Magnetite Crystals Research Articles

Magma mixing, degassing and late sulfide saturation: Insights into the 1976–2000 eruptive sequence at White Island, New Zealand

This paper reports new petrological and chemical data of ejecta from the 1976–2000 eruptive sequence of White Island, New Zealand. We provide evidence of mixing between shallow stored (0.7–1 km) andesitic to dacitic melts and deeper primitive mafic magma carrying high-Fo olivine, repeatedly injected throughout the sequence. Melt inclusions hosted in plagioclase, pyroxene and olivine were analyzed for major, trace and volatile elements. The low H2O contents in inclusions suggest it exsolves at depth while SO2 degassing is recorded during the rise and crystallization of the mafic magma. The higher solubility of Cl (as HCl and NaCl) delays its exsolution until shallow depth. Convection degassing is suggested to explain the large imbalance between elevated gas emissions and low amount of lava erupted. Frequent inputs of gas-rich, deeply derived magma are essential drivers for the counterflow of viscous degassed melts. Metal contents (Cu, Zn) of the residual mafic magma increases during olivine crystallization. This behavior changes during shallow differentiation of the andesitic magma, with metals leaving the silicate melt. While some metals may be lost to degassing, Cu, Ni, Ag and Au strongly partition into an immiscible sulfide melt. Saturation of such a sulfide melt phase occurs in the shallow environment, likely related to changes in redox state associated with magnetite crystallization and/or SO2 degassing.

Hexagonal magnetite in Algoma-type banded iron formations of the ca. 2.52 Ga Baizhiyan Formation, North China: Evidence for a green rust precursor?

Abstract Banded iron formations (BIFs) are iron-rich marine chemical sedimentary rocks, and their mineralogy and geochemistry can be used to gain insights into ancient ocean chemistry and biospheric evolution. Magnetite is the major iron-bearing mineral in many BIFs (particularly in the Archean) and is variably interpreted to be of primary, early diagenetic, or metamorphic origin. Different genetic interpretations for magnetite lead to divergent pictures of the Precambrian Earth system and its evolutionary models through time. The Baizhiyan Formation of the Neoarchean Wutai Group (Shanxi, North China) features magnetite-bearing, Algoma-type BIFs deposited ca. 2.52 Ga, in the lead-up to a major period of global iron formation deposition in the Paleoproterozoic. Abundant magnetite crystals found in the silica-rich bands of these BIFs show euhedral, hexagonal morphology. We suggest that this hexagonal magnetite likely represents pseudomorphs after green rust, a mixed-valence iron hydroxy-salt formed in the water column. The rare earth element composition of the BIFs shows negligible to slightly positive Ce anomalies (CeSN/CeSN* = 1.03 ± 0.07), which is characteristic of a dominantly anoxic water column. The presence of positive Eu anomalies (EuSN/EuSN* <3.9) suggests a substantial influence from proximal hydrothermal fluids. The co-occurrence of siderite layers associated with the magnetite-bearing strata may indicate iron cycling associated with ferruginous bottom seawater conditions. Geochemical signatures of the Baizhiyan BIFs are consistent with the interpretation that the magnetite was transformed from metastable green rust. This green rust could have formed via several processes, including the partial oxidation of Fe(II) by molecular oxygen/photoferrotrophs, the reaction of settling ferrihydrite with Fe(II)-rich hydrothermal fluids under anoxic conditions, or local dissimilatory iron reduction. In all cases, the contribution of primary green rust to BIF formation requires iron redox cycling, and similar pseudomorphs in the form of hexagonal magnetite may be more common in the geological record. Our findings support the models in which green rust was an important primary constituent of the Precambrian iron cycle, and the potential interactions of green rust with other elements (e.g., phosphorus) should be taken into consideration when reconstructing Precambrian biogeochemical cycles.

Geochemistry of magnetite from the Hongniu–Hongshan Cu skarn deposit in Yunnan Province, SW China

