Magnesium Hydroxide Research Articles

Study on the mechanism of controlling the morphology of basic magnesium carbonate prepared under different hydration conditions

Basic magnesium carbonate is gaining prominence in flame retardant materials due to its excellent flame-retardant properties and clean decomposition products. This study investigates a hydration-carbonation method to address challenges related to the preparation, morphology control, and stability of magnesium basic carbonate. The impact of hydration conditions on the morphology of the carbonate was analyzed using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results indicate that spherical magnesium basic carbonate with regular morphology and uniform particle size can be achieved at a hydration temperature of 50°C for 1.5 hours. However, extending the hydration time and increasing the temperature resulted in irregular morphologies. Molecular dynamics simulations using the CASTEP and Forcite modules of Materials Studio were employed to understand the influence of hydration-carbonation conditions on the carbonate's morphology. The simulations revealed that the (1 1 1) and (2 0 0) crystal faces of MgO, with higher surface energies, promote the formation of precursor magnesium hydroxide nuclei, leading to heterogeneous magnesium alkali carbonate at elevated temperatures. Prolonged hydration time resulted in fragmented carbonate structures. To control the morphology of magnesium alkali carbonate, it is essential to optimize hydration temperature and duration. The simulation results corroborate experimental findings, providing deeper insights into the liquid-gas-solid adsorption relationships during the carbonation process. This study offers valuable guidelines for the controlled synthesis of magnesium basic carbonate, enhancing its applicability in flame retardant materials.

Effect of magnesium hydroxide fly ash compounded flame retardant on the properties of polyvinyl chloride

Abstract This study investigated the effects of compound flame retardants on polyvinyl chloride (PVC) film. Four F-M/PVC composite film materials (F0.1M0.1/PVC, F0.1M0.2/PVC, F0.1M0.3/PVC, and F0.1M0.4/PVC) were obtained by blending different ratios of fly ash (FA) and magnesium hydroxide (MH(OH)2, MH) compounded flame retardants (F-M) with PVC. The mechanical properties, thermal stability, and smoke density of the composite film materials were examined. The results showed that the loss of mechanical properties of F0.1M0.2/PVC composites was small. TGA analysis showed that the thermal stability of the four F-M/PVC composites was improved. The degradation temperature of pure PVC at T50 was 286.5°C, and that of F0.1M0.2/PVC composites was 335.38°C. Smoke density analysis showed that the maximum smoke density of pure PVC was 6.310, and the maximum smoke density of the composite material (F0.1M0.4/PVC) was reduced to 5.960, which had a better smoke suppression effect. For the comprehensive utilization of Salt Lake magnesium resources, the development of PVC composite film materials to provide the experimental basis has a strong practical value.

Research Progress in Preparation of Magnesium Hydroxide from Bischofite in Qinghai Salt Lakes

Research Progress in Preparation of Magnesium Hydroxide from Bischofite in Qinghai Salt Lakes

Investigating Anti-Bacterial and Anti-COVID-19 Virus Properties and Mode of Action of Pure Mg(OH)2 and Copper-infused Mg(OH)2 Nanoparticles and Coated Polypropylene Surfaces

Robust anti-microbial surfaces that are non-toxic to users have widespread application in medical, industrial, and domestic arenas. Magnesium hydroxide has recently gained attention as an anti-microbial compound that is non-toxic, biocompatible, and environmentally friendly. Here we demonstrate melt compound and thermally embossed methods for coating polypropylene with Mg(OH)2 nanoplatelets and copper-infused Mg(OH)2 nanoplatelets. Polypropylene articles coated with Mg(OH)2 nanoplatelets and copper-infused Mg(OH)2 nanoplatelets exhibit a log 8 kill of E.coli within 24 hours. In addition, Mg(OH)2 NPs suspension, at 0.25% reduced SARSCoV-2 virus titers in the solution by 2.5 x 103 PFU/mL or 29.4%, while the Cu-infused Mg(OH)2 NPs suspension, at 0.25% reduced titers by 8.1 x 103 PFU/mL or 95.3%. Fluorescence microscopy revealed that reactive oxygen species (ROS) are produced in bacteria in response to Mg(OH)2 and Cu-infused Mg(OH)2 nanoplatelets which appears to be an important but not the sole mode of anti-microbial action of the nanoplatelets. Plastics with anti-microbial surfaces from where biocides are non-leachable are highly desirable. This work provides a general fabrication strategy for developing anti-microbial plastic surfaces.

