Major Minerals Research Articles

The application of KMnO4 in reverse flotation separation of chalcopyrite and talc and its selective depression mechanism

Talc exhibits excellent floatability and, as a major silicate gangue mineral associated with chalcopyrite, significantly obstructs the purification and smelting of chalcopyrite. This study investigates the reverse flotation separation of chalcopyrite and talc using KMnO4 as a depressant and DDA (dodecylamine) as a collector within a reverse flotation system. Single mineral flotation experiments show that after adding KMnO4, the recovery of chalcopyrite in 38–74 μm is only 6.86 %, whereas the recovery of talc in 45–106 μm and 25–45 μm are 93.47 % and 89.25 %, respectively. Further experiments with artificially mixed ores demonstrate that KMnO4 effectively achieves the separation of chalcopyrite and talc. The depression mechanism of KMnO4 on chalcopyrite and talc was analyzed using Zeta potential, contact angle measurement, AFM (atomic force microscopy), FTIR (Fourier transform infrared spectroscopy), XPS (X-ray photoelectron spectroscopy), and DFT (density functional theory) calculations. Mechanistic analysis indicates that in an alkaline environment, chalcopyrite can undergo a redox reaction with KMnO4, forming hydrophilic hydroxide species (Cu(OH)2, Fe(OH)3) on the chalcopyrite surface, which depresses chalcopyrite flotation. In contrast, the surface properties of talc are relatively stable and difficult to react with KMnO4, which cannot depress the flotation of talc. Therefore, KMnO4 can be used as an efficient and selective depressant for the reverse flotation separation of chalcopyrite and talc.

Study on the influence of indentation depths on the fracture characterization and acoustic emission characteristics of minerals in granite using nanoindentation

To investigate the intrinsic mechanisms of rock rupture at the mesoscale, this study employed nanoindentation tests on three primary minerals in granite at various indentation depths. Concurrently, rupture signals generated throughout the indentation process were recorded using the PCI-2 acoustic emission (AE) system. The results revealed that crack lengths in quartz and feldspar increased with indentation depth, whereas mica exhibited negligible radial cracking, showing only short, irregular cracks around the edges of the indentation marks. As indentation depth increased, the intensity of plastic deformation at the indentation point also increased, leading to a gradual reduction in fracture toughness and a corresponding rise in AE amplitude and energy. All three minerals generally showed a higher proportion of high-frequency signals compared to low-frequency signals, with the distribution characteristics of these signals being significantly influenced by the mineral properties. Quartz and feldspar exhibited relatively balanced frequency distributions, while mica had a higher proportion of high-frequency signals. At different indentation depths, most signals displayed characteristics of higher RA values and lower AF values, indicating that, at the mesoscale, the rupture modes of the three major minerals in granite are predominantly shear failures.

Circular economy strategies in sedimentary phosphate mine reclamation: Development of technosol from phosphate waste rock

Proper management of mine waste plays a crucial role in minimizing environmental impacts. One potential solution to tackle this problem involves transforming mine waste rock into soil to facilitate the process of mine restoration. The aim of this study was to assess the mineralogical, chemical, and physical characteristics of technosol derived from phosphate mine waste dumps. Following this evaluation, a novel rehabilitation strategy was proposed. For this purpose, a total of 32 samples were systematically collected across a 4 ha area of technosols, which had been established in accordance with the waste rock soil rehabilitation strategy involving geomorphic reshaping. According to the findings, phosphate mining left the soil with a sandy texture, resulting in a degraded soil structure with severely unfavorable crop growth conditions, notably poor stability, and low water retention. The chemistry of the studied soils was characterized by the dominance of CaO (29.02 wt%± 1.01) > SiO2 (27.61 wt% ± 0.61) > P2O5 (11.34 wt% ± 0.23) > MgO (5.97 wt%±0.16). Mineralogically, the samples were mainly formed by quartz, dolomite, calcite, apatite, and clay minerals. The prevalence of dolomite played a significant role in enhancing the accessibility of Mg as an essential nutrient and the occurrence of apatite in the soil resulted in the presence of P2O5. However, the abundance of Ca was linked to three major minerals: calcite, apatite, and dolomite. X-ray fluorescence analyses demonstrated that the concentrations of Fe2O3, K2O, and SO3 did not exceed 2 wt%.Organic matter, represented by SOC <0.2% and N < 0.02%, demonstrated an extraordinary deficiency in the study area. The analysis of element bioavailability confirmed that the soil was rich in Ca (10383,26 mg/kg), Mg (278,47 mg/kg), Zn (12,82 mg/kg), and Cu (3,7 mg/kg) but deficient in other essential nutrients such as P, K, S, Mn, and Fe. Our research results provide a set of recommendations aimed at enhancing existing mine rehabilitation practices applicable to both pre- and post-rehabilitation phases, leveraging automated mineralogy and circular economy principles. Notably, we propose a rehabilitation strategy to be implemented prior to the geomorphic reshaping phase, which is intended to reduce costs and efforts associated with soil reconstitution.