The Hongniu–Hongshan Cu skarn deposit is located in the central part of the Zhongdian porphyry and skarn Cu belt in southwestern China. We investigated the petrography and trace-element chemistry of magnetite in the deposit to examine the nature and origin of the ore-forming fluids. Three types of magnetite were identified in porphyritic granite and skarn in the Hongniu–Hongshan deposit. Mt-type1 crystallized from magmas, is typical magmatic magnetite. Mt-type2 formed later than type1, but earlier than the syn-ore stage, and was related to magmatic–hydrothermal activity. Mt-type3 formed during the early syn-ore stage, is hydrothermal skarn magnetite. The magnetites have variable K, Mg, Al, Ti, V, Cr, Mn, Co, Ni, Cu, Pb, Zn, Ga, W, Sn, and Ge contents. The high contents of Ti, V and Cr in the Mt-type1 is largely controlled by its magmatic origin. For the type 2 magnetites, the high Al, Ti, and Ga contents were controlled by hydrothermal fluid composition and temperature, and V, Sn, and Cr were controlled by fO2 values. The enrichment of Mg, Mn, and Zn in the Mt-type3 was largely due to fluid–rock interactions. Co-precipitating mineral phases appear to have exerted less control on magnetite compositions in the deposit. Some of the Mt-type2 had experienced coupled dissolution and reprecipitation (CDR) processes. The infiltration of saline hydrothermal fluids is considered to enhance CDR processes in the skarn deposit. We suggest that the crystallization of magnetite in the porphyritic granite reduced the sulfate content of the magma, which resulted in Cu and Au being complexed more readily into fluids. The precipitation of Mt-type3 might have resulted in a change from an oxidized to a more reduced environment, thereby creating conditions favorable for the precipitation of Cu sulfides.

Preparation and Dielectric Properties of the Amorphous Basaltic Glass

Due to the continuous basalt fiber is a kind of amorphous material, only the basaltic glass without crystallization can represent its dielectric properties. To explore the dielectric properties of the continuous basalt fiber, amorphous basaltic glass must be prepared. The present research focuses on the influence of chemical component on the preparation process of the amorphous basaltic glass and its dielectric properties. The basaltic rocks from different places of China were melted at 1500 °C, then the melt was poured into the mould, at last glass sample was annealed at 650 °C for 2 h. Ten groups of basaltic rocks were studied, and the results showed that the melt viscosity of basaltic rocks with 55–58 % SiO2 was high at 1500 °C. The high-content of Fe2O3 in basaltic rocks was found to enhance the formation of magnetite (Fe3O4) crystal during the annealing process. The other five groups of basaltic rocks were suit to the amorphous basaltic glass. At 1 MHz, the best dielectric constant of amorphous basaltic glass is 6.55, the dielectric loss is 4.034 × 10− 3.

Features of the Geological Structure and Genesis of the Tebinbulak Deposit (Ridge Sultan-Uvais)

In this article, we want to draw attention to the hysteron-magmatic origin of titanium-magnetite ores of the Tibinbulak gabbro-peridotite complex located in the northwestern part of the Sultan-Uvais ridge. Which is the only outlet of the Phanerozoic foundation between the mountain structures of the Urals and the Southern Tien Shan. The article examines the characteristic features of petrochemical and structural features of ore minerals (ilmenite, magnetite) and the main rock-forming minerals of the gabbro-peridotite complex (peridotite, pyroxenite, tebinnite, pyroxene hornblendite and plagioclase) with clarification of the structural relationships. It was found that magnetite mineralization of the Tebinbulak intrusion was superimposed on ultrabasic rocks in the final stages of crystallization of the latter. Prolonged auto-metasomatic transformations led to the enlargement of magnetite crystals in places subject to decay. In this case, aggregates of spinel - hercynite with sphene rims were formed. Simultaneously with the formation of sphene, ilmenite crystals appeared in the form of radiant needle-shaped aggregates. In this case, the primary crystals of magnetite lost their faces and became shapeless. Relatively large precipitates of titano-magnetite formed at this stage with the filling of cracks in the rock and interstices between minerals. Based on the data presented, we note that the titano-magnetite ores of the Tebinbulak deposit arose in the late magmatic (hysteron-geneous) setting of auto-metamorphic replacement of the main carriers of iron and titanium pyroxene and plagioclase with hornblende. Also, the studied geochemical composition of ores damages that the titano-magnetite ores of the Tebinbulak deposit are a complex raw material, from which not only iron but also vanadium concentrate can be extracted.

Biocompatibility of Bacterial Magnetosomes as MRI Contrast Agent: A Long-Term In Vivo Follow-Up Study.