A Wound Exudate‐Activated Yarn Battery for Antimicrobial Electrical Fabric Dressing

AbstractExcessive inflammation poses a major challenge to wound care, with massive exudation and bacterial infection being the prominent factors contributing to the inflammation. Current biomaterials can achieve passive or interactive wound repair through exudate absorption and anti‐infection. However, they cannot actively modulate the cellular behavior associated with skin wound repair. Inspired by the endogenous electric field (EF), the present study develops an antimicrobial and self‐powered electrical fabric dressing (EFD). An EFD with multifunctional properties of wound exudate collection, anti‐infection, and self‐powered electrical stimulation (ES) is assembled via weaving a series of hydrophilically modified cotton yarn‐based batteries. Upon contact with the wound, EFD absorbs the wound exudate owing to its high hydrophilicity and utilizes it as the natural electrolyte to activate the battery. With the endogenous power supply, the ES‐promoted polarization of macrophage, as well as the migration and proliferation of fibroblasts, enhancing the active wound repair process. Moreover, the dressings exhibit excellent antibacterial properties, attributable to the synergistic effects of the cationic polymer brushes on the cotton yarn and the anodic by‐product (magnesium hydroxide) during discharging. Thus, the wound exudate‐activated EFD can effectively manage wound exudates, prevent bacterial infection, and provide self‐powered electrotherapy to facilitate active wound tissue repair.

A Simple and Efficient Magnesium Hydroxide Modification Strategy for Flame-Retardancy Epoxy Resin.

Magnesium hydroxide, as a green inorganic flame-retardancy additive, has been widely used in polymer flame retardancy. However, magnesium hydroxide is difficult to disperse with epoxy resin (EP), and its flame-retardancy performance is poor, so it is difficult to use in flame-retardant epoxy resin. In this study, an efficient magnesium hydroxide-based flame retardant (MH@PPAC) was prepared by surface modification of 2-(diphenyl phosphine) benzoic acid (PPAC) using a simple method. The effect of MH@PPAC on the flame-retardancy properties for epoxy resins was investigated, and the flame-retardancy mechanism was studied. The results show that 5 wt% MH@PPAC can increase the limiting oxygen index for EP from 24.1% to 38.9%, achieving a V-0 rating. At the same time, compared to EP, the peak heat release rate, peak smoke production rate, total smoke production rate, and peak CO generation rate for EP/5 wt% MH@PPAC composite material decreased by 53%, 45%, 51.85%, and 53.13% respectively. The cooperative effect for PPAC and MH promotes the formation of a continuous and dense char layer during the combustion process for the EP-blend material, significantly reducing the exchange for heat and combustible gases, and effectively hindering the combustion process. Additionally, the surface modification of PPAC enhances the dispersion of MH in the EP matrix, endowing EP with superior mechanical properties that meet practical application requirements, thereby expanding the application scope for flame-retardant EP-blend materials.

