Lithological Variations Research Articles

A new rock physics model for fractured oil shale reservoirs in Mahu oil field

The exploration of unconventional reservoirs such as oil shale has become a focus of research in the oil/gas industry, but due to the diversity of lithology and structural complexity of shale reservoirs, the study of their rock physics laws is a challenge. By analyzing the physical, lithologic, and fluid characteristics of oil shale reservoirs in the Mahu area of Xinjiang, China, we adopted a variety of effective-medium theories to carry out rock physics modeling. We analyzed the differences in the calculation results of various theoretical models, and finally constructed a set of rock physics modeling processes suitable for oil shale reservoirs. The analysis shows that the calculation results of Voigt-Reuss-Hill (VRH) and Hashin-Shtrikman (HS) average for mixed mineral matrix are very similar, but there are certain differences between the upper and lower bounds calculated by them. The upper and lower bounds of HS average are closer than VRH average. We used the Kuster-Toksoz effective-medium, differential effective-medium (DEM), and self-consistent approximation models to construct the rock skeleton and analyzed the differences of the models. The results of the three models are almost identical, but their assumptions and limitations differ. We used DEM in the final shale model, considering the large porosity and the order of inclusion filling. According to the fracture distribution characteristics of oil shale reservoirs, we used an inclined fracture model to describe the fractures with different structural characteristics. Finally, the established shale rock physics model was used to calculate the actual logging data, and the results of elastic parameters are consistent with the measured data. Through the inversion of the fracture parameters, the inversion results are consistent with the measured results as a whole, indicating that the model has certain applicability to the simulation of oil shale reservoirs.

Classification of geologic materials used in the Sukhothai Historical Park of Thailand using a portable X-ray fluorescence analyzer and petrographic analysis

The Sukhothai Historical Park, designated as a world heritage site in Thailand, encompasses the remnants of the Sukhothai Kingdom and serves as a valuable locus for geological and geoarchaeological investigations. Situated in the Sukhothai province, the region is characterized by diverse lithologies, including slate, phyllite, and laterite, as well as red bricks (synthetic materials), utilized in the construction of various ancient structures. Petrographic analysis using polarized light microscopy reveals the phyllites as the primary dimension stones, exhibiting foliated and mylonitic textures with small quartz augen. A portable X-ray fluorescence analyzer was employed for geochemical analysis and the analysis of major oxides and trace elements. The resulting data facilitated the classification of protoliths and comparison with rocks from an abandoned quarry near Saritphong Dam in the western part of the historical park. Notably, phyllites utilized in several prominent structures within the park; Wat Saphan Hin, Wat Pa Daeng 2, Wat Thap Sakae, Wat Chetuphon, Wat Sri Chum, and Wat Mangkorn Temples, exhibited similar characteristics to those in the Wat Khao Noi old quarry, as confirmed by Rubidium (Rb) and Strontium (Sr) values. The SiO2/Al2O3 and FeO/K2O ratios were pivotal in identifying the protoliths of the studied phyllites as shales. In summary, the primary dimension stones for Sukhothai Historical Park originated from the western mountain within the park, with laterites sourced from foothill areas. The presence of quartz pebbles in red bricks suggests local sediment utilization, and quartz additions were employed to enhance structural strength. This comprehensive geoarchaeological study sheds light on the geological composition of the Sukhothai Historical Park, providing valuable insights into the selection and utilization of construction materials in this historically significant site.

Geologic context of Chang'e-6 candidate landing regions and potential non-mare materials in the returned samples