Derived from magnetotactic bacteria (MTB), magnetosomes consist of magnetite crystals enclosed within a lipid bilayer membrane and are known to possess advantages over artificially synthesized nanoparticles because of the narrow size distribution, uniform morphology, high purity and crystallinity, single magnetic domain, good biocompatibility, and easy surface modification. These unique properties have increasingly attracted researchers to apply bacterial magnetosomes (BMs) in the fields of biology and medicine as MRI imaging contrast agents. Due to the concern of biosafety, a long-term follow-up of the distribution and clearance of BMs after entering the body is necessary. In this study, we tracked changes of BMs in major organs of mice up to 135 days after intravenous injection using a combination of several techniques. We not only confirmed the liver as the well-known targeted organs of BMs, but also found that BMs accumulated in the spleen. Besides, two major elimination paths, as well as the approximate length of time for BMs to be cleared from the mice, were revealed. Together, the results not only confirm that BMs have high biocompatibility, but also provide a long-term in-vivo assessment which may further help to forward the clinical applications of BMs as an MRI contrast agent.

Cryptochromes in Mammals and Birds: Clock or Magnetic Compass?

Species throughout the animal kingdom use the Earth's magnetic field (MF) to navigate using either or both of two mechanisms. The first relies on magnetite crystals in tissue where their magnetic moments align with the MF to transduce a signal transmitted to the central nervous system. The second and the subject of this paper involves cryptochrome (CRY) proteins located in cone photoreceptors distributed across the retina, studied most extensively in birds. According to the "Radical Pair Mechanism" (RPM), blue/UV light excites CRY's flavin cofactor (FAD) to generate radical pairs whose singlet-to-triplet interconversion rate is modulated by an external MF. The signaling product of the RPM produces an impression of the field across the retinal surface. In birds, the resulting signal on the optic nerve is transmitted along the thalamofugal pathway to the primary visual cortex, which projects to brain regions concerned with image processing, memory, and executive function. The net result is a bird's orientation to the MF's inclination: its vector angle relative to the Earth's surface. The quality of ambient light (e.g., polarization) provides additional input to the compass. In birds, the Type IV CRY isoform appears pivotal to the compass, given its positioning within retinal cones; a cytosolic location therein indicating no role in the circadian clock; relatively steady diurnal levels (unlike Type II CRY's cycling); and a full complement of FAD (essential for photosensitivity). The evidence indicates that mammalian Type II CRY isoforms play a light-independent role in the cellular molecular clock without a photoreceptive function.

Volcano Sedimentary Origin of Archaean Banded Iron Formation of Nellore Schist Belt from Chundi-Malakonda-Ayyavaripalle Area, Prakasam District, Andhra Pradesh and its Petro-chemical Characterization

Abstract Banded iron formations (BIFs) are the most significant source of iron in the world. The present study addresses the petrographic and geochemical characterization of the BIF from Chundi-Malakonda-Ayyavaripalle area in the Nellore schist belt of Prakasam district, Andhra Pradesh, their genesis and iron enrichment processes. Six bands of banded magnetite quartzite (BMQ) of Archaean age occur in the area. Field investigations and petrography revealed that the studied BIF samples are hard, compact, weathered and composed of alternate layers of magnetite/martite and subordinate quartz, biotite and muscovite. The BIFs occur in three associations: volcanic (Band 1,3,4,5), sedimentary (Band 6) and volcano-sedimentary (Band 2). The geochemical composition of the whole rock reveals that iron and silica represent 78.48% to 91.74% of the average composition. The total iron (TFe) contents range from 16.25 to 61.80 wt % (average of 38.47 wt %) and is consistent with low-grade siliceous BIF by global standards. All BIFs have high SiO2/Al2O3, Fe/Ti, and low Al/(Al+Fe+Mn), which suggest a mixed hydrogenous and hydrothermal origins. Geochemical results for the BIFs lead to the conclusion that all the BIFs are of Algoma-type with Precambrian affinity and formed in small sloped or terraced silled basins in the back-arc areas with MORB affinity, surrounding an immature island arc. Depending on the degree of replacement and shape of the magnetite crystals, two textural types of magnetite (Magnetite-I and Magnetite-II) are observed. Ore formation occurs in three stages: Magnetite (protore), Martites and Martite-goethites.

The Petrology of the Tarosero Volcanic Complex: Constraints on the Formation of Extrusive Agpaitic Rocks