Polyurethane nanofibers incorporated magnesium hydroxide followed by hydrothermal treatment using chitosan and silver nanoparticles to improve the biological properties

AbstractThe study aimed to explore the potential of magnesium hydroxide (Mg[OH]₂) nanoparticles (NPs) incorporated into polyurethane (PU) fibers, which were further coated with chitosan and silver (Ag) NPs. The hydrothermal approach was adopted to add the properties of chitosan and Ag NPs to the as‐spun fibers. These samples were characterized by field emission scanning electron microscope (FE‐SEM), EDS, Fourier transform infrared spectroscopy, thermogravimetric analysis, and contact angle measurements. The diameter of concocted fibers was found to be 0.79 ± 0.31 μm to 2.5 ± 0.9 μm. The presence of Mg(OH)2 decreased the fiber diameter from 2.05 ± 1.2 μm to 0.79 ± 0.31 μm; however, after hydrothermal coating, the diameter increased from 0.79 ± 0.31 μm to 2.5 ± 0.9 μm. The contact angle on pristine PU showed 105.53 ± 0.8°, that is, hydrophobicity, which was diminished to 9.3 ± 0.8° by the reorientation of PU with Mg(OH)2, chitosan and Ag NPs, that is, indicative of hydrophilic character. Biomineralization was evaluated by incubating in simulated body fluid, and the EDS and FE‐SEM indicated that composite fibers could induce apatite formation. Cell viability was measured using MTT assay, and cell adhesion/proliferation was confirmed by DAPI staining and FE‐SEM. The composite scaffolds promoted 3T3‐L1 to grow confluently.

Evaluation of enhanced nanofiltration membranes for improving magnesium recovery schemes from seawater/brine: Integrating experimental performing data with a techno-economic assessment

The global demand for valuable metals and minerals necessitates the exploration of alternative, sustainable approaches to mineral recovery. Seawater mining has emerged as a promising option, offering a vast reserve of minerals and an environmentally friendly alternative to land-based mining. Among the various techniques, Nanofiltration (NF) has gained significant attention as a preliminary treatment step in Minimum Liquid Discharge (MLD) and Zero Liquid Discharge (ZLD) schemes. This study focused on the potential of two underexplored commercial polyamide based NF membranes, Synder NFX and Vontron VNF1, with enhanced divalent over monovalent separation factors, in optimizing the extraction of magnesium hydroxide (Mg(OH)2) from seawater and seawater reverse osmosis (SWRO) brines. The research encompassed a thorough characterization of the membranes utilizing advanced physic-chemical analytical techniques, followed by rigorous experimental assessments using synthetic seawater and SWRO brine in concentration configuration. The findings highlighted the superior selectivity of NFX for magnesium recovery from SWRO brine and the promising concentration factors of VNF1 for seawater treatment. Cross-validation of experimental data with a mathematical model demonstrated the model's reliability as a process design tool in predicting membrane performance. A comprehensive techno-economic evaluation demonstrates the potential of NFX, operating optimally at 23 bar pressure and 70% permeate recovery rate, to yield an estimated annual revenue of 5.683 M€/yr through Mg(OH)2 production from SWRO brine for a plant with a nominal capacity of 0.8 Mm3/y. This research shed light on the promising role of NF membranes in enhancing mineral recovery taking benefit of their separation factors and emphasizes the economic viability of leveraging NF technology for maximizing magnesium recovery from seawater and SWRO brines.

The effect of spray drying parameters on drying of magnesium silicate hydroxide microspheres

Magnesium hydroxide silicate (MSH), as an antiwear additive for lubricating oil, effectively solves the problem that conventional additives contain chlorine, phosphorus and sulfur, which are harmful to environment. However, it is ineffective to prepare MSH powder by traditional drying combined with mechanical ball milling. So the purpose of this study is to prepare smooth MSH microspheres with controllable particle size and moisture content by adjusting spray drying parameters based on hydrothermal synthetic MSH suspension. Results showed that the particle size of MSH microsphere was reduced from 5.5 ± 2.9 μm to 2.78 ± 1.37 μm, and the moisture content was reduced from 7.3% to 4.43% by decreasing solid-liquid ratios and rotating speed of peristaltic pump, or raising inlet temperature of hot air, flow rate of compressed gas and inlet air. In addition, due to the surface energy difference at the interface between liquid-gas and solid-gas during the drying process, nano flaky MSH continuously moved to the center of the droplet, and the capillary force generated by gaps between MSH nanosheets discharges the moisture in the wet core, so that the MSH nanosheets gather and finally form dense and smooth MSH microspheres.

