Volatilization Losses Research Articles

Using the von Bertalanffy Model to Describe Ammonia Volatilization from Conventional and Stabilized Nitrogen Fertilizers in Coffee Crop System

ABSTRACT It has been increasingly important to control N-fertilizers, seeking high efficiency. This study aims to describe, using the von Bertalanffy model, the cumulative losses of nitrogen (N) by ammonia volatilization (NH3-N) from conventional and stabilized N-fertilizers applied in coffee orchard. The experiment was performed in Lavras municipality, Minas Gerais state, Brazil during the 2015/2016 coffee growing season. A randomized block design was used, with seven treatments (stabilized and conventional N-fertilizers) and three fertilizer applications. The evaluated stabilized and conventional N-fertilizers were: 1) prilled urea; 2) ammonium sulfate; 3) urea dissolved in water; 4) ammonium nitrate 5) urea + Cu + B; 6) urea + anionic polymer and; 7) urea + NBPT. Volatilization losses were evaluated, and the highest percentage of NH3-N losses occurred with prilled urea and urea + anionic polymer, with losses greater than 30% of N-applied depending on the number of installments. However, in the 2nd nitrogen fertilization, the von Bertalanffy model did not reach convergence for these treatments, which may have been influenced by the rainfall volume in the period. The lowest NH3-N losses were found for ammonium nitrate and ammonium sulfate, with losses that did not exceed 0.6%. The parameters were all significant and had biological interpretation, and the results will contribute to the development of more efficient fertilizers technologies for farmers. The von Bertalanffy model was adequate to describe the cumulative loss of N by volatilization of ammonia from conventional and stabilized N-fertilizers for coffee crop areas.

Trace Silicon Determination in Biological Samples by Inductively Coupled Plasma Mass Spectrometry (ICP-MS): Insight into the Volatility of Silicon Species in Hydrofluoric Acid Digests for Optimal Sample Preparation and Introduction to ICP-MS

A method for the determination of trace levels of silicon from biological materials by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. The volatility of water-soluble silicon species, hexafluorosilicic acid (H2SiF6), and sodium metasilicate (Na2SiO3) was investigated by evaporating respective solutions (50 µg/mL silicon) in HNO3), nitric acid + hydrochloric acid (HNO3 + HCl), and nitric acid + hydrochloric acid + hydrofluoric acid (HNO3 + HCl + HF) at 120 °C on a hot-block to near dryness. The loss of silicon from H2SiF6 solutions was substantial (>99%) regardless of the digestion medium. Losses were also substantial (>98%) for metasilicate solutions heated in HNO3 + HCl + HF, while no significant loss occurred in HNO3 or HNO3 + HCl. These results show that H2SiF6 species were highly volatile and potential losses could confound accuracy at trace level determinations by ICP-MS if digestates prepared in HF are heated to eliminate HF. Among the various matrices comprising major elements, sodium appeared to be effective in reducing silicon loss from H2SiF6 solutions. Excess sodium chloride (NaCl) matrix provided better stability, improving silicon recoveries by up to about 80% in evaporated HF digestates of soil and mine waste samples, but losses could not be fully prevented. To safely remove excess acids and circumvent the adverse effects of excess HF (e.g., risk of high Si background signals), a two-step digestion scheme was adopted for the preparation of biological samples containing trace silicon levels. A closed-vessel digestion was performed either in 4 mL of concentrated HNO3 and 1 mL of concentrated HCl or 4 mL of concentrated HNO3, 1 mL of concentrated HCl and 1 mL of concentrated HClO4 on a hot plate at 140 °C. Digestates were then evaporated to incipient dryness at 120 °C to remove the acids. A second closed-vessel digestion was carried out to dissolve silicates in 0.5 mL of concentrated HNO3 and 0.5 mL of concentrated HF at 130 °C. After digestion, digestates were diluted to 10 mL. The solution containing about 5% HNO3 and 5% HF was directly analyzed by ICP-MS equipped with an HF-inert sample introduction system. The limit of detection was about 110 µg/L for 28Si when using the Kinetic Energy Discrimination (KED) mode. The method was used to determine silicon in various plant and tissue certified reference materials. Data were acquired for 28Si using KED and standard (STD) modes, and 74Ge and 103Rh as internal standard elements. There was not any significant difference between the accuracy and precision of the results obtained with 74Ge and 103Rh within the same measurement mode. Precision, calculated as relative standard deviation for four replicate analyses, varied from 5.3 (tomato leaves) to 21% (peach leaves) for plant and from 2.2 (oyster tissue) to 33% (bovine liver) for tissue SRM/CRMs. Poor precision was attributed to material heterogeneity and the large particle size distribution. An analysis of lung tissue samples from those with occupational exposure to silica dust revealed that tissues possessed substantial levels of water-soluble silicates, but the most silicon was present in the particulate matter fraction.

