environmental issues that affect their surrounding regions. Modern aquaculture seeks to achieve sustainable growth that offers a balance between environmental, economic, and social perspectives, and new aquaculture technologies have been developed and improved in recent decades. One such innovation is the biofloc technology (BFT) system, which is considered an alternative to conventional aquaculture because it allows for aquatic organism production with minimal water exchange, high stocking densities, and the possibility of high levels of productivity. Life Cycle Assessment (LCA) is one of the most common methodologies used to compare the environmental performance of different systems, considering resource consumption and the emission of pollutants during the productive life cycle. The present study uses LCA to compare the environmental performance of Penaeus vannamei shrimp production in two BFT systems, an intensive system in a pond and a super-intensive system in a greenhouse. The Functional Unit used was 1.0 ton of shrimp (animals with an average final weight of 12 g). The boundaries of the system were defined as from the cradle to the farm gate. Input data related to the use of natural resources, energy consumption, and environmental emissions were obtained over eight cycles of intensive and super-intensive production. The following results were obtained for intensive and super-intensive systems, respectively: global warming (GWP100a) 5691.12 and 5512.42 kg CO2 eq; acidification 59.57 and 59.05 kg SO2-eq; eutrophication 25.96 and 25.80 kg PO4 eq; ozone layer depletion (OLP) 0.000319 and 0.000311 kg CFC-11 eq; human toxicity 1165.98 and 1233.33 kg 1.4-DB-eq; aquatic ecotoxicity 1344.13 and 1925.96 kg 1.4-DB eq; marine ecotoxicity 1881,643.65 and 2070,517.23 kg 1.4-DB eq; terrestrial ecotoxicity 24.26 and 33.54 kg 1.4-DB eq; photochemical oxidation 2.10 and 2.03 kg C2H4 eq; abiotic depletion 0.006487 and 0.008359 kg Sb eq; abiotic depletion of fossil fuels 35,612.80 and 34,504.39 MJ. Among the eleven evaluated impact categories, the intensive system showed better results in five categories, while the super-intensive system showed better performance in six categories. Feed (reference diet) was the most significant factor in the environmental performance of the evaluated systems. Based on these results, we conclude that feed and electricity had the most environmental impact in both systems. In general, when comparing the use of production factors and productivity between the systems, it becomes more evident that the SS is more efficient than the SI.

Microplastic aquatic impacts included in Life Cycle Assessment

Although Life Cycle Impact Assessment (LCIA) methods assess a wide range of environmental impacts, ecological impacts of plastic pollution are not commonly included. Here, characterization factors of Polypropylene (PP), Low density polyethylene (LDPE) and Polyethylene Terephthalate (PET) microplastics were assessed. Fate was assessed through the multimedia fate model Simplebox4Plastics. Ecological effects were based on species sensitivity distributions. Macroplastic impacts were included though a conversion fraction. The characterization factors were included in ReCipe2016 method and applied to two consumer packaging films to show the relevance of including plastic pollution in LCAs. Plastic losses were assessed using material flow analysis. The freshwater and marine ecotoxicity midpoint indicators were dominated by plastic pollution impacts, whilst these impacts were limited on ecosystem quality as endpoint. Extending this methodology to additional polymers and additional methodological developments will help to obtain a more complete picture of plastic pollution in LCA and to identify effective mitigation options.

Comparative life cycle assessment of integrated renewable energy-based power systems