Construction of durable flame retardant, anti-dripping, and smoke-suppressing recycled polyester fabric

Recycled poly(ethylene terephthalate) (R-PET) fabrics offer a sustainable and eco-friendly alternative to virgin PET but exhibit high flammability and increased smoke emission. In this study, magnesium hydroxide nanoparticles (nano-Mg(OH)2) with the particle size of 53 nm were synthesized and combined with cyclic phosphate ester through high-temperature and high-pressure immersion technology. The organic‒inorganic flame retardant (FR) agents were expected to penetrate the R-PET fibers, thus achieving high washing durability for flame retardancy and smoke suppression. The surface structural performance of nano-Mg(OH)2 and the smoke and heat suppression capacity, FR performance, mechanism and laundering resistance of the modified R-PET samples were also explored. The organic‒inorganic FR system significantly improved the FR properties and anti-dripping ability of R-PET while significantly reducing smoke and heat generation. Moreover, the modified R-PET fabrics exhibited self-extinguishing ability even after 40 washes, indicating their high washing resistance. The organic‒inorganic FR system was effective in both gas and condensed phase, providing multilevel fire safety. This study provides efficient and durable FR-functionalized R-PET fabrics with low smoke suppression and high fire safety.

Development of sunflower husk reinforced polypropylene based sustainable composites: An experimental investigation of mechanical and thermal performance

AbstractClimate change, shrinking resources, and rising raw material costs have pushed the industry to create more sustainable, and lightweight materials. Natural fiber composites are materials of interest for replacing conventional materials such as steel. Sunflower husks (SH), among many other natural fibers, are readily accessible as agricultural waste and have advantageous properties. In this study, sunflower husks were mixed with polypropylene (PP) matrix using a twin‐screw extruder, and then tests specimens for experimental characterizations were manufactured through injection molding. The tensile tests revealed that the inclusion of SH into PP decreased the load‐bearing capacity of the composites by around 20% and increased their impact resistance by over 200%, while reducing the ductility by about eight times. Moreover, magnesium hydroxide (Mg(OH)2) was incorporated into the composites as a flame retardant, and it has improved the stiffness and impact resistance of the composites. Besides, incorporation of SH and Mg(OH)2 elevated significantly the glass transition temperature of the composites. The use of Mg(OH)2 delayed 60% the flame retention of the composites observed from UL‐94 HB flammability testing. In summary, they could be suitable for components such as spare wheel wells, seat backs, trunk floor, the acoustic panel behind the door, and airbag housing.

Highly Stable Hybrid Pigments Prepared from Organic Chromophores and Fluorinated Hydrotalcites

Structural hydroxide groups in layered magnesium–aluminum double hydroxides were partially replaced by fluoride ions. Fluorinated and fluorine-free materials were used as hosts for two dyes, carminic acid and hydroxyl naphthol blue, resulting in a hybrid pigment color palette. The pigments were produced by two ways, either incorporating chromophore during the synthesis of the layered double hydroxide or in a post-synthesis step through the memory effect of the LDHs. Additionally, the pigments were protected with a magnesium hydroxide phase to prevent the color from fading over time. The pigments were stable for periods as long as 10 years. The color properties of the pigments were significantly influenced by the host of dye since the presence of fluorine directly influences the acid–base properties of the layered double hydroxides. The pigments conferred their color to white cream in the preparation of colored creams. The colored creams acquired the color of the layered pigment.