Hydrocarbon Extraction with Ionic Liquids.

Separation and reaction processes are key components employed in the modern chemical industry, and the former accounts for the majority of the energy consumption therein. In particular, hydrocarbon separation and purification processes, such as aromatics extraction, desulfurization, and denitrification, are challenging in petroleum refinement, an industrial cornerstone that provides raw materials for products used in human activities. The major technical shortcomings in solvent extraction are volatile solvent loss, product entrainment leading to secondary pollution, low separation efficiency, and high regeneration energy consumption due to the use of traditional organic solvents with high boiling points as extraction agents. Ionic liquids (ILs), a class of designable functional solvents or materials, have been widely used in chemical separation processes to replace conventional organic solvents after nearly 30 years of rapid development. Herein, we provide a systematic and comprehensive review of the state-of-the-art progress in ILs in the field of extractive hydrocarbon separation (i.e., aromatics extraction, desulfurization, and denitrification) including (i) molecular thermodynamic models of IL systems that enable rapid large-scale screening of IL candidates and phase equilibrium prediction of extraction processes; (ii) structure-property relationships between anionic and cationic structures of ILs and their separation performance (i.e., selectivity and distribution coefficients); (iii) IL-related extractive separation mechanisms (e.g., the magnitude, strength, and sites of intermolecular interactions depending on the separation system and IL structure); and (iv) process simulation and design of IL-related extraction at the industrial scale based on validated thermodynamic models. In short, this Review provides an easy-to-read exhaustive reference on IL-related extractive separation of hydrocarbon mixtures from the multiscale perspective of molecules, thermodynamics, and processes. It also extends to progress in IL analogs, deep eutectic solvents (DESs) in this research area, and discusses the current challenges faced by ILs in related separation fields as well as future directions and opportunities.

BIOGAS PRODUCTION POTENTIAL FROM ANAEROBIC CO-DIGESTION OF FOOD WASTE AND ANIMAL MANURE

The potential of biogas production by the anaerobic codigestion (AcoD) of canteen food waste and animal manure was investigated using the biochemical methane potential assay (BMP). The BMP assay was conducted under thermophilic temperature of 35 °C in a batch process at digestion time of 40 d. Waste substrate mixture was digested at a fixed proportion of 1:1 with different animal manure as co-substrate. Maximum cumulative biogas production (418 ml g-1 VS) was achieved during codigestion of food waste with pig manure > chicken manure (408 ml g-1 VS) > goat manure (319 ml g-1 VS). Generally, all manure codigested reactors produced 1.01 to 1.34 times more biogas than food waste alone indicating the synergistic effect of codigestion on overall biogas productivity. With analogous increase in biogas production, manure amendment produced significant (p<0.05) substrate biodegradation in terms of total and volatile solids loss. The microbial load profile prior and post-AD revealed significant reduction (p<0.05)in microbial species suggestion that anaerobic digestion can be adopted as a method of waste treatment and hygienization.

Development of a gastroprotector from Algrizea minor essential oil complexed with β-Cyclodextrin