Enhancing yields of Pleurotus ostreatus and Lentinula edodes mushrooms using water hyacinth (Eichhornia crassipes [Mart.] Solms) supplemented with locally available feedstock as substrate

This study assessed the performance of Pleurotus ostreatus and Lentinula edodes mushrooms on a variety of substrate combinations. Water hyacinth, rice husk, and cow dung were employed as substrates. Mushroom growth performance, yield, proximate composition, and mineral content were among the variables evaluated. The results indicate significant differences (p < 0.05) in spawn run duration, first harvest duration, total yield, and biological efficiency among the substrate combinations for the mushroom species. The substrate combination of 80% water hyacinth and 20% cow dung consistently exceeded the performances of others, demonstrating higher total yield (863.00 and 799.81 g/bag) and biological efficiency (88.51% and 82.03%) for P. ostreatus and L. edodes mushrooms, respectively. Proximate analysis results also demonstrated that this substrate combination produced mushrooms with higher protein (14.72 and 12.04%) and carbohydrate (55.11 and 58.05%) contents for P. ostreatus and L. edodes, respectively. P, K, Mg, Na, Ca, Fe, Zn, and Cd levels in P. ostreatus samples ranged from 1700 to 2700, 28100 to 39500, 1600 to 7800, 291.55 to 400.23, 310.37 to 372.70, 26.42 to 45.47, 61.87 to 70.40, and 1.13–1.25 mg/kg on average, respectively. The levels for P, K, Mg, Na, Ca, Fe, Zn, and Cd ranged from 19700 to 22700, 22500 to 25000, 2100 to 2500, 250.96 to 300.90, 284.66 to 296.19, 24.04 to 29.49, 74.03 to 83.98, and 1.31–1.45 mg/kg for L. edodes samples. The evaluated mushrooms grown on the various substrate combinations contain higher major and minor minerals needed in the human diet than toxic elements. This indicated that the evaluated edible mushrooms had high important mineral levels and could be considered a good source of vital elements. They are also very good at balancing nutrient supply scarcity, which is common in developing countries like Ethiopia. However, according to the World Health Organization's permissible limits for human intake, adequate attention and control of daily dietary intake is necessary for specific elements.

Changes in the nanomechanical properties of the constituent minerals in the ductile fauske marble and the brittle kuru granite during progressive failure

The nanoscale elastic moduli and hardness of the constituent minerals of the Class II Kuru granite and the Class I Fauske marble were experimentally investigated. The aims were to correlate the microcrack patterns with the nanomechanical properties of the minerals, and to help understand the important roles of the nanomechanical properties of the minerals in brittle and ductile behaviors. Cylindrical rock specimens were uniaxially loaded to various stress levels in both the pre- and post-peak stages. The specimens were then unloaded to zero, and two thin sections –– one parallel with and the other perpendicular to the loading direction –– were prepared from each specimen. Nano-indentation tests were conducted on the thin sections to measure the elastic moduli and hardness of the major constituent minerals in the rocks. The test results showed that both the elastic moduli and hardness of the minerals abruptly decreased when the applied stress was above 80 % of the uniaxial compressive strength of the rock in the pre-peak stage and also in the entire post-peak stage. At the same time, the values of the two properties became more scattered with increasing damage to the minerals. The number of intragranular cracks was significantly less in the harder quartz and microcline than in the softer calcite. The abundant intragranular cracks in the calcite dissipated most of the strain energy in the Class I marble, such that the rock was not burstable after failure. A small number of intragranular cracks were created in the quartz and microcline in the Class II granite, such that most of the strain energy in the minerals was released to eject rock after failure. Intragranular cracking is thus a key factor in determining whether a rock is burst-prone or not.