Fast and complete recovery of magnesium from sea bittern to synthesize magnesium hydroxide hexagonal nanosheet for enhanced flame retardancy and mechanical properties of epoxy resin

Magnesium is the most abundant element in sea bittern, of which preferential and high-efficient recovery is significant for extraction of other valuable elements, such as lithium etc. In this work, a two-step method was proposed to rapidly and completely extract magnesium from sea bittern. Firstly, solid sodium hydroxide (NaOH) was directly added to sea bittern to convert magnesium to mesh-structure magnesium hydroxide (Mg(OH)2) intermediate, where Mg(OH)2 seeds were pre-added to accelerate the filtration process. Subsequently, mesh-structure Mg(OH)2 intermediate was hydrothermally transformed to Mg(OH)2 hexagonal nanosheet with size of 40–60 nm. The synthesized Mg(OH)2 hexagonal nanosheets after modification by sodium stearate were applied to enhancement in flame retardancy and mechanical properties of epoxy resin (EP). When the addition amount of Mg(OH)2 hexagonal nanosheets is 9 wt%, in contrast to pure EP, the formed composite showed decreased heat release rate, smoke production rate, total heat release and total smoke production by 63.5 %, 66.3 %, 39.2 % and 46.2 %, respectively. Simultaneously, tensile and bending strength of this composite were increased by 104.0 % and 61.9 %. This work gives a high-value route for magnesium in sea bittern without diluting sea bittern concentration, which would contribute to the high-value utilization of sea bittern in a cost-effective way.

Microstructural and mechanical analysis of magnesium chloride stabilization in highly plastic swelling clayey soils

In recent years, there has been an increasing interest in investigating the use of non-traditional additives for stabilizing problematic soils. As the demand for eco-friendly alternatives to cement rises, magnesium chloride, a widely used deicer and dust suppressor, has emerged as a potential choice. This study aims to provide a comprehensive understanding of the microstructural changes that occur and affect the macro behavior of treated bentonite (B) and yellow marl (YM). To achieve this, MgCl2 solution was added to the soils at 3, 6, 9, and 12 percent by dry weight of the soil, and samples were cured for 7, 14, and 28 days at 5°C, 25°C, and 35°C. The mechanical properties of the treated soils were then evaluated using the unconfined compression test, direct shear test, and pressure chamber test (SWCC), while microstructural analysis techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX), and Fourier transform infrared spectroscopy (FTIR) were employed to examine the mechanism of MgCl2 stabilization. The results indicate that adding MgCl2 and extending the curing period significantly increased both soils' unconfined compressive strength (UCS). However, the UCS value decreased for treated samples cured at temperatures higher than 25°C due to an incomplete cation exchange process and the reduction of apparent cohesion. A part of the gained strength from apparent cohesion and matric suction in the unsaturated samples was lost when the samples reached full saturation during the direct shear test. Changes in the particle size, pore size, and pore void distribution due to the MgCl2 stabilization affected the SWCCs of the treated soils. Microstructural analyses revealed the formation of magnesium hydration products, such as magnesium silicate hydrate (M-S-H) and magnesium aluminate hydrate (M-A-H), which contributed to the strength increase by increasing grain size, filling the pores, binding fine particles within coarse grains, and forming a flocculated structure through recrystallization of MgCl2 and the formation of cementitious gel. Additionally, for B, adding MgCl2 led to soil flocculation through ion exchange, while for YM, the same process occurred due to the greater surface tension of the saline solution encircling the particles.

The Properties of Magnesium Silicate Hydrate Prepared from the Magnesium Silicate Minerals in the Earth’s Crust

In order to explore a wider range and lower cost of raw materials for the preparation of magnesium silicate hydrate (M-S-H), an acid-leaching method was employed to extract and separate high-purity magnesium hydroxide (Mg(OH)2) with a purity higher than 97% and amorphous silica with a purity higher than 90% from four types of natural silicate minerals (serpentine, peridotite, zeolite, and montmorillonite). These two intermediate products, which are amorphous silica and magnesium hydroxide, were used to prepare M-S-H, and the influence of curing at two temperatures, 50 °C and 80 °C, on the properties of M-S-H was investigated. The results showed that with the increase in curing temperature, the bound water content, tetrahedral polymerization degree, and Mg(OH)2 content increased. There was a good correlation between the increase in strength and the bound water content of M-S-H. This work provides a possible technological route for expanding the raw materials for preparing magnesium silicate hydrate cementitious materials and utilizing the abundant magnesium silicate minerals in the Earth’s crust.