Algrizea minor, a member of the Myrtaceae family, is found in the Cerrado and Caatinga biomes. Essential oils (EO) are highly volatile, prompting the need to minimize volatilization losses and enhance their therapeutic effects. Cyclodextrins, cyclic and inert oligosaccharides, have the capability to form inclusion complexes with various molecules. Gastritis, an inflammatory condition, manifests painful episodes that may involve gastric and duodenal peptic ulcers. This study aims to evaluate the pharmacological potential of Algrizea minor essential oil in both free and complexed forms with β-Cyclodextrin (β-CD). The inclusion complex was created by combining essential oil and β-CD in a 1:1 ratio based on the molecular weight of the major compound in the oil. Characterization was conducted using Fourier-Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), and Thermogravimetry (TG). Gastroprotective capacity, physical barrier, and pathways of gastroprotection were assessed. The essential oil distinguished itself with the presence of β-Pinene and α-Pinene. Characterization of the inclusion complex revealed features of both the EO and β-CD. Tests demonstrated the curative efficacy of both free and complexed oils, with effectiveness dependent on the dosage. Intense gastroprotective activity was observed, with 90.25% and 99% inhibition of gastric injury for the free and complexed oils, respectively. It was determined that the pharmacological mechanism of action involves the stimulation of sulfhydryl compound production, the expression of nitric oxide (NO) and ATP-dependent potassium channels. Cytokines and oxidative stress were measured, and their responses contradicted the gastroprotection analysis. The tests highlighted the curative efficiency of both free and complexed oils, showing intensified gastroprotective activity when Algrizea minor essential oil was complexed with β-Cyclodextrin.

Indoor-Outdoor Oxidative Potential of PM2.5 in Wintertime Fairbanks, Alaska: Impact of Air Infiltration and Indoor Activities.

The indoor air quality of a residential home during winter in Fairbanks, Alaska, was investigated and contrasted with outdoor levels. Twenty-four-hour average indoor and outdoor filter samples were collected from January 17 to February 25, 2022, in a residential area with high outdoor PM2.5 concentrations. The oxidative potential of PM2.5 was determined using the dithiothreitol-depletion assay (OPDTT). For the unoccupied house, the background indoor-to-outdoor (I/O) ratio of mass-normalized OP (OPmDTT), a measure of the intrinsic health-relevant properties of the aerosol, was less than 1 (0.53 ± 0.37), implying a loss of aerosol toxicity as air was transported indoors. This may result from transport and volatility losses driven by the large gradients in temperature (average outdoor temperature of -19°C/average indoor temperature of 21 °C) or relative humidity (average outdoor RH of 78%/average indoor RH of 11%), or both. Various indoor activities, including pellet stove use, simple cooking experiments, incense burning, and mixtures of these activities, were conducted. The experiments produced PM2.5 with a highly variable OPmDTT. PM2.5 from cooking emissions had the lowest OP values, while pellet stove PM2.5 had the highest. Correlations between volume-normalized OPDTT (OPvDTT), relevant to exposure, and indoor PM2.5 mass concentration during experiments were much lower compared to those in outdoor environments. This suggests that mass concentration alone can be a poor indicator of possible adverse effects of various indoor emissions. These findings highlight the importance of considering both the quantity of particles and sources (chemical composition), as health metrics for indoor air quality.

Atmospheric Loss in Giant Impacts Depends on Preimpact Surface Conditions

Earth likely acquired much of its inventory of volatile elements during the main stage of its formation. Some of Earth’s proto-atmosphere must therefore have survived the giant impacts, collisions between planet-sized bodies, that dominate the latter phases of accretion. Here, we use a suite of 1D hydrodynamic simulations and impedance-match calculations to quantify the effect that preimpact surface conditions (such as atmospheric pressure and the presence of an ocean) have on the efficiency of atmospheric and ocean loss from protoplanets during giant impacts. We find that—in the absence of an ocean—lighter, hotter, and lower-pressure atmospheres are more easily lost. The presence of an ocean can significantly increase the efficiency of atmospheric loss compared to the no-ocean case, with a rapid transition between low- and high-loss regimes as the mass ratio of atmosphere to ocean decreases. However, contrary to previous thinking, the presence of an ocean can also reduce atmospheric loss if the ocean is not sufficiently massive, typically less than a few times the atmospheric mass. Volatile loss due to giant impacts is thus highly sensitive to the surface conditions on the colliding bodies. To allow our results to be combined with 3D impact simulations, we have developed scaling laws that relate loss to the ground velocity and surface conditions. Our results demonstrate that the final volatile budgets of planets are critically dependent on the exact timing and sequence of impacts experienced by their precursor planetary embryos, making atmospheric properties a highly stochastic outcome of accretion.