Tracing magmatic footprints: Influence of a CO2-rich melt on the mineral assemblage of the San José del Guaviare Syenite, SE Colombia

A combined optical and electron microscopy (SEM, EDS, and EPMA) study was conducted on ten rock samples from the Proterozoic San José del Guaviare Syenite (SJGS), southeastern Colombia, to utilize minor and trace minerals in interpreting the magmatic evolution of these silica undersaturated rocks. The major minerals of the sampled syenites are nepheline, Fe-rich clinopyroxene, amphibole, alkali feldspar, and biotite. The minor minerals are titanite, calcite, cancrinite, and sodalite. Trace minerals are the niobium- or rare earth element-rich minerals pyrochlore, columbite, euxenite, britholite, ancylite-Ce and wöhlerite. Apatite, rhodochrosite, strontianite, fluorite, zircon, magnetite, ilmenite, and pyrite occur as traces as well. Crystallization started with primary (magmatic) calcite and Nb-rich minerals pyrochlore, columbite, euxenite, and a first generation of apatite, which occur as inclusions in foids, feldspars, and Fe-rich clinopyroxenes. Calcite is enriched in light rare earth elements and Sr, with low Mg concentrations, while primary apatite has high Sr concentrations. Both minerals have a composition typical for minerals crystallized in carbonatites. The presence of calcite and high Fe and low Ti clinopyroxene point to CO2-saturated conditions. During cooling, fluorbritholite-Ce formed as individual grains or by a fluid-enhanced apatite-britholite transformation. The formation of Fe-rich amphibole, often at the expense of Fe-rich clinopyroxene, reveals a decreasing influence of CO2 and temperature. Presumably, the transformation of orthoclase into microcline occurred simultaneously. Perthitic microcline as a second K-feldspar generation indicates slow cooling from high temperatures. A late stage of CO2-rich hydrothermal-metasomatic processes is suggested by the growth of secondary cancrinite, Sr-Mn carbonates and ancylite-Ce. The composition of primary and early crystallized calcite and apatite makes their origin as residues of an early segregated or independently formed mantle-derived carbonatitic melt more likely than crystallization from a CO2-rich syenitic melt. An origin from melted crustal carbonates is unlikely as well. Therefore, the presence of a carbonatitic melt at an early magmatic evolutive stage, as opposed to a non-carbonatitic melt at a late stage, seems possible for the SJGS rocks.

Unstable Sliding of Plagioclase Gouge and Deformation Mechanisms Under Hydrothermal Conditions With Effective Normal Stresses of 100–300 MPa

AbstractPlagioclase feldspar is a major mineral in mafic crustal rocks. To better understand the deformation mechanism of plagioclase feldspar during frictional faulting, we conducted shearing experiments on simulated plagioclase gouge in a wide range of effective normal stress of 100–300 MPa, pore‐water pressure of 30–100 MPa, and temperatures ranging from 100°C to 600°C. The coefficient of friction is found to range from 0.65 to 0.74 across the entire temperature range, showing no significant thermal weakening process. Except for a case at 200°C with an effective normal stress of 300 MPa, the frictional sliding is velocity weakening over the whole temperature range, showing a steady‐state rate dependence (a−b) ranging from −0.5 × 10−3 to −8.6 × 10−3. This property facilitates nucleation of unstable slips in frictional faulting. Above 200°C, the direct rate effect parameter (a) and the evolution effect parameter (b) of friction increase with temperature up to a threshold of 400°C or 500°C, depending on the effective normal stress. This thermal enhancement suggests thermally activated creep at contact junctions governed by intergranular pressure solution, as evidenced by microstructural signatures indicating the prevalence of very fine precipitates formed at the surfaces of gouge particles as a result of pressure solution. In frictional sliding of plagioclase, a low effective normal stress of 100 MPa corresponds to a higher degree of velocity weakening and tends to facilitate seismic slip rather than slow slips, whereas the high effective normal stress of 300 MPa corresponds to a minor velocity weakening which may cause slow‐slip events in faults of limited size.