Our understanding of the lunar farside from orbital remote sensing is limited by the lack of ground-truth constraints from returned samples. China's Chang'e-6 (CE-6) mission plans to land at the southern rim of the Apollo basin in the South Pole-Aitken basin on the lunar farside and return ∼2 kg samples. In this study, we conduct analyses on the local geological context of the CE-6 candidate landing regions, with a focus on the non-mare ejecta. The CE-6 candidate landing region has been divided into three subunits. According to our analyses, the northeastern subunit is adjacent to the lowest elevation (and one of the highest excavation depth) of this region where the materials from the deepest crust may exist. The northwestern subunit is affected by the magnesian ejecta from young crater. Returning these non-mare ejecta will provide key insights into the magnesian lithologies that occurred in the lunar farside, whose petrogenesis is long debated. As for the southern light plains unit, a topographic positive feature (unofficially termed as Mons White) located at the west of the light plains is identified in this work. Three scenarios were proposed for its origin: (1) A volcanic complex built on special magmatism in the SPA basin; (2) Remnants of the central uplift of an ancient impact basin; (3) Target surface folded and uplifted by the Apollo basin impact event. Gradual lithological variations in the Mons White are discovered. The White crater has likely ejected materials with these gradual lithologies into the CE-6 candidate landing regions. The Orientale basin ejecta also exists on the light plains. These non-mare materials, if could be sampled by the CE-6 mission, will significantly help refine the lunar chronostratigraphic system from the pre-Nectarian/Aitkenian to the late Imbrian. Thus, we suggest that landing on the southern light plains will achieve the maximum scientific outcomes for the CE-6 mission, from a perspective of sample diversity.

Downslope variability in deep-water slope channel fill facies and stacking patterns

Lithologic variations in deep-water slope channel systems provide critical insight into sedimentary processes on deep-water slopes, and are a key control on natural resource distribution and connectivity in subsurface reservoirs associated with ancient deep-water systems. While many studies have described these variations at outcrop-scale along depositional strike (across-channel), few have focused on documenting along-depositional-dip changes due to: (1) the dearth of along-slope perspectives afforded by outcrops; or (2) limited resolution and coverage of subsurface data sets. In this study, slope channel elements (≤30 m thick; ≤400 m wide) and composite channelform bodies composed of ≥2 stacked channel elements (channel complexes and channel systems; >30 m thick; >400 m wide) were characterized along a 50-km-long depositional-dip-oriented outcrop belt of the Campanian-Maastrichtian Tres Pasos Formation (Chile) to constrain longitudinal changes in channel fill character and stacking patterns. Results show that channel elements become more sandstone-rich downdip. Outcrop observations are supported by channel element net-to-gross ratios (measures of sandstone proportion), which increase downdip. Sandstone-prone channel elements within channel complexes and channel systems are more prevalent downdip; however, variability in lateral and vertical offset between successive channel elements downdip results in a poor correlation between net-to-gross values and paleoslope position when composite channelform bodies are considered. These findings suggest that the along-slope distribution of coarse-grained sediment in channel systems is tied to the degree of coarse-grained sediment bypass and erosion that occurs along a slope. The results of this study provide a detailed perspective into downdip changes in slope channel fill and stacking patterns, and help clarify aspects of analogous subsurface reservoirs, including sandstone proportion trends for several scales of deep-water slope channel architecture.

Lawsonite and Garnet Oxygen Isotope Record of Fluid‐Rock Interaction During Subduction

AbstractDuring the subduction of an oceanic plate, fluids are released from metabasaltic crust, metasediment, and serpentinite under high‐pressure/low‐temperature conditions. Although some fluids may eventually leave the slab, some participate in metamorphic reactions within the slab during subduction and exhumation. To identify fluid sources and other controls influencing mineral composition, we report the in situ‐measured δ18O of lawsonite and garnet in blueschist‐ to eclogite‐facies rocks from 10 subduction zones that represent various field settings, including mélanges, structurally coherent terranes, and an eclogite xenolith derived from a subducted plate. Lawsonite records distinct δ18O depending on the host rock type and other rock types that were fluid sources during lawsonite growth. In general, lawsonite in metabasalt (7.6 ± 0.2–14.8 ± 1.1‰) is isotopically lighter than in metasediment (20.6 ± 1.4–24.1 ± 1.3‰) but heavier than in metagabbro (4.0 ± 0.4–7.9 ± 0.3‰). The extent of δ18O fractionation was evaluated for lawsonite–fluid and lawsonite–garnet pairs as a function of temperature (T). Results demonstrate that variations of >1.7‰ in lawsonite and >0.9‰ in garnet are not related to changing T. More likely, the relative contributions of fluids derived from isotopically heavier lithologies (e.g., sediments) versus lighter lithologies (e.g., ultramafic rocks) are the major control. Monte Carlo simulations were performed to investigate the sources of metasomatic fluids and the water/rock ratio that formed lawsonite‐bearing metasomatite. Results indicate that δ18OLws and δ18OGrt record interactions with fluids sourced from diverse lithologies (sediment, serpentinite), further supporting that δ18OLws is a useful indicator of subduction fluid‐rock interactions.