Large Carbonaceous Chondrite Parent Bodies Favored by Abundance–Volatility Modeling: A Possible Chemical Signature of Pebble Accretion

Primitive meteorite groups such as the Vigarano, Mighei, and Karoonda carbonaceous chondrites have enigmatic patterns of elemental abundances, with moderately volatile elements—those that transition from vapor to condensate between ∼400 and ∼900 K—defining plateaus of subequal abundances despite a wide range in volatility. In detail, each group defines a plateau with distinctive nonmonotonic “chemical fingerprints” that have been attributed to combinations of mixing, vaporization/condensation, and fluid-mediated metasomatism—but the extent to which these processes can reproduce the observed variability has not been quantified. Starting with primitive Ivuna chondrite, a two-stage, two-component equilibrium condensation–vaporization model—with gravity implemented as Jeans escape—can explain large-scale plateaus in these chondrite groups, as well as more complex, nonmonotonic small-scale variations. For all three chondritic meteorite groups, models favor earlier high-temperature fractionation under low-gravity conditions followed by a low-temperature fractionation event that took place on a protoplanet at least as large as Ceres. The second fractionation event may represent the fractionation of incoming materials to the planetesimal during protracted pebble accretion. Models with only thermally driven volatile loss, gravity, and mixing can explain more than 80% of the observed compositional variability in these meteorite groups. In our five-parameter model, using only five randomly selected elements yields uselessly large ranges of planet sizes and temperatures, ranges that converge with increasing numbers of elements. These results suggest that even simple models are prone to generating inaccurate conclusions when constrained by too few observations, a fault likely held by more complex models as well.

Enhancing nitrogen use efficiency and yield of maize (Zea mays L.) through Ammonia volatilization mitigation and nitrogen management approaches

Management of nitrogen (N) fertilizer is a critical factor that can improve maize (Zea mays L.) production. On the other hand, high volatilization losses of N also pollute the air. A field experiment was established using a silt clay soil to examine the effect of sulfur-coated urea and sulfur from gypsum on ammonia (NH3) emission, N use efficiency (NUE), and the productivity of maize crop under alkaline calcareous soil. The experimental design was a randomized complete block (RCBD) with seven treatments in three replicates: control with no N, urea150 alone (150 kg N ha−1), urea200 alone (200 kg N ha−1), urea150 + S (60 kg ha−1 S from gypsum), urea200 + S, SCU150 (sulfur-coated urea) and SCU200. The results showed that the urea150 + S and urea200 + S significantly reduced the total NH3 by (58 and 42%) as compared with the sole application urea200. The NH3 emission reduced further in the treatment with SCU150 and SCU200 by 74 and 65%, respectively, compared to the treatment with urea200. The maize plant biomass, grain yield, and total N uptake enhanced by 5–14%, 4–17%, and 7–13, respectively, in the treatments with urea150 + s and urea200 + S, relative to the treatment with urea200 alone. Biomass, grain yield, and total N uptake further increased significantly by 22–30%, 25–28%, and 26–31%, respectively, in the treatments with SCU150 and SCU200, relative to the treatment with urea200 alone. The applications of SCU150 enhanced the nitrogen use efficiency (NUE) by (72%) and SCU200 by (62%) respectively, compared with the sole application of urea200 alone. In conclusion, applying S-coated urea at a lower rate of 150 kg N ha−1 compared with a higher rate of 200 kg N ha−1 may be an effective way to reduce N fertilizer application rate and mitigate NH3 emission, improve NUE, and increase maize yield. More investigations are suggested under different soil textures and climatic conditions to declare S-coated urea at 150 kg N ha−1 as the best application rate for maize to enhance maize growth and yield.

Review of melt inclusions in lunar rocks: constraints on melt and mantle composition and magmatic processes