Investigation of Crystallization Growth Characteristics of Mg(OH)2 Crystals under Unconstrained Conditions.

Utilizing MgO as the precursor and deionized water as the solvent, this study synthesized nanoparticles of Mg(OH)2 via hydrothermal methods, aiming to control its purity, particle size, and morphology by understanding its growth under non-uniform nucleation. Characterization of crystal morphology and structure was conducted through scanning electron microscopy and X-ray diffraction, while laser particle size detection assessed the secondary particle size distribution. The study focused on how MgO's hydrothermal process conditions influence Mg(OH)2 crystal growth, particularly through ion concentration and release rate adjustments to direct crystal growth facets. These adjustments shifted the dominant growth plane, enhancing the peak intensity ratio I001/I101 from 1.03 to 2.14, thereby reducing surface polarity and secondary aggregation of crystals. The study of the physicochemical properties of the same sample at different times revealed the pattern of crystal dissolution and recrystallization. A 2 h hydrothermal reaction notably altered the particle size distribution, with a decrease in particles sized 0.2~0.4 μm and an increase in those sized 0.4~0.6 μm, alongside new particles over 1 μm, indicating a shift toward uniformity through dissolution and recrystallization. Optimal conditions (6% magnesium oxide concentration, 160 °C, 2 h) led to the synthesis of highly dispersed, uniformly sized magnesium hydroxide, showcasing a simple, eco-friendly, and high-yield process.

Yield stress modification of suspensions of irregularly shaped particles by addition of spherical colloidal silica

Magnesium hydroxide (Mg(OH)2) suspensions are encountered in the nuclear industry as legacy waste that is to be packaged for long-term storage. It is desirable to increase the solids content of the waste to minimize the total volume, yet this would produce high yield stress fluids that are difficult to process. However, high solids content suspensions of low yield strength are desired. Blending nano-silica (nano-SiO2) into a high yield stress suspension of 27 vol% Mg(OH)2, the suspension yield stress was reduced from 86 Pa to 47 Pa. X-ray CT imaging revealed that approximately two-thirds of the 3 vol% nano-SiO2 added to the Mg(OH)2 suspension was well-dispersed, with the rest forming large clusters that had minimal interaction with the Mg(OH)2 network. SEM images showed small aggregates/individual particles of nano-SiO2 dispersed between Mg(OH)2 particles. We conclude that the finely dispersed nano-SiO2 act like ball bearings to lubricate contacts between the irregularly shaped Mg(OH)2 particles, thus decreasing yield stress. When aging the samples for several days, the yield stress of the binary suspension increased, reversing the yield stress reduction that was observed within the first day. The network stiffening is attributed to the formation of magnesium silicate hydrate (MSH) due to a reaction between soluble Mg2+ and Si(OH)4. The MSH precipitates onto the nano-SiO2 to fuse particles together, thus reducing their effectiveness as flow modifiers. While this is a side effect of this particular binary suspension, the initial yield stress drop remains encouraging to provide the desired fluid conditions to process legacy wastes.