Abstract The Quaternary Tarosero volcano is situated in the East African Rift of northern Tanzania and mainly consists of trachyte lavas and some trachytic tuffs. In addition, there are minor occurrences of extrusive basalts, andesites and latites, as well as peralkaline trachytes, olivine trachytes and phonolites. Some of the peralkaline phonolites contain interstitial eudialyte, making Tarosero one of the few known occurrences for extrusive agpaitic rocks. This study investigates the genetic relationships between the various rock types and focuses on the peculiar formation conditions of the extrusive agpaitic rocks using a combination of whole-rock geochemistry, mineral chemistry, petrography, thermodynamic calculations, and major and trace element modelling. The Tarosero rocks formed at redox conditions around or below the fayalite–magnetite–quartz buffer (FMQ). During multi-level magmatic fractionation at depths between ∼40 km and the shallow crust, temperature decreased from >1100 °C at near-liquidus conditions in the basalts to ∼700 °C in the peralkaline residue. Fractional crystallization models and trace element characteristics do not indicate a simple genetic relationship between the trachytes and the other rock types at Tarosero. However, the genetic relationships between the primitive basalts and the intermediate latites can be explained by high-pressure fractional crystallization of olivine + clinopyroxene + magnetite + plagioclase + apatite. Further fractionation of these mineral phases in addition to amphibole and minor ilmenite led to the evolution towards the peralkaline trachytes and phonolites. The eudialyte-bearing varieties of the peralkaline phonolites required additional low-pressure fractionation of alkali feldspar and minor magnetite, amphibole and apatite. In contrast to the peralkaline trachytes and phonolites, the peralkaline olivine trachytes contain olivine instead of amphibole, thus indicating a magma evolution at even lower pressure conditions. They can be modelled as a derivation from the latites by fractional crystallization of plagioclase, clinopyroxene, magnetite and olivine. In general, agpaitic magmas evolve under closed-system conditions, which impede the escape of volatile phases. In the case of the extrusive agpaitic rocks at Tarosero, the early exsolution of fluids and halogens was prevented by a low water activity. This resulted in high concentrations of rare earth elements (REE) and other high field strength elements (HFSE) and the formation of eudialyte in the most evolved peralkaline phonolites. Within the peralkaline rock suite, the peralkaline olivine trachytes contain the lowest HFSE and REE concentrations, consistent with mineralogical evidence for formation at a relatively high water activity. The lack of amphibole fractionation, which can act as a water buffer of the melt, as well as the evolution at relatively low-pressure conditions caused the early exsolution of fluids and loss of water-soluble elements. This prevented a strong enrichment of HFSE and REE before the magma was finally extruded.

Carbonate assemblages in Cold Bokkeveld CM chondrite reveal complex parent body evolution

AbstractThe paragenesis of carbonates in the Cold Bokkeveld CM chondrite is determined from a detailed petrographic, chemical, spectroscopic, and isotopic study of nine associations of carbonates (aragonite, calcite, and dolomite) with other secondary minerals that occur within the meteorite. Our study reveals the existence of carbonates displaying petrographic features that are distinct from those of type 1 and type 2 carbonates commonly observed in CM2 meteorites. These include carbonates interstitial to octahedral magnetite crystals, for which a new designation of “type 1c” is suggested. The O isotopic values of dolomite (δ18O ranging from +21.1 to +25.8‰ and Δ17O from −4.9 to −4.0‰) are similar to those measured in dolomites from other CM chondrites. The presence of complex carbonates with a CaCO3 core and Mg‐enriched rim implies several generations of fluids and/or their evolving composition on the CM parent body(ies). Petrographic characteristics indicate at least six stages of potentially overlapping carbonate and phyllosilicate formation events. We show that type 1 and type 2 calcite have distinct Raman spectral characteristics. Type 1 calcite is characterized by very broad peaks, whereas type 2 calcite displays narrow peaks similar to those of typical abiotic terrestrial calcite, suggesting high crystallinity. A carbonate Raman spectrum showing features characteristic of both aragonite and calcite likely documents an aragonite‐calcite phase transition. Raman spectroscopy also reveals the presence of organic matter in the majority of carbonates. This indicates that organic carbon was mobilized by aqueous fluids for extended periods.

Micrometer-sized magnetite synthesis using Fe(OH)2(s) as a precursor for technetium sequestration from liquid nuclear waste streams