Abstract. Mineral-hosted melt inclusions provide a window into magmatic processes and pre-eruptive liquid compositions. Because melt inclusions are small (typically < 100 µm), the study of lunar melt inclusions is enabled by advancements of microbeam instrumental techniques. In the 1970s immediately following the Apollo and Luna missions, major and minor oxide concentrations of lunar melt inclusions were measured using electron microprobes. The data were used to understand magma evolution, and they revealed the immiscibility of two silicate liquids in the late stage of lunar magma evolution. More recently, the development of secondary ion mass spectrometry as well as laser ablation–inductively coupled plasma–mass spectrometry has enabled the measurement of key volatile elements and other trace elements in lunar melt inclusions, down to about the 0.1 ppm level. The applications of these instruments have ushered in a new wave of lunar melt inclusion studies. Recent advances have gone hand in hand with improved understanding of post-entrapment loss of volatiles. These studies have provided deep insights into pre-eruptive volatiles in lunar basalts, the abundance of volatiles in the lunar mantle, the isotopic ratios of some volatile elements, and the partition of trace elements between host olivine and melt inclusions. The recent studies of lunar melt inclusions have played a critical role in establishing a new paradigm of a fairly wet Moon with about 100 ppm H2O in the bulk silicate Moon (rather than a “bone-dry” Moon) and have been instrumental in developing an improved understanding of the origin and evolution of the Moon.

Sulfide compositions of young Chang’e-5 basalts and implications for sulfur isotopes in lunar basalt sources

Sulfides are accessory phases in lunar rocks butare important forunderstanding lunar interior processes as well as impacts on the lunar surface.Whether or not the lunar mantle had achieved sulfide saturation during magma ocean evolution and displays homogeneous sulfur isotopes remains under debate. TheChang’e-5 (CE-5) mission returned young (2.0 Ga) basalts from a mare terrain in thenorthern Oceanus Procellarum.Here we study chemical and sulfur isotopic compositions (δ34SV-CDT) of sulfides from CE-5 basaltic fragments and combine them with δ34S of other young (3.1–3.0 Ga) lunar low-Ti basalt (NWA 10597 and NWA 4734) and gabbro meteorites (NWA 6950) to compare them with Apollo low-Ti and high-Ti mare basalts. The sulfides in basaltic fragments of CE-5 are troilites (FeS) with lowabundances ofNi, Co, and Cu(e.g., Ni < 0.04 wt% and Ni/Co < 0.3). Textures and chemical compositions indicate that most troilites arelate-stage crystallization products fromthe highly evolvedCE-5 basalts. Several troilites occur in the matrices of impactite clasts and are intergrown with Fe–Ni metal(12–36 wt% Ni, Ni/Co of 12–39). These troilites are distinct from the major population of troilites withnoticeably higher Ni abundances (mostly > 0.2 wt% with Ni/Co of 1–3) andreconcile with the addition of meteoritic materials into the impact melts.The δ34SV-CDTof large troilite grains (>10 μm) from the CE-5 basaltic fragments and lunar meteorites were obtained by high-precision, high-spatial-resolution femtosecond laser ablation MC-ICP-MS which achieved external uncertainty (0.65 ‰, 2SD at 8-μm laser spots) like nano-SIMS. Sulfur degassing during surficial effusive lava flow likely led to a slightdecrease inδ34S (by ∼ 1 ‰) for some basaltic fragments; however, such effects were limited to the scale of bulk rock samples, consistent with previous results. The mean δ34Sof troilites in CE-5 basaltic fragments (0.35 ± 0.25 ‰, 2SE, n = 45) is similar to those of ancient (3.8–3.1 Ga old) Apollo low-Ti and high-Ti mare basalts and the young gabbro cumulate NWA 6950 (0.56 ± 0.21 ‰, 2SE, n = 10). The paired NWA 10597 and NWA 4734 show consistent δ34S, lower than most values by ∼ 0.5 ‰. Current data thus indicate that most mantle sources of lunar basalts would be homogeneous for δ34S(0.6 ± 0.3 ‰) and minor regions may be different. The overall homogenous δ34S from different mantle sources with variably low sulfur contents supports sulfide-undersaturated accumulation of the lunar magma ocean, which was inherited from strong volatile loss and evaporative fractionation during the formation of the Moon.