Effect of Different Sizes and Heights on the Removal Efficiency of Composite Clay Filter for Gold Mine Site Wastewater Remediation

Wastewater from mining-related activities contains toxic elements that require remediation, and most available wastewater filters have inconsistent flow rates and removal efficiency due to their thickness. This study, therefore, examined the effect of height and size on the flow rate and removal efficiency of a clay composite filter for wastewater remediation. The developed clay filter and its composites were characterized using various techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The XRF analysis showed that the clay contained 91.38% major minerals, including iron oxide (Fe2O3), aluminum oxide (Al2O3), and silica (SiO2), which could enhance the filtration process. Additionally, FTIR revealed that both the clay and the filter are rich in functional groups, including kaolinite and illite, which could promote the filtration process. Further analysis showed that the filters had an average adsorption rate of 87.32%, an average flow rate of 0.891 L/hr, and an average removal efficiency of 99.6%. An increase in the height of a small-diameter filter resulted in a 0.21% increase in removal efficiency, while for larger diameters, the removal efficiency decreased by 0.11%. Conversely, increasing the diameter of a short filter increased the efficiency by 0.25%, while for taller filters, the removal efficiency decreased by 0.07%. Therefore, this work demonstrated that both height and diameter have noticeable effects on flow rate: as height increases, flow rate decreases, and as diameter increases, flow rate increases. The filter's efficiency is somewhat affected by both height and diameter, with a small increase in efficiency noted at greater heights and a slight decrease in efficiency noted at larger diameters.

Integrated Geophysical Investigation using Aero-radiometric and Electrical Methods for Potential Gold mineralization within Yauri/Zuru Schist Belts, Kebbi State NW Nigeria

This study used aero-radiometric, 2D electrical resistivity tomography (ERT), and induced polarization (IP) methods to delineate gold mineralization potential. The study also confirmed and followed-up on regions with major structural features identified in previous aeromagnetic studies in the area. A half-degree airborne radiometric data of sheet 118_Yelwa from the NGSA, which contains three radioelements (%K, eTh, and eU) were used in this study. These datasets were processed and analyzed with Oasis Montaj Grid Math expression builder to obtain the %K_ratio_eTh and Ternary grid anomalies. The results identified zones E and F as hydrothermally altered regions that may harbour gold mineralization. These findings were consistent with the regions of major structural features identified in previous aeromagnetic studies in the area. The zones were located in the eastern parts of Ngaski, Yauri (Yelwa), Shanga, and Agwara, as well as Magama's northwest region. However, zone F1 (the eastern portion of Ngaski/Yauri) has been further investigated using 2ERT and IP detailed geophysical methods in a dipole-dipole configuration. The results of geoelectric techniques along profiles 1, 2, and 3 identified the major gold mineralization potential zones, which were labeled A1, A, and C. These regions have low/high resistivity and chargeability signatures, and could thus be interpreted as potential target zones for metallic mineral exploration, particularly gold mineralization. The regions are located in the northern part of Mararraba and southwest of the Jinsani areas of Kebbi State.