Evaluating ASTER data and field spectrometry for lithological discrimination in semi-arid region, Northeast Kohat Plateau, Pakistan

This study employs data of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor to delineate and map the distribution of sedimentary lithologies in the semi-arid region of Kohat Plateau, Pakistan. False color composites (FCC) and various image transformation and enhancement techniques including the principal component analysis (PCA), minimum noise fraction (MNF), and band rationing (BR) were used successfully to differentiate four lithological classes. These lithologies include chemically/biochemically formed beds of the marine environment and detrital sequences of marginal marine to the riverine environment. FCC from original reflectance data, PCA, and BR techniques displayed more prominent lithological variation. To map the lithology and show the potential of ASTER data, field spectrometry over the barren lithologies was carried out. The end-member spectra from field spectrometry shows strong agreement with the pixels spectra from ASTER scene. The Spectral Angle Mapper (SAM) mapping method was then used to produce a classified lithological map, where the image pixels spectra proved more suitable reference, in comparison to the end-member spectra. The accuracy of the classified lithological map was evaluated based on field-based point data, which resulted an overall accuracy of 70% and a Kappa coefficient value of 0.679. Carbonates and evaporites showed relatively higher user and producer accuracies which are attributed to their topographic behavior and weathered scree over the adjacent rock unit. The final lithological map provided a clearer picture of surface geology where the existing geological maps lacked lithological continuity.

Comprehensive Facies Analysis and Depositional Environments of the Kikim Formation, Garba Mountain, South Palembang Subbasin, Indonesia

This study provides an exhaustive facies analysis of the Kikim Formation within the Garba Mountain area of the South Palembang Subbasin, emphasizing the stratigraphic significance and depositional environments during the Paleogene period. Utilizing field data collected from the Bumi Agung and Batu Belang measurement lines, this research categorizes various lithofacies using Miall’s (1978) classification scheme, identifying eight distinct lithofacies and four facies associations indicative of a predominantly fluvial depositional setting. The results depict a detailed sedimentological framework, showing that the Kikim Formation was characterized by a braided river system with significant gravel and sandstone deposits. This analysis not only sheds light on the geological history and processes shaping the South Sumatra Basin but also enhances the understanding of its potential hydrocarbon reservoirs. By detailing the lithological diversity and facies distribution, this paper contributes to the broader geological knowledge required for effective exploration and management of the region's natural resources.

Substantial composition and technological treatment of potassium rocks of the Upper Pechora salt basin

The material composition of potassium and potassium-magnesium salts of the Upper Pechora salt-bearing basin was studied, their lithological variability was established over the area of productive strata, depending on the tectonic features of the foundation. The main mining and geological conditions that complicate the possibility of their extraction and the environmental conditions for organizing mining and processing production of mineral salts were established. The basic physical and technological properties of sylvinite and carnallite rocks mined by the mine method were studied for their enrichment by halurgical and flotation methods. The objectives of the work were: determining the material composition, studying textural and structural features and assessing the technological processing of potassium rocks in the Upper Pechora salt-bearing basin. When solving the problems, the following methods were used: a study of the textural and structural features of sylvinites using the petrographic method; the chemical composition of samples and solutions was analyzed by AES spectrometry; the mineral composition of the water-insoluble residue is determined by X-ray quantitative phase analysis.