Determining buffering capacity of polydimethylsiloxane-based passive dosing for hydrophobic organic compounds in large-volume bioassays

Polydimethylsiloxane (PDMS) is the most widely used material for passive dosing. However, the ability of PDMS to maintain constant water concentrations of chemicals in large-volume bioassays was insufficiently investigated. In this study, we proposed a kinetic-based method to determine the buffering capacity of PDMS for maintaining constant water concentrations of hydrophobic organic contaminants (HOCs) in large-volume bioassays. A good correlation between log Kow and PDMS-water partitioning coefficients (log KPW) was observed for HOCs with log Kow values ranging from 3.30 to 7.42. For low-molecular-weight HOCs, volatile loss was identified as the primary cause of unstable water concentrations in passive dosing systems. Slow desorption from PDMS resulted in a reduction of water concentrations for high-molecular-weight HOCs. The volume ratio of PDMS to water (RV) was the key factor controlling buffering capacity. As such, buffering capacity was defined as the minimum RV required to maintain 90% of the initial water concentration and was determined to be 0.0076–0.032 for six representative HOCs. Finally, passive dosing with an RV of 0.014 was validated to effectively maintain water concentrations of phenanthrene in 2-L and 96-h toxicity tests with adult mosquitofish. By determining buffering capacity of PDMS, this study recommended specific RV values for cost-efficient implementation of passive dosing approaches in aquatic toxicology, particularly in large-volume bioassays.

Ascent of volatile-rich felsic magma in dykes: a numerical model applied to deep-sourced porphyry intrusions

SUMMARY Dyke propagation is a mechanism for more rapid ascent of felsic magmas through the crust than is possible via diapirs or percolative flow. As it ascends, the magma undergoes complex physical and chemical transformations induced by decompression and cooling. These processes dramatically change the magma density and viscosity, which in turn affect magma ascent rate and the depth at which the dyke arrests. We present a mathematical model of dyke propagation for silicic magmas taking into account the presence of multiple volatile species (H2O and CO2), bubble growth, heat advection and loss, crystallization and latent heat release. We consider conditions for dykes associated with porphyry ore deposits, which may represent an end-member in rapid ascent of felsic magmas from depth. In particular, we simulate the propagation of dykes launched from a deep (900 MPa), volatile-saturated magma source, testing the effects of the magma H2O/CO2 content, temperature and mass on its ascent rate and final emplacement depth. The model predicts short ascent times (hours to days), with a large increase in viscosity at shallow depth, leading to stagnation and solidification of the dyke. Higher initial water content, higher temperature and larger mass of the magma in the dyke promote faster propagation and shallower arrest. Volatile loss from ascending magma remains limited until the stagnation depth, providing a potential mechanism for transfer of deep volatiles to hypabyssal blind intrusions associated with porphyry ore deposits. Our findings are applicable to the problem of silicic magma ascent through the crust more generally.

Profile of red wine partially dealcoholized with a membrane-based technique and strategies to mitigate the loss of volatile compounds

In recent years, climate change has led to higher grape must sugar content and, consequently, increased alcohol by volume. Evaporative or pertraction is a common method for post-fermentation ethanol removal from wines, but it selectively removes some less polar volatile compounds along with ethanol.To mitigate volatile substance loss, this study investigates blending of the red wine (Marzemino-Cabernet blend) with obtained dealcoholized samples from it by industrial evaporative pertraction system, while maintaining the final product within a two-percentage-point reduction in ethanol. Thus MIX 1 and MIX 2 blends were prepared, reducing the ABV of the initial wine (12.5% alcohol by volume) to 10.5% and 9.5%.Chemical analyses highlighted that most alcohols, acetates, and ethyl esters of fatty acids decreased with alcohol by volume reduction. However, compounds with polar groups (acetoin and acetovanillone), C13-norisoprenoids, and certain lactones showed increasing trends. Sensory analysis indicated high scores for sweetness and smoothness in the blended wines, with a decrease in acidic taste. Floral scents notably increased, particularly in MIX 2, closely resembling the initial wine’s sensory profile.The blending of initial wine with appropriately dealcoholized wine samples has proven to be an effective strategy for preserving bouquet and color of dealcoholized wines. This approach broadens the consumer base by catering to people who prefer low-alcohol options, have dietary restrictions, or are health-conscious, but who still wish to savor wines with aromatic quality rather than a flat taste. This strategy is crucial in the wine industry as it successfully addresses technical challenges and ensures economic viability.

Optimizing Nitrogen Sources in Top Dressing for Wheat: Field Study on Growth, Yield, and Ammonia Volatilization.