• Transformation of Fe(OH) 2 (s) to micrometer-sized magnetite in waste stream at 75 °C. • Solution pH/temperature/oxidation kinetics play key roles in final mineral products. • An increase in pH or Fe(II) amendment improved tc removal from waste streams. • Tc sequestration as TcO 2 •2H 2 O or through Tc(IV)-magnetite incorporation. • More tc incorporation into magnetite at elevated temperatures and pH conditions. Systematic batch experiments under variable adjusted physicochemical conditions were conducted to explore optimization of micrometer-sized magnetite synthesis for Tc sequestration from radionuclide waste streams using Fe(OH) 2 (s) as the precursor. Extensive solid characterizations using X-ray diffraction, microscopy and spectroscopic methods were performed to identify mineral phases, assess changes in particle morphology and size distribution, as well as Tc speciation and incorporation, in the produced mineral phases. The results show that the solution pH, temperature, and oxidation kinetics play key roles in the final mineral products. Micrometer-sized magnetite crystals (0.62–0.96 µm, on average) with well-defined dodecahedral or octahedral structures were synthesized under near neutral (~pH 8) or alkaline (~pH 13) conditions at 75 °C, respectively; whereas goethite dominated the end products at room temperature. An increase in pH at 75 °C improved Tc removal from 27% (near neutral pH) to 42% (alkaline pH), but the removal process remained inhibited by redox-competitive Cr(VI) present in the waste streams. By adding additional Fe(II) to the system, Tc sequestration was dramatically improved up to 87% without observable changes in the solid product. The sequestrated Tc existed as TcO 2 •2H 2 O and/or Tc(IV) incorporated into magnetite, where extended X-ray absorption fine structure (EXAFS) spectroscopy showed that more Tc was incorporated into magnetite at elevated temperatures and pH conditions, with complete Tc(IV) incorporation into magnetite occurring under 75 °C-pH 13 conditions. Our results indicate that optimal micrometer-sized magnetite can be produced for Tc sequestration by reacting Fe(OH) 2 (s) with a waste stream simulant under elevated pH (~13) and temperature (75 °C) conditions. The incorporation of reduced Tc(IV) into stable micrometer-sized magnetite provides a viable supplemental immobilizing technology that may be used to improve nuclear waste treatment and disposal needs.

Preparation of Fe3O4 particles with unique structures from nickel slag for enhancing microwave absorption properties

Recycling valuable metal elements from metallurgical slags and exploring their functional material applications have attracted more recent attention. In this paper, Fe3O4 particles with unique structures, solid solutions of Mg, Ni, and Co and inlays of silicates in magnetite crystals were extracted from nickel slag by molten oxidation and magnetic separation processes. The microstructure, morphology, magnetic and electromagnetic properties, and microwave absorption performance of the Fe3O4 particles were characterized. The results show that the Fe3O4 crystals oxidized at 1400 °C exhibit granular shapes with a uniform distribution in the silicate matrix, while they change into both dendritic and granular morphology at 1450 °C and finally into dendritic structures at 1500 °C. The Fe3O4 particles prepared at 1400 °C reach an optimal reflection loss value of −29.90 dB under a thickness of 3.5 mm and an effective absorbing frequency band of 3.28 GHz (5.52–8.80 GHz), indicating that their unique structure favours microwave absorption. The joint action of strong magnetic loss and the appropriate dielectric loss were supposed to sustain the absorption mechanism of the Fe3O4 particles.

Мінералогічні особливості відновлених окатишів Північного гірничозбагачувального комбінату (Криворізький басейн)

The advantages of reduced iron ore pellets over oxidized ones have been considered. The chemical and physical parameters of the primary material have been given: iron ore (magnetite) concentrate (iron content is 67.30 mass %; particle size distribution is 97.0 % of 0.056 mm fraction), bentonite (montmorilonit content is 70.43 mass %; particle size distribution is 94.5% of 0.056 mm fraction), ground coke. The course of experiments has been described. The zonal structure of the obtained pellets has been characterized: the central zone is composed of hematite with relics of magnetite; intermediate one contains magnetite particles with inclusions of hematite; peripheral zone includes subidiomorphic crystals of magnetite and their dendritic aggregates. The bentonite component in the central and intermediate zones retained a crypto-crystalline structure, in the peripheral one it had been transformed into a crystalline aggregate of garnet and pyroxene. Emphasis is placed on the need to verify the impact of various indicators of temperature, firing time, quantitative ratios of charge components, mineral and chemical composition of the cementing material on mineralogical transformations.

Characterizing the Source of the Eastern Galicia Magnetic Anomaly (NW Spain): The Role of Extension in the Origin of Magnetization at the Central Iberian Arc