Multi-step modeling of well logging data combining unsupervised and deep learning algorithms for enhanced characterization of the Quaternary aquifer system in Debrecen area, Hungary

In this research, a multi-step modeling approach is followed using unsupervised and deep learning algorithms to interpret the geophysical well-logging data for improved characterization of the Quaternary aquifer system in the Debrecen area, Hungary. The Most Frequent Value-Assisted Cluster Analysis (MFV-CA) is used to map lithological variations within the aquifer system. Additionally, the Csókás method is used to discern both vertical and horizontal fluctuations in hydraulic conductivity. MFV-CA is introduced to cope with the limitation of the conventional Euclidean distance-based k-means clustering known for its low resistance to outlying values, resulting in deformed cluster formation. However, the computational time and demands of MFV-CA are evident, making them costly and time-consuming. As a result, Deep Learning (DL) methods are suggested to provide fast characterization of the groundwater aquifers. These methods include Multi-Layer Perceptron Neural Networks (MLPNN), Convolutional Neural Networks (CNN), Recurrent Neural Networks (RNN), and Long Short-Term Memory (LSTM), which are implemented for classification and regression. The classification categorized the inputs into three distinct lithologies trained initially by the results of MFV-CA. At the same time, the regression model offered a continuous estimations of hydraulic conductivity trained by the results of the Csókás model. The results demonstrated significant compatibility between the outcomes derived from the clustering and Csókás approaches and DL algorithms. Accordingly, the lithofacies and hydraulic conductivity variations across the main hydrostratigraphical units are mapped. This integration enhanced the understanding of the groundwater system, offering promising inputs for groundwater and development and management.

3D geological and petrophysical modeling of Alam El-Bueib Formation using well logs and seismic data in Matruh Field, northwestern Egypt

There are several productive petroleum fields in the North Western Desert (WD) of Egypt, which received extensive investigations regarding their petroleum potential. However, a few studies tackled the Matruh Oil Field, which contains the oil prolific Early Cretaceous Alam El-Bueib Formation (AEB Fm) reservoir. The reservoir intervals of the AEB Fm show substantial lithological variations across the basin. Therefore, it is necessary to analyze the vertical and lateral distributions in terms of their lithological and petrophysical properties. To achieve this objective, wireline logs of four wells and 20-2D seismic lines were used to construct a depth-structure contour map for the studied part of the field. This map was used to build the field’s structure model and to identify the fault patterns in the basin through several seismic lines. Analyses of well logs data and lithology were used to estimate the petrophysical properties of AEB sandstone units AEB-1, AEB-3A, AEB-3C, and AEB-6. Results show that the AEB-6 Unit is the most promising hydrocarbon-bearing unit. It has a net pay of 20–160 feet, a shale volume of 5–20%, an effective porosity of 14–20%, and a hydrocarbon saturation of 70–88%. The structure-depth maps indicate a number of normal faults with two principal NE-SW and NW–SE trends, which probably act as structural traps in the Matruh Oil Field. The constructed structure-depth maps and calculated petrophysical parameters were used to build a three-dimensional reservoir model. A blind well was used to validate the accuracy and reliability of the facies, porosity, and saturation models for the AEB Fm units, ensuring a good match between log-derived data and built models. The AEB Fm shows regional heterogeneous variations in its petrophysical characteristics. It exhibits unconventional reservoir characteristics in a N–S direction and conventional reservoir characteristics in an E–W direction. This observed heterogeneity shows the need to carry out further investigations to comprehensively assess the hydrocarbon potential of AEB Fm in different areas of the Matruh Basin.

The northern wheatear is reducing its distribution in its southernmost European range and moving to higher altitudes

Under the current pattern of climate change, mountain bird populations are generally shifting their ranges to higher elevations, tracking their climatic optima. Nevertheless, space limitations at high altitudes constrain mountain species' resilience to climatic change, making them particularly vulnerable. In extreme cases, the climatic niche of some species can move beyond mountaintops, ultimately driving such species to extinction. This study presents the case of the northern wheatear Oenanthe oenanthe in mainland Spain and compares its breeding distribution from 2003 to 2022. Spain, where the species mostly occupies mountain areas, represents its southernmost distribution limit in Europe. We built environmental favourability models using information from the two most recent Spanish bird atlases and a set of climatic, topographic, human activity and lithological variables to determine the factors affecting the occurrence of the species. The influence of climate compared to all other factors was obtained using variation partitioning analysis. The northern wheatear has suffered a strong reduction (67%) in occupied areas and also in favourability throughout mainland Spain (especially in the south) where climate change may have far‐reaching consequences, including local extinctions. Climate explained more than 90% of the variation in the model obtained for 2022. Interestingly, the occupied areas were, on average, 100 m higher in 2022 than in 2003. If the effects of climate warming persist, the northern wheatear will likely disappear in its southernmost distribution limit, being the Sierra de las Nieves National Park population the most vulnerable in mainland Spain. For this reason, it is necessary to implement monitoring programmes for northern wheatear populations, with priority for mountain systems wherein they already occupy higher elevations, as well as further studies on other mountain species.