In alkaline calcareous soils, ammonia volatilization is the primary nitrogen (N) loss process, resulting in the reduced N use efficiency of crops. This study aimed at assessing the impact of different N sources for top dressing on ammonia volatilization, as well as their effects on wheat growth and yield over two years. In each year, half of the recommended N was applied as a basal dose using diammonium phosphate (DAP) and urea. The remaining half was top-dressed 35 days after sowing with various sources: prilled urea (PU), granular urea (GU), ammonium sulfate (AS), and calcium ammonium nitrate (CAN) in the first year; PU, urea coated with a urease inhibitor from 20 g (VnU-20) and 40 g (VnU-40) leaves of Vachellia nilotica, biochar-coated urea (BU), and urease inhibitor paraphenylenediamine-coated urea (PPDU) in the second year. Ammonia volatilization losses were tracked for up to 12 weeks from sowing. Ammonia losses from basal-applied N remained consistent in both years, comprising around 4% of the applied N. In the first year, top-dressed AS resulted in the highest losses, followed by GU, while losses from urea and CAN were statistically similar. In the second year, coated fertilizers showed lower ammonia losses compared to PU, with VnU-40 displaying the least losses, 48% less than PU. Nitrogen concentration in wheat grain and straw exhibited a negative correlation with ammonia losses. The choice of top-dressed N source influenced tillering, biological, straw, and grain yields of wheat. In the first year, CAN provided maximum yield benefits, and in the second year, VnU-20 exhibited 27% more grain yield than PU. These findings suggest that top dressing with coated urea, especially VnU-20, has the potential to reduce ammonia losses, improve crop nitrogen status, and enhance economic yield compared to other nitrogen sources.

PFAS occurrence and distribution in yard waste compost indicate potential volatile loss, downward migration, and transformation.

We discovered high concentrations of PFAS (18.53 ± 1.5 μg kg-1) in yard waste compost, a compost type widely acceptable to the public. Seventeen out of forty targeted PFAS, belonging to six PFAS classes were detected in yard waste compost, with PFCAs (13.51 ± 0.99 μg kg-1) and PFSAs (4.13 ± 0.19 μg kg-1) being the dominant classes, comprising approximately 72.5% and 22.1% of the total measured PFAS. Both short-chain PFAS, such as PFBA, PFHxA, and PFBS, and long-chain PFAS, such as PFOA and PFOS, were prevalent in all the tested yard waste compost samples. We also discovered the co-occurrence of PFAS with low-density polyethylene (LDPE) and polyethylene terephthalate (PET) plastics. Total PFAS concentrations in LDPE and PET separated from incoming yard waste were 7.41 ± 0.41 μg kg-1 and 1.35 ± 0.1 μg kg-1, which increased to 8.66 ± 0.81 μg kg-1 in LDPE and 5.44 ± 0.56 μg kg-1 in PET separated from compost. An idle mature compost pile revealed a clear vertical distribution of PFAS, with the total PFAS concentrations at the surface level approximately 58.9-63.2% lower than the 2 ft level. This difference might be attributed to the volatile loss of short-chain PFCAs, PFAS's downward movement with moisture, and aerobic transformations of precursor PFAS at the surface.

Lunar Mare Lava Flow Dynamics and Emplacement: Predictions of Non-Newtonian Flow Dynamics, Syn- and Post-emplacement Cooling and Volatile Release Patterns, and Vertical and Lateral Flow Structure Development

We apply basic principles of magma ascent from deep source regions and its eruption into a low-gravity vacuum environment to develop a theoretical treatment of the fluid dynamics and thermodynamics of mare basalt lava flow emplacement and evolution on the Moon. The vacuum conditions influenced the release of volatiles in magma passing through lava fountains, thus controlling the syn- and post-emplacement vesicularity of the resulting deposits. To explain observed lengths and volumes of Mare Imbrium–type flows, high (106–105 m3 s−1) initial magma eruption rates were needed. Combined with low lunar magma viscosity, these caused flows to be initially turbulent. Resulting high radiative heat loss and consequent high crystallization rates caused rapid non-Newtonian rheological evolution and suppression of turbulence at tens of kilometers from vents. Slower cooling rates in the subsequent laminar parts of flows imply distinctive crystal growth rate histories. In a four-phase sequence, (i) initial transient dike-tip gas release followed by (ii) Hawaiian fire fountain activity with efficient volatile loss (iii) transitioned to (iv) Strombolian explosions in a lava lake. Late-stage lava now able to retain volatiles intruded and inflated existing flow deposits after flow front advance ceased. Volatiles forced out of solution by second boiling as lava cooled caused additional inflation. Low gravity and lack of atmospheric pressure commonly produced very vesicular lava. Escape of such lava through cracks in flow crusts is a possible source of ring-moat dome structures; collapse of such lava may explain irregular mare patches.