Phosphorus availability from olivine for biospheres

Phosphorus plays a multifaceted role for all known life and hence understanding its sources on the early Earth provides constraints on how life developed to incorporate this element into its biochemistry. Currently, the major phosphorus mineral group on the surface of the Earth are the apatites, which are poorly soluble calcium phosphates and hence may not have been a good source of phosphorus on the early Earth. An alternative source of phosphorus may be the mineral olivine. Given that olivine makes up a large part of the upper mantle of Earth and presumably other rocky planets and moons, it stands to reason that olivine may be a potential phosphorus reservoir for prebiotic chemical environments. Here we examine the phosphorus content of 10 olivine samples from different terrestrial localities to determine their P content and P speciation. We find that extracts of the samples contain varying amounts of phosphate, and some contain pyrophosphate. Olivine may have served as a source of phosphate on the early Earth and possibly elsewhere in the solar system, and its dissolution could have supplied this nutrient to a nascent biosphere.

Characteristics of Semiconducting Minerals Affects Microbial Communities in Purple Soils

Purple soil is rich in semiconducting minerals, but the impact of these minerals on soil properties and associated microbiome assemblages has received little attention. To better understand the influence of semiconducting minerals in soils, samples were collected from 4 soil classifications, including purple soil, siltstone, farmland, and new formed soil. Goethite was the main semiconducting mineral in purple soil followed by rutile and birnessite, while for siltstone, rutile was the major semiconducting mineral. Proteobacteria (77.77–98.56%) was the most prevalent phylum among all samples, with the second most abundant phylum being Cyanobacteria (purple soil and farmland) and Firmicutes (siltstone and new formed soil). According to the average path length in network analysis, purple soil showed higher species segregation, which suggested purple soil was potentially more susceptible to external interference than the other types. The relationship between microbes may be synergistic due to the positive links between microbial phyla. Rutile affected microbial composition to the greatest extent, accounting for 13.66% of the total variation in microbial assembly, while goethite (r= –0.0947) and birnessite (r = 0.0215) content were also associated with changes in microbial composition. These results demonstrated that semiconducting minerals affected the structure and potential energy utilization of soil microbial communities.

Reduced partition function ratios of iron, magnesium, oxygen, and silicon isotopes in olivine: A GGA and GGA + U study

Olivine, typically occurring as a forsterite-fayalite solid solution, is a major rock-forming mineral in mafic and ultramafic igneous rocks, and it is important for understanding the genesis, evolution, and alteration of its host rocks. In this study, both GGA and GGA + U methods were employed to calculate the reduced partition function ratios of Fe, Mg, O, and Si isotopes for the forsterite-fayalite solid solution, aiming to elucidate the impacts of Fe content and Hubbard U correction on the isotope fractionation signatures of Fe, Mg, O, and Si in olivine. On the whole, the βFe-factor, βMg-factor, βO-factor, and βSi-factor decrease with increasing Fe content. The linear correlations between β-factors and bond lengths obtained from GGA + U are better compared to those from GGA. The Hubbard U correction can increase the βFe-factor. When Fe/(Fe + Mg) ≤ 1/8, ≤ 1/2, and ≤ 1/2, the effect of Hubbard U correction on βMg-factor, βO-factor, and βSi-factor can be considered negligible, respectively, suggesting that the βMg-factor, βO-factor, and βSi-factor of Fe-bearing olivine calculated using GGA + U and those of Fe-free minerals calculated using GGA can be combined to derive 103lnα and trace geological processes. Furthermore, equilibrium fractionation of Fe, Mg, O, and Si isotopes between olivine and other minerals, including troilite, clinopyroxene, and garnet, were also calculated. Our results are helpful in interpreting the observed data regarding Fe, Mg, O, and Si isotopic compositions of olivine, leading to a comprehensive understanding of relevant geological processes.