Solid bitumen as an indicator of petroleum migration, thermal maturity, and contact metamorphism: A case study in the Barrandian Basin (Silurian - Devonian), Czech Republic

Silurian and Devonian marine shales and limestones of the Barrandian Basin host abundant black solid, non-fluorescing bitumens that fill tectonic fractures and veins, and occlude fossil moulds and diagenetic concretions. Solid bitumen, interpreted as thermally degraded petroleum, entered the rocks during several successive episodes of fracture-bound petroleum migration that occurred during deeper burial of the strata. Regional distribution of bitumen reflectance values that range between ∼0.9–2.3% Rr, correlate with variations of its FT-IR and Raman spectroscopic characteristics and aromatic hydrocarbon composition, and collectively evidence the maturity trend increasing across the basin from the southwest to the northeast. The reflectance of chitinozoans and graptolites (∼0.8–1.9% Rr) in the country rocks and homogenization temperatures of hydrocarbon fluid inclusions document palaeotemperatures ranging between ∼90–150 °C, characteristic of the oil window zone grading into the gas/condensate zone. Although in a basin-wide perspective the averaged values of solid bitumen and zooclast optical reflectance converge and indicate the same northeastern-increasing regional diagenetic trend, solid bitumen reflectance values vary considerably at individual localities and even within some bitumen samples. The wide scatter of optical reflectance values and the heterogeneity of optical properties, which were attributed to the presence of multiple source rocks in the basin, the variable lithology of bitumen host rocks, or other variables, hamper the use of solid bitumen as a simple alternative to zooclast/vitrinite reflectance palaeothermometers in a given basin. On the other hand, the highly anisotropic domain and the mesophase “coking” textures of the solid bitumen that were recognized in the NE part of the basin provide unique evidence on an anomalous, hitherto unrecognized, geologically short-lasting thermal event that affected the Palaeozoic rocks. A line of indirect evidence suggests that the coking of the bitumen was caused by a cryptic intrusion, possibly a concealed branch of the Central Bohemian Pluton, which intruded into the strata during the Variscan orogeny. More rarely occurring semi-solid, vividly yellow fluorescing waxy bitumen, that postdates solid bitumen in some fractures and voids, does not reveal a regional thermal maturation trend. It precipitated from relict waxy oils that migrated through the strata during a post-Neogene uplift of the Barrandian region.

System-scale dynamics of long-term sediment and phosphorus accumulation in contrasting valley-bottom wetlands in dryland landscapes of South Africa

Anthropogenic-induced acceleration of sediment and associated nutrients presents a serious challenge to water resource management across the globe. While wetlands are potential natural solutions, little is known of how well key wetland types attenuate downstream sediment fluxes and how these relate to local- and catchment-scale factors. This research aimed to develop an understanding of patterns and rates of sediment and phosphorus retention in valley-bottom wetlands in South Africa. The geomorphology, sedimentology and historical accretion rates of three wetlands which offered diversity in size, catchment position and degree of organic accumulation were compared to ascertain the impact of local- and catchment-scale factors. Estimates of sediment and associated phosphorus accumulation suggest higher rates in clastic sediment-dominated wetlands (1089–7655 g sediment m−2 yr−1, 0.4–1.6 g-P m−2 yr−1) compared to an organic sediment-dominated system (601–1308 g-sediment m−2 yr−1, 0.2–0.3 g-P m−2 yr−1). Sediment accretion rates generally increased longitudinally, indicating that distal wetland reaches act as sediment and phosphorus retention hotspots. Phosphorus distribution patterns were primarily attributed to variations in organic matter content and associated aluminium and iron complexing agents in fine-grained sediment deposits, while particle size distributions were less important. However, the relevance of individual complexing agents in phosphorus dynamics varied among wetlands with differing landscape conditions. Contrasts between these systems reflect variations in catchment lithology and hydroclimatic regime, which influence the relative magnitude of sediment supply and vegetation productivity. We postulate that intermediate-sized wetlands characterised by catchments around 900 ha in size, gentle longitudinal slopes (∼2 %), a high proportion of fine sediment deposition, limited organic matter breakdown, and a long vegetation growing season provide optimal conditions for sediment and phosphorus accumulation. This system-scale information is essential to guide management decisions to identify and prioritize within-catchment ‘hotspots’ of sediment and phosphorus retention.