Nitrogen retention capacity of paddy soil improved under long-term garlic-rice rotation

ABSTRACT Although significant differences in soil nitrogen levels exist under different paddy-upland rotations, the main reason for this is unclear. The nitrogen retention capacity and loss of ammonia volatilisation, leaching, etc. of paddy soil with large differences in nitrogen levels from two long-term rotations, garlic-rice and wheat-rice, were measured using the soil column simulation method. The results showed that the loss rate of leaching was only 5.4%, whereas that of ammonia volatilisation was up to 22.8%, which was the main nitrogen loss way of paddy soil under the two rotations. The average ammonia volatilisation rates under wheat-rice rotation with high and low nitrogen application rates were 12.1% and 40.2% higher than that under garlic-rice rotation, leading to a decrease in the total nitrogen loss amount and rate through ammonia volatilisation by 29.8% and 8.8%, respectively. As a result, nitrogen retention in the soil under garlic-rice rotation increased by 12.7%. In conclusion, the long-term garlic-rice rotation could significantly inhibit ammonia volatilisation, thus improving the soil nitrogen retention capacity. The straw return may increase soil organic matter content, reduce ammonia volatilisation loss, and enhance soil nitrogen retention capacity and productivity.

Rubidium isotopic compositions of angrites controlled by extensive evaporation and partial recondensation.

The planetesimals in the solar system exhibit varying degrees of moderately volatile elements (MVEs) depletion compared to the protosolar composition. Revealing the relevant mechanisms is crucial for exploring early solar system evolution. Most volatile-depleted materials in the solar system exhibit enrichments in the heavier isotopes of MVEs, which have traditionally been attributed to the loss of volatiles through partial evaporation. Angrites are so far an exception as they are enriched in the lighter isotopes of K. This has been interpreted as reflecting condensation processes. Here, we present Rb isotopic data of angrites and find that they have lighter Rb isotopic compositions than Vesta, Mars, and the Moon. The δ87Rb value of the angrite parent body (APB) is estimated to range between -1.19‰ and -0.67‰. The extremely light Rb isotopic composition of the APB is likely a result of the kinetic recondensation of Rb after near-complete evaporation during the magma ocean stage. This finding provides further support for the partial recondensation model to explain the light Rb and K isotopic compositions of the APB. In addition, the APB, alongside other terrestrial planetary bodies (e.g., Earth, Mars, Moon, and Vesta), exhibit a strong correlation between their Rb and K isotopic compositions. This coupling of Rb and K isotopes is indicative of a volatility-driven isotopic fractionation rather than nucleosynthetic anomalies. The extremely light Rb-K isotopic signatures of the APB suggest that beyond evaporation, condensation plays an equally significant role in shaping the planetary-scale distributions of volatile elements.

Nitric oxide fumigation can affect the metabolism of volatile compounds derived from analyses of fatty acids and amino acids in post-harvest flat peach during cold storage

The loss of aroma volatiles can significantly reduce the economic value of postharvest flat peach during cold storage. In this study, the mechanism of NO fumigation regulating the aroma volatiles during cold storage at 1 ± 0.5 °C was investigated. The possible effects of NO on storage quality, VOCs, enzyme activity related to the fatty acid metabolism pathway, and the level of fatty acids and amino acids in fruit were analyzed. The results indicated that treatment with 10 μL L−1 NO maintained higher VC, firmness, SSC, TA, and restrained increase of MDA as well as the rotting rate. 10 μL L−1 NO treatment significantly supported a higher abundance of aldehydes before day 18 and encouraged the production of esters after day 18 of fruit under cold storage, which was associated with higher activity of ADH, AAT, HPL and LOX after day 18.10 μL L−1 NO treatment led to higher content of unsaturated acids, including OA, LA before day 18 and maintained higher content of LeA during the whole cold storage. According to these findings, 10 μL L−1 NO treatment may be a viable strategy to preserve the main aromatic volatiles and extend the shelf life of flat peaches.