AbstractThe Eastern Galicia Magnetic Anomaly is the best studied anomaly of the Central Iberian Arc. This is due to its location, on the Lugo‐Sanabria gneiss dome, and to the fact that its source rocks crop out in the Xistral Tectonic Window. Multiple studies of this anomaly have been carried out, but still, new results keep on shedding light on its understanding. This paper presents the first results on rock magnetic analyses, natural remanent magnetization, anisotropy of the magnetic susceptibility, X‐ray diffraction, and stable isotopes geochemistry carried out on the source rocks of this anomaly. Results suggest that magnetization responds to the increase in oxygen fugacity underwent by rocks affected by late Variscan (330‐300 Ma) extensional tectonics. Extensional detachments were the pathways that allowed the entrance of fluids that led to syntectonic crystallization of magnetite and hematite in metasediments and inhomogeneous S‐Type granitoids derived from their partial melting. Accordingly, magnetization is not linked to lithologies, but to extensional structures developed in the late Carboniferous/earliest Permian, during the Kiaman reverse superchron. Systematic reverse magnetic remanence exhibited by hematite‐bearing samples confirms the age of the magnetization and adds complexity to the interpretation of the anomaly. Understanding the EGMA contributes to the interpretation of other anomalies existing in the CIA, also located on thermal domes. The observed extension‐related magnetization probably affected most of the NW Iberian Massif, thus hindering the study of previous tectonics by paleomagnetic techniques. This work aims to provide new hints to interpret magnetic anomalies located in extensional tectonic contexts worldwide.

Chemical composition of magnetite and chlorite from the stringer zone of the Nudeh volcanogenic massive sulfide (VMS) deposit, Iran: geological implications

The southwest Sabzevar basin situated in the Sabzevar zone is considered to be an attractive metallogenic province in Iran that hosts both volcanogenic massive sulfide (VMS) and stratiform manganese deposits. The Nudeh Besshi-type VMS deposit is located in the Lower Late Cretaceous volcano-sedimentary sequence. The ore mineralization in this deposit is hosted in the alkali olivine basalt flow and tuffaceous silty sandstone rocks. The Nudeh VMS deposit consists of 2 million metric tons of Cu-Zn massive sulfide overlying a Cu-Fe-rich stringer. The massive sulfide orebody consists dominantly of pyrite, chalcopyrite, friedrichite, magnetite, and sphalerite, together with minor quartz, chlorite, and sericite. Chloritization, silicification, and sericitization are the main wall-rock alteration types; alteration intensity increases towards the stringer zone. Chloritized footwall rocks extend up to 20 m below the stringer zone. The quartz-bearing stringer veins also contain pyrite, chalcopyrite, magnetite, and bornite. Magnetite crystals from the stringer ores show variable contents of many elements, such as MgO (0.05 wt%), Al2O3 (0.63 wt%), TiO2 (0.07 wt%), V2O3 (0.045 wt%), SiO2 (0.65 wt%), CoO (0.10 wt%), NiO (0.009 wt%), ZnO (0.023 wt%), and CaO (0.03 wt%). The moderate to high V contents are interpreted to result from relatively reduced, seafloor hydrothermal activiy. Compositional variations of magnetite are possibly related to variations in oxygen fugacity, temperature, and water/rock interaction. Within the stringer zone, chlorite 2 (Chl-2) in the vein-veinlets and chlorite 1 (Chl-1) in the chloritized alkali olivine basalt rock are chemically indistinguishable, with 26.92–34.67 wt% FeO and 5.99–14.01 wt% MgO. Chlorite geothermometer studies indicate crystallization formation temperatures of 414 °C (Chl-1) and 303 °C (Chl-2), respectively.

Reconciling bubble nucleation in explosive eruptions with geospeedometers

Magma from Plinian volcanic eruptions contains an extraordinarily large numbers of bubbles. Nucleation of those bubbles occurs because pressure decreases as magma rises to the surface. As a consequence, dissolved magmatic volatiles, such as water, become supersaturated and cause bubbles to nucleate. At the same time, diffusion of volatiles into existing bubbles reduces supersaturation, resulting in a dynamical feedback between rates of nucleation due to magma decompression and volatile diffusion. Because nucleation rate increases with supersaturation, bubble number density (BND) provides a proxy record of decompression rate, and hence the intensity of eruption dynamics. Using numerical modeling of bubble nucleation, we reconcile a long-standing discrepancy in decompression rate estimated from BND and independent geospeedometers. We demonstrate that BND provides a record of the time-averaged decompression rate that is consistent with independent geospeedometers, if bubble nucleation is heterogeneous and facilitated by magnetite crystals.

Novel Extracellular Electron Transfer Channels in a Gram-Positive Thermophilic Bacterium.

