A 34-band k ⋅ p model is used to compute the standard k ⋅ p band parameters at Γ, X and L valleys in indirect-band-gap bulk materials for Td (AlAs) and Oh (Si, Ge) group semiconductors. The values of the effective masses for electrons, heavy and light holes in the Γ, X and L valleys are in very good agreement with those reported in other publications. Satisfactory agreement with available experimental data is also obtained by the present model. Finally, our results show that the Luttinger parameters, the κ valence band parameter and the effective Landé factor g* are in good agreement with available experimental data. In particular, the adjustment of the k ⋅ p Hamiltonian parameters proved that the g* of AlAs, Ge and Si are respectively 1.50, −2.79 and 1.96, which are in good agreement with the experimental values of 1.52, −2.50 and 1.99.
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