Low-temperature Applications Research Articles

Ideal Bi-Based Hybrid Anode Material for Ultrafast Charging of Sodium-Ion Batteries at Extremely Low Temperatures.

Sodium-ion batteries have emerged as competitive substitutes for low-temperature applications due to severe capacity loss and safety concerns of lithium-ion batteries at - 20°C or lower. However, the key capability of ultrafast charging at ultralow temperature for SIBs is rarely reported. Herein, a hybrid of Bi nanoparticles embedded in carbon nanorods is demonstrated as an ideal material to address this issue, which is synthesized via a high temperature shock method. Such a hybrid shows an unprecedented rate performance (237.9mAhg-1 at 2Ag-1) at - 60°C, outperforming all reported SIB anode materials. Coupled with a Na3V2(PO4)3 cathode, the energy density of the full cell can reach to 181.9 Wh kg-1 at - 40°C. Based on this work, a novel strategy of high-rate activation is proposed to enhance performances of Bi-based materials in cryogenic conditions by creating new active sites for interfacial reaction under large current.

III–V heterostructure tunnel field-effect transistor operation at different temperature regimes

Tunnel field-effect transistors (TFETs) are a potential alternative to MOSFETs for low-temperature electronics. We provide an in-depth experimental characterization of TFETs analyzing the fundamental physical behavior at different temperature regimes. TFET characteristics from 13 to 300 K both in forward and reverse bias are discussed by employing a variation in InAs/InGaAsSb/GaSb heterojunction vertical nanowire devices. Evaluation of the TFET Negative Differential Resistance (NDR) characteristics at different temperatures is established as a technique to probe the dopant incorporation. It is observed that the temperature dependence of the Fermi degeneracy and Fermi-Dirac distribution largely influences the transistor performance at each operating temperature. Our investigation reveals that the TFETs demonstrate lower subthreshold swing than the physical limit of MOSFETs above 125 K. For low-temperature applications, the devices can be operated down to a low operating bias of 0.1 V, while for high temperature, a larger bias of 0.3 V is preferred.

Crystal structure, magnetic property and cryogenic magnetocaloric effect of Gd4Al2O9 aluminate

Developing magnetic materials with excellent magnetocaloric effect (MCE) is a vital prerequisite for practical magnetic refrigeration (MR) applications. Herein, a single-phased polycrystalline Gd4Al2O9 compound was fabricated using the co-precipitation method, and its structure, magnetic property together with magnetocaloric performance were investigated. The Gd4Al2O9 compound was found to crystallize in the monoclinic structure space group P21/c with lattice parameters a = 7.4852 Å, b = 10.5561 Å, c = 11.1774 Å, β = 108.95° and V=835.3107 Å3, and the constituent elementals had valence states of Gd3+, Al3+ and O2−. Excellent comprehensive MCE performance was observed for the Gd4Al2O9 compound in low-temperature regions. The obtained values of maximal magnetic entropy change, temperature-averaged entropy change (3 K) and relative cooling power under the magnetic flux density change of 0–7 T are 26.31 J/kg·K, 25.09 J/kg·K and 317.05 J/kg. The Gd4Al2O9 compound shows impressive comprehensive MCE performances compared with some recently reported rare earth-based MR materials with prominent performances, meaning that it is a suitable candidate material for low-temperature MR applications.

Carbonate-mediated Mars-van Krevelen mechanism on CuxO/CeO2 catalysts for boosting CO oxidation

Copper-cerium-based catalysts have gained considerable attention for their excellent performance in low-temperature CO oxidation applications. In this context, the carbonate-mediated Mars-van Krevelen (M−vK) pathway stands out as a promising route for enhancing catalytic performance. Herein, we prepared three CuxO/CeO2 nanocatalysts with varying copper content using Cu2O nanocrystals (Cu2O NCs) and Ce-BTC metal–organic frameworks (MOFs) as dual precursors. The optimal catalyst exhibits excellent performance (T100 value of 110 °C) comparable to the precious metal catalyst. Through integrating in-depth experimental results and density functional theory (DFT) calculations, we reveal the intricate interplay of interfacial synergistic catalysis and carbonate-mediated M−vK mechanisms, confirming that carbonate species generated under mild conditions significantly promote CO oxidation on CuxO/CeO2 nanocatalysts. Based on the comparison of the transition state (TS) energy barrier between the traditional and the carbonate-mediated M−vK mechanism reaction paths, we found that carbonate species is easier to form and establish the rate-determining step (viz., carbonate → CO2, the energy barrier of 1.51 eV). This study sheds light on the importance of carbonate species in modulating the catalytic behaviour of copper-cerium catalysts and provides valuable insights for designing efficient catalysts for CO oxidation applications.