Porous carbon network-based composite phase change materials with heat storage capacity and thermal management functions

Porous carbon network-based phase change composites have been widely used in energy storage and thermal management related fields. At present, the demand of energy crisis for photothermal energy storage and the prevention and management of thermal abuse of electronic equipment constantly promote the development of carbon-based composite phase change materials (PCMs). Therefore, a series of new composite materials filled with PCMs and polyethylene glycol (PEG) and added with flame-retardant magnesium hydroxide were developed, which makes the composites show certain flame-retardant ability in high-temperature environments. The results show that the thermal conductivity increases from 0.25 to 0.94 W/m·K, and the latent heat of phase change remains at 142.7 J/g. In addition, due to the capillary effect caused by the synergistic effect of multi-pore carbon (MPC) structure and cellulose macromolecular chain, the composite material has good shape stability, which effectively prevents the leakage behavior of PCMs during solid-liquid phase change. Moreover, the absorbance of the composite material can reach 1.28 L/(g cm) in the ultraviolet–visible light range of 200 nm–800 nm, and its photothermal conversion efficiency can reach 90.8 %. Therefore, this material has a broad application prospect in the thermal management of electronic equipment and photothermal energy storage devices.

Enhancement in efficiency of solar photovoltaic power generation with the assistance of PVC/TiO2 reflective composite applied for double-sided power generation

Solar photovoltaic power generation is a productive and environmentally friendly technique. The results of objective evaluations show that double-sided power generation is more efficient than single-sided power generation, with a possible increase of 5 %–30 %. Hence, it is necessary to identify a composite that reflects the exact sunlight waveband (300–1100 nm) onto the backside of photovoltaic panels used for double-sided power generation. Herein, two different crystalline types of titanium dioxide (TiO2), rutile (R–TiO2) and anatase (A-TiO2), were combined with plasticized polyvinyl chloride (PVC) to create composites. A comparative analysis was conducted with other commonly utilized reflective fillers, such as barium sulfate (BaSO4) and magnesium hydroxide (Mg(OH)2). As a result, the R–TiO2 was identified as the most appropriate substance to be blended with PVC for the production of PVC/R–TiO2 composite. As the quantity of R–TiO2 increased from 0 to 100 phr, reflectance in the distinctive waveband of 300–1100 nm of the PVC/R–TiO2 rose from 5.30 % to 82.97 %. Moreover, an improvement in the thermal conductivity of PVC/R–TiO2 sample was observed, which increased by 59.2 % from 0.179 W m−1 K−1 to 0.285 W m−1 K−1, indicating a positive effect on heat transfer. The rheological measurement showed that the amount of reflective filler was inversely proportional to the compatibility of the reflective filler with plasticized PVC in the overall composite system, whereas the thermogravimetric analysis indicated that the thermal stability of the composites improved as the number of reflective fillers increased. Substantially, PVC/R–TiO2 composites exhibit better performance in enhancing the power generation efficiency of solar photovoltaic panels.

Experimental study on flexible flame retardant phase change materials for reducing thermal runaway propagation of batteries

The current research on phase change materials (PCM) for Battery Thermal Management Systems (BTMS) often focuses on a single characteristic, either flame retardancy or flexibility. PCM with both flexibility and flame retardancy is relatively uncommon, and studies on flexible PCMs have lacked experimental validation of their effectiveness. This study explored the optimal ratio of aluminium hydroxide (ATH)/ magnesium hydroxide (MTH)/ ammonium polyphosphate (APP), successfully creating a flexible flame-retardant PCM and applying it to battery cooling. The ratio of ATH/MTH/APP was determined as 9: 3:8, providing features such as leak resistance, high thermal conductivity, flame retardancy, and flexibility. Compared to the blank sample without flame retardants, the Peak Heat Release Rate (PHRR) and Total smoke production (TSP) of the PCM decreased by 48 % and 24.3 %, respectively. When applied to BTMS, the PCM restricted the battery's surface peak temperature and maximum temperature difference to 48.76 °C and 4.07 °C, respectively, at a discharge rate of 6C. After applying pressure to leverage flexibility, the temperature difference was further reduced to 1.76 °C, demonstrating the effectiveness of flexibility. In Thermal Runaway (TR) experiments, the PCM delayed the time triggered by TR by 84 s and reduced the maximum temperature by 92.3 °C. This work successfully combines flame retardancy and flexibility, offering valuable insights for the application of flame retardant flexible CPCM in BTMS and other relevant fields.