Integrated renewable-based power cycles should be employed to produce more sustainable electricity. This is a comparative life cycle assessment (LCA) of three combined power plants, encompassing: case 1 involving combined geothermal and wind, case 2 featuring combined geothermal and solar, and case 3 integrating wind and solar systems. The base case perovskite solar cell (PSC) modelling assumes a 3-year lifespan and a power conversion efficiency of 17 %. However, diverse scenarios are evaluated through a sensitivity assessment involving enhancements in lifetime and efficiency. The base case evaluation emphasizes that the phases with the most significant negative environmental effects which includes the drilling of geothermal wells, construction of wind plants, and manufacturing and installation of PSCs. The midpoint findings indicate that boosting the power conversion efficiency of PSC from 17 % to 35 % yields a notable decrease in environmental impact. Moreover, extending the lifetime from 3 to 15 years led to reduction in CO2 emissions from 0.0373 and 0.0185 kg CO2 eq/kWh to 0.026 and 0.0079 kg CO2 eq/kWh in cases 2 and 3, respectively. Assessing worst and best-case scenarios highlights significant declines in certain impact categories. In case 3, terrestrial ecotoxicity (TE), photochemical oxidant formation (POF), human toxicity (HT), marine ecotoxicity (ME), and marine eutrophication (MU) saw reductions exceeding 88 % compared to worst-case results. The environmental effects observed in cases 2 and 3 stem from toxicity and metal depletion, mainly linked to the PSC. Endpoint results revealed that when considering a PSC lifespan of 10 years or more, the detrimental ecosystem impacts of cases 2 and 3 become less severe than those of case 1. Uncertainty assessment has been done for different cases and impact categories. The study's results are also novel in which it evaluated the innovative PSC technology when integrated with other renewable resources, contrasting it with other integrated plants.

Life cycle and efficiency assessment of fixed-bed bioreactor using recycled shredded plastics compared with conventional activated sludge bioreactor for dairy wastewater treatment

Adopting a highly efficient and low-cost bed bioreactor for the treatment of high-strength dairy wastewater has received unprecedented significance. Therefore, the concept of “waste as a resource” was brought up in this study and recycled shredded plastics (RSPs) were used to structure a fixed bed for activated sludge expansion. The performance of the RSP-attached growth system (AGS) and conventional suspended growth system (SGS) with intermittent anaerobic/aerobic conditions were scrutinized for dairy wastewater treatment. In addition, their environmental repercussions, greenhouse gas (GHG) emissions, and ecological footprint were explored to provide innovative insights into the field of research. The AGS system outperformed with substantial COD, nitrate, and phosphorus removal efficiencies (>89 %) in hydraulic retention time of 4 h, aeration time of 27 min, and COD/P ratio of 120. Notably, the SGS system outcompeted in the environmental impacts and energy usage, which accounted for 1.03–4.38 times higher than that for the AGS system. The electricity consumption and wastewater treatment process had striking roles in human carcinogenic toxicity, freshwater/marine ecotoxicity, and human health. The most required energy for AGS and SGS operations was supplied by fossil fuels, which increment GHG emissions from 4.31 to 8.77 kg CO2 eq for the AGS and SGS, respectively. Moreover, the reduction of electricity usage dramatically decreased human carcinogenic toxicity and marine ecotoxicity. Summing up, this study sheds light on the RSPs' capability to support activated sludge and ensure alignment with environmental criteria for dairy wastewater treatment.

Environmental and economic implications of applying augmented reality in express parcel delivery in China

State-of-the-art information and communication technologies (ICTs), such as augmented reality (AR), have been increasingly adopted in express delivery. However, their environmental and economic impacts remain underexamined. We pioneer to assess the environmental and economic performances of applying AR in a parcel distribution center for express delivery, using a perspective life cycle assessment (LCA) approach and a traditional life cycle costing (LCC) method. On the basis of our field investigation and literature analysis, three scenarios, namely Baseline Scenario, AR Scenario, and AR+ Scenario, are developed consistent with current and potential AR applications in parcel delivery. Our findings indicate that AR and AR+ Scenarios are more environmentally sustainable than Baseline Scenario, exhibiting a decrease in global warming potential (GWP) by 13.44 % and 13.06 %, respectively. With the introduction of AR, the values of most selected impact categories show notable declines, except for human toxicity potential and marine ecotoxicity potential. The total endpoint scores decreased by 13.39 % and 12.86 % in the AR Scenario and AR+ Scenario, respectively. Moreover, the AR Scenario and AR+ Scenario are economically advantageous, demonstrating cost reductions of 38.59 % and 49.31 %, respectively, compared with the Baseline Scenario. Most substantial benefits associated with AR occur in the picking & sorting process, exhibiting improved accuracy and efficiency. Our sensitivity analysis underscores the substantial benefit associated with applying AR in routing improvement; 1 % routing improvement leads to a reduction of 0.27 kg CO2-Eq. Moreover, the sensitivity analysis also shows that labor cost is the most influential factor in the overall economic performance; its 1 % fluctuation leads to a change of 1.37 USD in the total cost. Our uncertainty analysis suggests that using more advanced processing units in AR devices leads to superior economic performance, but at greater environmental costs due to increased metallic contents. Based on these assessments, we provide managerial and theoretical implications on adopting smart ICTs in logistics.