ZnO/Organic superlattice with phase composite structure for enhanced thermoelectric performance at low temperature

Semiconducting metal oxides, such as zinc oxide (ZnO), are gaining recognition for thermoelectric applications due to their temperature stability, availability, eco-friendliness, and cost-effectiveness. However, ZnO faces challenges in achieving high ZT value due to its low carrier concentration and high thermal conductivity. Traditional methods, like doping and defect engineering, have shown limited success in overcoming these challenges. In this study, we introduce a unique superlattice structure with a phase-composite composition that significantly decreases thermal conductivity through enhanced phonon scattering while maintaining the power factor by inducing new resonant conducting states near the mobility edge. By optimizing nanolayer thickness and doping concentration, we achieved a remarkable power factor of 14.6 μW cm−1 K−2 and reduced thermal conductivity to ∼1.97 W m−1 K−1 at room temperature in samples with 6 nm-thick ZnO nanolayers fabricated at 100 °C. This leads to a ZT value of ∼0.22 at 300 K, the highest among metal oxide thermoelectric materials at low temperatures, which further increases to ∼0.55 at 510 K. These findings demonstrate the potential of hybrid superlattices for efficient low-temperature thermoelectric applications.

Enhancing Low-Temperature Sensor Applications: Synergistic Effects of Ni Doping and SnO2 Interlayer on Spin-Coated ZnO Thin Films on Glass Substrate

This study investigates the effects of Nickel doping and a SnO2 interlayer on the structural, morphological, optical, and electrical properties of ZnO thin films. Undoped and Ni-doped ZnO films were fabricated on glass substrates, with and without an SnO2 interlayer, using the sol-gel spin coating method. The samples—denoted as ZG (undoped ZnO), NZG (Ni-doped ZnO), ZSG (undoped ZnO with SnO2 interlayer), and NZSG (Ni-doped ZnO with SnO2 interlayer)—underwent comprehensive characterization via XRD, AFM, PL, UV-Vis spectroscopy, Hall effect measurements, Hot probe, and Two-point method. XRD analysis confirmed successful Ni incorporation and enhanced ZnO crystallinity, particularly in the presence of the SnO2 interlayer. AFM analysis revealed improved grain distribution and size due to the synergistic effects of Ni doping and the SnO2 interlayer. UV-Vis results indicated significant impacts on transparency and the Urbach energy, with Ni doping alone broadening the bandgap. PL measurements showed that the synergistic effects quenched UV luminescence associated with the glass substrate, enhancing visible luminescence. Chromaticity analysis suggested that ZSG and NZSG samples are suitable for warm blue region applications. Electrical measurements revealed n-type conductivity across all films except NZG, with Ni doping increasing resistivity. Additionally, the ZSG (PTC) sensor exhibited a slightly higher sensitivity (0.3852 Ω/°C) compared to the NZSG sensor (0.3782 Ω/°C), with a similar trend observed in NTC sensors. These findings suggest that Ni-doped ZnO films with SnO2 interlayers could potentially serve as thermistors and RTDs, offering promising applications in temperature sensing and optoelectronics.