Biogenic transformation of Fe minerals, associated with extracellular electron transfer (EET), allows microorganisms to exploit high-potential refractory electron acceptors for energy generation. EET-capable thermophiles are dominated by hyperthermophilic archaea and Gram-positive bacteria. Information on their EET pathways is sparse. Here, we describe EET channels in the thermophilic Gram-positive bacterium Carboxydothermus ferrireducens that drive exoelectrogenesis and rapid conversion of amorphous mineral ferrihydrite to large magnetite crystals. Microscopic studies indicated biocontrolled formation of unusual formicary-like ultrastructure of the magnetite crystals and revealed active colonization of anodes in bioelectrochemical systems (BESs) by C. ferrireducens. The internal structure of micron-scale biogenic magnetite crystals is reported for the first time. Genome analysis and expression profiling revealed three constitutive c-type multiheme cytochromes involved in electron exchange with ferrihydrite or an anode, sharing insignificant homology with previously described EET-related cytochromes thus representing novel determinants of EET. Our studies identify these cytochromes as extracellular and reveal potentially novel mechanisms of cell-to-mineral interactions in thermal environments.

Characteristics and significance of aegirine and arfvedsonite in Boziguoer Nb-Ta-Zr-Rb-REE deposit related to alkaline granite, Xinjiang

碱性造岩矿物能够记录碱性岩源区特征、岩浆演化以及晚期成矿的重要信息，是开展碱性岩成岩成矿研究的有效手段。波孜果尔碱性花岗岩型铌-钽-锆-铷-稀土矿床位于塔里木北缘-中亚南天山晚古生代造山带，是塔里木地块北缘铌成矿带中典型的碱性岩型矿床。本文通过对含矿岩体中的霓石和钠铁闪石开展矿物学研究，结合全岩成分揭示波孜果尔稀有-稀土金属矿床含矿岩体的岩石类型、演化特征、构造背景及成矿条件。研究发现，含矿碱性岩体由霓石钠铁闪石碱长花岗岩、霓石钠铁闪石石英碱长正长岩、霓石钠铁闪石碱长正长岩组成。不同岩相岩石均表现出相似的稀土和微量元素配分模式，以富集轻稀土元素和高场强元素，亏损大离子亲石元素和重稀土元素为特征，具有显著的负Eu异常，指示三种岩石类型是同源岩浆演化的产物。含矿岩体中的辉石为霓石-霓辉石，角闪石为钠铁闪石。霓石和钠铁闪石稀土和微量元素配分模式相似且含量都较低，富集重稀土、亏损轻稀土，具有显著的负Eu异常，并富集Zr、Hf等高场强元素，亏损Ba、Sr等大离子亲石元素。霓石和钠铁闪石微量元素特征指示三个岩相单元的演化程度由低到高依次为霓石钠铁闪石碱长花岗岩→霓石钠铁闪石石英碱长正长岩→霓石钠铁闪石碱长正长岩，且结晶分异作用控制了岩体的形成。同时，早期霓石钠铁闪石碱长花岗岩的钠铁闪石呈现Ce正异常，晚期岩相中则无异常，指示演化的早期阶段氧逸度较高，随着磁铁矿等氧化物的结晶熔体趋于还原。波孜果尔含矿岩体成矿元素除Rb外分布并不均匀，表现为演化早期的岩相富集Nb，而演化晚期的岩相更富集稀土和Zr。进一步研究发现，塔里木北缘碱性岩带发育的铌、稀土、钽、锆、铷、铀等稀有稀土金属矿化与地幔柱引起的幔源岩浆底侵有关，其构造背景可能为地幔柱对造山带的叠置。;Alkaline minerals can record the important information of source area characteristics, magmatic evolution and late mineralization of alkaline rocks, which is an effective means for the study of diagenesis and mineralization of alkaline rocks. Boziguoer Nb-Ta-Zr-Rb-REE deposit is a typical deposit related to alkaline rocks, which is located in the Late Paleozoic orogenic belt of the southern Tianshan-the northern margin of Tarim block. Based on mineralogical study of aegirine and arfvedsonite in the ore-bearing intrusion, combining with its whole rock compositions, this paper reveals the rock types, evolution characteristics, tectonic setting and metallogenic conditions of the intrusion in the Boziguer rare-earth metal deposit. The rock types of ore-bearing intrusion are aegirine arfvedsonite alkali feldspar granite, aegirine arfvedsonite quartz alkali feldspar syenite and aegirine arfvedsonite alkali feldspar syenite. All of the three types of rocks show similar REE and trace element distributions, with enriched LREE and HFSE, depleted HREE and LILE, and a significant negative Eu anomaly, indicating that they are the products of homologous magmatic evolution. The pyroxene group minerals are aegirine, and the amphibole group minerals are arfvedsonite. Aegirine and arfvedsonite show similar distribution patterns of trace and rare earth elements, which are characterized by enriched HREE and depleted LREE with a significant Eu negative anomaly. They all show enrichment in HFSE (Zr, Hf), depletion in LILE, such as Ba and Sr. Trace element and REE distributions of these minerals indicate that the degree of their evolution from low to high is: aegirine arfvedsonite alkali feldspar granite→aegirine arfvedsonite quartz alkali feldspar syenite→aegirine arfvedsonite alkali feldspar syenite, showing the formation of the intrusion is controlled by crystallization and differentiation. The arfvedsonite of aegirine arfvedsonite alkali feldspar granite shows a positive anomaly of Ce, indicating a high oxygen fugacity environment at the early stages of its evolution. The crystallization of magnetite in the early lithofacies make the evolution environment of the melt tend to be reduced. The Rb in all rock types is equally distributed, and the rocks of early evolution stage is more enriched in Nb, while that of the late-stage more enriched in REE and Zr. The mineralization of rare earth metals such as Nb, REE, Ta, Zr, Rb and U developed in the alkaline rock belt in the northern margin of Tarim basin is related to the mantle magma underplating caused by mantle plume, and its tectonic setting may be the superposition of mantle plume to orogenic belt.