Viability of the steam-based extraction of extra-heavy crude oil using nanoparticles: Exergy and life-cycle assessment

The growing energy demand has prompted the research community to seek more efficient and sustainable resource extraction methods, particularly in the case of crude oil. Investigating the potential of nanotechnology to enhance crude-oil recovery from extra-heavy and heavy crude-oil reserves is crucial for optimizing resource utilization, improving economic viability, minimizing environmental impacts, driving technological advancement, ensuring energy security, and meeting market demands. In this study, we investigated the implementation of exergy analysis (ExA) on nanotechnology in oil-recovery processes, which has not previously been explored. This involved a life-cycle assessment (LCA) to evaluate the environmental impacts and to complement the ExA in order to optimize operations. To environmentally and thermodynamically analyze the extraction process of extra-heavy crude oil, four scenarios were evaluated: i) steam injection at 0.5 quality; ii) steam injection at 1.0 quality; iii) steam injection at 0.5 quality with 500 mg L−1 of nanoparticles; and iv) steam injection at 1.0 quality with 500 mg L−1 of nanoparticles. The nanofluids used (AlNi1 and AlNi1Pd1) consisted of 500 mg L−1 of alumina (Al2O3) doped with a 1.0 % mass fraction of nickel (Ni) (i.e., AlNi1), and the same amount of alumina doped with a 1.0 % mass fraction of Ni and palladium (Pd) (i.e., AlNi1Pd1). Both nanofluids were supplemented with 1000 mg L−1 of Tween 80. The experiments were conducted in a laboratory and numerical simulation was used to upscale the different scenarios. Considering the equilibrium K-values model, a multiphase/multicomponent flow model coupled with an energy transport equation was utilized. Nanocatalyst transport, as per the experimental data, involved non-equilibrium transference between the liquid phases and the rock surface. The laboratory data were used to calibrate the model, which was then scaled up to reservoir conditions to estimate the oil recovery obtained from deploying in-situ upgrading processes at the field scale. Exergy calculations were performed on the involved flows and porous media in order to assess the crude-oil quality throughout the process. An LCA was implemented to evaluate the reduction in environmental impact achieved by using steam injection at X = 1.0 quality, with and without nanoparticles. The results of the ExA showed that using nanoparticles allowed crude oil with a higher energy quality to be obtained. Furthermore, the ExA showed that the increase in steam quality had a more significant effect on the exergy destroyed in the process than the use of nanomaterials, demonstrating the good performance of the proposed technology. Environmental analyses showed that marine ecotoxicity, urban land occupation, particulate matter formation, and global warming potential were the most-impacted categories, significantly contributing to total environmental impacts, after the fossil depletion impact category for all scenarios. In conclusion, using bimetallic nanoparticles in crude-oil extraction produces a better product with better energy and environmental performance.