Thermodynamic re-optimisation of the CaO-FeO-Fe2O3 system integrated with experimental phase equilibria studies (Part II – Thermodynamic optimisation)

The Ca-Fe-O system is essential for understanding the chemical equilibria involved in copper production using calcium ferrite slags. It forms a core component of a complex 20-component Cu-Pb-Zn-Fe-Ca-Si-O-S-Al-Mg-Cr-Na-As-Sn-Sb-Bi-Ag-Au-Ni-Co system developed for diverse applications in ferrous and non-ferrous metallurgy. This study re-evaluates the Ca-Fe-O system using recent experimental phase equilibrium data acquired by the authors [1] through advanced equilibration, quenching, and Electron Probe X-ray Microanalysis (EPMA) techniques. Thermodynamic properties of solid phases have been revised in accordance with the recommendations for the third generation of Calphad databases. Liquid endmember heat capacities have been refined to describe glass transition behaviour in supercooled liquids. The updated properties of liquid endmembers significantly extend the applicability of the database, enabling lower-temperature applications related to toxic element leaching from amorphous and partially crystallized slags. The revised, higher melting temperature of CaO enhances predictive accuracy in multicomponent systems. Liquid slag phase has been modelled within the Modified Quasichemical Formalism to account for short-range ordering phenomena. Recent advances in modelling and optimization technique made it possible to assess experimental data within the Ca-Fe-O system as an integral part of a large multicomponent dataset, applicable for industrial conditions.

Metabolite changes by combined treatment, ethyl formate and low temperature, in Drosophila suzukii

Although ethyl formate (EF) fumigant and low temperature applications are widely used for pest management, studies related to their mechanisms of action and subsequent metabolic changes in Drosophila suzukii models are still unclear. In this study, a comparative metabolome analysis was performed to investigate the major metabolites modified by EF and low temperature and how they are related to and affect insect physiology. Most of the identified metabolites function in metabolic pathways related to the biosynthesis of amino acids, nucleotides and cofactors. In addition, a combined treatment with EF and low temperature significantly altered the tricarboxylic acid cycle (TCA) and the levels of the purine and pyrimidine classes of metabolites. Interestingly, the levels of cytochrome P450 and glutathione metabolites involved in detoxification dramatically changed under stress conditions compared to those in the control group.

Significant enhancement in the magnetic properties of Cr2Te3 nanosheets by atom substitution doping.

Ferromagnetic Cr2Te3 nanocrystals, with their high spin-orbit coupling and low symmetry, have attracted considerable attention as rare-earth-free magnetic nanomaterials due to their potential to achieve high magnetic anisotropy. However, their relatively low values of remanence (Mr) and saturation (MS) magnetisation limit their energy product, making them unsuitable for practical applications. Herein, we report a straightforward one-pot heat-injection technique for the synthesis of high-remanence hexagonal Cr2Te3 nanosheets by heterogeneous doping with atoms of M (M = V, Mn and Se). The doped materials provide enhanced Mr and MS at an unchanged Curie temperature (TC), resulting in excellent hard magnetic properties. With Mn doping, the Mr of the matrix increases significantly, reaching 18.38 emu g-1 at 5 K, far exceeding the original undoped Cr2Te3 nanosheets. The nearly square hysteresis loop makes it valuable for many low temperature applications. These results provide a valuable case for tuning the magnetism of ferromagnetic Cr2Te3 by substitutional doping.

Enhanced magnetocaloric effect in nano-sized Dy3Ga5O12 garnet: A comparative study on the effect of solid-state and wet-chemical synthesis

This study investigates the magnetic and structural properties of bulk and nanosized Dy3Ga5O12 (DGG) synthesized through solid-state and wet chemical methods to assess the impact of particle size. The single-phase composition of the synthesized materials was determined by X-ray diffraction analysis (XRD). XRD and TEM analysis revealed the formation of nanosized DGG via the wet chemical route at 750 °C/2h. The nano DGG exhibits enhanced magnetocaloric effect compared to its bulk counterpart, suggesting its potential as a promising material for low-temperature magnetic refrigeration applications.