Temperature dependence of the magnetic interactions taking place in monodisperse magnetite nanoparticles having different morphologies

We report on the temperature dependence of the interactions present in single crystal magnetite nanoparticles having octahedral and spherical morphologies. From our results we conclude that the inter-particle interactions are, at all temperatures and in both octahedral and spherical nanoparticles, demagnetizing in nature. These interactions are not describable in terms of a mean field but local and linked to the poles present at the surfaces of the particles and particles clusters. In both samples, the peak on the field dependence of the interactions has an associated maximum that decreases in magnitude with an increase of the measuring temperature. Also, that peak gets narrower when the temperature is increased. The high order multipolar moments of the octahedral nanoparticles, originated by the fact that their morphology includes the presence of edges an dihedra, is detectable in the larger field range in which the interactions are observable in these samples in comparison with that corresponding to the spherical nanoparticles, exhibiting close-to-dipolar moments.

Copper-Gold Fertility of Arc Volcanic Rocks: A Case Study from the Early Permian Lizzie Creek Volcanic Group, NE Queensland, Australia

Abstract The Early Permian Lizzie Creek Volcanic Group of the northern Bowen Basin, NE Queensland, Australia, has compositions that range from basalt through andesite to rhyolite with geochemical signatures (e.g., enrichment in Cs, Rb, Ba, U, Th, and Pb, depletion in Nb and Ta) that are typical of arc lavas. In the Mount Carlton district the Lizzie Creek Volcanic Group is host to high-sulfidation epithermal Cu-Au-Ag mineralization, whereas farther to the south near Collinsville (~50 km from Mount Carlton) these volcanic sequences are barren of magmatic-related mineralization. Here, we assess whether geochemical indicators of magma fertility (e.g., Sr/Y, La/Yb, V/Sc) can be applied to volcanic rocks through study of coeval volcanic sequences from these two locations. The two volcanic suites share similar petrographic and major element geochemical characteristics, and both have undergone appreciable hydrothermal alteration during, or after, emplacement. Nevertheless, the two suites have distinct differences in alteration-immobile trace element (V, Sc, Zr, Ti, REE, Y) concentrations. The unmineralized suite has relatively low V/Sc and La/Yb, particularly in the high SiO2 rocks, which is related to magma evolution dominated by fractionation of clinopyroxene, plagioclase, and magnetite. By contrast, the mineralized suite has relatively high V/Sc but includes high SiO2 rocks with depleted HREE and Y contents, and hence high La/Yb. These trends are interpreted to reflect magma evolution under high magmatic H2O conditions leading to enhanced amphibole crystallization and suppressed plagioclase and magnetite crystallization. These rocks have somewhat elevated Sr/Y compared to the unmineralized suite, but as Sr is likely affected by hydrothermal mobility, Sr/Y is not considered to be a reliable indicator of magmatic conditions. Our data show that geochemical proxies such as V/Sc and La/Yb that are used to assess Cu-Au fertility of porphyry intrusions can also be applied to cogenetic volcanic sequences, provided elemental trends with fractionation can be assessed for a volcanic suite. These geochemical tools may aid regional-scale exploration for Cu-Au mineralization in convergent margin terranes, especially in areas that have undergone limited exhumation or where epithermal and porphyry mineralization may be buried beneath cogenetic volcanic successions.