The Xilaokou carbonate-sulfide vein type gold deposit: A distinct mineralization in the giant Jiaodong gold province, North China

The Xilaokou gold deposit with ca. 50 t of gold reserve @ 2.7 g/t represents a novel type (carbonate-sulfide vein type) of gold mineralization within the Jiaodong gold province. However, its mineralization age and metallogenic mechanism remain poorly constrained, hindering a comprehensive understanding of the ore-forming processes in the Jiaodong gold province. In this study, we employ syn-ore stage hydrothermal monazite in situ U-Pb geochronology to determine the ore-forming age of the Xilaokou gold deposit. Additionally, we conduct in situ LA-(MC)-ICP-MS elemental mapping and sulfur isotope analysis in ore-related pyrite to unravel the sulfur source(s) and provide new insights into the ore-forming processes of the Xilaokou gold deposit. Our findings reveal the following key points: (1) U-Pb dating of hydrothermal monazite in Au-bearing pyrite yields an ore-forming age of119.9 ± 3.0 Ma. This age is consistent with the mineralization ages (around 120 ± 5 Ma) of other gold deposits in the region, including Liaoshang-, Jiaojia-, and Linglong-type deposits. (2) Gold in pyrite primarily occurs as micro-grains (5–20 μm) within pyrite fissures associated with sphalerite and galena. (3) Elemental mapping and sulfur isotope analysis indicate that major Au mineralization is linked to elevated concentrations of As, Sb, and Tl, along with heavy sulfur isotope values (δ34S∼24.7 ‰). (4) Early-stage Au mineralization is characterized by enrichment of As, Cu, and Bi, with normal sulfur isotopic composition (δ34S∼8 ‰). We propose that the carbonate-sulfide vein type gold deposits represented by the Liaoshang and Xilaokou gold deposits in the Jiaodong gold province are genetically linked to quartz-sulfide vein and disseminated type deposits. The major ore-forming stage involved the addition of S and Au from a metamorphic massif at slightly lower temperatures. These findings highlight a new exploration direction within the North China Craton. In summary, the Xilaokou gold deposit provides valuable insights into gold mineralization processes in Jiaodong, emphasizing the importance of considering diverse deposit types and their genetic relationships in the region.

From melt- to crystal-rich magmatic systems during rift localization: Insights from mineral chemistry in Central Afar (Ethiopia)

Magmatism plays a key role in accommodating and localizing extension during continental breakup. However, how the crustal magmatic systems evolve at the continental-ocean transition is poorly understood. We address these questions by studying the evolution of the magmatic system in the rift of Central Afar (Ethiopia), currently marking the transition from continental rifting to oceanic spreading. We focus on the voluminous and widespread Upper Stratoid Series (2.6–1.1 Ma) and the following Central Afar Gulf Series (1.1–0.6 Ma), the latter corresponding to localization of volcanism in narrow magmatic segments. We carried out the first systematic study of major and trace element mineral chemistry for these two Series and integrated it with geothermobarometry estimates and geochemical modeling, to reconstruct the evolution of the magmatic system architecture during rift localization. The Upper Stratoid magmas evolved by fractional crystallization in a melt-rich, moderately zoned, middle-lower crustal (10–18 km) magmatic system, from where they rose directly to the surface. Polybaric plagioclase convection and dissolution of a plagioclase-rich crystal mush is recorded in the phenocryst texture and chemistry. The Central Afar Gulf magmas evolved at similar depth in a more complex and dynamic storage system, with magma rising and mixing through multiple, relatively small, crystal-rich and interconnected reservoirs. Our study documents the transition during the continental breakup, from an overall stable and melt-rich magmatic system feeding the voluminous and homogeneous Upper Stratoid eruptions to a more dynamic, interconnected and crystal-rich situation feeding small-volume eruption while the rift localizes.

Nutritional and Medicinal uses of Different Types of Berries and Rabbit

This abstract will provide an outline of the nutritional and therapeutic benefits of several berries. It will focus on the major vitamins, minerals, antioxidants, and phytochemicals found in berries, as well as how these compounds can benefit overall health and well-being. The study will also look into the possible therapeutic applications of berries in the prevention and treatment of several health disorders, including cardiovascular disease, diabetes, and cancer. It will discuss the differences in nutrient profiles and bioactive chemicals found in various berry species, as well as how these variances may influence their distinct health-promoting properties. Furthermore, the abstract will discuss any potential safety risks or contraindications related with berry eating, particularly for people who have certain medical problems or are taking specific drugs.

