Laser-induced breakdown spectroscopy (LIBS) has been demonstrated to diagnose the surface element distribution of plasma-facing components (PFCS) in fusion devices. However, the magnetic field intensity and polarity near the wall surface change frequently and cannot be measured in real time, which will affect the analytical accuracy of LIBS results. The determination of the strength and polarity direction of the magnetic field near the surface will be conducive to the quantitative analysis of LIBS and provide valuable information for the distribution of the magnetic field near the surface of PFCs. In this work, the effects of magnetic fields on the characteristics of laser-induced Mo plasma, such as the ablation depth and mass, the spatio-temporal evolution behavior of spectrum and the plasma parameters, were first systematically investigated. The different phenomenon of continuum radiation, Mo I line and Mo II line under the magnetic field were mutually verified by optical emission spectroscopy and fast plasma imaging methods. Meanwhile, an approach for measurement of the magnetic field intensity and polarity near the surface of PFCS by LIBS method has been proposed and investigated. When the magnetic field polarity is changed, the spatial distribution profile of Mo spectrum will drift in the opposite direction affected by of the Lorentz force, which realizes the measurement of magnetic field polarity. Moreover, the splitting distance of Mo I line caused by Zeeman effect with the variable magnetic fields were preliminarily calculated. The experimental values of splitting distance agree well with the theoretical values that calculated by the known magnetic field strength. These results confirm the feasibility of measuring the magnetic field intensity and polarity of PFCs surface by LIBS approach.
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