Fluid-metasomatized rocks with extremely low δ26Mg values in subducted oceanic lithosphere: Implications for mantle Mg isotope heterogeneity and the origin of low-δ26Mg magmas

The subduction of oceanic slabs with diverse lithologies greatly contributes to the geochemical heterogeneity of the mantle. Oceanic metasomatism leads to the formation of rocks with heterogeneous geochemical characteristics, which can be further modified by fluid–rock interactions during subduction zone processing. Investigations of exhumed high-pressure oceanic rocks not only shed light on the compositional variations that occur during oceanic metasomatism and subduction processes but also help in understanding mantle heterogeneity and magma genesis. Here, we present a comprehensive Mg–O–Sr–Nd isotope study on eclogite-facies Mg- and Ca-metasomatized rocks (Ti-clinohumite dikelets and metarodingites, respectively) and their host meta-serpentinites from the Voltri Massif (Ligurian Western Alps). Compared to their Fe–Ti gabbroic protoliths, the Ti-clinohumite (Ticl) dikelet and metarodingite are characterized by high MgO contents (∼32–38 wt%) and CaO contents (∼17–25 wt%), respectively. These Mg- and Ca-enriched rocks both display low δ26Mg values of −0.54 ‰ to −0.43 ‰ and −1.49 ‰ to −0.82 ‰, respectively, while the serpentinite hosts have mantle-like δ26Mg values of −0.26 ‰ to −0.20 ‰. The Ticl-chlorite rind rimming the metarodingite has a low δ26Mg value of −1.00 ‰. No carbonate minerals were found for metasomatized rocks that have low δ18O values ranging from +2.0 ‰ to +3.4 ‰, demonstrating that their low δ26Mg signature cannot be attributed to metasomatism by fluids involved with carbonate components. The increase in MgO content and decrease in δ26Mg in the Ticl dikelets are ascribed to fluid-induced mass transfer through low-δ26Mg fluids buffered by serpentinization of the host ultramafic rocks. The metarodingite has comparable MgO but extremely low δ26Mg values compared to those of the gabbroic protolith. By integrating reported Mg isotope data for low-grade rodingites, we propose that the low δ26Mg values of metarodingites are ascribed to isotopic exchange with serpentinizing fluids during progressive rodingitization reactions at the seafloor. However, the extremely low δ26Mg value of the Voltri metarodingite (as low as −1.49 ‰) may be attributed to further metasomatic modification in the subduction zone. High pressure metamorphic recrystallization of these metasomatized rocks play a limited role in their Mg isotope compositions. Therefore, our results show that the oceanic metasomatized metarodingite and Ticl-bearing dikes hosted in serpentinite display systematically low-δ26Mg features. Such isotopically light Mg compositions can be preserved during subduction to eclogite-facies conditions. Hence, subduction of these metasomatized rocks may lead to the transfer of a low-δ26Mg component into the deep mantle, which was overlooked thus far and may further contribute to the origin of low-δ26Mg magmas.