The mechanical properties of Lucaogou shale layered samples and the influence of minerals on fracture propagation

Shale oil is one of the most promising alternative unconventional energies in the world, and Lucaogou Formation shows significant exploration potential, becoming the primary target in northwestern China. This paper compared the mechanical properties of shale layered samples from oil layer and interlayer of Lucaogou Formation, using uniaxial compressive tests with real-time micro-CT scanning. After that, the mineral analysis was conducted on one cross-section of the fractured sample to analyze the influence of mineral composition and distribution on micro-crack propagation. Such research has rarely been reported before. The results showed the surface porosity and elastic modulus of oil-bearing samples is larger than that of the interlayer samples, while the uniaxial compressive strength is lower. Besides, when there is only one dominant mineral with a content greater than 60%, a main crack tends to form at this area; When there are 2∼3 major minerals with a content of 10%∼60%, a fractured zone with many fine micro-cracks is more likely to form here. Finally, the higher the Moh’s hardness of the mineral, the more difficult it is for micro-cracks to develop through it.

Shifting Toward Clean Energy Technology: Assessing Vietnam Critical Minerals Demand and Domestic Resources

Abstract Vietnam is progressing toward an energy transition to achieve the 2050 net-zero emissions target by switching from fossil fuel-based to clean energy technologies. According to Politburo’s Resolution No. 55, the renewable energy share in the total primary energy supply will account for 30% by 2045. The newly approved National Power Development Plan set the target to increase the renewables share to 63% of total installed capacity by 2050. The demand for clean energy equipment, such as solar photovoltaic modules, wind turbines, and batteries, is expected to grow rapidly as a result of the decarbonization pathways for the power and transportation sectors in the coming decades. The manufacturing of clean energy equipment will require substantial amounts of critical minerals. Therefore, this study evaluates the demand for major critical minerals in producing clean energy equipment, including cobalt, copper, lithium, nickel, silicon, and rare earth elements. The critical minerals demand is estimated based on critical mineral intensities and additional capacities of clean energy equipment to be installed in 2021-2030 and 2031-2050 stages under Vietnam’s current policies. The results show that the total critical minerals demand in 2021-2030 and 2031-2050 is estimated to increase approximately three-fold and 15-fold, respectively, compared to the 2021 level. Furthermore, the article reviews Vietnam’s critical mineral resources and the potential contribution to domestic and global supply in the coming years.

Textural and chemical variations in peridotite induced by hydrous melt migration in mantle under the back-arc spreading

This study presents the structural and petrological characteristics of mantle peridotites in relation to the rock-hydrous melt reaction found in the Hayachine ultramafic complex, NE Japan. We conducted sampling, microstructural observations, crystal-orientation analyses, and major element composition analyses of the major constituent minerals in the peridotites. We used 17 serpentinized peridotites that preserved better mantle textures. The peridotites are composed of lherzolite to harzburgite, consisting of olivine, orthopyroxene, clinopyroxene, amphibole, and spinel. The peridotites were classified into two textures according to olivine grain size: coarse-grained (ca. 2–3 mm) and fine-grained (ca. 0.3–0.5 mm). Fine-grained peridotites were newly found in this study and were characterized by aggregates of orthopyroxene and amphibole with a large number of spinel inclusions. Based on olivine crystal-preferred orientation (CPO), we found that the coarse-grained peridotites were further classified into Group 1 (A type CPO) and 2 (AG type CPO) and the fine-grained peridotites were accordingly classified into Group 3 (weak CPO). The systematic continuity in the chemical compositions of the minerals suggests that Group 1 peridotites partially melted to form Group 2 peridotites, followed by Group 3 peridotites, due to further reaction of Group 2 peridotites with hydrous melts. These textural and chemical variations in the peridotites could have resulted from rock-hydrous melt reactions under back-arc spreading and subsequent processes.