Testing a novel life cycle assessment based framework for produced water management from offshore oilfield operations

As worldwide reliance on the petroleum industry persists, environmental concerns associated with offshore oilfield operations continue to present a critical challenge for sustainable management. This study develops and tests a novel life cycle assessment (LCA)-based framework to examine strategies for produced water (PW) management from offshore oilfield operations. The framework encompasses experimental designs under a dynamic modelling system coupled with stepwise linear regression, multi-criteria decision analysis (MCDA), and fluctuating scenarios in Enhanced Oil Recovery (EOR) and other internal reuse options including cooling systems, drilling operations, and utility services. Two strategies for treatment train technologies were tested with various PW compositions, sludge management options, and variable EOR demands. When comparing conventional (corrugated plate interceptor, hydrocylone and nutshell filter) with recent treatment/disposal technologies (tubular separation, combined fiber coalescence and mechanical vapor compression), the LCA revealed that the latter increased operational efficiency (14%), reduced cost (6.5%) and the overall environmental impact categories (66%). The scenario that exhibited the lowest emissions incorporated recent treatment technologies and land application for sludge management. This configuration demonstrated considerable environmental advantages, evidenced by significant reductions in key impact indicators including freshwater eutrophication (74%), global warming (64%), marine ecotoxicity (58%), and stratospheric ozone depletion (44%) when compared to the baseline scenario with conventional treatment-disposal methods. The system dynamics model revealed that the internal reuse options exploited 23%–47% of PW inflow, indicating a significant annual surplus of unused PW that presents an opportunity for external applications to enhance sustainability. In closure, we argue that the proposed framework offers a valuable tool for waste management practitioners, facilitating the identification and selection of strategies with minimal environmental impacts for PW management.

Strong economic incentives of ship scrubbers promoting pollution

In response to stricter regulations on ship air emissions, many shipowners have installed exhaust gas cleaning systems, known as scrubbers, allowing for use of cheap residual heavy fuel oil. Scrubbers produce large volumes of acidic and polluted water that is discharged to the sea. Due to environmental concerns, the use of scrubbers is being discussed within the International Maritime Organization. Real-world simulations of global scrubber-vessel activity, applying actual fuel costs and expenses related to scrubber operations, show that 51% of the global scrubber-fitted fleet reached economic break even by the end of 2022, with a surplus of €4.7 billion in 2019 euros. Within five years after installation, more than 95% of the ships with the most common scrubber systems reach break even. However, the marine ecotoxicity damage cost, from scrubber water discharge in the Baltic Sea Area 2014–2022, amounts to >€680 million in 2019 euros, showing that private economic interests come at the expense of marine environmental damage.

Life cycle analysis of the wastewater treatment system in Zabol Industrial Town: Environmental impacts, energy demand, and greenhouse gas emissions.

Use of effective environmental remediation facilities represents a crucial strategy for water reclamation and addressing the challenges of water scarcity. The objective of this study was to assess the wastewater treatment system (WWTS) in Zabol Industrial Town using the life cycle assessment method. Primary data, collected annually for a functional unit of 1 m3 of wastewater treatment, were subjected to analysis using the ReCiPe, Cumulative Energy Demand, and Intergovernmental Panel on Climate Change (IPCC) methods. Human carcinogenic toxicity (50%), freshwater ecotoxicity (13%), and marine ecotoxicity (10%) were the primary environmental impacts due to the WWTS performance. The discharge of heavy metals during sludge generation, coupled with the consumption of natural gas and oil, especially for electricity production, were pivotal factors contributing to the environmental burdens observed. Furthermore, chemical oxygen demand (COD) (56.34%), electricity consumption (>15.47%), and total phosphorous (>4.49%) significantly threatened human health and ecosystem categories, while fossil fuel consumption had the greatest impact on resources. Nonrenewable fossil fuels, namely, natural gas (47.2%) and oil (38.27%), played a predominant role in the energy provision of the system. The IPCC analysis depicted the emissions of CO2 (86.77%) and CH4 (12.16%) stemming from the process of electricity generation. Based on the outcomes of the sensitivity analysis, implementing a 10% increase in COD yielded an increment in all impacts within the range of 1.40% to 6.83%. Given Iran's geographic location and the unique climatic conditions in Zabul, use of solar and wind energy to energize the WWTS can substantially alleviate its environmental burdens. This study presents a comprehensive framework for evaluating the environmental impact, energy consumption, and carbon footprint of a WWTS. Integr Environ Assess Manag 2024;20:1747-1758. © 2024 SETAC.