Schmidt-hammer R-values from glacially-scoured bedrock surfaces across glacier-foreland boundaries: Insights into Holocene weathering rates with implications for exposure-age dating

Schmidt-hammer R-values were measured on glacially-scoured bedrock outcrops located inside and outside of 11 ‘Little Ice Age’ glacier-foreland boundaries in the Jotunheimen and Jostedalsbreen regions of southern Norway. Analysing paired samples differing in exposure age by ~10,000 years constitutes a field experiment on chemical weathering rates within and between regions. Mean R-values (± 95 % confidence intervals) from inside sites were 65.9 ± 0.6 and 66.9 ± 0.6 for rock surfaces composed of pyroxene-granulite gneiss in Jotunheimen at altitudes of 990–1360 m above sea level and granite and granitic gneiss in the Jostedalsbreen region at 270–620 m a.s.l. The corresponding values from outside sites of 39.9 ± 0.9 and 39.0 ± 0.9 were significantly lower, indicating a higher degree of chemical weathering. In contrast, regional differences in mean R-values were insignificant. A similar pattern is reflected in indices of rock weathering (39.0 % for Jotunheimen and 41.6 % for Jostedalsbreen), and weathering rate (2.8 R-value units and 3.0 units per 1000 years, respectively). These results imply an estimated minimum age resolution of Schmidt-hammer exposure-age dating of ~265–315 years and a maximum age range of ~20,000 years. They suggest potential application of the Schmidt hammer to both studies of weathering rates and exposure-age dating at the regional scale, despite lithological variation associated with different rock types and climatic variation associated with altitudinal differences of up to 1000 m between the sites.

Geochemical Characteristics of Trace Elements of Hot Springs in the Xianshuihe–Xiaojiang Fault Zone

Trace elements in hot-spring waters are indicators for tracing hydrochemical processes, such as the deep circulation of geothermal water, the degree of water–rock interaction, redox reactions, the contamination of shallow water by thermal water, etc. In this study, 74 hot springs in the Xianshuihe–Xiaojiang Fault Zone (XSHF-XJF) were chosen for an investigation of the geochemical characteristics of trace elements using classic geochemical tools and multivariate statistical analysis. The results indicated (1) the hot-spring waters were mainly derived from atmospheric precipitation as indicated by δD and δ18O values that generally increased with decreasing elevations; (2) the high concentrations of B, As, Fe, and Mn in the waters, as well as the values of the Water Quality Index (WQI), indicated that the water quality was spatially heterogeneous and the hot-spring waters are not entirely suitable for drinking; and (3) B/Cl ratios showed that hot springs have different reservoir sources in the XSHF and XJF, respectively. The leaching of surrounding rock during water circulation contributed predominantly to the trace elements of the study’s waters. Diversity of lithology was the main factor affecting their concentrations. In addition, deep circulation controlled by the fault could influence trace-element enrichment. Our results offer a guide for the exploration and use of geothermal resources.

Integrated Geotechnical and Electrical Resistivity Tomography to Map the Lithological Variability Involved and Breaking Surface Evolution in Landslide Context: A Case Study of the Targa Ouzemour (Béjaia)

The specific lithology of the southern part of Bejaia city represents a major limitation to urban settlement and expansion. This is partly due to landslides that tend to affect this region. To date, one of these landslides in this region has occurred in the Targa Ouzemour area, where the damage extended approximately six hectares. The main purpose of this study is to identify the failure surfaces characterizing the internal structure of this landslide as well as the significant influence of groundwater on slope instability, which manifests as surface cracking and subsidence. We have combined several geotechnical and geophysical methods, including field observations. The exploitation of the collected geotechnical data from the six (06) boreholes drilled in the landslide zone has allowed for knowledge to be gained on the lithological components, as well as the characterizations of physical and mechanical properties on a range of different types of affected rocks, whereas electrical resistivity tomography (ERT) data allowed an in-depth examination, leading us to reconstruct the landslide geometry and particularly to evaluate the hydrological characteristics of the studied site. Moreover, the resistivity contrast patterns provided more clarity to discern between the various lithological formations that are still stable or actively moving within this landslide. All these findings have contributed to the construction of a characteristic geomodel that highlights the failure surfaces over which displacement is still experienced. Finally, with the evidence of rainfall effects on the deformation and stability of the slope, specific landslide remedial measures were accordingly suggested.