Experimental study and chemical equilibrium calculation on the mineral transformation of high-alkali coal under oxy-fuel condition

The study aimed to study the mineral transformation of high-alkali coal to address the ash-related issues in oxy-fuel combustion. However, the traditional ashing method alone is inappropriate to study the mineral transformation at the initial stage of coal combustion due to the high ashing temperature. Hence, both the plasma ashing method (<200 °C) and traditional ashing method (600–1200 °C) were employed in this research to prepare the ash samples for characterization. The plasma ashing method is an efficient way to determine the original minerals in coal because it can consume the organic matter at low temperature. The recirculation of flue gas in oxy-fuel combustion can lead to high SO2 and H2O concentrations, while their influences on mineral transformation need to be clarified. In this work, SO2 and H2O were injected into CO2 to simulate the recycled flue gas (RFG). Furthermore, the chemical equilibrium calculation was conducted besides multiple experimental tests to acquire more comprehensive information of mineral transformation. The results show that high sodium and calcium contents are determined in these high-alkali coals, and two of them are rich in iron. In O2/CO2 atmosphere, some sodium (e.g. NaCl) volatilizes into the gas phase and the others converts into aluminosilicates (e.g. NaAlSi3O8) during the heating process. The calcium salts (mainly CaCO3 and CaSO4) decompose and produce silicates, aluminosilicates, and magnesium silicates. The major iron-containing minerals are identified as FeS, FeS2, and Fe2O3. Both FeS and FeS2 are oxidized into Fe2O3 below 600 °C. Moreover, the kaolinite (Al2Si2O5(OH)4) in raw coals decomposes at low temperature (<600 °C). In O2/RFG atmosphere, the additions of SO2 and H2O enhance the sulfation of AAEMs (alkali and alkaline earth metals) and delay the decomposition of sulfates. The productions of some silicates, aluminosilicates, and magnesium silicates of AAEMs are inhibited to varying degrees, and there could be complicated salts containing sulfur (e.g. hauyne). The transformations of iron-containing minerals are little related to the presences of SO2 and H2O. This work obtained the transformations of main minerals in high-alkali coal under O2/CO2 and O2/RFG conditions, which helps to address the ash-related issues.

Update on the 53Mn-53Cr ages of dolomite in the Ivuna CI chondrite and asteroid Ryugu sample

Aqueous alteration in planetesimals is one of the earliest geological processes in the solar system. The timing of aqueous alteration sheds light on the timescale of material evolution through water–rock interaction in small bodies. The 53Mn-53Cr decay system, where a short-lived radionuclide 53Mn decays to 53Cr with a half-life of 3.7 Myr, is a powerful tool for dating carbonates in primitive meteorites that formed during aqueous alteration. In CI chondrites and samples returned from asteroid Ryugu, a major carbonate mineral is dolomite (CaMg(CO3)2) and could be dated precisely because of their relatively high Mn abundances. However, the lack of a proper dolomite standard for secondary ion mass spectrometry (SIMS) hinders us from obtaining accurate Mn/Cr ratios of carbonates, resulting in erroneous formation ages. In this work, we synthesized Mn-, Cr-, and Fe-bearing crystalline dolomite as standard materials and evaluated the relative sensitivity factor (RSF) of Mn/Cr for SIMS analysis, namely, the ratio of Mn/Cr obtained using SIMS to true Mn/Cr. We found that the RSF values of the dolomite standards range from 0.8 to 0.9, slightly higher than that of calcite (CaCO3) (∼0.7), and increase with their Fe contents. We used the newly evaluated RSF values to date dolomite in the Ivuna CI chondrite and obtained an initial 53Mn/55Mn ratio of (3.95 ± 0.49) × 10−6 (95 % confidence interval) and the corresponding absolute age of 4564.0 + 0.6/−0.7 Ma. Our new initial 53Mn/55Mn ratio is 26 ± 19 % higher than that obtained by a previous study for the same dolomite grain using a calcite standard. This difference is consistent with the difference between the RSF values of dolomite and calcite. Based on these results, we updated the initial 53Mn/55Mn ratio previously reported for dolomite in the Ryugu sample A0058 to be (3.21 ± 0.66) × 10−6, which corresponds to an absolute age of 4562.8 + 1.0/−1.2 Ma. This age seems to be the best estimate for the formation age of dolomite in Ryugu currently available.