Cu–Cu joint with great strength using In/Sn–58Bi hybrid soldering at low temperature (90 °C)

This study investigates Cu single-sided solder joints using hybrid soldering (In + Sn58Bi) at reflow temperatures ranging from 80 to 130 °C. The wetting angles of 27° at 90 °C and 22° at 130 °C demonstrated good wettability. The hybrid solders were composed of γ-In(Sn, Bi) and Bi(In, Sn)2 phases, forming Cu6(In, Sn)5 interfacial intermetallic compounds (IMCs). Thermodynamic calculations proved that the hybrid soldering possessed a low liquid temperature of 86.8 ° C, making it suitable for low-temperature applications. The hybrid solders demonstrated notable mechanical performance, with microhardness values exceeding 10 HV—higher than Sn–52In solder (6 HV). Sandwich hybrid-solder joints, reflowed at 90 and 130 ° C, outperformed Sn–52In soldering strength (30.1 and 35.5 MPa) by over 135% and 175%. Additionally, the hybrid solder contains only 41.9 wt% In, lower than Sn–52In, reducing material costs. This study reveals the hybrid solder system offers a promising low-cost and good-strength solution for low-temperature soldering applications.

Investigation of a Novel Thermochemical Reactor for Medium- and Low-Temperature Heating Applications in Buildings

This research paper investigates a novel triangular honeycomb thermochemical energy storage reactor for low- and medium-temperature applications in buildings, emphasizing its potential to enhance sustainable heating. Using a validated 3D numerical model, the reactor’s performance is analyzed in depth across various configurations, focusing on key parameters such as energy storage density, pressure drop, internal air flow distribution, and round-trip efficiency. Results show that the reactor achieved an energy storage density of 872 kJ/kg and a round-trip thermal efficiency of 41.51% under optimal conditions. Additionally, the triangular honeycomb reactor (30°, 60, and 90°) configuration achieved the highest temperature lift of 48.7 °C. In a feasibility analysis for residential heating in northern China, the reactor with 30°, 60°, and 90° angles required 24.91% less volume to meet daily heating demands compared to other configurations. This study contributes valuable insights for the development of efficient, low-carbon heating solutions for low- and medium-temperature applications in buildings, offering interesting advancements in the field of thermochemical energy storage technology.

Optimizing cascade refrigeration systems with low GWP refrigerants for Low-Temperature Applications: A thermodynamic analysis

This study offers a comprehensive thermodynamic analysis of a cascade refrigeration system conducted for low-temperature applications, focusing on the use of low-GWP and zero-ODP refrigerants to improve efficiency and sustainability. The target of this study is to explore the performance of the system using a combination of refrigerants: low-temperature cycle refrigerants such as R744, while high-temperature cycle refrigerants such as R717, R1234yf, R1234ze(E), R1336mzz(E), and R1336mzz(Z), respectively. The ECS model incorporating in REFPROP 10.0a tool was utilized to extract the data through coding for analysis. The assessment of this system involves the examination of various parameters such as its coefficient of performance, total compressor workload, total exergy, and exergy efficiency across various operational conditions. The results are compared with and without superheated and subcooled conditions to understand the impact of these parameters on the system performance. The system with R744 in the low-temperature cycle and R717, R1234yf, R1234ze(E), R1336mzz(E), and R1336mzz(Z) in the high-temperature cycle provides a higher COP and lower total compressor work compared to the conventional cascade refrigeration system. In optimal CRS, the R744-R717 pair attains the highest COP of 2.05 at the lowest possible compressor work from 9.53 to 4.87 kW than other refrigerants pair while evaporator temperature shifting from −55 °C to −20 °C. The exergy efficiency of R744/R717 is found at 26.47 % at an evaporator temperature of −55 °C, but it extends to a peak of 51.73 % at −20 °C. The study also shows that the superheating and sub-cooling of the refrigerants have a significant impact on the performance of the cascade refrigeration system. Superheating and sub-cooling at 10 °C, improves the COP of the system by reducing the compressor work and increasing the heat transfer efficiency. The research offers valuable insights into the system’s thermodynamic performance when employing low GWP refrigerants in low-temperature applications. These findings have the potential to guide the design and optimization of cascade refrigeration systems over the range of low-temperature applications.