Geodiversity in the Amazon drainage basin.

The Amazon is the largest drainage basin on Earth and contains a wide variety of abiotic landscape features. In spite of this, the geodiversity in this basin has not yet been objectively evaluated. We address this knowledge gap by combining a meta-analysis of an existing global geodiversity map and its components with a systematic literature review, to identify the key characteristics of geodiversity in the Amazon drainage basin (ADB). We also evaluate how these global geodiversity component maps, that are based on the geology, geomorphology, soils and hydrology, could be refined to better reflect geodiversity in the basin. Our review shows that geology-through lithological diversity and geological structures-and hydrology-through hydrological processes that influence geomorphology and soil diversity-are the main determinants of geodiversity. Based on these features, the ADB can be subdivided into three principal regions: (i) the Andean orogenic belt and western Amazon, (ii) the cratons and eastern Amazon, and (iii) the Solimões-Amazon river system. Additional methods to map geomorphological and hydrological diversity have been identified. Future research should focus on investigating the relationship between the geodiversity components and assess their relationship with biodiversity. Such knowledge can enhance conservation plans for the ADB. This article is part of the Theo Murphy meeting issue 'Geodiversity for science and society'.

Lithofacies Characteristics of Gulong Shale and Its Influence on Reservoir Physical Properties

The lithofacies characteristics of the Qingshankou Formation (K2qn) shale in the Gulong Depression are crucial for oil exploration and development. This study investigates the K2qn shale lithofacies characteristics and their impact on reservoir physical properties using scanning electron microscopy (SEM), high-pressure mercury injection (HPMI), and logging quantification. The results indicate that the main minerals in K2qn shale are quartz, plagioclase, and clay. The sedimentary structures are classified into three types: laminated, layered, and massive. The K2qn shale lithofacies can be categorized into 12 types based on a combination of lithology and sedimentary structure. The main types are laminated clayey shale, layered clayey shale, and layered felsic shale. The larger the average pore size of the K2qn lithofacies, the stronger the heterogeneity of pore size distribution in space and the better the pore-to-throat connectivity. The impact of K2qn shale lithofacies on reservoir physical properties is mainly due to differences in lithology, complemented by variations in the sedimentary structural model. Under certain diagenetic or tectonic conditions, a layered sedimentary structural model of lithofacies may not increase reservoir permeability. Generally, felsic and carbonate rocks in tidal flat environments promote the development of shale with high permeability and porosity, while lithofacies deposited in static water environments below the wave base in lake basins typically exhibit low permeability and porosity. The physical properties of a reservoir are primarily influenced by the differences in pore throat characteristics resulting from variations in lithology.

Precambrian to Pleistocene 40Ar/39Ar dating of clinopyroxene-hosted melt inclusions

Abstract Clinopyroxene is a rock-forming mineral that commonly hosts melt inclusions in mafic to intermediate composition volcanic and plutonic rocks. It is highly resistant to alteration compared to other co-existing phenocrysts such as plagioclase. Several recent studies have 40Ar/39Ar dated clinopyroxene in Neoproterozoic to Miocene basalts and dolerites. To assess the viability of the technique at the youngest end of the geologic time scale, we performed 40Ar/39Ar incremental heating experiments on clinopyroxene-hosted melt inclusions from a variety of mafic lithologies and tectonic settings. Most samples produced precise plateau ages including several Quaternary basalts to andesites as young as 0.6 Ma. All data are indistinguishable from new and/or published 40Ar/39Ar ages on groundmass or plagioclase from the same samples. The source of potassium (K) and resulting 40Ar* within clinopyroxene has been debated, but thus far has only been inferred based on 40Ar/39Ar data. Using electron probe microanalysis (EPMA) we show that there is negligible K in the clinopyroxene host, but substantial K (e.g., 1–4 wt%) in trapped melt inclusions and minor amounts in plagioclase inclusions. Thus, melt inclusions, which are common in phenocrysts in basaltic magmas, can be used to obtain accurate and precise 40Ar/39Ar ages for difficult-to-date volcanic and plutonic rocks from the Precambrian to the Pleistocene.