Thermal-hydraulic performance of R1234yf in brazed plate heat exchanger at low saturation temperature and mass flux conditions: Experimental investigation

This study investigated the heat transfer coefficient (hr) and two-phase frictional pressure drop during the evaporation of R1234yf within an offset strip fin (OSF)-structured brazed plate heat exchanger (BPHE). The work is conducted at a saturation temperature (Ts) of −3 to 3 °C, with mass flux (G) ranging from 25 to 45 kg m−2 s−1 and heat flux (q) between 15 and 23 kW m−2 across a vapor quality (x) range of 0.1–0.8. Understanding these behaviors is critical for optimizing BPHEs in low-temperature applications, such as heat pumps, where energy efficiency is essential. The novelty of this work lies in its exploration of operating conditions that are less studied in the literature, particularly the impact of low Ts, low G, and high q on hr and two-phase frictional pressure drop in an OSF-BPHE with R1234yf. Unlike prior studies focusing on convection-dominated boiling, our findings reveal a coexistence of nucleate and convective boiling mechanisms, especially at different vapor qualities. The hr is significantly influenced by q at x < 0.6, G at x > 0.6, and Ts across all x. In contrast, evidence of dryout at high x highlights the importance of these parameters in managing heat transfer efficiency. The results indicate a strong correlation between the two-phase frictional pressure drop and G, with a marked increase in it at higher G. Besides, this study reveals flow characteristics commonly linked with both macrochannel and minichannel flows, enhancing novelty by bridging the gap between these two regimes. These findings challenge existing literature correlations that predominantly emphasize convection-dominated behavior and contribute to a better understanding of the dual boiling mechanisms in BPHEs.

The Ether’s Chain Length Effect in Electrolyte for Hard carbon towards Efficient Sodium Storage at Low Temperature

The synergy between ether-based electrolytes (EBEs) and hard carbon (HC) in sodium-ion batteries (SIBs) enhances Coulombic efficiency, durability, and rate capability. Despite these advantages, the intricate relationship of how the molecular structure of ether solvents modifies electrolyte properties and, subsequently, sodium storage performance remains inadequately explored, especially for low-temperature applications, limiting the advancement of EBEs. Our study investigates ethylene glycol ether-based electrolytes with varying chain lengths to understand their influence on reaction kinetics and sodium storage. Notably, HC electrodes paired with NaPF6/ethylene glycol dimethyl ether exhibit superior performance, achieving 247.5 mAh g-1 after 2000 cycles at 1.0Ag-1. Even at -20 °C, these cells exhibit impressive endurance, retaining capacities of 257.5 mAh g-1 in half cells and 75.5 mAh g-1 in full cells at 0.1Ag-1 after 100 cycles, considering the entire mass of active material. Our thorough analysis indicates that the ether solvent with shorter chain length, distinguished by its low solvation-free energy and accelerated ionic kinetics, promotes rapid de-solvation and the formation of an inorganic-rich interface. Through this study, we illuminate the pivotal influence of solvent chain length on sodium storage in hard carbon, contributing to foundational insights towards the design of sophisticated electrolytes for SIBs.

Fiber-to-Chip Packaging With Robust Fiber Fusion Splicing for Low-Temperature Applications

Fiber-to-Chip Packaging With Robust Fiber Fusion Splicing for Low-Temperature Applications

A Review of the Energy-Saving Potential of Phase Change Material-Based Cascaded Refrigeration Systems in Chinese Food Cold Chain Industry

As the global demand for food increases, the efficiency and environmental sustainability of refrigeration systems have become increasingly critical issues. Cascaded refrigeration systems (CRSs) are widely used in the Chinese food cold chain due to their capacity to meet a wide range of temperature requirements. However, energy consumption of these systems is always high. If phase change materials (PCMs) are combined with the refrigeration systems, the energy-saving effect is remarkable. The paper reviews the integration of PCMs within CRS, focusing on their potential to reduce energy consumption, thereby improving food safety and reducing reliance on conventional, electricity-intensive refrigeration methods. The study categorizes and explores the low-temperature applications of PCMs in CRS, providing novel insights into enhancing energy efficiency in food cold chain logistics. Despite most PCM research focusing on single-stage systems, this review innovates by introducing PCM integration in multistage cascade systems, which is particularly relevant for low-temperature requirements. The discussion encompasses the structure, working fluids, and applications of CRSs in the cold chain, emphasizing the role of PCMs in sustainable cold chain management. The review concludes by highlighting the need for further research on PCMs in CRS, especially regarding their economic viability and large-scale implementation potential.

Investigation the Performance of an Evacuated Tube Solar Collector Filled with MWCNT/ Water Nanofluid Under the Climate Conditions of Al-Hilla (Iraq)

The main obstacles to securing the future of humanity are the rising energy demand and the constrained supply of conventional energy sources. In order to guarantee the sustainability of energy in this world for the present and the future, solar energy is a desirable source of energy. Solar thermal collectors with evacuated tubes are primarily employed in domestic settings. Even in low-temperature applications, replacing the working fluid with nanofluid can improve heat transfer. The effect of Multi-Walled Carbon Nanotubes (MWCNT) and water nanofluid as working fluids in evacuated tube solar collectors(ETSC) is used to investigate the collector's thermal performance experimentally. Three different volume fraction of (MWCNT) nanoparticles of (0.01%, 0.03% and 0.05%) were examined at various volume flow rates ranging from (1 to 3 L/min). Experiments were performed in Al –Hilla, Iraq. The results show an enhancement in the efficiency with increase in the volume fraction of(MWCNT)nanoparticles and volume flow rate (i.e. concentration (0.05%) and volume flow rate (3L/min). The temperature difference of the fluid at concentration (0.05%) and volume flow rate (1L/min) increased up to (86.84 %) with adding (MWCNT) nanoparticles compared with the water. The results showed, maximum efficiency enhancement of the collector at concentration (0.05%) and volume flow rate (3L/min) about (69.63%) compared with water.

Performance assessment on a modified precision refrigeration cycle using low GWP mixtures

Recently, with the increasing worldwide demand for low-temperature freezers, applying natural working medium hydro-carbon refrigerants for them has been widely concerned. Auto-cascade refrigeration cycle (ARC), as an efficient refrigeration technology, has been widely applications. However, the low separation efficiency of the refrigerant mixtures of the conventional ARC leads to its poor performance. Therefore, this paper presents a modified auto-cascade refrigeration cycle (MARC) using low GWP hydro-carbon refrigerants R170 and R290 for low-temperature freezer applications. In MARC, the two auxiliary separators are applied to make more low-boiling working fluid into evaporator to improve the volumetric cooling capacity (qev) and COP. The characteristics of conventional ARC and MARC are evaluated with theoretical method. The important parameters such as evaporating temperature and intermediate temperature for MARC are also detailed discussed. The theoretical research results suggest the MARC is more energy-saving and feasible. The improved cycle offers significant improvements in qev, COP and exergy efficiency. In detail, for MARC, the qev can be lifted by 40.3–91.3 % and the COP can be improved by 30.6–70.4 % compared with the ARC system. Therefore, the modified MARC shows its potential advantages for low-temperature freezer applications.

Economic Analyses of a New Power and Cooling System at Low Temperature Applications

Recent research suggests that the implementation of more efficient combined cooling and power systems, which enable the cogeneration of electricity and cooling, can enhance the efficiency of hybrid plants. The present investigation is motivated by finding that, in the literature review on combined power and cooling systems, there is very limited information on the coupling of the organic Rankine cycle (ORC) and the ejector refrigeration cycle (ERC) with low sink temperatures. A suggested approach to do this involves using hot exhaust gas and waste heat engines to power an ORC hybrid system. To enhance the ORC–ERC system's performance, three heater configurations use waste heat from the ORC turbine exhaust, ejector, and engine waste heat to heat the working fluid. Renewable energy sources are the primary focus of most current research initiatives. The present research focuses on unique ORC and ERC systems, considered as combined power and cooling systems, with the goal of improving exergy performance at low temperatures. The suggested ORC–ERC can generate energy destruction of 69.85 kW at a source temperature of 155 °C, with an exergetic efficiency of 76.9% at the turbine. Setting the entrainment ratio at 0.5 results in a total sum unit cost of products (SUCP) of 465 $/kW‐h for the ORC–ERC. Furthermore, the 37.83% exergy destruction ratio introduces heat exchanger 2 (HE2) as the primary cause of the suggested ORC–ERC's irreversibility. A detailed parametric study reveals that altering the hot source temperature and entrainment ratio improves the system's SUCP. The current examination at high sink temperatures may be expanded to an advanced exergoenvironmental investigation.